The first binuclear iron fullerene derivative of(η 2 C 60 )[Fe(CO) 2(C 5H 5)] 2 , which was yellow brown and sensitive to air and moisture, was prepared by the reaction of trans [Fe(CO) 2(C 5H 5)] 2 with C 60 in benz...The first binuclear iron fullerene derivative of(η 2 C 60 )[Fe(CO) 2(C 5H 5)] 2 , which was yellow brown and sensitive to air and moisture, was prepared by the reaction of trans [Fe(CO) 2(C 5H 5)] 2 with C 60 in benzene under an atmosphere of dried nitrogen using conventional Schlenk techniques and has been characterized by using elementary analysis and IR, 1H NMR, 13 C NMR and XPS spectra. The infrared spectrum of the title compound indicates the disappearance of ν CO at 1 760 cm -1 for bridge carbonyl and the appearance of the only terminal CO lying at a higher wave number than that of the starting material, which reveals the electron deficient behavior of C 60 . And the important 1H, 13 C NMR chemical shift and XPS of trans [Fe(CO) 2(C 5H 5)] 2 , C 60 and its novel complex along with their relative assignments are briefly discussed.展开更多
The ability of water soluble β alanine C 60 adducts for superoxide anion radical scavenging has been studied by spectrophotometry and the modified pyrogallol auto oxidation method. It is found that β alanine C 60 ad...The ability of water soluble β alanine C 60 adducts for superoxide anion radical scavenging has been studied by spectrophotometry and the modified pyrogallol auto oxidation method. It is found that β alanine C 60 adducts have an excellent efficiency in eliminating superoxide radical generated from auto oxidation of pyrogallol. At a mass concentration level of 150 μg/mL for β alanine C 60 adducts, the radical scavenging efficiency is approximately equivalent to one enzyme unit, in vitro experiments show that β alanine C 60 adducts can enhance the activity of mouse thymus cells and prolong their life time span. It reveals the potential use of these β alanine C 60 adducts as the novel potent free radical scavengers in biological systems.展开更多
The fullerene complex, η 2 C 60 [Ru(NO)(PPh 3)] 2, has been prepared by the reaction of C 60 with Ru(NO) 2(PPh 3) 2 under a nitrogen atmosphere and refluxing. The new complex was characterized by means of elemental a...The fullerene complex, η 2 C 60 [Ru(NO)(PPh 3)] 2, has been prepared by the reaction of C 60 with Ru(NO) 2(PPh 3) 2 under a nitrogen atmosphere and refluxing. The new complex was characterized by means of elemental analysis, IR, XPS, electronic spectra and 31 P NMR. The results show that the complex of η 2 form can be formed by C 60 bonding to Ru(NO) 2(PPh 3) 2 in the σ π way and there is hyperconjugation effect in the molecule. So electrons will flow easier and photoelectric effect for this new compound is expected. In addition, the structure of the complex has been supposed. The ruthenium is 4 coordinate in the complex, bonding to two carbon atoms, to one PPh 3 and to one NO.展开更多
A series of styrene/acrylamide copolymers were synthesized. The PAm molar fraction in copolymers varies from 1 8% to 33%. Then the C 60 containing copolymers were obtained by the reaction of St/Am copolymer with C 60 ...A series of styrene/acrylamide copolymers were synthesized. The PAm molar fraction in copolymers varies from 1 8% to 33%. Then the C 60 containing copolymers were obtained by the reaction of St/Am copolymer with C 60 in toluene at 30 ℃ and 80 ℃, respectively. The products are orange or brown powders and soluble in common solvents, such as CH 2Cl 2, CHCl 3, toluene, THF etc .. The C 60 moiety in copolymers varies from 0 49% to 1 45%(weight percentage ratio). The results also show that with the increase of mole percentage of amide group in copolymers, the weight percentage of C 60 increases while the C 60 /amide mole ratios in copolymers decline. In addition, raising the reaction temperature enhances the reactivity. The UV Vis spectra show that C 60 containing copolymers have a stronger adsorption from 400 nm to 500 nm than pure C 60 and C 60 doped copolymers have. Increasing the C 60 content in those samples, the characteristic peak of C 60 at 330 nm was suppressed gradually by a strong wide adsorption band from 290 nm to 350 nm, which reveals that amide group can react with C 60 and the C 60 is chemically bonded to the copolymers.展开更多
