Perovskite solar cells(PSCs)have emerged as a promising photovoltaic technology because of their high light absorption coefficient,long carrier diffusion distance,and tunable bandgap.However,PSCs face challenges such ...Perovskite solar cells(PSCs)have emerged as a promising photovoltaic technology because of their high light absorption coefficient,long carrier diffusion distance,and tunable bandgap.However,PSCs face challenges such as hysteresis effects and stability issues.In this study,we introduced a novel approach to improve film crystallization by leveraging 4-tert-butylpyridine(TBP)molecules,thereby enhancing the performance and stability of PSCs.Our findings demonstrate the effective removal of PbI_(2)from the perovskite surface through strong coordination with TBP molecules.Additionally,by carefully adjusting the concentration of the TBP solution,we achieved enhanced film crystallinity without disrupting the perovskite structure.The TBP-treated perovskite films exhibit a low defect density,improved crystallinity,and improved carrier lifetime.As a result,the PSCs manufactured with TBP treatment achieve power conversion efficiency(PCE)exceeding 24%.Moreover,we obtained the PCE of 21.39%for the 12.25 cm^(2)module.展开更多
This work aims at evaluating the reliability of the GEANT4(GEometry ANd Tracking 4) Monte Carlo(MC) toolkit in calculating the power deposition on the Megawatt Pilot Experiment(MEGAPIE), the first liquid–metal spalla...This work aims at evaluating the reliability of the GEANT4(GEometry ANd Tracking 4) Monte Carlo(MC) toolkit in calculating the power deposition on the Megawatt Pilot Experiment(MEGAPIE), the first liquid–metal spallation target worldwide. A new choice of codes to study and optimize this target is provided. The evaluation of the GEANT4 toolkit is carried out in comparison with the MCNPX and FLUKA MC codes. The MEGAPIE is an international project led by the Paul Scherrer Institute in Switzerland. It aims to demonstrate the safe operation of an intense neutron source to power the next generation of nuclear reactors, accelerator-driven systems(ADSs). In this study, we used the GEANT4 MC toolkit to calculate the power deposited by fast protons on the MEGAPIE target.The calculation focuses on several structures and regions.The predictions of our calculations were compared and discussed with that of the MCNPX and FLUKA codes,adopted by the MEGAPIE project. The comparison shows that there is a very good agreement between our results and those of the reference codes.展开更多
A“cloud-edge-end”collaborative system architecture is adopted for real-time security management of power system on-site work,and mobile edge computing equipment utilizes lightweight intelligent recognition algorithm...A“cloud-edge-end”collaborative system architecture is adopted for real-time security management of power system on-site work,and mobile edge computing equipment utilizes lightweight intelligent recognition algorithms for on-site risk assessment and alert.Owing to its lightweight and fast speed,YOLOv4-Tiny is often deployed on edge computing equipment for real-time video stream detection;however,its accuracy is relatively low.This study proposes an improved YOLOv4-Tiny algorithm based on attention mechanism and optimized training methods,achieving higher accuracy without compromising the speed.Specifically,a convolution block attention module branch is added to the backbone network to enhance the feature extraction capability and an efficient channel attention mechanism is added in the neck network to improve feature utilization.Moreover,three optimized training methods:transfer learning,mosaic data augmentation,and label smoothing are used to improve the training effect of this improved algorithm.Finally,an edge computing equipment experimental platform equipped with an NVIDIA Jetson Xavier NX chip is established and the newly developed algorithm is tested on it.According to the results,the speed of the improved YOLOv4-Tiny algorithm in detecting on-site dress code compliance datasets is 17.25 FPS,and the mean average precision(mAP)is increased from 70.89%to 85.03%.展开更多
Electrode material based on a novel core–shell structure consisting of NiCoS（NCS） solid fiber core and Mn S（MS） sheet shell（NCS@MS） in situ grown on carbon cloth（CC） has been successfully prepared by a simple...Electrode material based on a novel core–shell structure consisting of NiCoS（NCS） solid fiber core and Mn S（MS） sheet shell（NCS@MS） in situ grown on carbon cloth（CC） has been successfully prepared by a simple sulfurization-assisted hydrothermal method for high performance supercapacitor. The synthesized NiCoS@Mn S/CC electrode shows high capacitance of 1908.3 F gat a current density of 0.5 A gwhich is higher than those of NiCoSand Mn S at the same current density. A flexible all-solid-state asymmetric supercapacitor（ASC） is constructed