Three-dimensional(3D) synthetic aperture radar(SAR)extends the conventional 2D images into 3D features by several acquisitions in different aspects. Compared with 3D techniques via multiple observations in elevation, ...Three-dimensional(3D) synthetic aperture radar(SAR)extends the conventional 2D images into 3D features by several acquisitions in different aspects. Compared with 3D techniques via multiple observations in elevation, e.g. SAR interferometry(InSAR) and SAR tomography(TomoSAR), holographic SAR can retrieve 3D structure by observations in azimuth. This paper focuses on designing a novel type of orbit to achieve SAR regional all-azimuth observation(AAO) for embedded targets detection and holographic 3D reconstruction. The ground tracks of the AAO orbit separate the earth surface into grids. Target in these grids can be accessed with an azimuth angle span of360°, which is similar to the flight path of airborne circular SAR(CSAR). Inspired from the successive coverage orbits of optical sensors, several optimizations are made in the proposed method to ensure favorable grazing angles, the performance of 3D reconstruction, and long-term supervision for SAR sensors. Simulation experiments show the regional AAO can be completed within five hours. In addition, a second AAO of the same area can be duplicated in two days. Finally, an airborne SAR data process result is presented to illustrate the significance of AAO in 3D reconstruction.展开更多
We report 75As-nuclear magnetic resonance(NMR)and nuclear quadrupole resonance(NQR)measurements on transition-metal arsenides LaRu2As2,KCa2Fe4As4F2,and A2Cr3As3.In the superconducting state of LaRu2As2,a Hebel–Slicht...We report 75As-nuclear magnetic resonance(NMR)and nuclear quadrupole resonance(NQR)measurements on transition-metal arsenides LaRu2As2,KCa2Fe4As4F2,and A2Cr3As3.In the superconducting state of LaRu2As2,a Hebel–Slichter coherence peak is found in the temperature dependence of the spin-lattice relaxation rate 1/T1 just below Tc,which indicates that LaRu2As2 is a full-gap superperconducor.For KCa2Fe4As4F2,antiferromagnetic spin fluctuations are observed in the normal state.We further find that the anisotropy rate RAF=Tc 1/Tab 1 is small and temperature independent,implying that the low energy spin fluctuations are isotropic in spin space.Our results indicate that KCa2Fe4As4F2 is a moderately overdoped iron-arsenide high-temperature superconductor with a stoichiometric composition.For A2Cr3As3(A=Na,K,Rb,Cs),we calculate the electric field gradient by first-principle method and assign the 75As-NQR peaks to two crystallographically different As sites,paving the way for further NMR investigation.展开更多
By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI o...By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI of R<SUB>1</SUB> line of GSGG:Cr<SUP>3+</SUP> at 70 K have been calculated, respectively. Their physical origins have been revealed. It is found that the admixture of and base-wavefunctions in the wavefunctions of R<SUB>1</SUB> level of GSGG:Cr<SUP>3+</SUP> at 70 K is remarkable under the normal pressure, and the degree of the admixture rapidly decreases with increasing pressure. The change of the degree of the admixture with the pressure plays a key role for not only the pure electronic PS of R<SUB>1</SUB> line but also the PS of R<SUB>1</SUB> line due to EPI. The detailed calculations and analyses show that the pressure-dependent behaviors of the pure electronic PS of R<SUB>1</SUB> line and the PS of R<SUB>1</SUB> line due to EPI are quite different. It is the combined effect of them that gives rise to the total PS of R<SUB>1</SUB> line, which has satisfactorily explained the experimental data (including a reversal of PS of R<SUB>1</SUB> line). In contributions to PS of R<SUB>1</SUB> line due to EPI at 70 K, the temperature-independent contribution is much larger than the temperature-dependent contribution. The former results from the interaction between the zero-point vibration of the lattice and localized electronic state.展开更多
