H-1,2,3-Diazaphospholes 3a3h were prepared from various ketone acylhydrazones and phosphorus trichlo-ride in the presence of triethylamine. Compounds 3 underwent feasible hetero-Diels-Alder reactions with cyclopen-tad...H-1,2,3-Diazaphospholes 3a3h were prepared from various ketone acylhydrazones and phosphorus trichlo-ride in the presence of triethylamine. Compounds 3 underwent feasible hetero-Diels-Alder reactions with cyclopen-tadiene to afford the respective anellated [1,2,3]diazaphospholes 4a4d as well as 4a'4d' in moderate yields. The endo rule in the reaction was observed under kinetic control conditions.展开更多
基金the National Natural Science Foundation of China (No. 20372015).
文摘H-1,2,3-Diazaphospholes 3a3h were prepared from various ketone acylhydrazones and phosphorus trichlo-ride in the presence of triethylamine. Compounds 3 underwent feasible hetero-Diels-Alder reactions with cyclopen-tadiene to afford the respective anellated [1,2,3]diazaphospholes 4a4d as well as 4a'4d' in moderate yields. The endo rule in the reaction was observed under kinetic control conditions.