by using NiCoS@Mn S/CC as positive electrode, active carbon/CC as negative electrode and KOH/poly（vinyl alcohol）(PVA) as electrolyte. The optimized ASC shows a maximum energy density of 23.3 Wh kgat 1 A g, a maximum power density of about7.5 kw kgat 10 A gand remarkable cycling stability. After 9000 cycles, the ASC still exhibited67.8% retention rate and largely unchanged charge/discharge curves. The excellent electrochemical properties are resulted from the novel core–shell structure of the NiCoS@Mn S/CC electrode, which possesses both high surface area for Faraday redox reaction and superior kinetics of charge transport. The NiCoS@Mn S/CC electrode shows a promising potential for energy storage applications in the future.展开更多
Total dose effects and single event effects on radiation-hardened power vertical double-diffusion metal oxide semiconductor（VDMOS） devices with composite SiO2-Si3N4 film gates are investigated.The relationships amon...Total dose effects and single event effects on radiation-hardened power vertical double-diffusion metal oxide semiconductor（VDMOS） devices with composite SiO2-Si3N4 film gates are investigated.The relationships among the important electrical parameters of the samples with different thickness SiO2-Si3N4 films,such as threshold voltage,breakdown voltage,and on-state resistance in accumulated dose,are discussed.The total dose experiment results show that the breakdown voltage and the on-state resistance barely change with the accumulated dose.However,the relationships between the threshold voltages of the samples and the accumulated dose are more complex,and not only positively drift,but also negatively drift.At the end of the total dose experiment,we select the group of samples which have the smaller threshold voltage shift to carry out the single event effect studies.We find that the samples with appropriate thickness ratio SiO2-Si3N4 films have a good radiation-hardening ability.This method may be useful in solving both the SEGR and the total dose problems with the composite SiO2-Si3N4 films.展开更多
The calculation time in the Monte Carlo simulations consistently represents an essential issue. It is often very long, and its decrease constitutes a challenge for the simulator. Generally, an MC simulation is qualifi...The calculation time in the Monte Carlo simulations consistently represents an essential issue. It is often very long, and its decrease constitutes a challenge for the simulator. Generally, an MC simulation is qualified as quality or not according to two main criteria: the calculation time and the accuracy of the results. However, in most cases, the optimization of one criterion affects negatively the other. Therefore, a compromise between both of them is always required in this kind of simulation. The present work aims at studying the impact of the production threshold(or cut) of the GEANT4 toolkit on the calculation of the power deposition in the MEGAPIE spallation target.The production threshold of secondaries is a GEANT4 intrinsic parameter. It indicates the limit of energy we can reach in the production of secondary particles. This study has allowed us to make the following conclusions. First,the influence of the cut on the calculation of the deposited power depends on the volume size, its arrangement and the importance of the electromagnetic processes occurring within. Second, the accuracy of the calculations can be acceptable only below a given value of the cut energy.Third, this accuracy remains almost unchangeable from a certain value of the cut. The study has also made it possible to explore the prevalence of certain interactions in the zone of spallation in the MEGAPIE target.展开更多
Diode end-pumped solid-state lasers have the potential to yield high quality laser beams with high efficiency for laser range finding and warning receiver applications as well as day and night military laser designati...Diode end-pumped solid-state lasers have the potential to yield high quality laser beams with high efficiency for laser range finding and warning receiver applications as well as day and night military laser designation systems. In this paper we presents theoretical calculations using Advanced Dynamics Professional LASCAD software and experimental studies for a high power pigtailed fiber diode laser module of 8 W operating at 808 nm with a specially designed high efficiency cooling system, end pumped high-efficiency Nd:YVO4 laser of 3 × 3 × 10 mm rod and overall cavity length of 44 mm. To the best of our knowledge a self Q-switching effects was generated in Nd:YVO4 laser by changing the cavity dimensions and the position of the intracavity KTP crystal at certain regime of operation for the first time, in which the cavity length is reduced to be 30 mm and the distance between Nd:YVO4 rod and KTP crystal is only 1mm. Self Q-switched laser pulse at 532 nm with high peak power of 96 W, pulse width of 88 ns at FWHM and repetition rate of 400 kHz was achieved. Experimental studies of a passive Q-switched Nd:YVO4 laser using Cr:YAG crystal with three different transmissions of 30%, 40% and 70% were investigated. Passive Q-switched laser pulse at 1064 nm and narrow line width of less than 1.5 nm with highest peak power of nearly 18 kW, short pulse width of less than 4 ns at FWHM and higher repetition rate of 45 kHz using Cr:YAG with transmission of 30% was achieved for the first time.展开更多
