Through controlled mechanical alloying treatment, TiFe and LaNi5 particles combined together on the surface of TiFe. This kind of compound particles can be easily activated at room temperature and an H2-pressure of 4...Through controlled mechanical alloying treatment, TiFe and LaNi5 particles combined together on the surface of TiFe. This kind of compound particles can be easily activated at room temperature and an H2-pressure of 4.0 MPa. LaNi5 particles provided 'window' and 'path' for entrance of hydrogen from the surface to the interior of TiFe alloy.展开更多
The ultrafine Mo-Y_(2)O_(3)composite powders were successfully synthesized by innovative freeze-drying method.Consequently,the freeze-dried Mo-Y_(2)O_(3)composite powders with high sintering activities possess an aver...The ultrafine Mo-Y_(2)O_(3)composite powders were successfully synthesized by innovative freeze-drying method.Consequently,the freeze-dried Mo-Y_(2)O_(3)composite powders with high sintering activities possess an average grain size of 54 nm.After low temperature sintering at 1600°C,the Mo-Y_(2)O_(3)alloys maintaining a high density(99.6%)have the finest grain size(620 nm)comparing with available literature about oxide dispersion strengthened molybdenum alloy(ODS-Mo).The oxide particles remain their small size(mainly<50 nm)within Mo grains and at Mo grain boundaries.Furthermore,the Y_(5)MO_(2)O_(12)particles were firstly observed within Mo matrix,and its formation can absorb nearby oxygen impurities,which involves the purification of Mo matrix.The mechanical properties show that Mo-Y_(2)O_(3)alloy possess a high hardness of 487±28 HV_(0.2),a high yield strength of 902 MPa,a high compressive strength of1110 MPa,respectively.Our work suggests that freeze-drying and subsequent low temperature sintering can shed light on the preparation of ultrafine ODS-Mo alloys with high performance.展开更多
文摘Through controlled mechanical alloying treatment, TiFe and LaNi5 particles combined together on the surface of TiFe. This kind of compound particles can be easily activated at room temperature and an H2-pressure of 4.0 MPa. LaNi5 particles provided 'window' and 'path' for entrance of hydrogen from the surface to the interior of TiFe alloy.
基金the National Natural Science Foundation of China(No.51822404)the Natural Science Foundation of Tianjin(No.18JCYBJC17900)+1 种基金supported by the Science and Technology Program of Tianjin(Nos.19YFZCGX00790 and 18YFZCGX00070)Researchers Supporting Project number(No.RSP-2021/6),King Saud University,Riyadh,Saudi Arabia。
文摘The ultrafine Mo-Y_(2)O_(3)composite powders were successfully synthesized by innovative freeze-drying method.Consequently,the freeze-dried Mo-Y_(2)O_(3)composite powders with high sintering activities possess an average grain size of 54 nm.After low temperature sintering at 1600°C,the Mo-Y_(2)O_(3)alloys maintaining a high density(99.6%)have the finest grain size(620 nm)comparing with available literature about oxide dispersion strengthened molybdenum alloy(ODS-Mo).The oxide particles remain their small size(mainly<50 nm)within Mo grains and at Mo grain boundaries.Furthermore,the Y_(5)MO_(2)O_(12)particles were firstly observed within Mo matrix,and its formation can absorb nearby oxygen impurities,which involves the purification of Mo matrix.The mechanical properties show that Mo-Y_(2)O_(3)alloy possess a high hardness of 487±28 HV_(0.2),a high yield strength of 902 MPa,a high compressive strength of1110 MPa,respectively.Our work suggests that freeze-drying and subsequent low temperature sintering can shed light on the preparation of ultrafine ODS-Mo alloys with high performance.