食品加工过程中的美拉德反应有助于形成一些热诱导毒性产物,包括晚期糖基化终末产物(advanced glycation end products,AGEs)和5-羟甲基糠醛(5-hydroxymethylfurfural,5-HMF)。食源性AGEs在体内的积累和循环与糖尿病并发症的发生有关,...食品加工过程中的美拉德反应有助于形成一些热诱导毒性产物,包括晚期糖基化终末产物(advanced glycation end products,AGEs)和5-羟甲基糠醛(5-hydroxymethylfurfural,5-HMF)。食源性AGEs在体内的积累和循环与糖尿病并发症的发生有关,同时可能诱发氧化应激、炎症和动脉粥样硬化。5-HMF的代谢物5-磺基氧甲基糠醛(5-sulfooxymethylfurfural,5-SMF)有潜在基因毒性和致癌性。如何控制热加工食品中这些危害物的形成已成为食品行业的关注焦点。本文从美拉德反应和焦糖化反应两条途径探究了AGEs和5-HMF的形成机理,并对近5年二者的检测方法进行了综述,阐述了各类方法的优缺点,以期为建立二者的通用检测方法奠定基础。在此基础上,从削减前体物质的供给、阻断中间体的转化,以及去除已经生成的AGEs和5-HMF这3个方面着手,综述了近年来相应所采用的抑制策略,以期为AGEs和5-HMF在食品中的控制及热加工食品质量与安全管理提供理论依据。展开更多
A series of different transition metals(V,Co,Cr,Mn,Fe,Ni,Cu and Zn) promoted H-ZSM-5 catalysts were prepared by impregnation method and characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM) and tra...A series of different transition metals(V,Co,Cr,Mn,Fe,Ni,Cu and Zn) promoted H-ZSM-5 catalysts were prepared by impregnation method and characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM) and transmission electron microscopy(TEM).The catalytic activity of these catalysts was evaluated for the selective catalytic reduction(SCR) of NO with NH_3 as reductant in the presence of oxygen.The results revealed that the catalytic activity of Cu-ZSM-5 nanocatalyst for NO conversion to N_2 was 80%at 300 ℃,which was the best among various promoted metals.Design of experiments(DOEs) with Taguchi method was employed to optimize NH_3-SCR process parameters such as NH_3/NO ratio,O_2 concentration,and gas hourly space velocity(GHSV) over Cu-ZSM-5 nanocatalyst at 250 and 300 ℃.Results showed that the most important parameter in NH_3-SCR of NO is O_2 concentration;followed by NH_3/NO ratio and GHSV has little importance.The NO conversion to N_2 of 63.1%and 94.86%was observed at 250℃ and 300℃,respectively under the obtained optimum conditions.展开更多
Nanocrystalline Gd3Ga5O12:Eu3+ with cubic phase was prepared by a urea homogeneous precipitation method. X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), Fourier transform infrared spectrosc...Nanocrystalline Gd3Ga5O12:Eu3+ with cubic phase was prepared by a urea homogeneous precipitation method. X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric and differential thermal analysis (TG-DTA) and photoluminescence spectra were used to characterize the samples. The effects of the initial solution pH value and urea content on the structure of the sample were studied. The XRD results show that pure phase Gd3Ga5O12 can be obtained at pH =6 and pH =8 of the initial solution. The average crystallite size can be calculated as in the range of 24~33 nm. The average crystallite size decreases with increasing molar ratio of urea to metal ion. The results of excitation spectra and emission spectra show that the emission peaks are ascribed to 5D0→7FJ transitions of Eu3+, and the magnetic dipole transition originated from 5D0 →7F1 of Eu3+ is the strongest; the broad excitation bands belong to change transfer band of Eu?O and the host absorption of Gd3Ga5O12. An efficient energy transfer occurs from Gd3+ to Eu3+.展开更多
With the aid of Meteorological Information Composite and Processing System (MICAPS), satellite wind vectors derived from the Geostationary Meteorological Statellite-5 (GMS-5) and retrieved by National Satellite Meteor...With the aid of Meteorological Information Composite and Processing System (MICAPS), satellite wind vectors derived from the Geostationary Meteorological Statellite-5 (GMS-5) and retrieved by National Satellite Meteorology Center of China (NSMC) can be obtained. Based on the nudging method built in the fifth-generation Mesoscale Model (MM5) of Pennsylvania State University and Na- tional Center for Atmospheric Research, a data preprocessor is developed to convert these satellite wind vectors to those with specified format required in MM5. To examine the data preprocessor and evaluate the impact of satellite winds from GMS-5 on MM5 simulations, a series of numerical experimental fore- casts consisting of four typhoon cases in 2002 are designed and implemented. The results show that the preprocessor can process satellite winds smoothly and MM5 model runs successfully with a little extra computational load during ingesting these winds, and that assimilation of satellite winds by MM5 nudging method can obviously improve typhoon track forecast but contributes a little to typhoon intensity forecast. The impact of the satellite winds depends heavily upon whether the typhoon bogussing scheme in MM5 was turned on or not. The data preprocessor developed in this paper not only can treat GMS-5 satellite winds but also has capability with little modification to process derived winds from other geostationary satellites.展开更多