By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI o...By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI of R<SUB>1</SUB> line, R<SUB>2</SUB> line, and U band of GSGG:Cr<SUP>3+</SUP> at 300 K have been calculated, respectively. The calculated results are in good agreement with all the experimental data. Their physical origins have also been explained. It is found that the mixing-degree of and base-wavefunctions in the wavefunctions of R<SUB>1</SUB> level of GSGG:Cr<SUP>3+</SUP> at 300 K is remarkable under normal pressure, and the mixing-degree rapidly decreases with increasing pressure. The change of the mixing-degree with pressure plays a key role not only for the 'pure electronic' PS of R<SUB>1</SUB> line and R<SUB>2</SUB> line but also the PS of R<SUB>1</SUB> line and R<SUB>2</SUB> line due to EPI. The pressure-dependent behaviors of the 'pure electronic' PS of R<SUB>1</SUB> line (or R<SUB>2</SUB> line) and the PS of R<SUB>1</SUB> line (or R<SUB>2</SUB> line) due to EPI are quite different. It is the combined effect of them that gives rise to the total PS of R<SUB>1</SUB> line (or R<SUB>2</SUB> line). In the range of about 15 kbar ~ 45 kbar, the mergence and/or order-reversal between levels and levels take place, which cause the fluctuation of the rate of PS for with pressure. At 300 K, both the temperature-dependent contribution to R<SUB>1</SUB> line (or R<SUB>2</SUB> line or U band) from EPI and the temperature-independent one are important.展开更多
In this paper a controller of pulse coupling feedback (PCF) is designed to control chaotic systems. Control principles and the technique to select the feedback coefficients are introduced. This controller is theoret...In this paper a controller of pulse coupling feedback (PCF) is designed to control chaotic systems. Control principles and the technique to select the feedback coefficients are introduced. This controller is theoretically studied with a three dimensional (3D) chaotic system. The artificial simulation results show that the chaotic system can be stabilized to different periodic orbits by using the PCF method, and the number of the periodic orbits are 2^n×3^m p (n and m are integers). Therefore, this control method is effective and practical.展开更多
Ⅰ. INTRODUCTIONA problem needing urgent resolution in the world at present is the study of the polyacetylene (PA) conductive material which is stable in the air. We produce the polyacetylene-like sulfide (SLPA) which...Ⅰ. INTRODUCTIONA problem needing urgent resolution in the world at present is the study of the polyacetylene (PA) conductive material which is stable in the air. We produce the polyacetylene-like sulfide (SLPA) which is stable in the air from polyvinyl chloride, and characterize its structure and property, and make studies on the influence of sulfidation on PA’s electronic property by means of the quantum method.展开更多
AIM:To investigate the biomechanical properties and practical application of absorbable materials in orbital fracture repair.METHODS:The three-dimensional(3D)model of orbital blowout fractures was reconstructed using ...AIM:To investigate the biomechanical properties and practical application of absorbable materials in orbital fracture repair.METHODS:The three-dimensional(3D)model of orbital blowout fractures was reconstructed using Mimics21.0 software.The repair guide plate model for inferior orbital wall fracture was designed using 3-matic13.0 and Geomagic wrap 21.0 software.The finite element model of orbital blowout fracture and absorbable repair plate was established using 3-matic13.0 and ANSYS Workbench 21.0 software.The mechanical response of absorbable plates,with thicknesses of 0.6 and 1.2 mm,was modeled after their placement in the orbit.Two patients with inferior orbital wall fractures volunteered to receive single-layer and double-layer absorbable plates combined with 3D printing technology to facilitate surgical treatment of orbital wall fractures.RESULTS:The finite element models of orbital blowout fracture and absorbable plate were successfully established.Finite element analysis(FEA)showed that when the Young’s modulus of the absorbable plate decreases to 3.15 MPa,the repair material with a thickness of 0.6 mm was influenced by the gravitational forces of the orbital contents,resulting in a maximum total deformation of approximately 3.3 mm.Conversely,when the absorbable plate was 1.2 mm thick,the overall maximum total deformation was around 0.4 mm.The half-year follow-up results of the clinical cases confirmed that the absorbable plate with a thickness of 1.2 mm had smaller maximum total deformation and better clinical efficacy.CONCLUSION:The biomechanical analysis observations in this study are largely consistent with the clinical situation.The use of double-layer absorbable plates in conjunction with 3D printing technology is recommended to support surgical treatment of infraorbital wall blowout fractures.展开更多
