Poly{2,5-bis[(p-methoxyphenyl)oxycarbonyl]styrene}was successfully synthesized.This new polymer has a structure characteristic of mesogen-jacketed liquid cyrstalline polymers(MJLCPs)and does form a liquid crystal phas...Poly{2,5-bis[(p-methoxyphenyl)oxycarbonyl]styrene}was successfully synthesized.This new polymer has a structure characteristic of mesogen-jacketed liquid cyrstalline polymers(MJLCPs)and does form a liquid crystal phase above its glass transition.It thus became the starting member of a new series of MJLCPs.The synthesis of the polymer as well as the liquid crystalline properties of the polymer and its monomer was discussed.A brief comparison of the new monomer and polymer with some previously reported counterparts was also included.展开更多
基金This work is supported by the National Natural Science Foundation of China.
文摘Poly{2,5-bis[(p-methoxyphenyl)oxycarbonyl]styrene}was successfully synthesized.This new polymer has a structure characteristic of mesogen-jacketed liquid cyrstalline polymers(MJLCPs)and does form a liquid crystal phase above its glass transition.It thus became the starting member of a new series of MJLCPs.The synthesis of the polymer as well as the liquid crystalline properties of the polymer and its monomer was discussed.A brief comparison of the new monomer and polymer with some previously reported counterparts was also included.
