Plasma spray-physical vapor deposition（PS-PVD） as a novel coating process based on low-pressure plasma spray（LPPS） has been significantly used for thermal barrier coatings（TBCs）.A coating can be deposited from l...Plasma spray-physical vapor deposition（PS-PVD） as a novel coating process based on low-pressure plasma spray（LPPS） has been significantly used for thermal barrier coatings（TBCs）.A coating can be deposited from liquid splats, nano-sized clusters, and the vapor phase forming different structured coatings, which shows obvious advantages in contrast to conventional technologies like atmospheric plasma spray（APS） and electron beam-physical vapor deposition（EBPVD）. In addition, it can be used to produce thin, dense, and porous ceramic coatings for special applications because of its special characteristics, such as high power, very low pressure, etc. These provide new opportunities to obtain different advanced microstructures, thus to meet the growing requirements of modern functional coatings. In this work, focusing on exploiting the potential of gas-phase deposition from PS-PVD, a series of 7 YSZ coating experiments with various process conditions was performed in order to better understand the deposition process in PS-PVD, where coatings were deposited on different substrates including graphite and zirconia. Meanwhile, various substrate temperatures were investigated for the same substrate. As a result, a deposition mechanism of heterogeneous nucleation has been presented showing that surface energy is an important influencing factor for coating structures. Besides, undercooling of the interface between substrate and vapor phase plays an important role in coating structures.展开更多
7 YSZ coating was prepared by plasma sprayphysical vapor deposition(PS-PVD) technique based on a specific experimental design.The microstructure and deposition properties of 7 YSZ coating along the radius of plasma je...7 YSZ coating was prepared by plasma sprayphysical vapor deposition(PS-PVD) technique based on a specific experimental design.The microstructure and deposition properties of 7 YSZ coating along the radius of plasma jet were investigated in detail.Results show that the coating presents regional characteristic in the radial direction,which could be divided into three typical zones:In Zone Ⅰ,the coating is all composed of columnar structures with cauliflower structure,and the coating properties including the surface roughness and deposition efficiency(DE) are almost stable;in Zone Ⅲ,the coating is made up of solid particles,droplet and gas phase mixed without columnar structures;Zone Ⅱ is between Zone Ⅰ and ZoneⅢ, in which there are columns with domed top and small particles.Based on experiment results,a model on the state and distribution of particles in plasma jet was proposed to clarify the regional characteristic.This study is helpful to comprehend and control coatings deposition by PS-PVD technique.展开更多
The plasma sprayed ZrO2-7 wt%Y2O3(7YSZ)coating has been widely applied in aircraft engine as a thermal barrier coating.In this study,the duplex TBC system(MCrAlY+7YSZ)were deposited onto 304 stainless steel substrate ...The plasma sprayed ZrO2-7 wt%Y2O3(7YSZ)coating has been widely applied in aircraft engine as a thermal barrier coating.In this study,the duplex TBC system(MCrAlY+7YSZ)were deposited onto 304 stainless steel substrate by APS.Four principal spraying parameters during the deposition of 7YSZ coating were optimized by using orthogonal experimental design,including the stand-off distance,plasma power,preheating temperature and powder feeding rate.Their influences on the coating's microstructure,adhesion and its mechanical properties were studied and the optimized parameters were finally obtained.The results showed that the dependence of the spraying parameters on the properties of 7YSZ coating is highly correlated to the melting condition of the in-flight particles.展开更多
基金Project(2012CB625100)supported by the National Basic Research Program of ChinaProject(2012AA03A512)supported by the National High-tech Research and Development Program of China
基金financially supported by the National Key Research Program(2017YFB0306100)the Project of Guangdong Academy of Sciences(2017GDASCX-0843,2017GDASCX-0202)+2 种基金the Guangdong Science and Technology Research Project(2014B070706026)Guangdong Natural Science Foundation(2016A030312015,2017A030310315)Guangzhou Science and Technology Research Project(201605131008557,201707010385,201510010095)~~
基金financial supports from National Key Research Program (2017YFB0306100)Guangdong Academy of Sciences (No. 2017GDASCX-0843)+3 种基金Guangdong Technical Research Program (Nos. 201707010385, 2014B070706026, 2013B061800053)Guangdong Natural Science Foundation (No. 2016A030312015)National Natural Science Foundation of China (No. 51501044)Guangzhou Technical Research Program (No. 201707010385)
文摘Plasma spray-physical vapor deposition（PS-PVD） as a novel coating process based on low-pressure plasma spray（LPPS） has been significantly used for thermal barrier coatings（TBCs）.A coating can be deposited from liquid splats, nano-sized clusters, and the vapor phase forming different structured coatings, which shows obvious advantages in contrast to conventional technologies like atmospheric plasma spray（APS） and electron beam-physical vapor deposition（EBPVD）. In addition, it can be used to produce thin, dense, and porous ceramic coatings for special applications because of its special characteristics, such as high power, very low pressure, etc. These provide new opportunities to obtain different advanced microstructures, thus to meet the growing requirements of modern functional coatings. In this work, focusing on exploiting the potential of gas-phase deposition from PS-PVD, a series of 7 YSZ coating experiments with various process conditions was performed in order to better understand the deposition process in PS-PVD, where coatings were deposited on different substrates including graphite and zirconia. Meanwhile, various substrate temperatures were investigated for the same substrate. As a result, a deposition mechanism of heterogeneous nucleation has been presented showing that surface energy is an important influencing factor for coating structures. Besides, undercooling of the interface between substrate and vapor phase plays an important role in coating structures.
基金financially supported by Guangdong Natural Science Foundation (No.2016A030312015)the Science and Technology Cooperation Project of Guangdong Province (No.2013B050800027)the Science and Technology Cooperation Project of Guangzhou (No.201508030001)。
文摘7 YSZ coating was prepared by plasma sprayphysical vapor deposition(PS-PVD) technique based on a specific experimental design.The microstructure and deposition properties of 7 YSZ coating along the radius of plasma jet were investigated in detail.Results show that the coating presents regional characteristic in the radial direction,which could be divided into three typical zones:In Zone Ⅰ,the coating is all composed of columnar structures with cauliflower structure,and the coating properties including the surface roughness and deposition efficiency(DE) are almost stable;in Zone Ⅲ,the coating is made up of solid particles,droplet and gas phase mixed without columnar structures;Zone Ⅱ is between Zone Ⅰ and ZoneⅢ, in which there are columns with domed top and small particles.Based on experiment results,a model on the state and distribution of particles in plasma jet was proposed to clarify the regional characteristic.This study is helpful to comprehend and control coatings deposition by PS-PVD technique.
文摘The plasma sprayed ZrO2-7 wt%Y2O3(7YSZ)coating has been widely applied in aircraft engine as a thermal barrier coating.In this study,the duplex TBC system(MCrAlY+7YSZ)were deposited onto 304 stainless steel substrate by APS.Four principal spraying parameters during the deposition of 7YSZ coating were optimized by using orthogonal experimental design,including the stand-off distance,plasma power,preheating temperature and powder feeding rate.Their influences on the coating's microstructure,adhesion and its mechanical properties were studied and the optimized parameters were finally obtained.The results showed that the dependence of the spraying parameters on the properties of 7YSZ coating is highly correlated to the melting condition of the in-flight particles.
