A differential pulse voltammetric method was developed for the sensitive andselective determination of Cu(II) at 4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-l,3,5-triazine modifiedcarbon paste electrode in 0.05 mol/L KHC_...A differential pulse voltammetric method was developed for the sensitive andselective determination of Cu(II) at 4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-l,3,5-triazine modifiedcarbon paste electrode in 0.05 mol/L KHC_8H_4O_4 solution (pH = 4.02). The oxidation peak of Cu(II)was observed at 0.065 V(vs Ag/AgCl) by scanning the potential in positive direction. The analysisprocedure consisted of an open circuit accumulation step in stirred sample solution. It was followedby medium exchange to a clean solution and subsequently an anodic potential scan was affected toobtain the voltammetric peak. The current was proportional to the concentration of the Cu(II) ion ina range of 1 X 10^(-7) -1 X 10^(-4) mol/L for 6 min accumulation; the most of metal ions did notinterfere with the determination. The developed method was applied to Cu (II) determination incoal-ash sample, the results agreed with that of atomic adsorption spectroscopy (AAS).展开更多
The reaction of 4-amino-3,5-bis(imidazol-l-ylmethyl)-1,2,4-triazole (abit) and manganese(Ⅱ) salts yields four coordination polymers {[Mn(abit)3](C104)z}n (1), {[Mn(abit)3](PF6)2},, (2), [Mn(abit)...The reaction of 4-amino-3,5-bis(imidazol-l-ylmethyl)-1,2,4-triazole (abit) and manganese(Ⅱ) salts yields four coordination polymers {[Mn(abit)3](C104)z}n (1), {[Mn(abit)3](PF6)2},, (2), [Mn(abit)(dca)2(H2O)2],, (3a) and [Mn(abit)(dca)2(H2O)2]n (3b). Compounds 1 and 2 are one-dimensional triple-stranded chain. Compounds 3a and 3b are polymorphous and construct one-dimensional single chain. The conformational analysis is performed. The thermal properties have been investigated.展开更多
Reaction of FeCIz'6H20, pyridine-2,4,6-tricarboxylic acid(H3pyta) and NaOH in the hydrothermal system at 185 ℃ resulted in the formation of 1D coordination polymer[Fe(Hpyta)(H2O)2](1) based on Fe-Hpyta chain...Reaction of FeCIz'6H20, pyridine-2,4,6-tricarboxylic acid(H3pyta) and NaOH in the hydrothermal system at 185 ℃ resulted in the formation of 1D coordination polymer[Fe(Hpyta)(H2O)2](1) based on Fe-Hpyta chains. When the abpt[abpt=-4-amino-3,5-bis(4-pyridyl)-l,2,4-triazole] ligand was employed in the reaction system, a 3D supramolecular porous network (H2bpt)[Fe(pyta)(H2O)2]·4H2O(2) was obtained. The framework was constructed with negative (Fe-pyta) chains and the positive H3bpt^+ in situ, formed from the abpt reagent, to form 1D channels filled with guest water molecules via hydrogen-bonds. X-Ray diffraction crystal structure analysis shows that complex 1 crystallized in the monoclinic system, space group C2/c, a=1.1490(5) nm, b=0.9008(4) nm, c=1.0058(5) nm, B=107.254(9)°, V=0.9942(8) nm3, Z=4; and complex 2 crystallizes in the triclinic system, space group P1 with a=0.90392(11) nm, b=0.96027(11 ) nm, c=1.55540(18) nm, a=73.558(2)°,B= 86.126(2)°,r= 68.745(2)°, V=1.2059(2) nm^3 and Z=2.展开更多
Two new diaryheptanoids, (5S)-5-acetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)-3- heptanone (1) and (3S,5S)-3,5-diacetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)heptane (2) were isolated from the rhizomes of Zingiber officina...Two new diaryheptanoids, (5S)-5-acetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)-3- heptanone (1) and (3S,5S)-3,5-diacetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)heptane (2) were isolated from the rhizomes of Zingiber officinale. Their structures were elucidated by spectral methods.展开更多
文摘A differential pulse voltammetric method was developed for the sensitive andselective determination of Cu(II) at 4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-l,3,5-triazine modifiedcarbon paste electrode in 0.05 mol/L KHC_8H_4O_4 solution (pH = 4.02). The oxidation peak of Cu(II)was observed at 0.065 V(vs Ag/AgCl) by scanning the potential in positive direction. The analysisprocedure consisted of an open circuit accumulation step in stirred sample solution. It was followedby medium exchange to a clean solution and subsequently an anodic potential scan was affected toobtain the voltammetric peak. The current was proportional to the concentration of the Cu(II) ion ina range of 1 X 10^(-7) -1 X 10^(-4) mol/L for 6 min accumulation; the most of metal ions did notinterfere with the determination. The developed method was applied to Cu (II) determination incoal-ash sample, the results agreed with that of atomic adsorption spectroscopy (AAS).
基金Project supported by the National Natural Science Foundation of China (No. 20671066), the Jiangsu Province (No. BK2006049), and the Funds of Key Laboratory of Organic Synthesis of Jiangsu Province.
文摘The reaction of 4-amino-3,5-bis(imidazol-l-ylmethyl)-1,2,4-triazole (abit) and manganese(Ⅱ) salts yields four coordination polymers {[Mn(abit)3](C104)z}n (1), {[Mn(abit)3](PF6)2},, (2), [Mn(abit)(dca)2(H2O)2],, (3a) and [Mn(abit)(dca)2(H2O)2]n (3b). Compounds 1 and 2 are one-dimensional triple-stranded chain. Compounds 3a and 3b are polymorphous and construct one-dimensional single chain. The conformational analysis is performed. The thermal properties have been investigated.
基金the Scientific and Technological Project of Guangdong Province, China(No.2006B36703005)
文摘Reaction of FeCIz'6H20, pyridine-2,4,6-tricarboxylic acid(H3pyta) and NaOH in the hydrothermal system at 185 ℃ resulted in the formation of 1D coordination polymer[Fe(Hpyta)(H2O)2](1) based on Fe-Hpyta chains. When the abpt[abpt=-4-amino-3,5-bis(4-pyridyl)-l,2,4-triazole] ligand was employed in the reaction system, a 3D supramolecular porous network (H2bpt)[Fe(pyta)(H2O)2]·4H2O(2) was obtained. The framework was constructed with negative (Fe-pyta) chains and the positive H3bpt^+ in situ, formed from the abpt reagent, to form 1D channels filled with guest water molecules via hydrogen-bonds. X-Ray diffraction crystal structure analysis shows that complex 1 crystallized in the monoclinic system, space group C2/c, a=1.1490(5) nm, b=0.9008(4) nm, c=1.0058(5) nm, B=107.254(9)°, V=0.9942(8) nm3, Z=4; and complex 2 crystallizes in the triclinic system, space group P1 with a=0.90392(11) nm, b=0.96027(11 ) nm, c=1.55540(18) nm, a=73.558(2)°,B= 86.126(2)°,r= 68.745(2)°, V=1.2059(2) nm^3 and Z=2.
文摘Two new diaryheptanoids, (5S)-5-acetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)-3- heptanone (1) and (3S,5S)-3,5-diacetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)heptane (2) were isolated from the rhizomes of Zingiber officinale. Their structures were elucidated by spectral methods.