The sixth Data Release （DR6） of the Sloan Digital Sky Survey （SDSS） provides more photometric regions, new features and more accurate data around globular cluster Palomar 5. A new method, Back Propagation Neural N...The sixth Data Release （DR6） of the Sloan Digital Sky Survey （SDSS） provides more photometric regions, new features and more accurate data around globular cluster Palomar 5. A new method, Back Propagation Neural Network （BPNN）, is used to estimate the cluster membership probability in order to detect its tidal tails. Cluster and field stars, used for training the networks, are extracted over a 40 × 20 deg^2 field by color-magnitude diagrams （CMDs）. The best BPNNs with two hidden layers and a Levenberg-Marquardt （LM） training algorithm are determined by the chosen cluster and field samples. The membership probabilities of stars in the whole field are obtained with the BPNNs, and contour maps of the probability distribution show that a tail extends .5.42° to the north of the cluster and another tail extends 3.77° to the south. The tails are similar to those detected by Odenkirchen et al., but no more debris from the cluster is found to the northeast in the sky. The radial density profiles are investigated both along the tails and near the cluster center. Quite a few substructures are discovered in the tails. The number density profile of the cluster is fitted with the King model and the tidal radius is determined as 14.28＇. However, the King model cannot fit the observed profile at the outer regions （R 〉 8＇） because of the tidal tails generated by the tidal force. Luminosity functions of the cluster and the tidal tails are calculated, which confirm that the tails originate from Palomar 5.展开更多
The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by t...The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by the freezing-point depression method . The results of γ± are 0. 9945-0. 7695, it is in close agreement with that by isopiestic method.展开更多
Li[Li1/3Ti5/3O4] spinel-framework structure material is a kind of great interest for negative electrodes in energy storage cell. The synthesis of nanocrystalline Li[Li1/3Ti5/3O4] by sol-gel method using inorganic comp...Li[Li1/3Ti5/3O4] spinel-framework structure material is a kind of great interest for negative electrodes in energy storage cell. The synthesis of nanocrystalline Li[Li1/3Ti5/3O4] by sol-gel method using inorganic compounds and citric acid is developed, and single phase powder is obtained above 700 ℃. The electrochemical performances (of Li[Li1/3Ti5/3O4]) cathodes in lithium cell are studied. Special capacities are 131 mA·h·g-1 at 0.5C rate and 154 mA·h·g-1 at 0.1C in cycle test. No passivation layer is formed on Li[Li1/3Ti5/3O4] anode in lithium ion battery, and it is much safer than lithium metal and carbonaceous anodes. Faradic impedance in the charged cell is remarkably higher than that in discharged state, which is caused by distinct conductivities of Li[Li1/3Ti5/3O4] and (Li2[Li1/3Ti5/3O4].)展开更多
4,4-Dialkyl-2-oxazolin-5-ones are prepared by one step reaction of 2-oxazolin-5-one with the magnesium methyl carbonate(MMC)and alkyIhalides.It is a novel and convenient method for synthesis of α, Υ-disubstitutcd α...4,4-Dialkyl-2-oxazolin-5-ones are prepared by one step reaction of 2-oxazolin-5-one with the magnesium methyl carbonate(MMC)and alkyIhalides.It is a novel and convenient method for synthesis of α, Υ-disubstitutcd α-amino acid by hydrolysis of 4,4-dialkyl-2-oxazolin-5-ones.展开更多
In this letter, the φ^6 ＋ φ^5 model in （D ＋ 1） dimensions can be solved by a truncated series method. A series of solitary solutions of the φ^6 ＋ φ^5 model in （D ＋ 1） dimensions have be obtained.