A 28 V-half-regulated power bus topology and an integrated PCDU (Power Conditioning and Distribution Unit) were adopted to meet the energy demand for the Chang'e 4 relay satellite.This paper first introduces the m...A 28 V-half-regulated power bus topology and an integrated PCDU (Power Conditioning and Distribution Unit) were adopted to meet the energy demand for the Chang'e 4 relay satellite.This paper first introduces the mission features and composition of the PSDS (Power Supply and Distribution System) for the Chang'e 4 relay satellite.Due to this satellite's unusual orbit,operational mode and project restrictions,special analysis and design was conducted on the PSDS from the perspective of weight-reduction,power management,and reliability and so on.Extreme low temperature storage of SA (Solar Array) was considered and how the antenna affects the SA was analyzed.A new kind of high-specific-energy 45 Ah (Ampere-hour) battery cell was used for the first time.To make sure that the satellite would successfully pass the long shadow zones,a 100% DOD (Depth of Discharge) experiment was carried out on the battery.Since the sunlight is almost always available and there are very few times for the battery to charge or discharge,battery care to extend its lifetime is also discussed.PCDU is a device that integrates power conditioning and power distribution in one unit.The PCDU on Chang'e 4 relay satellite can output more power with less weight because of the adoption of a 28 V-half-regulated power bus topology which was also used for the first time and used lighter material for its mechanical framework.Experiment under low temperature on PCDU was conducted as well and a hot backup equalizing charge technique which is beneficial to keep performance of the battery is illustrated.The power distribution module,which is a module of PCDU,enhances the power utilization security by utilizing a static impedance measurement and build-in-test to avoid possible short circuits.As for EED (Electrical Explosive Device) module,a protection plug was specially designed and three switches with different functions were connected in series to prevent the EED from exploding by error.In addition,the allowable minimum EED bus voltage for each EED was evaluated in case of low battery voltage caused by the possible postponement of the launching time.Complete verification experiments on the ground were conducted to confirm the correctness of the design and on-orbit test data conformed to the expected results and theoretical calculation.The power supply and distribution system has been working normally since the day the Chang'e 4 relay satellite was launched into space.展开更多
基金financial support from various entities,including the Foundation of Anhui Science and Technology University[HCYJ202201]the Anhui Science and Technology University’s Student Innovation and Entrepreneurship Training Program[S202310879115,202310879053]+4 种基金the Key Project of Natural Science Research in Anhui Science and Technology University[2021ZRZD07]the Chuzhou Science and Technology Project[2021GJ002]the Anhui Province Key Research and Development Program[202304a05020085]the Natural Science Research Project of Anhui Educational Committee[2023AH051877]The Opening Project of State Key Laboratory of Advanced Technology for Float Glass[2020KF06,2022KF06]。
文摘Perovskite solar cells(PSCs)have emerged as a promising photovoltaic technology because of their high light absorption coefficient,long carrier diffusion distance,and tunable bandgap.However,PSCs face challenges such as hysteresis effects and stability issues.In this study,we introduced a novel approach to improve film crystallization by leveraging 4-tert-butylpyridine(TBP)molecules,thereby enhancing the performance and stability of PSCs.Our findings demonstrate the effective removal of PbI_(2)from the perovskite surface through strong coordination with TBP molecules.Additionally,by carefully adjusting the concentration of the TBP solution,we achieved enhanced film crystallinity without disrupting the perovskite structure.The TBP-treated perovskite films exhibit a low defect density,improved crystallinity,and improved carrier lifetime.As a result,the PSCs manufactured with TBP treatment achieve power conversion efficiency(PCE)exceeding 24%.Moreover,we obtained the PCE of 21.39%for the 12.25 cm^(2)module.