The Haiyang-2D altimetry mission of China is one of the first Low Earth Orbit(LEO)satellites that can receive new B1C/B2a signals from the BeiDou-3 Navigation Satellite System(BDS-3)for Precise Orbit Determination(POD...The Haiyang-2D altimetry mission of China is one of the first Low Earth Orbit(LEO)satellites that can receive new B1C/B2a signals from the BeiDou-3 Navigation Satellite System(BDS-3)for Precise Orbit Determination(POD).In this work,the achievable accuracy of the single-receiver ambiguity resolution for onboard LEO satellites is studied based on the real measurements of new BDS-3 frequencies.Under normal conditions,six BDS-3 satellites on average are visible.However,the multipath of the B1C/B2a code observations presents some patchy patterns that cause near-field variations with an amplitude of approximately 40 cm and deteriorate the ambiguity-fixed rate.By modeling those errors,for the B2a code,a remarkable reduction of 53%in the Root Mean Square(RMS)is achieved at high elevations,along with an increase of 8%in the ambiguity-fixed rates.Additionally,an analysis of the onboard antenna’s phase center offsets reveals that when compared to the solutions with float ambiguities,the estimated values in the antenna’s Z direction in the solutions with fixed ambiguities are notably smaller.The independent validation of the resulting POD using satellite laser ranging at 16 selected high-performance stations shows that the residuals are reduced by a minimum of 15.4%for ambiguity-fixed solutions with an RMS consistency of approximately 2.2 cm.Furthermore,when compared to the DORIS-derived orbits,a 4.3 cm 3D RMS consistency is achieved for the BDS-3-derived orbits,and the along-track bias is reduced from 2.9 to 0.4 cm using ambiguity fixing.展开更多
The high unoccupied d band energy of Ni_(3)N basically results in weak orbital coupling with water molecule,consequently leading to slow water dissociation kinetics.Herein,we demonstrate Cr doping can downshift the un...The high unoccupied d band energy of Ni_(3)N basically results in weak orbital coupling with water molecule,consequently leading to slow water dissociation kinetics.Herein,we demonstrate Cr doping can downshift the unoccupied d orbitals and strengthen the interfacial orbital coupling to boost the water dissociation kinetics.The prepared Cr-Ni_(3)N/Ni displays an impressive overpotential of 37 mV at 10 mA·cmgeo-2,close to the benchmark Pt/C in 1.0 M KOH solution.Refined structural analysis reveals the Cr dopant exists as the Cr-N_(6)states and the average d band energy of Ni_(3)N is also lowered.Density functional theory calculation further confirms the downshifted d band energy can strengthen the orbital coupling between the unpaired electrons in O 2p and the unoccupied state of Ni 3d,which thus facilitates the water adsorption and dissociation.The work provides a new concept to achieve on-demand functions for hydrogen evolution catalysis and beyond,by regulating the interfacial orbital coupling.展开更多
Pediatric orbital trapdoor fractures are common in children and adolescents and usually require emergency surgical intervention.Herein,a personalized 3D printing-assisted approach to surgical treatment is proposed,ser...Pediatric orbital trapdoor fractures are common in children and adolescents and usually require emergency surgical intervention.Herein,a personalized 3D printing-assisted approach to surgical treatment is proposed,serving to accurately and effectively repair pediatric orbital trapdoor fractures.We first investigated stress distribution in external force-induced orbital blowout fractures via numerical simulation,determining that maximum stresses on inferior and medial walls exceed those on superior and lateral walls and thus confer higher probability of fracture.We also examined 36 pediatric patients treated for orbital trapdoor fractures between 2014 and 2019 to verify our theoretical construct.Using 3D printing technique,we then created orbital models based on computed tomography(CT)studies of these patients.Absorbable implants were tailor-made,replicating those of 3D-printed models during surgical repairs of fractured orbital bones.As follow-up,we compared CT images and clinical parameters(extraocular movements,diplopia,enophthalmos)before and 12 months after operative procedures.There were only two patients with diplopia and six with enophthalmos>2 mm at 12 months,attesting to the efficacy of our novel 3D printing-assisted strategy.展开更多