Using a low power microwave generator and a surfatron discharge cavity, Ti3O5 was synthesized via the hydrogenation of TiO2 in surface wave induced microwave plasma. Besides, the chemical behavior of hydrogen in the p...Using a low power microwave generator and a surfatron discharge cavity, Ti3O5 was synthesized via the hydrogenation of TiO2 in surface wave induced microwave plasma. Besides, the chemical behavior of hydrogen in the plasma and its influence on the formation of Ti3O5 were preliminarily studied.展开更多
文摘食品加工过程中的美拉德反应有助于形成一些热诱导毒性产物,包括晚期糖基化终末产物(advanced glycation end products,AGEs)和5-羟甲基糠醛(5-hydroxymethylfurfural,5-HMF)。食源性AGEs在体内的积累和循环与糖尿病并发症的发生有关,同时可能诱发氧化应激、炎症和动脉粥样硬化。5-HMF的代谢物5-磺基氧甲基糠醛(5-sulfooxymethylfurfural,5-SMF)有潜在基因毒性和致癌性。如何控制热加工食品中这些危害物的形成已成为食品行业的关注焦点。本文从美拉德反应和焦糖化反应两条途径探究了AGEs和5-HMF的形成机理,并对近5年二者的检测方法进行了综述,阐述了各类方法的优缺点,以期为建立二者的通用检测方法奠定基础。在此基础上,从削减前体物质的供给、阻断中间体的转化,以及去除已经生成的AGEs和5-HMF这3个方面着手,综述了近年来相应所采用的抑制策略,以期为AGEs和5-HMF在食品中的控制及热加工食品质量与安全管理提供理论依据。
基金financial support from University of Tabriz and Iranian Nanotechnology Initiative
文摘A series of different transition metals(V,Co,Cr,Mn,Fe,Ni,Cu and Zn) promoted H-ZSM-5 catalysts were prepared by impregnation method and characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM) and transmission electron microscopy(TEM).The catalytic activity of these catalysts was evaluated for the selective catalytic reduction(SCR) of NO with NH_3 as reductant in the presence of oxygen.The results revealed that the catalytic activity of Cu-ZSM-5 nanocatalyst for NO conversion to N_2 was 80%at 300 ℃,which was the best among various promoted metals.Design of experiments(DOEs) with Taguchi method was employed to optimize NH_3-SCR process parameters such as NH_3/NO ratio,O_2 concentration,and gas hourly space velocity(GHSV) over Cu-ZSM-5 nanocatalyst at 250 and 300 ℃.Results showed that the most important parameter in NH_3-SCR of NO is O_2 concentration;followed by NH_3/NO ratio and GHSV has little importance.The NO conversion to N_2 of 63.1%and 94.86%was observed at 250℃ and 300℃,respectively under the obtained optimum conditions.
基金financially supported by the Science and Technology Research Project of Department of Education of Liaoning Province,China(No.L2011063)
文摘Nanocrystalline Gd3Ga5O12:Eu3+ with cubic phase was prepared by a urea homogeneous precipitation method. X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric and differential thermal analysis (TG-DTA) and photoluminescence spectra were used to characterize the samples. The effects of the initial solution pH value and urea content on the structure of the sample were studied. The XRD results show that pure phase Gd3Ga5O12 can be obtained at pH =6 and pH =8 of the initial solution. The average crystallite size can be calculated as in the range of 24~33 nm. The average crystallite size decreases with increasing molar ratio of urea to metal ion. The results of excitation spectra and emission spectra show that the emission peaks are ascribed to 5D0→7FJ transitions of Eu3+, and the magnetic dipole transition originated from 5D0 →7F1 of Eu3+ is the strongest; the broad excitation bands belong to change transfer band of Eu?O and the host absorption of Gd3Ga5O12. An efficient energy transfer occurs from Gd3+ to Eu3+.
基金Supported by Major State Basic Research Development Program of China (973 Program, No.2005CB4223-01) and Key Technologies R & D Program of China (No.2001BA603B-01).
