Methylcyclopentenyl cations(MCP+)have been regarded as active intermediates during methanol conversion,however,their function mode in the reaction are still uncertain.In our recent report,trimethylcyclopentenyl cation...Methylcyclopentenyl cations(MCP+)have been regarded as active intermediates during methanol conversion,however,their function mode in the reaction are still uncertain.In our recent report,trimethylcyclopentenyl cation(triMCP+)and its deprotonated counterpart(trimethylcyclopentadiene,tri MCP)were directly captured on H-RUB-50 catalyst with small cavity by the aid of in situ 13C MAS NMR spectroscopy,and their higher catalytic reactivity were clarified by 12C/13C-CH3OH isotopic switch experiment.In this contribution,an alternative route-cyclopentadienes-based cycle was applied on methanol conversion catalyzed on the H-RUB-50,in which ethene was produced with the participation of tri MCP+as critical intermediate.Then the cyclopentadienes-based cycle was predicted to be energetically favorable for ethene formation by density functional theory(DFT)calculations.The energetic comparison of paring mechanism in the aromatics-based cycle and cyclopentadienes-based cycle with the involvements of trimethylcyclopentadienyl(tri MCPdi+)and tri MCP+as the corresponding active intermediates suggests that cyclopentadienes-based cycle is a feasible route for ethene formation.Furthermore,this work highlights the importance of the steric constraint and the host-guest interaction induced by the zeolite with cavity structure in the formation of intermediates and reaction pathway.展开更多
4-ary pulse amplitude modulation(4PAM) signals with 33% and 50% return-to-zero(RZ) clocks are generated for passive optical network(PON). We demonstrate that RZ-4PAM signals with duty cycles of 33% and 50% after trans...4-ary pulse amplitude modulation(4PAM) signals with 33% and 50% return-to-zero(RZ) clocks are generated for passive optical network(PON). We demonstrate that RZ-4PAM signals with duty cycles of 33% and 50% after transmission over 20-km-long single mode fiber(SMF) at 10 Gbit/s can be directly detected by using one photo detector,and the original data can also be restored by one M-ary threshold detector and one 4PAM sequence decoder. The optical spectra of 33% and 50% RZ-4PAM signals are measured,and their eye-diagrams before and after transmission are also analyzed. Simulation results show that 33% and 50% RZ-4PAM downlink signals can be received effectively,and the received power values are-15.1 d Bm and-13.8 d Bm when the bit error rate(BER) is 10^(-6). Moreover,33% RZ-4PAM optical signals have better reception performance than 50% RZ-4PAM optical signals.展开更多
基金the financial support from the National Natural Science Foundation of China(Nos.91745109,21703239 and 21972142)the Key Research Program of Frontier Sciences,CAS,Grant No.QYZDY-SSW-JSC024+2 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2014165)the International Partnership Program of Chinese Academy of Sciences,Grant No.121421KYSB20180007Liaoning Revitalization Talents Program(XLYC1807227)。
文摘Methylcyclopentenyl cations(MCP+)have been regarded as active intermediates during methanol conversion,however,their function mode in the reaction are still uncertain.In our recent report,trimethylcyclopentenyl cation(triMCP+)and its deprotonated counterpart(trimethylcyclopentadiene,tri MCP)were directly captured on H-RUB-50 catalyst with small cavity by the aid of in situ 13C MAS NMR spectroscopy,and their higher catalytic reactivity were clarified by 12C/13C-CH3OH isotopic switch experiment.In this contribution,an alternative route-cyclopentadienes-based cycle was applied on methanol conversion catalyzed on the H-RUB-50,in which ethene was produced with the participation of tri MCP+as critical intermediate.Then the cyclopentadienes-based cycle was predicted to be energetically favorable for ethene formation by density functional theory(DFT)calculations.The energetic comparison of paring mechanism in the aromatics-based cycle and cyclopentadienes-based cycle with the involvements of trimethylcyclopentadienyl(tri MCPdi+)and tri MCP+as the corresponding active intermediates suggests that cyclopentadienes-based cycle is a feasible route for ethene formation.Furthermore,this work highlights the importance of the steric constraint and the host-guest interaction induced by the zeolite with cavity structure in the formation of intermediates and reaction pathway.
基金supported by the National Natural Science Foundation of China(No.61107064)the Chongqing University Innovation Team Founding(No.KJTD201320)+3 种基金the Natural Science Foundation of Chongqing Science & Technology Commission(Nos.cstc2014jcyj A40046 and cstc2016jcyj A1233)the Science and Technology Special Funds of Wanzhou District in Chongqing Citythe Chongqing Graduate Student Research Innovation Project(No.CYS15225)the Chongqing Three Gorges University Graduate Scientific Research Innovation Project
文摘4-ary pulse amplitude modulation(4PAM) signals with 33% and 50% return-to-zero(RZ) clocks are generated for passive optical network(PON). We demonstrate that RZ-4PAM signals with duty cycles of 33% and 50% after transmission over 20-km-long single mode fiber(SMF) at 10 Gbit/s can be directly detected by using one photo detector,and the original data can also be restored by one M-ary threshold detector and one 4PAM sequence decoder. The optical spectra of 33% and 50% RZ-4PAM signals are measured,and their eye-diagrams before and after transmission are also analyzed. Simulation results show that 33% and 50% RZ-4PAM downlink signals can be received effectively,and the received power values are-15.1 d Bm and-13.8 d Bm when the bit error rate(BER) is 10^(-6). Moreover,33% RZ-4PAM optical signals have better reception performance than 50% RZ-4PAM optical signals.