目的探索根据骨折患者的cT数据应用3D打印机制作个体化眼眶模型的方法。方法将患者眼眶CT的医学数字成像和通信格式(digital imaging and communications in medicine,DICOM)影像数据通过交互式医学图像控制系统(materialise’s int...目的探索根据骨折患者的cT数据应用3D打印机制作个体化眼眶模型的方法。方法将患者眼眶CT的医学数字成像和通信格式(digital imaging and communications in medicine,DICOM)影像数据通过交互式医学图像控制系统(materialise’s interactive medical image control system,mimics)软件三维重建,生成3D模型文件格式(STL)文件,通过开源三维打印程序(ReplicatorG)软件将STL文件转化成X3g文件,最后X3g文件通过3D打印机(Maker Bot Replicator2)等比例打印出三维立体眼眶模型。结果根据每个眼眶骨折患者的CT影像DICOM数据成功打印出个体化等比例眼眶骨折的三维实体模型。结论基于mimics软件、ReplicatorG软件及3D打印机制作的等比例眼眶实体三维模型,使临床医生能够更加充分地了解骨折的形态、面积及其与周围骨骼的三维结构关系。展开更多
Ab initio LCAO-MO-SCF calculations for several typical molecules containing phosphorus have been undertaken to study the role of phosphorus 3d orbitals in the bonding.It is emphasized that the discussion about the 3d ...Ab initio LCAO-MO-SCF calculations for several typical molecules containing phosphorus have been undertaken to study the role of phosphorus 3d orbitals in the bonding.It is emphasized that the discussion about the 3d orbital participation in bonding should be based on a reasonable choice of basis sets and it seems suitable to choose the atomic orbitals in proper molecular environment as the basis set.As an approximation,the optimized minimal STO-NG basis sets have been adopted in the present paper.The results obtained well exhibit the model of 3d orbital participation in bonding. It is shown that under the influence of highly electronegative ligands the phosphorus 3d orbitals con- tract greatly,their energy levels drop considerably,and thus they can effectively participate in bond- ing.The presence of highly electronegative ligands seems necessary.The contribution of 3d orbitals to bonding is achieved mainly through the concertedformation of σ bonds and p-d backbonds,though the contribution to σ bonding is minor.The three-center,four-electron bond modelis only approxi- mately correct.The results of the present paper demonstrate that the model of 3d orbital participation in bonding favoured by experimental chemists is reasonable and possesses sound ground.展开更多
The role of the sulfur 3d orbitals in bond formation is discussed by taking into account the influence of the environment on the orbitals of the sulfur atom in the molecules. The ca cula- tion results of a series of p...The role of the sulfur 3d orbitals in bond formation is discussed by taking into account the influence of the environment on the orbitals of the sulfur atom in the molecules. The ca cula- tion results of a series of prototype molecules containing sulfur such as SF_2, SF_4, NSF_3, SF_1, H_2S are reported. It is convincingly shown that in highly electronegative environment the energy levels of the sulfur 3d orbitals are reduced to the vicinity of those of the ligand valence orbitals and their spatial distributions are contracted to the bonding area, and therefore they can participate in bond formation to a certain extent, which is enhanced by the formation of the d-p π back bonds. It seems that the result reported in this paper is helpful for the solution of the long-standing debate about the sulfur 3d orbital participation in bond formation.展开更多
Only one-dimensional (1D)deformation along the radar line of sight (LOS)can be obtained using differential interferometry synthetic aperture radar (D-InSAR),and D-InSAR observation is insensitive to deformation in the...Only one-dimensional (1D)deformation along the radar line of sight (LOS)can be obtained using differential interferometry synthetic aperture radar (D-InSAR),and D-InSAR observation is insensitive to deformation in the north direction.This study inferred three-dimensional (3D)deformation of a mining subsidence basin by combining the north-south deformation predicted by a probability integral method with the LOS deformation obtained by D-InSAR.The 15235 working face in Fengfeng mining area (Hebei Province,China)was used as the object of study.The north-south horizontal movement was predicted by the probability integral method according to the site's geological and mining conditions.Then,the vertical and east-west deformation fields were solved by merging ascend-orbit RadarSAT-2, descend-orbit TerraSAR,and predicted north-south deformation based on a least squares method.Comparing with the leveling data,the results show that the vertical deformation accuracy of the experimental method is better than the inversed vertical deformation neglecting the horizontal deformation.Finally,the impact of the relationship between the azimuth of the working face and the SAR imaging geometry on the monitoring of the mining subsidence basin was analyzed.The results can be utilized in monitoring mining subsidence basins by single SAR image sources.展开更多
