An acrylic monomer bearing carbazole moiety,3 methacrylamido 9 ethylcarbazole (MAECz)was synthesized and polymerized radically.Fluorescence studies showed that at the same chromophore concentration,the fluorescence in...An acrylic monomer bearing carbazole moiety,3 methacrylamido 9 ethylcarbazole (MAECz)was synthesized and polymerized radically.Fluorescence studies showed that at the same chromophore concentration,the fluorescence intensity of the polymer (P(MAECz) was much stronger than that of the monomer.This can be explained by what we termed fluorescence “Structural Self Quenching Effect”(SSQE).The stern volmer constants of P(MAECz) in solution quenched by several electron deficient vinyl monomers were obtained.It was found that the quenching efficiency of the quenchers was relevant to the degree of the electron deficiency.Also,the photopolymerization of acrylonitrile (AN) initiated by MAECz was investigated kinetically and a tentative initiation mechanism was proposed.展开更多
Kinetics of the coordination reaction of tetrakis(Ncarbomethoxymethyl3pyridyl) porphyrin(abbr. H2TβNACMSPyP) with Cu?ion has been studied in ophthalic acid buffer system in an ionic strength of 0.5mol...Kinetics of the coordination reaction of tetrakis(Ncarbomethoxymethyl3pyridyl) porphyrin(abbr. H2TβNACMSPyP) with Cu?ion has been studied in ophthalic acid buffer system in an ionic strength of 0.5mol·dm-3(KCI) at 35.0±0.1℃.The reaction is catalyzed by ophthalic ion. The effect of concentration of the catalyst, metal ion and pH value of solution was discussed. The kinetics equation of the reaction were obtained as d/dt=16.15{(1.0+3.35×1052)/1.0+1.57×10-42}T. The mechanism of the reaction was proposed. The deformation of the ring of porphyrins is the general condition in the reaction. Keyowrds:展开更多
文摘An acrylic monomer bearing carbazole moiety,3 methacrylamido 9 ethylcarbazole (MAECz)was synthesized and polymerized radically.Fluorescence studies showed that at the same chromophore concentration,the fluorescence intensity of the polymer (P(MAECz) was much stronger than that of the monomer.This can be explained by what we termed fluorescence “Structural Self Quenching Effect”(SSQE).The stern volmer constants of P(MAECz) in solution quenched by several electron deficient vinyl monomers were obtained.It was found that the quenching efficiency of the quenchers was relevant to the degree of the electron deficiency.Also,the photopolymerization of acrylonitrile (AN) initiated by MAECz was investigated kinetically and a tentative initiation mechanism was proposed.
文摘Kinetics of the coordination reaction of tetrakis(Ncarbomethoxymethyl3pyridyl) porphyrin(abbr. H2TβNACMSPyP) with Cu?ion has been studied in ophthalic acid buffer system in an ionic strength of 0.5mol·dm-3(KCI) at 35.0±0.1℃.The reaction is catalyzed by ophthalic ion. The effect of concentration of the catalyst, metal ion and pH value of solution was discussed. The kinetics equation of the reaction were obtained as d/dt=16.15{(1.0+3.35×1052)/1.0+1.57×10-42}T. The mechanism of the reaction was proposed. The deformation of the ring of porphyrins is the general condition in the reaction. Keyowrds:
