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金属离子和氧化剂对4-氯酚光化学降解的影响 被引量:7
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作者 郁志勇 宋林 +2 位作者 朱燕 孙震 唐晓纯 《应用科学学报》 CAS CSCD 2003年第4期419-422,共4页
在实验条件下,Mn2+/Fe2+/Cu2+/Zn2+/Al3+/Y3+/La3+(特别是Y3+和La3+)、KMnO4/K2S2O8/KClO3/KClO4/KBrO3/KIO3对4氯酚光化学降解起加速作用,且随其浓度增大而增强.KIO4对4氯酚光化学降解起抑制作用,且随其浓度增大而增强.KClO3/KBrO3+Y3+... 在实验条件下,Mn2+/Fe2+/Cu2+/Zn2+/Al3+/Y3+/La3+(特别是Y3+和La3+)、KMnO4/K2S2O8/KClO3/KClO4/KBrO3/KIO3对4氯酚光化学降解起加速作用,且随其浓度增大而增强.KIO4对4氯酚光化学降解起抑制作用,且随其浓度增大而增强.KClO3/KBrO3+Y3+对4CP光化学降解的加速作用更为显著.无光照时,KMnO4、KIO4+Mn2+/Fe2+都能够使4氯酚立刻发生化学降解,尤其以KMnO4、KIO4+Mn2+的作用更为显著. 展开更多
关键词 金属离子 氧化剂 4-氯酚 光化学降解 饮用水
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Immobilization of microorganisms using carrageenan gels coated with chitosan and application to biodegradation of 4-chlorophenol 被引量:2
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作者 Wang Jianlong Li Ping +2 位作者 Shi Hanchang Qian Yi China Zhou Ding 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1997年第3期30-34,共5页
A new cell immobilization method based on the replacement of KCl by KCl+chitosan as the gelling agent was developed. The experimental results showed that through addition of chitosan into gelling agent, the mechanica... A new cell immobilization method based on the replacement of KCl by KCl+chitosan as the gelling agent was developed. The experimental results showed that through addition of chitosan into gelling agent, the mechanical strength and the thermal stability of the carrageenan gel were greatly improved. The new immobilization method was used to entrap a chlorophenol degrading microorganism. The immobilized microbial cells were applied for chlorophenol biodegradation. The experiments demonstrated that immobilized cells exhibit a higher bioactivity in the degradation of chlorophenol than free cells. 展开更多
关键词 CARRAGEENAN CHITOSAN IMMOBILIZATION 4 chlorophenol biodegradation.
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Synergistic photocatalytic effect of porous g-C_3N_4 in a Cr(Ⅵ)/4-chlorophenol composite pollution system 被引量:1
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作者 Kai Wei Kexin Li +4 位作者 Zhenxing Zeng Yuhua Dai Liushui Yan Huiqin Guo Xubiao Luo 《Chinese Journal of Catalysis》 CSCD 北大核心 2017年第11期1804-1811,共8页
The photocatalytic reduction of aqueous Cr(VI)to Cr(III)was preliminarily studied using porousg‐C3N4as a photocatalyst under acidic conditions.The observed synergistic photocatalytic effect ofporous g‐C3N4on a Cr(VI... The photocatalytic reduction of aqueous Cr(VI)to Cr(III)was preliminarily studied using porousg‐C3N4as a photocatalyst under acidic conditions.The observed synergistic photocatalytic effect ofporous g‐C3N4on a Cr(VI)/4‐chlorophenol(4‐CP)composite pollution system was further studiedunder different pH conditions.Compared with single‐component photocatalytic systems for Cr(VI)reduction or4‐CP degradation,the Cr(VI)reduction efficiency and4‐CP degradation efficiency weresimultaneously improved in the Cr(VI)/4‐CP composite pollution system.The synergistic photocatalyticeffect in the Cr(VI)/4‐CP composite pollution system can be attributed to the acceleratedredox reaction between dichromate and4‐CP by electron transfer with porous g‐C3N4. 展开更多
关键词 Composite pollution Synergistic photocatalysis Porous g‐C3N4 Cr(VI) 4‐Chlorophenol
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