文摘This work aims at evaluating the reliability of the GEANT4(GEometry ANd Tracking 4) Monte Carlo(MC) toolkit in calculating the power deposition on the Megawatt Pilot Experiment(MEGAPIE), the first liquid–metal spallation target worldwide. A new choice of codes to study and optimize this target is provided. The evaluation of the GEANT4 toolkit is carried out in comparison with the MCNPX and FLUKA MC codes. The MEGAPIE is an international project led by the Paul Scherrer Institute in Switzerland. It aims to demonstrate the safe operation of an intense neutron source to power the next generation of nuclear reactors, accelerator-driven systems(ADSs). In this study, we used the GEANT4 MC toolkit to calculate the power deposited by fast protons on the MEGAPIE target.The calculation focuses on several structures and regions.The predictions of our calculations were compared and discussed with that of the MCNPX and FLUKA codes,adopted by the MEGAPIE project. The comparison shows that there is a very good agreement between our results and those of the reference codes.
基金supported by the Science and technology project of State Grid Information&Telecommunication Group Co.,Ltd (SGTYHT/19-JS-218)
文摘A“cloud-edge-end”collaborative system architecture is adopted for real-time security management of power system on-site work,and mobile edge computing equipment utilizes lightweight intelligent recognition algorithms for on-site risk assessment and alert.Owing to its lightweight and fast speed,YOLOv4-Tiny is often deployed on edge computing equipment for real-time video stream detection;however,its accuracy is relatively low.This study proposes an improved YOLOv4-Tiny algorithm based on attention mechanism and optimized training methods,achieving higher accuracy without compromising the speed.Specifically,a convolution block attention module branch is added to the backbone network to enhance the feature extraction capability and an efficient channel attention mechanism is added in the neck network to improve feature utilization.Moreover,three optimized training methods:transfer learning,mosaic data augmentation,and label smoothing are used to improve the training effect of this improved algorithm.Finally,an edge computing equipment experimental platform equipped with an NVIDIA Jetson Xavier NX chip is established and the newly developed algorithm is tested on it.According to the results,the speed of the improved YOLOv4-Tiny algorithm in detecting on-site dress code compliance datasets is 17.25 FPS,and the mean average precision(mAP)is increased from 70.89%to 85.03%.
基金supported by the Grant-in-Aid for Scientific Research (KAKENHI) program, Japan (C, Grant Number 15K05597)Takahashi Industrial and Economic Research Foundation (Takahashi Grant Number 06-003-154)
文摘Electrode material based on a novel core–shell structure consisting of NiCoS（NCS） solid fiber core and Mn S（MS） sheet shell（NCS@MS） in situ grown on carbon cloth（CC） has been successfully prepared by a simple sulfurization-assisted hydrothermal method for high performance supercapacitor. The synthesized NiCoS@Mn S/CC electrode shows high capacitance of 1908.3 F gat a current density of 0.5 A gwhich is higher than those of NiCoSand Mn S at the same current density. A flexible all-solid-state asymmetric supercapacitor（ASC） is constructed by using NiCoS@Mn S/CC as positive electrode, active carbon/CC as negative electrode and KOH/poly（vinyl alcohol）(PVA) as electrolyte. The optimized ASC shows a maximum energy density of 23.3 Wh kgat 1 A g, a maximum power density of about7.5 kw kgat 10 A gand remarkable cycling stability. After 9000 cycles, the ASC still exhibited67.8% retention rate and largely unchanged charge/discharge curves. The excellent electrochemical properties are resulted from the novel core–shell structure of the NiCoS@Mn S/CC electrode, which possesses both high surface area for Faraday redox reaction and superior kinetics of charge transport. The NiCoS@Mn S/CC electrode shows a promising potential for energy storage applications in the future.
文摘Total dose effects and single event effects on radiation-hardened power vertical double-diffusion metal oxide semiconductor（VDMOS） devices with composite SiO2-Si3N4 film gates are investigated.The relationships among the important electrical parameters of the samples with different thickness SiO2-Si3N4 films,such as threshold voltage,breakdown voltage,and on-state resistance in accumulated dose,are discussed.The total dose experiment results show that the breakdown voltage and the on-state resistance barely change with the accumulated dose.However,the relationships between the threshold voltages of the samples and the accumulated dose are more complex,and not only positively drift,but also negatively drift.At the end of the total dose experiment,we select the group of samples which have the smaller threshold voltage shift to carry out the single event effect studies.We find that the samples with appropriate thickness ratio SiO2-Si3N4 films have a good radiation-hardening ability.This method may be useful in solving both the SEGR and the total dose problems with the composite SiO2-Si3N4 films.
