1,4-dioxane pollution is characterized by its early identification, widespread sources and extensive distribution. The pollutant is highly mobile and persistent in the water environment and is classified as a B2(proba...1,4-dioxane pollution is characterized by its early identification, widespread sources and extensive distribution. The pollutant is highly mobile and persistent in the water environment and is classified as a B2(probable) human carcinogen. After reviewing recent researches on the pollution status,transport and transformation characteristics of 1,4-dioxane in the water environment, as well as the environmental pollution remediation and treatment technologies, and the status of environmental regulation,this paper addresses that the distribution of 1,4-dioxane in water bodies is significantly correlated with chlorinated hydrocarbon pollutants such as 1,1,1-trichloroethane(1,1,1-TCA) and trichloroethylene(TCE).It is noteworthy that 1,4-dioxane often occurs in symbiosis with 1,1,1-TCA and has a similarity contamination plume distribution to 1,1,1-TCA. The natural attenuation of 1,4-dioxane in groundwater environment is weak, but there is a certain degree of biological oxidation attenuation. Current methods for treating 1,4-dioxane pollution mainly include extraction-treatment technology, advanced oxidation treatment technology, modified biological treatment technology and phytoremediation technology, all of which have their limitations in practical application. Currently, there is no environmental regulation available for the 1,4-dioxane pollution worldwide, and no enforceable standard established for defining the health trigger levels of 1,4-dioxane in drinking water. Research on this contaminant in China is generally limited to the site or laboratory scale, and there are no studies on the environmental risk and quality standards for 1,4-dioxane in the water environment.展开更多
The ring-opening polymerization of 1,4-dioxan-2-one (PDO) was carried out by lanthanum tris(2,6-di-tert-butyl-4- methylphenolate) (La(OAr)3) as novel single component initiaLor. The influences of polymerizatio...The ring-opening polymerization of 1,4-dioxan-2-one (PDO) was carried out by lanthanum tris(2,6-di-tert-butyl-4- methylphenolate) (La(OAr)3) as novel single component initiaLor. The influences of polymerization reaction temperature and the molar ratio of monomer to initiator on the monomer conversion and molecular weight of poly(1,4-dioxan-2-one) (PPDO) were explored. PPDO with high viscosity average molecular weight of 1.95×10^5 can be prepared at 40℃ when [PDO]/ [La(OAr)3] molar ratio was 800. Mechanism investigation shows that the polymerization proceeds through a "coordination- insertion" mechanism with selective rupture of acyl-oxygen be,nd of PDO.展开更多
A new cyclic monomer, 2-oxo-3-methylene-5, 6-diphenyl-1, 4-dioxan, was synthesized. Thestructure of the intermediates and the monomer were determined by IR,~1H NMR,^(13)C NMR andelemental analysis. This new monomer is...A new cyclic monomer, 2-oxo-3-methylene-5, 6-diphenyl-1, 4-dioxan, was synthesized. Thestructure of the intermediates and the monomer were determined by IR,~1H NMR,^(13)C NMR andelemental analysis. This new monomer is different from other cyclic monomers in this series,it isa solid (mp 108--109℃)and not very reactive, but still can undergo free radical ring-openingpolymerization. The free radical polymerization was carried out at 130℃. The structure of theresulting polymer was discussed and charaterized by IR, ~1H NMR, ^(13)C NMR and elementalanalysis. The molecular weight of the polymer was estimated by viscosity determination.展开更多
A rare earth Schiff base complex:lanthanum tris(N-phenylethyl-3,5-di-t-butylsalicylaldiminato)s [La(OPEBS)_3] was successfully applied as single component initiator for the ring-opening polymerization of 1,4-dioxan-2-...A rare earth Schiff base complex:lanthanum tris(N-phenylethyl-3,5-di-t-butylsalicylaldiminato)s [La(OPEBS)_3] was successfully applied as single component initiator for the ring-opening polymerization of 1,4-dioxan-2-one (PDO) in bulk.The influence of reaction conditions,such as polymerization temperature,the molar ratio of the monomer to initiator (M/I) on the monomer conversion and molecular weight of the polymer has been investigated.Poly(1,4-dioxan-2-one) with a viscosity-average molecular weight (My) o...展开更多
BaWO4 nanorods have been successfully synthesized in w/o microemulsion system containing barium ions via a simple reaction between Ba2+ and . The BaWO4 Nanorods were characterized by XRD, TEM, and SEM, respectively. R...BaWO4 nanorods have been successfully synthesized in w/o microemulsion system containing barium ions via a simple reaction between Ba2+ and . The BaWO4 Nanorods were characterized by XRD, TEM, and SEM, respectively. Results showed that the solvents composition—volume ratio of 4-dioxane and distilled water—played the key role in the formation of BaWO4 Nanorods. Furthermore, the strong vibration at 925 cm﹣1 on its Raman spectrum indicated that the BaWO4 nanorods is good at stimulating Raman scattering in transient and steady-state, making it as a promising candidate material for laser with self-raman conversion of radiation inside the active medium.展开更多
