Oxidation of Al_2O_3-30%TiCN-0.2%Y_2O_3 Composite

The oxidation behavior of Al2O3-30%TiCN-0.2%Y2O3 composite and its effect on high temperature bending strength was studied. The result indicates that the mass gain during static oxidation of the material under normal atmosphere follows the parabolic law. Oxide increases with increasing temperature and prolonging time. It has good oxidation resistance. The product of oxidation of the material is TiO2. Therefore, the volume of the material expands. The oxide film is destroyed because residual stress inside the oxide film is released. Proper oxidation is beneficial to the improvement of bending strength of Al2O3-30%TiCN-0.2%Y2O3 composite. The strength increase is up to 4.5%.

30%SiCp/2024Al复合材料动态再结晶临界条件

采用Gleeble-1500D热模拟试验机对30%SiCp/Al复合材料进行热模拟试验,其变形温度为623~773K、应变速率为0.01~10s-1。采用加工硬化率法对应力-应变数据进行处理,结合lnθ-ε曲线的拐点和（-（lnθ）/ε）-ε）曲线最小值的判据,研究了该复合材料动态再结晶临界条件。结果表明,30%SiCp/2024Al复合材料的真应力-应变曲线主要以动态再结晶软化机制为特征,峰值应力（σp）随变形温度降低或应变速率升高而增加;该材料的lnθ-ε曲线出现拐点,（-（lnθ）/ε）-ε）曲线出现最小值;临界应变（εc）随变形温度升高与应变速率降低而减小,且临界应变与峰值应变（εp）之间具有相关性,即εc=0.563εp;临界应变与Zener-Hollomon参数（Z）之间的函数关系为εc=7.96×10-3Z0.038。

Effects of Y_2O_3 on Thermal Shock of Al_2O_3/TiCN Composites

Thermal shock resistance of Al2O3-TiCN(30%)-Y2O3(0.2%) composite was studied by hot pressing(HP) method at different temperatures. The study shows that thermal shock resistance of the material is determined by its microstructure and reinforced mechanism. According to SEM and calculation of thermal shock, the fractured surface of Al2O3-30%TiCN-0.2%Y2O3 composite is undulate. The residual strength of Al2O3-30%TiCN-0.2%Y2O3 is higher than Al2O3-30%TiCN at 200～800 ℃ after thermal shock. Cracks initiation resistance (R′)and cracks propagation resistance (R″″)of Al2O3-30%TiCN-0.2%Y2O3 composite increases 12% and 5% respectively compared with that of Al2O3-30%TiCN. It matches with experimental results. The addition of Y2O3 forms YAG that inhibits crystal growth, and increases fracture stress, fracture toughness, cracks initiation resistance and cracks propagation resistance. Therefore, thermal shock resistance increases. The fracture work of Al2O3-30%TiCN and Al2O3-30%TiCN-0.2%Y2O3 composites are 132 and 148 J·m-2 respectively.

30% SiC_p/2024Al复合材料的热变形行为

在Gleeble-1 500D热模拟机上采用等温压缩实验研究30%SiC_p/Al复合材料的高温压缩变形行为,获得该材料在温度为623~773 K,应变速率为0.01-10 s^(-1)的条件下的真应力-应变曲线,并在考虑摩擦和变形热效应的基础上对真应力-应变曲线进行修正。对修正后的峰值应力进行线性回归,建立该材料的本构方程。根据材料动态模型,计算并建立30%SiC_p/Al复合材料的热加工图,据此确定热变形流变失稳区。在应变速率为0.01 s^(-1)时,随热变形温度升高,该复合材料发生动态再结晶的体积分数增加。

30% SiC_p/Al复合材料热变形及动态再结晶行为

采用Gleeble-1500D热模拟试验机研究30%SiCp/Al复合材料在温度为623~773 K、应变速率为0.01~10 s-1下的热变形及动态再结晶行为。结果表明：材料的高温流变应力-应变曲线主要以动态再结晶软化机制为特征,峰值应力随变形温度降低或应变速率升高而增大,材料热激活能为272.831 k J/mol。以试验数据为基础,建立q-s和？q/？s-s曲线,从而进一步获得动态再结晶的临界应变和稳态应变,通过试验数据的回归分析,建立动态再结晶的临界应变模型和稳态应变模型,并在此基础上,获得所需要材料的动态再结晶图。

Bi对Al-30% Mg_2Si复合材料组织和性能的影响

为了研究铋(Bi)对Al-30%Mg2Si复合材料显微组织和力学性能的影响,利用原位内生工艺制备了Al-30%Mg2Si复合材料,并加入不同量的Bi对其细化变质.利用扫描电镜进行显微组织观察,并利用布氏硬度计和液压式万能试验机进行力学性能测试.试验结果显示,稀土Bi的质量分数由0%增加至5%时,初生相Mg2Si的平均晶粒尺寸先减小后变大,而抗拉强度、硬度和伸长率则先提高后减小;当Bi加入量约为3%时,初生相Mg2Si显微组织细化效果最为明显,综合力学性能最好.