Mechanical properties of quenching,intercritical quenching and tempering （QLT） treated steel containing Ni of 9% were evaluated from specimens subject to various tempering temperatures. The detailed microstructures ...Mechanical properties of quenching,intercritical quenching and tempering （QLT） treated steel containing Ni of 9% were evaluated from specimens subject to various tempering temperatures. The detailed microstructures of steel containing Ni of 9% at different tempering temperatures were observed by optical microscope （OM） and transmission electron microscope （TEM）. The volume fraction of austenite was estimated by XRD. The results show that high strength and cryogenic toughness of steel containing Ni of 9% are obtained when the tempering temperature are between 540 and 580 ℃. The microstructure keeps the dual phase lamellar structure after the intercritical quenching and there is cementite created in the Ni-rich constituents when tempering temperature is 540 ℃. When tempering temperatures are between 560 and 580 ℃,the reversed austenites （γ′） grow up and the dual phase lamellar structure is not clear. The γ′ becomes instable at 600 ℃. When tempered at temperature ranging from 500 to 520 ℃,the increase of dislocation density in the lamellar matrix makes both tensile strength and yield strength decrease. When tempered at 540 ℃ and higher temperature,the yield strength decreases continuously because the C and alloying elements in the matrix are absorbed by the cementite and the γ′,so the yield ratio is decreased by the γ′. There are two toughness mechanisms at different tempering temperatures. One is that the precipitation of cementite absorbs the carbon in the steel which plays a major role in improving cryogenic toughness at lower temperature. Another is that the γ′ and the purified matrix become major role at higher tempering temperature. When the tempering temperature is 600 ℃,the stability of γ′ is decreased quickly,even the transformation takes place at room temperature,which results in a sharp decrease of Charpy-V impact energy at 77 K. The tempering temperature range is enlarged by the special distribution of cementite and the lamellar structure.展开更多
Many applications operate at sufficiently low temperature conditions where most structural steels become very brittle and, therefore, unsuitable for use in safety-critical structures. So the materials used in the vess...Many applications operate at sufficiently low temperature conditions where most structural steels become very brittle and, therefore, unsuitable for use in safety-critical structures. So the materials used in the vessels or storage tanks which keep the natural gas at liquefaction temperatures need to remain ductile and crack resistant with a high level of safety. The material also needs to have high strength in order to reduce the wall thickness of the container and it must permit welding without any risk of brittle fracture. 9% Ni steel plates are one of most common used materials in the LNG storage tank application. However, the welding procedure for 9% Ni steel plates requires high level of skills of welding that is strictly controlled welding parameter for balancing avoidance of cold and hot cracking and maintenance of high strength. Mechanical properties are important characteristics of the weldment that must confirm to the application feasibility as well as functional requirements of the welded joint. The only way to enhanced the mechanical properties of welded joint by controlling the parameters of using welding process. From the main variables of the arc welding process are the heat input and interpass temperature where the two variables control the thermal cycle of welding process. The experiment show that for thin test specimen with thickness ≤ 14 mm, the heat input range from 1.4 to 2 KJ/mm and controlling interpass temperature within 80°C give high tensile strength with improving the toughness properties of welded joint and reduce the probability of brittle fracture happened by increase the ductility and reduce the yield strength and increased the transition temperature.展开更多
基金Item Sponsored by National High Technology Research and Development Program of China (2007AA03Z506)
文摘Mechanical properties of quenching,intercritical quenching and tempering （QLT） treated steel containing Ni of 9% were evaluated from specimens subject to various tempering temperatures. The detailed microstructures of steel containing Ni of 9% at different tempering temperatures were observed by optical microscope （OM） and transmission electron microscope （TEM）. The volume fraction of austenite was estimated by XRD. The results show that high strength and cryogenic toughness of steel containing Ni of 9% are obtained when the tempering temperature are between 540 and 580 ℃. The microstructure keeps the dual phase lamellar structure after the intercritical quenching and there is cementite created in the Ni-rich constituents when tempering temperature is 540 ℃. When tempering temperatures are between 560 and 580 ℃,the reversed austenites （γ′） grow up and the dual phase lamellar structure is not clear. The γ′ becomes instable at 600 ℃. When tempered at temperature ranging from 500 to 520 ℃,the increase of dislocation density in the lamellar matrix makes both tensile strength and yield strength decrease. When tempered at 540 ℃ and higher temperature,the yield strength decreases continuously because the C and alloying elements in the matrix are absorbed by the cementite and the γ′,so the yield ratio is decreased by the γ′. There are two toughness mechanisms at different tempering temperatures. One is that the precipitation of cementite absorbs the carbon in the steel which plays a major role in improving cryogenic toughness at lower temperature. Another is that the γ′ and the purified matrix become major role at higher tempering temperature. When the tempering temperature is 600 ℃,the stability of γ′ is decreased quickly,even the transformation takes place at room temperature,which results in a sharp decrease of Charpy-V impact energy at 77 K. The tempering temperature range is enlarged by the special distribution of cementite and the lamellar structure.
文摘Many applications operate at sufficiently low temperature conditions where most structural steels become very brittle and, therefore, unsuitable for use in safety-critical structures. So the materials used in the vessels or storage tanks which keep the natural gas at liquefaction temperatures need to remain ductile and crack resistant with a high level of safety. The material also needs to have high strength in order to reduce the wall thickness of the container and it must permit welding without any risk of brittle fracture. 9% Ni steel plates are one of most common used materials in the LNG storage tank application. However, the welding procedure for 9% Ni steel plates requires high level of skills of welding that is strictly controlled welding parameter for balancing avoidance of cold and hot cracking and maintenance of high strength. Mechanical properties are important characteristics of the weldment that must confirm to the application feasibility as well as functional requirements of the welded joint. The only way to enhanced the mechanical properties of welded joint by controlling the parameters of using welding process. From the main variables of the arc welding process are the heat input and interpass temperature where the two variables control the thermal cycle of welding process. The experiment show that for thin test specimen with thickness ≤ 14 mm, the heat input range from 1.4 to 2 KJ/mm and controlling interpass temperature within 80°C give high tensile strength with improving the toughness properties of welded joint and reduce the probability of brittle fracture happened by increase the ductility and reduce the yield strength and increased the transition temperature.