基金supported by the National Natural Science Foundation of China (62001436)the Natural Science Foundation of Jiangsu Province under (BK 20190143,JSGG20190823094603691)。
文摘Three-dimensional(3D) synthetic aperture radar(SAR)extends the conventional 2D images into 3D features by several acquisitions in different aspects. Compared with 3D techniques via multiple observations in elevation, e.g. SAR interferometry(InSAR) and SAR tomography(TomoSAR), holographic SAR can retrieve 3D structure by observations in azimuth. This paper focuses on designing a novel type of orbit to achieve SAR regional all-azimuth observation(AAO) for embedded targets detection and holographic 3D reconstruction. The ground tracks of the AAO orbit separate the earth surface into grids. Target in these grids can be accessed with an azimuth angle span of360°, which is similar to the flight path of airborne circular SAR(CSAR). Inspired from the successive coverage orbits of optical sensors, several optimizations are made in the proposed method to ensure favorable grazing angles, the performance of 3D reconstruction, and long-term supervision for SAR sensors. Simulation experiments show the regional AAO can be completed within five hours. In addition, a second AAO of the same area can be duplicated in two days. Finally, an airborne SAR data process result is presented to illustrate the significance of AAO in 3D reconstruction.
基金National Natural Science Foundation of China(Grant Nos.11674377,11634015,and 11974405)the National Key R&D Program of China(Grant Nos.2017YFA0302904 and 2016YFA0300502)J.Y.also acknowledges support by the Youth Innovation Promotion Association of Chinese Academy of Sciences.
文摘We report 75As-nuclear magnetic resonance(NMR)and nuclear quadrupole resonance(NQR)measurements on transition-metal arsenides LaRu2As2,KCa2Fe4As4F2,and A2Cr3As3.In the superconducting state of LaRu2As2,a Hebel–Slichter coherence peak is found in the temperature dependence of the spin-lattice relaxation rate 1/T1 just below Tc,which indicates that LaRu2As2 is a full-gap superperconducor.For KCa2Fe4As4F2,antiferromagnetic spin fluctuations are observed in the normal state.We further find that the anisotropy rate RAF=Tc 1/Tab 1 is small and temperature independent,implying that the low energy spin fluctuations are isotropic in spin space.Our results indicate that KCa2Fe4As4F2 is a moderately overdoped iron-arsenide high-temperature superconductor with a stoichiometric composition.For A2Cr3As3(A=Na,K,Rb,Cs),we calculate the electric field gradient by first-principle method and assign the 75As-NQR peaks to two crystallographically different As sites,paving the way for further NMR investigation.
文摘By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI of R<SUB>1</SUB> line of GSGG:Cr<SUP>3+</SUP> at 70 K have been calculated, respectively. Their physical origins have been revealed. It is found that the admixture of and base-wavefunctions in the wavefunctions of R<SUB>1</SUB> level of GSGG:Cr<SUP>3+</SUP> at 70 K is remarkable under the normal pressure, and the degree of the admixture rapidly decreases with increasing pressure. The change of the degree of the admixture with the pressure plays a key role for not only the pure electronic PS of R<SUB>1</SUB> line but also the PS of R<SUB>1</SUB> line due to EPI. The detailed calculations and analyses show that the pressure-dependent behaviors of the pure electronic PS of R<SUB>1</SUB> line and the PS of R<SUB>1</SUB> line due to EPI are quite different. It is the combined effect of them that gives rise to the total PS of R<SUB>1</SUB> line, which has satisfactorily explained the experimental data (including a reversal of PS of R<SUB>1</SUB> line). In contributions to PS of R<SUB>1</SUB> line due to EPI at 70 K, the temperature-independent contribution is much larger than the temperature-dependent contribution. The former results from the interaction between the zero-point vibration of the lattice and localized electronic state.