In this paper, a novel synthetic strategy was developed to prepare functional polyphosphazenes. This strategy was successfully applied to synthesize the first C 60-contained polyphosphazenes. Thus, polyphosphazene tha...In this paper, a novel synthetic strategy was developed to prepare functional polyphosphazenes. This strategy was successfully applied to synthesize the first C 60-contained polyphosphazenes. Thus, polyphosphazene that contains azido groups as the side groups was obtained by a direct reaction. And then the azido groups reacted with C 60 moieties to yield the C 60-contained polyphosphazenes. The polymers were well characterized and exhibit an excellent solubility in common organic solvents.展开更多
文摘The first binuclear iron fullerene derivative of(η 2 C 60 )[Fe(CO) 2(C 5H 5)] 2 , which was yellow brown and sensitive to air and moisture, was prepared by the reaction of trans [Fe(CO) 2(C 5H 5)] 2 with C 60 in benzene under an atmosphere of dried nitrogen using conventional Schlenk techniques and has been characterized by using elementary analysis and IR, 1H NMR, 13 C NMR and XPS spectra. The infrared spectrum of the title compound indicates the disappearance of ν CO at 1 760 cm -1 for bridge carbonyl and the appearance of the only terminal CO lying at a higher wave number than that of the starting material, which reveals the electron deficient behavior of C 60 . And the important 1H, 13 C NMR chemical shift and XPS of trans [Fe(CO) 2(C 5H 5)] 2 , C 60 and its novel complex along with their relative assignments are briefly discussed.
文摘The ability of water soluble β alanine C 60 adducts for superoxide anion radical scavenging has been studied by spectrophotometry and the modified pyrogallol auto oxidation method. It is found that β alanine C 60 adducts have an excellent efficiency in eliminating superoxide radical generated from auto oxidation of pyrogallol. At a mass concentration level of 150 μg/mL for β alanine C 60 adducts, the radical scavenging efficiency is approximately equivalent to one enzyme unit, in vitro experiments show that β alanine C 60 adducts can enhance the activity of mouse thymus cells and prolong their life time span. It reveals the potential use of these β alanine C 60 adducts as the novel potent free radical scavengers in biological systems.
文摘The fullerene complex, η 2 C 60 [Ru(NO)(PPh 3)] 2, has been prepared by the reaction of C 60 with Ru(NO) 2(PPh 3) 2 under a nitrogen atmosphere and refluxing. The new complex was characterized by means of elemental analysis, IR, XPS, electronic spectra and 31 P NMR. The results show that the complex of η 2 form can be formed by C 60 bonding to Ru(NO) 2(PPh 3) 2 in the σ π way and there is hyperconjugation effect in the molecule. So electrons will flow easier and photoelectric effect for this new compound is expected. In addition, the structure of the complex has been supposed. The ruthenium is 4 coordinate in the complex, bonding to two carbon atoms, to one PPh 3 and to one NO.
文摘A series of styrene/acrylamide copolymers were synthesized. The PAm molar fraction in copolymers varies from 1 8% to 33%. Then the C 60 containing copolymers were obtained by the reaction of St/Am copolymer with C 60 in toluene at 30 ℃ and 80 ℃, respectively. The products are orange or brown powders and soluble in common solvents, such as CH 2Cl 2, CHCl 3, toluene, THF etc .. The C 60 moiety in copolymers varies from 0 49% to 1 45%(weight percentage ratio). The results also show that with the increase of mole percentage of amide group in copolymers, the weight percentage of C 60 increases while the C 60 /amide mole ratios in copolymers decline. In addition, raising the reaction temperature enhances the reactivity. The UV Vis spectra show that C 60 containing copolymers have a stronger adsorption from 400 nm to 500 nm than pure C 60 and C 60 doped copolymers have. Increasing the C 60 content in those samples, the characteristic peak of C 60 at 330 nm was suppressed gradually by a strong wide adsorption band from 290 nm to 350 nm, which reveals that amide group can react with C 60 and the C 60 is chemically bonded to the copolymers.
文摘In this paper, a novel synthetic strategy was developed to prepare functional polyphosphazenes. This strategy was successfully applied to synthesize the first C 60-contained polyphosphazenes. Thus, polyphosphazene that contains azido groups as the side groups was obtained by a direct reaction. And then the azido groups reacted with C 60 moieties to yield the C 60-contained polyphosphazenes. The polymers were well characterized and exhibit an excellent solubility in common organic solvents.
