The compressional behavlour of natural pyrope garnet is investigated by using angle-dlspersive synchrotron radiation x-ray diffraction and Raman spectroscopy in a diamond anvil cell at room temperature. The pressurein...The compressional behavlour of natural pyrope garnet is investigated by using angle-dlspersive synchrotron radiation x-ray diffraction and Raman spectroscopy in a diamond anvil cell at room temperature. The pressureinduced phase transition does not occur under given pressure. The equation of state of pyrope garnet is determined under pressure up to 25.3 GPa. The bulk modulus KTO is 199 GPa, with its first pressure derivative K′TO fixed to 4. The Raman spectra of pyrope garnet are studied. A new Raman peak nearly at 743 cm^-1 is observed in a bending vibration of the SiO4 tetrahedra frequency range at pressure of about 28 GPa. We suggest that the new Raman peak results from the lattice distortion of the SiO4 tetrahedra. All the Raman frequencies continuously increase with the increasing pressure. The average pressure derivative of the high frequency modes （650-1000 cm^-1） is larger than that of the low frequency （smaller than 650 cm^-1）. Based on these data, the mode Grǖneisen parameters for pyrope are obtained.展开更多
Calcium aluminate cement(CAC)is widely used as a binder for refractory materials,and thus the improvement in compressive strength is of vital importance for CAC applied at high temperature.For this purpose,nano-Ca_(10...Calcium aluminate cement(CAC)is widely used as a binder for refractory materials,and thus the improvement in compressive strength is of vital importance for CAC applied at high temperature.For this purpose,nano-Ca_(10)(PO_(4))_(6)(OH)_(2)additive with a ratio of 0.5–1.5 mass%was added with the water-cement ratio to be 0.4.X-ray diffraction and isothermal calorimetry analysis demonstrate that nano-Ca_(10)(PO_(4))_(6)(OH)_(2)additive can shorten the hydration process and promote the formation of main hydrates of CaAl2O4·10H2O(CAH10)and Ca2Al2O5·8H2O(C2AH8).In addition,scanning electron microscopy results suggest that nano-Ca_(10)(PO_(4))_(6)(OH)_(2)can protect CAH10 and C2AH8 from being destroyed during the calcination,guaranteeing that these thin lamellar crystals are intertwined to form the denser microstructure.Benefited from above effects,nano-Ca_(10)(PO_(4))_(6)(OH)_(2)can obviously improve the compressive strength of the CAC mortar samples cured for 7 d after calcination at 1100°C,while the improving effect is dependent upon its contents.Especially,compared with the one without the additive,the compressive strength of the sample with 1.0%nano-Ca_(10)(PO_(4))_(6)(OH)_(2)is increased by 14%.展开更多
为满足电能质量监测网存储与传输海量录波数据的需要,提出了提升格式的2维离散小波变换、多级树集合分裂(set partitioning in hierarchical tree,SPIHT)编码、算术编码相结合的数据压缩方法。为了有效降低数据的冗余度,该方法将采集的...为满足电能质量监测网存储与传输海量录波数据的需要,提出了提升格式的2维离散小波变换、多级树集合分裂(set partitioning in hierarchical tree,SPIHT)编码、算术编码相结合的数据压缩方法。为了有效降低数据的冗余度,该方法将采集的1维电能质量数据按整数倍周期排列为2维矩阵;采用提升格式的2维离散小波变换对数据进行压缩,然后对小波系数进行SPIHT编码,实现了对压缩性能的控制;最后采用算术编码进一步提高了压缩比。对几类常见的电能质量扰动数据进行了压缩实验,证明该方法具有较好的压缩性能。在不同压缩码率下对ATP-EMTP仿真模型得到的扰动数据进行了压缩实验,验证了该方法能通过控制压缩码率实现对压缩性能的控制。展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 10299040, and the National Basic Research Programme of China under Grant Nos 2001CB711201 and 2005CB724400.
文摘The compressional behavlour of natural pyrope garnet is investigated by using angle-dlspersive synchrotron radiation x-ray diffraction and Raman spectroscopy in a diamond anvil cell at room temperature. The pressureinduced phase transition does not occur under given pressure. The equation of state of pyrope garnet is determined under pressure up to 25.3 GPa. The bulk modulus KTO is 199 GPa, with its first pressure derivative K′TO fixed to 4. The Raman spectra of pyrope garnet are studied. A new Raman peak nearly at 743 cm^-1 is observed in a bending vibration of the SiO4 tetrahedra frequency range at pressure of about 28 GPa. We suggest that the new Raman peak results from the lattice distortion of the SiO4 tetrahedra. All the Raman frequencies continuously increase with the increasing pressure. The average pressure derivative of the high frequency modes （650-1000 cm^-1） is larger than that of the low frequency （smaller than 650 cm^-1）. Based on these data, the mode Grǖneisen parameters for pyrope are obtained.
基金The authors express their appreciation to the National Natural Science Foundation of China(Nos.51904021 and 51974021)the Fundamental Research Funds for the Central Universities(Nos.FRF-TP-19-008A1 and FRF-TP-19-004B2Z)+1 种基金China Postdoctoral Science Foundation(2019M660458 and 2020T130052)Beijing Excellent Talents Foundation for financial support.
文摘Calcium aluminate cement(CAC)is widely used as a binder for refractory materials,and thus the improvement in compressive strength is of vital importance for CAC applied at high temperature.For this purpose,nano-Ca_(10)(PO_(4))_(6)(OH)_(2)additive with a ratio of 0.5–1.5 mass%was added with the water-cement ratio to be 0.4.X-ray diffraction and isothermal calorimetry analysis demonstrate that nano-Ca_(10)(PO_(4))_(6)(OH)_(2)additive can shorten the hydration process and promote the formation of main hydrates of CaAl2O4·10H2O(CAH10)and Ca2Al2O5·8H2O(C2AH8).In addition,scanning electron microscopy results suggest that nano-Ca_(10)(PO_(4))_(6)(OH)_(2)can protect CAH10 and C2AH8 from being destroyed during the calcination,guaranteeing that these thin lamellar crystals are intertwined to form the denser microstructure.Benefited from above effects,nano-Ca_(10)(PO_(4))_(6)(OH)_(2)can obviously improve the compressive strength of the CAC mortar samples cured for 7 d after calcination at 1100°C,while the improving effect is dependent upon its contents.Especially,compared with the one without the additive,the compressive strength of the sample with 1.0%nano-Ca_(10)(PO_(4))_(6)(OH)_(2)is increased by 14%.
文摘为满足电能质量监测网存储与传输海量录波数据的需要,提出了提升格式的2维离散小波变换、多级树集合分裂(set partitioning in hierarchical tree,SPIHT)编码、算术编码相结合的数据压缩方法。为了有效降低数据的冗余度,该方法将采集的1维电能质量数据按整数倍周期排列为2维矩阵;采用提升格式的2维离散小波变换对数据进行压缩,然后对小波系数进行SPIHT编码,实现了对压缩性能的控制;最后采用算术编码进一步提高了压缩比。对几类常见的电能质量扰动数据进行了压缩实验,证明该方法具有较好的压缩性能。在不同压缩码率下对ATP-EMTP仿真模型得到的扰动数据进行了压缩实验,验证了该方法能通过控制压缩码率实现对压缩性能的控制。