文摘By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI of R<SUB>1</SUB> line, R<SUB>2</SUB> line, and U band of GSGG:Cr<SUP>3+</SUP> at 300 K have been calculated, respectively. The calculated results are in good agreement with all the experimental data. Their physical origins have also been explained. It is found that the mixing-degree of and base-wavefunctions in the wavefunctions of R<SUB>1</SUB> level of GSGG:Cr<SUP>3+</SUP> at 300 K is remarkable under normal pressure, and the mixing-degree rapidly decreases with increasing pressure. The change of the mixing-degree with pressure plays a key role not only for the 'pure electronic' PS of R<SUB>1</SUB> line and R<SUB>2</SUB> line but also the PS of R<SUB>1</SUB> line and R<SUB>2</SUB> line due to EPI. The pressure-dependent behaviors of the 'pure electronic' PS of R<SUB>1</SUB> line (or R<SUB>2</SUB> line) and the PS of R<SUB>1</SUB> line (or R<SUB>2</SUB> line) due to EPI are quite different. It is the combined effect of them that gives rise to the total PS of R<SUB>1</SUB> line (or R<SUB>2</SUB> line). In the range of about 15 kbar ~ 45 kbar, the mergence and/or order-reversal between levels and levels take place, which cause the fluctuation of the rate of PS for with pressure. At 300 K, both the temperature-dependent contribution to R<SUB>1</SUB> line (or R<SUB>2</SUB> line or U band) from EPI and the temperature-independent one are important.
基金Project supported by the National Natural Science Foundation of China (Grant No 20373021) and Natural Science Foundation of Liaoning Province, China (Grant No 2050790).
文摘In this paper a controller of pulse coupling feedback (PCF) is designed to control chaotic systems. Control principles and the technique to select the feedback coefficients are introduced. This controller is theoretically studied with a three dimensional (3D) chaotic system. The artificial simulation results show that the chaotic system can be stabilized to different periodic orbits by using the PCF method, and the number of the periodic orbits are 2^n×3^m p (n and m are integers). Therefore, this control method is effective and practical.
基金Project supported by the National Natural Science Foundation of China
文摘Ⅰ. INTRODUCTIONA problem needing urgent resolution in the world at present is the study of the polyacetylene (PA) conductive material which is stable in the air. We produce the polyacetylene-like sulfide (SLPA) which is stable in the air from polyvinyl chloride, and characterize its structure and property, and make studies on the influence of sulfidation on PA’s electronic property by means of the quantum method.
基金Supported by the National Natural Science Foundation of China(No.82060181)General Project funded by the Jiangxi Provincial Department of Education(No.GJJ2200194).
文摘AIM:To investigate the biomechanical properties and practical application of absorbable materials in orbital fracture repair.METHODS:The three-dimensional(3D)model of orbital blowout fractures was reconstructed using Mimics21.0 software.The repair guide plate model for inferior orbital wall fracture was designed using 3-matic13.0 and Geomagic wrap 21.0 software.The finite element model of orbital blowout fracture and absorbable repair plate was established using 3-matic13.0 and ANSYS Workbench 21.0 software.The mechanical response of absorbable plates,with thicknesses of 0.6 and 1.2 mm,was modeled after their placement in the orbit.Two patients with inferior orbital wall fractures volunteered to receive single-layer and double-layer absorbable plates combined with 3D printing technology to facilitate surgical treatment of orbital wall fractures.RESULTS:The finite element models of orbital blowout fracture and absorbable plate were successfully established.Finite element analysis(FEA)showed that when the Young’s modulus of the absorbable plate decreases to 3.15 MPa,the repair material with a thickness of 0.6 mm was influenced by the gravitational forces of the orbital contents,resulting in a maximum total deformation of approximately 3.3 mm.Conversely,when the absorbable plate was 1.2 mm thick,the overall maximum total deformation was around 0.4 mm.The half-year follow-up results of the clinical cases confirmed that the absorbable plate with a thickness of 1.2 mm had smaller maximum total deformation and better clinical efficacy.CONCLUSION:The biomechanical analysis observations in this study are largely consistent with the clinical situation.The use of double-layer absorbable plates in conjunction with 3D printing technology is recommended to support surgical treatment of infraorbital wall blowout fractures.