文摘With the aid of Meteorological Information Composite and Processing System (MICAPS), satellite wind vectors derived from the Geostationary Meteorological Statellite-5 (GMS-5) and retrieved by National Satellite Meteorology Center of China (NSMC) can be obtained. Based on the nudging method built in the fifth-generation Mesoscale Model (MM5) of Pennsylvania State University and Na- tional Center for Atmospheric Research, a data preprocessor is developed to convert these satellite wind vectors to those with specified format required in MM5. To examine the data preprocessor and evaluate the impact of satellite winds from GMS-5 on MM5 simulations, a series of numerical experimental fore- casts consisting of four typhoon cases in 2002 are designed and implemented. The results show that the preprocessor can process satellite winds smoothly and MM5 model runs successfully with a little extra computational load during ingesting these winds, and that assimilation of satellite winds by MM5 nudging method can obviously improve typhoon track forecast but contributes a little to typhoon intensity forecast. The impact of the satellite winds depends heavily upon whether the typhoon bogussing scheme in MM5 was turned on or not. The data preprocessor developed in this paper not only can treat GMS-5 satellite winds but also has capability with little modification to process derived winds from other geostationary satellites.
基金Supported by the National Natural Science Foundation of China
文摘The sixth Data Release （DR6） of the Sloan Digital Sky Survey （SDSS） provides more photometric regions, new features and more accurate data around globular cluster Palomar 5. A new method, Back Propagation Neural Network （BPNN）, is used to estimate the cluster membership probability in order to detect its tidal tails. Cluster and field stars, used for training the networks, are extracted over a 40 × 20 deg^2 field by color-magnitude diagrams （CMDs）. The best BPNNs with two hidden layers and a Levenberg-Marquardt （LM） training algorithm are determined by the chosen cluster and field samples. The membership probabilities of stars in the whole field are obtained with the BPNNs, and contour maps of the probability distribution show that a tail extends .5.42° to the north of the cluster and another tail extends 3.77° to the south. The tails are similar to those detected by Odenkirchen et al., but no more debris from the cluster is found to the northeast in the sky. The radial density profiles are investigated both along the tails and near the cluster center. Quite a few substructures are discovered in the tails. The number density profile of the cluster is fitted with the King model and the tidal radius is determined as 14.28＇. However, the King model cannot fit the observed profile at the outer regions （R 〉 8＇） because of the tidal tails generated by the tidal force. Luminosity functions of the cluster and the tidal tails are calculated, which confirm that the tails originate from Palomar 5.
文摘The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by the freezing-point depression method . The results of γ± are 0. 9945-0. 7695, it is in close agreement with that by isopiestic method.
文摘Li[Li1/3Ti5/3O4] spinel-framework structure material is a kind of great interest for negative electrodes in energy storage cell. The synthesis of nanocrystalline Li[Li1/3Ti5/3O4] by sol-gel method using inorganic compounds and citric acid is developed, and single phase powder is obtained above 700 ℃. The electrochemical performances (of Li[Li1/3Ti5/3O4]) cathodes in lithium cell are studied. Special capacities are 131 mA·h·g-1 at 0.5C rate and 154 mA·h·g-1 at 0.1C in cycle test. No passivation layer is formed on Li[Li1/3Ti5/3O4] anode in lithium ion battery, and it is much safer than lithium metal and carbonaceous anodes. Faradic impedance in the charged cell is remarkably higher than that in discharged state, which is caused by distinct conductivities of Li[Li1/3Ti5/3O4] and (Li2[Li1/3Ti5/3O4].)
文摘4,4-Dialkyl-2-oxazolin-5-ones are prepared by one step reaction of 2-oxazolin-5-one with the magnesium methyl carbonate(MMC)and alkyIhalides.It is a novel and convenient method for synthesis of α, Υ-disubstitutcd α-amino acid by hydrolysis of 4,4-dialkyl-2-oxazolin-5-ones.
基金The project supported by National Natural Science Foundation of China under Grant No. 10575026.Acknowledgments The author thanks Prof. S.Y. Lou for helpful discussions.
文摘In this letter, the φ^6 ＋ φ^5 model in （D ＋ 1） dimensions can be solved by a truncated series method. A series of solitary solutions of the φ^6 ＋ φ^5 model in （D ＋ 1） dimensions have be obtained.
文摘Using a low power microwave generator and a surfatron discharge cavity, Ti3O5 was synthesized via the hydrogenation of TiO2 in surface wave induced microwave plasma. Besides, the chemical behavior of hydrogen in the plasma and its influence on the formation of Ti3O5 were preliminarily studied.
