Novel compounds, （3,6-dichloro-2-nitrophenyl）（3-nitrophenyl）methanone（2）, （2-amino-3,6-dichloro- phenyl）（3-aminophenyl）methanone（3） and 1-[3-（2-amino-3,6-dichlorobenzoyl）phenyl]-1H-pyrrole-2,5-dione（4）...Novel compounds, （3,6-dichloro-2-nitrophenyl）（3-nitrophenyl）methanone（2）, （2-amino-3,6-dichloro- phenyl）（3-aminophenyl）methanone（3） and 1-[3-（2-amino-3,6-dichlorobenzoyl）phenyl]-1H-pyrrole-2,5-dione（4）, were synthesized from the initial compound 2,5-dichlorobenzophenone（1） and characterized by 1H NMR, 13C NMR, IR, mass spectrum and element analysis, respectively. The single crystal of compound 2 was obtained and determined by X-ray diffraction analysis. The single crystal data illustrates that it belongs to the monoclinic system, space group P21/c with a=0.7587（4） nm, b=2.4724（4） nm, c=0.8081（3） nm, α=90°, β=112.85（2）°, γ=90o, V=1.3970（9） nm3, Z=4, Dc=1.622 g/cm3, Mr（C13H6Cl2N2O5）=341.10, μ（Mo Kα）=0.49 mm？1, F（000）=688, the final R=0.048 and wR=0.144 for 1665 observed reflections with I2σ（I）. The title molecule forms a ＂T＂ type crystal structure and the dihedral angel of the two phenyl rings is 65.0（1）°.展开更多
A new triazene reagent 1-(6-ethoxyl-2-benzothiazolyl)-3-(4-nitrophenyl)-triazene (EtOBThTPT) has been synthesized. The colour reaction of EtOBTNPT with Hg(II) has been studied. At pH = 10.1-10.7, in the presence of Tr...A new triazene reagent 1-(6-ethoxyl-2-benzothiazolyl)-3-(4-nitrophenyl)-triazene (EtOBThTPT) has been synthesized. The colour reaction of EtOBTNPT with Hg(II) has been studied. At pH = 10.1-10.7, in the presence of Triton X-100, the reagent with Hg(II) forms an orange-yellow complex with high sensitivity. The molar absorptivity is 2.38 X 10(5) L.mol(-1).cm(-1). Beer's law is obeyed for Hg(II) in the range of 0-7 mu g/25 ml.展开更多
This paper introduces the synthesis of a new color reagent 1-(6-nitro-2-benzothiazolyl)3-(4-nitrophenyl)-triazene (NBTNPT) and the color reaction of NBTNPT with Cd (II) has been studied. In the presence of Triton X-10...This paper introduces the synthesis of a new color reagent 1-(6-nitro-2-benzothiazolyl)3-(4-nitrophenyl)-triazene (NBTNPT) and the color reaction of NBTNPT with Cd (II) has been studied. In the presence of Triton X-100, the reagent with Cd (II) forms an orange-yellow complex (1:1) at pH=11.5-12.3, the molar absorptivity is 2.81x10(5)L . mol(-1)m(-1) by dual-wavelength spectrophotometry, Beers law is obeyed in the range of 0-280 mu g/L for Cd (II).展开更多
文摘Novel compounds, （3,6-dichloro-2-nitrophenyl）（3-nitrophenyl）methanone（2）, （2-amino-3,6-dichloro- phenyl）（3-aminophenyl）methanone（3） and 1-[3-（2-amino-3,6-dichlorobenzoyl）phenyl]-1H-pyrrole-2,5-dione（4）, were synthesized from the initial compound 2,5-dichlorobenzophenone（1） and characterized by 1H NMR, 13C NMR, IR, mass spectrum and element analysis, respectively. The single crystal of compound 2 was obtained and determined by X-ray diffraction analysis. The single crystal data illustrates that it belongs to the monoclinic system, space group P21/c with a=0.7587（4） nm, b=2.4724（4） nm, c=0.8081（3） nm, α=90°, β=112.85（2）°, γ=90o, V=1.3970（9） nm3, Z=4, Dc=1.622 g/cm3, Mr（C13H6Cl2N2O5）=341.10, μ（Mo Kα）=0.49 mm？1, F（000）=688, the final R=0.048 and wR=0.144 for 1665 observed reflections with I2σ（I）. The title molecule forms a ＂T＂ type crystal structure and the dihedral angel of the two phenyl rings is 65.0（1）°.
文摘A new triazene reagent 1-(6-ethoxyl-2-benzothiazolyl)-3-(4-nitrophenyl)-triazene (EtOBThTPT) has been synthesized. The colour reaction of EtOBTNPT with Hg(II) has been studied. At pH = 10.1-10.7, in the presence of Triton X-100, the reagent with Hg(II) forms an orange-yellow complex with high sensitivity. The molar absorptivity is 2.38 X 10(5) L.mol(-1).cm(-1). Beer's law is obeyed for Hg(II) in the range of 0-7 mu g/25 ml.
文摘This paper introduces the synthesis of a new color reagent 1-(6-nitro-2-benzothiazolyl)3-(4-nitrophenyl)-triazene (NBTNPT) and the color reaction of NBTNPT with Cd (II) has been studied. In the presence of Triton X-100, the reagent with Cd (II) forms an orange-yellow complex (1:1) at pH=11.5-12.3, the molar absorptivity is 2.81x10(5)L . mol(-1)m(-1) by dual-wavelength spectrophotometry, Beers law is obeyed in the range of 0-280 mu g/L for Cd (II).