基金This work is partly sponsored by China Postdoctoral Science Foundation(Grant Nos.2021M702507)the National Natural Science Foundation of China(Grant Nos.42204020,42004020,42074032,41931075 and 42030109)the Key Research and Development Plan Project of Hubei Province(Grant Nos.2020BIB006).
文摘The Haiyang-2D altimetry mission of China is one of the first Low Earth Orbit(LEO)satellites that can receive new B1C/B2a signals from the BeiDou-3 Navigation Satellite System(BDS-3)for Precise Orbit Determination(POD).In this work,the achievable accuracy of the single-receiver ambiguity resolution for onboard LEO satellites is studied based on the real measurements of new BDS-3 frequencies.Under normal conditions,six BDS-3 satellites on average are visible.However,the multipath of the B1C/B2a code observations presents some patchy patterns that cause near-field variations with an amplitude of approximately 40 cm and deteriorate the ambiguity-fixed rate.By modeling those errors,for the B2a code,a remarkable reduction of 53%in the Root Mean Square(RMS)is achieved at high elevations,along with an increase of 8%in the ambiguity-fixed rates.Additionally,an analysis of the onboard antenna’s phase center offsets reveals that when compared to the solutions with float ambiguities,the estimated values in the antenna’s Z direction in the solutions with fixed ambiguities are notably smaller.The independent validation of the resulting POD using satellite laser ranging at 16 selected high-performance stations shows that the residuals are reduced by a minimum of 15.4%for ambiguity-fixed solutions with an RMS consistency of approximately 2.2 cm.Furthermore,when compared to the DORIS-derived orbits,a 4.3 cm 3D RMS consistency is achieved for the BDS-3-derived orbits,and the along-track bias is reduced from 2.9 to 0.4 cm using ambiguity fixing.
基金The work was supported by the National Natural Science Foundation of China(Nos.21771169 and 11722543)the National Key Research and Development Program of China(No.2017YFA0206703)+1 种基金Anhui Provincial Natural Science Foundation(No.BJ2060190077)Collaborative Innovation Program of Hefei Science Center,CAS,and the Fundamental Research Funds for the Central Universities(Nos.WK2060190074,WK2060190081,WK2310000066,and WK2060000015).
文摘The high unoccupied d band energy of Ni_(3)N basically results in weak orbital coupling with water molecule,consequently leading to slow water dissociation kinetics.Herein,we demonstrate Cr doping can downshift the unoccupied d orbitals and strengthen the interfacial orbital coupling to boost the water dissociation kinetics.The prepared Cr-Ni_(3)N/Ni displays an impressive overpotential of 37 mV at 10 mA·cmgeo-2,close to the benchmark Pt/C in 1.0 M KOH solution.Refined structural analysis reveals the Cr dopant exists as the Cr-N_(6)states and the average d band energy of Ni_(3)N is also lowered.Density functional theory calculation further confirms the downshifted d band energy can strengthen the orbital coupling between the unpaired electrons in O 2p and the unoccupied state of Ni 3d,which thus facilitates the water adsorption and dissociation.The work provides a new concept to achieve on-demand functions for hydrogen evolution catalysis and beyond,by regulating the interfacial orbital coupling.
文摘Pediatric orbital trapdoor fractures are common in children and adolescents and usually require emergency surgical intervention.Herein,a personalized 3D printing-assisted approach to surgical treatment is proposed,serving to accurately and effectively repair pediatric orbital trapdoor fractures.We first investigated stress distribution in external force-induced orbital blowout fractures via numerical simulation,determining that maximum stresses on inferior and medial walls exceed those on superior and lateral walls and thus confer higher probability of fracture.We also examined 36 pediatric patients treated for orbital trapdoor fractures between 2014 and 2019 to verify our theoretical construct.Using 3D printing technique,we then created orbital models based on computed tomography(CT)studies of these patients.Absorbable implants were tailor-made,replicating those of 3D-printed models during surgical repairs of fractured orbital bones.As follow-up,we compared CT images and clinical parameters(extraocular movements,diplopia,enophthalmos)before and 12 months after operative procedures.There were only two patients with diplopia and six with enophthalmos>2 mm at 12 months,attesting to the efficacy of our novel 3D printing-assisted strategy.