文摘1,4-dioxane pollution is characterized by its early identification, widespread sources and extensive distribution. The pollutant is highly mobile and persistent in the water environment and is classified as a B2(probable) human carcinogen. After reviewing recent researches on the pollution status,transport and transformation characteristics of 1,4-dioxane in the water environment, as well as the environmental pollution remediation and treatment technologies, and the status of environmental regulation,this paper addresses that the distribution of 1,4-dioxane in water bodies is significantly correlated with chlorinated hydrocarbon pollutants such as 1,1,1-trichloroethane(1,1,1-TCA) and trichloroethylene(TCE).It is noteworthy that 1,4-dioxane often occurs in symbiosis with 1,1,1-TCA and has a similarity contamination plume distribution to 1,1,1-TCA. The natural attenuation of 1,4-dioxane in groundwater environment is weak, but there is a certain degree of biological oxidation attenuation. Current methods for treating 1,4-dioxane pollution mainly include extraction-treatment technology, advanced oxidation treatment technology, modified biological treatment technology and phytoremediation technology, all of which have their limitations in practical application. Currently, there is no environmental regulation available for the 1,4-dioxane pollution worldwide, and no enforceable standard established for defining the health trigger levels of 1,4-dioxane in drinking water. Research on this contaminant in China is generally limited to the site or laboratory scale, and there are no studies on the environmental risk and quality standards for 1,4-dioxane in the water environment.
基金This work was financially supported by the financial support of National Natural Science Foundation of China (No. 20434020)
文摘The ring-opening polymerization of 1,4-dioxan-2-one (PDO) was carried out by lanthanum tris(2,6-di-tert-butyl-4- methylphenolate) (La(OAr)3) as novel single component initiaLor. The influences of polymerization reaction temperature and the molar ratio of monomer to initiator on the monomer conversion and molecular weight of poly(1,4-dioxan-2-one) (PPDO) were explored. PPDO with high viscosity average molecular weight of 1.95×10^5 can be prepared at 40℃ when [PDO]/ [La(OAr)3] molar ratio was 800. Mechanism investigation shows that the polymerization proceeds through a "coordination- insertion" mechanism with selective rupture of acyl-oxygen be,nd of PDO.
文摘A new cyclic monomer, 2-oxo-3-methylene-5, 6-diphenyl-1, 4-dioxan, was synthesized. Thestructure of the intermediates and the monomer were determined by IR,~1H NMR,^(13)C NMR andelemental analysis. This new monomer is different from other cyclic monomers in this series,it isa solid (mp 108--109℃)and not very reactive, but still can undergo free radical ring-openingpolymerization. The free radical polymerization was carried out at 130℃. The structure of theresulting polymer was discussed and charaterized by IR, ~1H NMR, ^(13)C NMR and elementalanalysis. The molecular weight of the polymer was estimated by viscosity determination.
基金supported by the National Natural Science Foundation of China (Key program,Nos.G20434020 and G20774078).
文摘A rare earth Schiff base complex:lanthanum tris(N-phenylethyl-3,5-di-t-butylsalicylaldiminato)s [La(OPEBS)_3] was successfully applied as single component initiator for the ring-opening polymerization of 1,4-dioxan-2-one (PDO) in bulk.The influence of reaction conditions,such as polymerization temperature,the molar ratio of the monomer to initiator (M/I) on the monomer conversion and molecular weight of the polymer has been investigated.Poly(1,4-dioxan-2-one) with a viscosity-average molecular weight (My) o...
文摘BaWO4 nanorods have been successfully synthesized in w/o microemulsion system containing barium ions via a simple reaction between Ba2+ and . The BaWO4 Nanorods were characterized by XRD, TEM, and SEM, respectively. Results showed that the solvents composition—volume ratio of 4-dioxane and distilled water—played the key role in the formation of BaWO4 Nanorods. Furthermore, the strong vibration at 925 cm﹣1 on its Raman spectrum indicated that the BaWO4 nanorods is good at stimulating Raman scattering in transient and steady-state, making it as a promising candidate material for laser with self-raman conversion of radiation inside the active medium.