A novel tetrafunctional initiator, C [CH_2O (CH_2)_3 OOCCH(Br)CH_3]_4 (1), was synthesized through the reaction oftetraol with α-bromopropionyl chloride, and then was used as initiator of atom transfer radical polyme...A novel tetrafunctional initiator, C [CH_2O (CH_2)_3 OOCCH(Br)CH_3]_4 (1), was synthesized through the reaction oftetraol with α-bromopropionyl chloride, and then was used as initiator of atom transfer radical polymerization (ATRP) in thepreparation of 4-armed polystyrene (PSt) with narrow polydispersity. The structure, molecular weight and molecular weightdistribution (MWD) of each arm were studied by ~1H-NMR and GPC data of hydrolyzed products of the 4-armed PSt. TheATRP of St using 1/CuBr/bpy as initiator system is of 'living' character based on the following evidence: narrow MWD,constant concentration of chain radical during the polymerization, control of molecular weight by the molar ratio of monomerconsumed to 1. The 4-armed poly(St-b-p-nitrophenyl methacrylate) [poly(St-b-NPMA)] was prepared by the ATRP ofNPMA using 4-armed PSt with terminal bromine as the initiator, and characterized by FT-IR, ~1H-NMR spectra and GPCcurves. The micelles with PSt as core, and PNPMA as shell were formed by dropping DMSO into a solution of 4-armedpoly(St-b-NPMA) in DMF, as proved by laser light scatter (LLS) method.展开更多
详细地介绍了一种基于MPEG-4压缩的嵌入式网络流媒体采集、传输和控制应用系统的设计与实现技术。该嵌入式平台采用203 MHz的ARM920T内核处理器S3C2410B,嵌入式操作系统采用Linux操作系统,用户可在这个系统平台上进行自主软件开发。视...详细地介绍了一种基于MPEG-4压缩的嵌入式网络流媒体采集、传输和控制应用系统的设计与实现技术。该嵌入式平台采用203 MHz的ARM920T内核处理器S3C2410B,嵌入式操作系统采用Linux操作系统,用户可在这个系统平台上进行自主软件开发。视频采集模块采用TI公司的TVP5145,视频压缩芯片采用硬压缩W IS GO7007B进行处理,将Y:Cb:Cr格式的视频流转换为MPEG-4编码。展开更多
基金This work was supported by the National Natural Science Foundation of China (Grant No. 29774027).
文摘A novel tetrafunctional initiator, C [CH_2O (CH_2)_3 OOCCH(Br)CH_3]_4 (1), was synthesized through the reaction oftetraol with α-bromopropionyl chloride, and then was used as initiator of atom transfer radical polymerization (ATRP) in thepreparation of 4-armed polystyrene (PSt) with narrow polydispersity. The structure, molecular weight and molecular weightdistribution (MWD) of each arm were studied by ~1H-NMR and GPC data of hydrolyzed products of the 4-armed PSt. TheATRP of St using 1/CuBr/bpy as initiator system is of 'living' character based on the following evidence: narrow MWD,constant concentration of chain radical during the polymerization, control of molecular weight by the molar ratio of monomerconsumed to 1. The 4-armed poly(St-b-p-nitrophenyl methacrylate) [poly(St-b-NPMA)] was prepared by the ATRP ofNPMA using 4-armed PSt with terminal bromine as the initiator, and characterized by FT-IR, ~1H-NMR spectra and GPCcurves. The micelles with PSt as core, and PNPMA as shell were formed by dropping DMSO into a solution of 4-armedpoly(St-b-NPMA) in DMF, as proved by laser light scatter (LLS) method.
文摘详细地介绍了一种基于MPEG-4压缩的嵌入式网络流媒体采集、传输和控制应用系统的设计与实现技术。该嵌入式平台采用203 MHz的ARM920T内核处理器S3C2410B,嵌入式操作系统采用Linux操作系统,用户可在这个系统平台上进行自主软件开发。视频采集模块采用TI公司的TVP5145,视频压缩芯片采用硬压缩W IS GO7007B进行处理,将Y:Cb:Cr格式的视频流转换为MPEG-4编码。