文摘目的探索根据骨折患者的cT数据应用3D打印机制作个体化眼眶模型的方法。方法将患者眼眶CT的医学数字成像和通信格式(digital imaging and communications in medicine,DICOM)影像数据通过交互式医学图像控制系统(materialise’s interactive medical image control system,mimics)软件三维重建,生成3D模型文件格式(STL)文件,通过开源三维打印程序(ReplicatorG)软件将STL文件转化成X3g文件,最后X3g文件通过3D打印机(Maker Bot Replicator2)等比例打印出三维立体眼眶模型。结果根据每个眼眶骨折患者的CT影像DICOM数据成功打印出个体化等比例眼眶骨折的三维实体模型。结论基于mimics软件、ReplicatorG软件及3D打印机制作的等比例眼眶实体三维模型,使临床医生能够更加充分地了解骨折的形态、面积及其与周围骨骼的三维结构关系。
基金The National Natural Science Foundation of China.
文摘Ab initio LCAO-MO-SCF calculations for several typical molecules containing phosphorus have been undertaken to study the role of phosphorus 3d orbitals in the bonding.It is emphasized that the discussion about the 3d orbital participation in bonding should be based on a reasonable choice of basis sets and it seems suitable to choose the atomic orbitals in proper molecular environment as the basis set.As an approximation,the optimized minimal STO-NG basis sets have been adopted in the present paper.The results obtained well exhibit the model of 3d orbital participation in bonding. It is shown that under the influence of highly electronegative ligands the phosphorus 3d orbitals con- tract greatly,their energy levels drop considerably,and thus they can effectively participate in bond- ing.The presence of highly electronegative ligands seems necessary.The contribution of 3d orbitals to bonding is achieved mainly through the concertedformation of σ bonds and p-d backbonds,though the contribution to σ bonding is minor.The three-center,four-electron bond modelis only approxi- mately correct.The results of the present paper demonstrate that the model of 3d orbital participation in bonding favoured by experimental chemists is reasonable and possesses sound ground.
文摘The role of the sulfur 3d orbitals in bond formation is discussed by taking into account the influence of the environment on the orbitals of the sulfur atom in the molecules. The ca cula- tion results of a series of prototype molecules containing sulfur such as SF_2, SF_4, NSF_3, SF_1, H_2S are reported. It is convincingly shown that in highly electronegative environment the energy levels of the sulfur 3d orbitals are reduced to the vicinity of those of the ligand valence orbitals and their spatial distributions are contracted to the bonding area, and therefore they can participate in bond formation to a certain extent, which is enhanced by the formation of the d-p π back bonds. It seems that the result reported in this paper is helpful for the solution of the long-standing debate about the sulfur 3d orbital participation in bond formation.
基金the National Natural Science Foundation of China (Grant Nos.41272389 and 41604005)A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (No.SZBF2011-6-B35)+2 种基金Special Fund for Public Projects of National Administration of Surveying, Mapping,and Geoinformation of China (No.201412016)Project supported by the Basic Research Project of Jiangsu Province (Natural Science Foundation)(No.BK20160218)the State Key Laboratory of Geohazard Prevention and Geoenviromnent Protection (Chengdu University of Technology)(No.SKLGP2016K008).
文摘Only one-dimensional (1D)deformation along the radar line of sight (LOS)can be obtained using differential interferometry synthetic aperture radar (D-InSAR),and D-InSAR observation is insensitive to deformation in the north direction.This study inferred three-dimensional (3D)deformation of a mining subsidence basin by combining the north-south deformation predicted by a probability integral method with the LOS deformation obtained by D-InSAR.The 15235 working face in Fengfeng mining area (Hebei Province,China)was used as the object of study.The north-south horizontal movement was predicted by the probability integral method according to the site's geological and mining conditions.Then,the vertical and east-west deformation fields were solved by merging ascend-orbit RadarSAT-2, descend-orbit TerraSAR,and predicted north-south deformation based on a least squares method.Comparing with the leveling data,the results show that the vertical deformation accuracy of the experimental method is better than the inversed vertical deformation neglecting the horizontal deformation.Finally,the impact of the relationship between the azimuth of the working face and the SAR imaging geometry on the monitoring of the mining subsidence basin was analyzed.The results can be utilized in monitoring mining subsidence basins by single SAR image sources.