文摘The calculation time in the Monte Carlo simulations consistently represents an essential issue. It is often very long, and its decrease constitutes a challenge for the simulator. Generally, an MC simulation is qualified as quality or not according to two main criteria: the calculation time and the accuracy of the results. However, in most cases, the optimization of one criterion affects negatively the other. Therefore, a compromise between both of them is always required in this kind of simulation. The present work aims at studying the impact of the production threshold(or cut) of the GEANT4 toolkit on the calculation of the power deposition in the MEGAPIE spallation target.The production threshold of secondaries is a GEANT4 intrinsic parameter. It indicates the limit of energy we can reach in the production of secondary particles. This study has allowed us to make the following conclusions. First,the influence of the cut on the calculation of the deposited power depends on the volume size, its arrangement and the importance of the electromagnetic processes occurring within. Second, the accuracy of the calculations can be acceptable only below a given value of the cut energy.Third, this accuracy remains almost unchangeable from a certain value of the cut. The study has also made it possible to explore the prevalence of certain interactions in the zone of spallation in the MEGAPIE target.
文摘Diode end-pumped solid-state lasers have the potential to yield high quality laser beams with high efficiency for laser range finding and warning receiver applications as well as day and night military laser designation systems. In this paper we presents theoretical calculations using Advanced Dynamics Professional LASCAD software and experimental studies for a high power pigtailed fiber diode laser module of 8 W operating at 808 nm with a specially designed high efficiency cooling system, end pumped high-efficiency Nd:YVO4 laser of 3 × 3 × 10 mm rod and overall cavity length of 44 mm. To the best of our knowledge a self Q-switching effects was generated in Nd:YVO4 laser by changing the cavity dimensions and the position of the intracavity KTP crystal at certain regime of operation for the first time, in which the cavity length is reduced to be 30 mm and the distance between Nd:YVO4 rod and KTP crystal is only 1mm. Self Q-switched laser pulse at 532 nm with high peak power of 96 W, pulse width of 88 ns at FWHM and repetition rate of 400 kHz was achieved. Experimental studies of a passive Q-switched Nd:YVO4 laser using Cr:YAG crystal with three different transmissions of 30%, 40% and 70% were investigated. Passive Q-switched laser pulse at 1064 nm and narrow line width of less than 1.5 nm with highest peak power of nearly 18 kW, short pulse width of less than 4 ns at FWHM and higher repetition rate of 45 kHz using Cr:YAG with transmission of 30% was achieved for the first time.
文摘A 28 V-half-regulated power bus topology and an integrated PCDU (Power Conditioning and Distribution Unit) were adopted to meet the energy demand for the Chang'e 4 relay satellite.This paper first introduces the mission features and composition of the PSDS (Power Supply and Distribution System) for the Chang'e 4 relay satellite.Due to this satellite's unusual orbit,operational mode and project restrictions,special analysis and design was conducted on the PSDS from the perspective of weight-reduction,power management,and reliability and so on.Extreme low temperature storage of SA (Solar Array) was considered and how the antenna affects the SA was analyzed.A new kind of high-specific-energy 45 Ah (Ampere-hour) battery cell was used for the first time.To make sure that the satellite would successfully pass the long shadow zones,a 100% DOD (Depth of Discharge) experiment was carried out on the battery.Since the sunlight is almost always available and there are very few times for the battery to charge or discharge,battery care to extend its lifetime is also discussed.PCDU is a device that integrates power conditioning and power distribution in one unit.The PCDU on Chang'e 4 relay satellite can output more power with less weight because of the adoption of a 28 V-half-regulated power bus topology which was also used for the first time and used lighter material for its mechanical framework.Experiment under low temperature on PCDU was conducted as well and a hot backup equalizing charge technique which is beneficial to keep performance of the battery is illustrated.The power distribution module,which is a module of PCDU,enhances the power utilization security by utilizing a static impedance measurement and build-in-test to avoid possible short circuits.As for EED (Electrical Explosive Device) module,a protection plug was specially designed and three switches with different functions were connected in series to prevent the EED from exploding by error.In addition,the allowable minimum EED bus voltage for each EED was evaluated in case of low battery voltage caused by the possible postponement of the launching time.Complete verification experiments on the ground were conducted to confirm the correctness of the design and on-orbit test data conformed to the expected results and theoretical calculation.The power supply and distribution system has been working normally since the day the Chang'e 4 relay satellite was launched into space.
