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^(93)Nb核磁共振研究铌酸纳米棒的水热晶化机理
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作者 申长志 张琳琳 +1 位作者 李新 申万岭 《波谱学杂志》 CAS 北大核心 2023年第4期376-384,共9页
氧化铌(Nb_(2)O_(5))及其水合物铌酸(Nb_(2)O_(5)·n H_(2)O)代表了一类重要的多相催化剂,然而其水热合成过程和机理尚不明确.本文采用^(93)Nb NMR,结合X射线粉末衍射、透射电镜等技术和量化计算,研究了以草酸铌铵为前驱体水热生成... 氧化铌(Nb_(2)O_(5))及其水合物铌酸(Nb_(2)O_(5)·n H_(2)O)代表了一类重要的多相催化剂,然而其水热合成过程和机理尚不明确.本文采用^(93)Nb NMR,结合X射线粉末衍射、透射电镜等技术和量化计算,研究了以草酸铌铵为前驱体水热生成铌酸纳米棒的晶化过程.结果表明草酸铌铵水热晶化过程中发生了水解-聚合反应,先是草酸铌铵水解,接着铌氧单体之间发生缩水聚合反应,最终生成了层内无序、层间有序结构的固体铌酸纳米棒.晶化过程符合“液相成核”机理,层状结构铌酸纳米棒在180℃下1 h内即可生成,后续水热处理并未使其明显长大,新的固体产物不断由溶液中独立生成. 展开更多
关键词 ^(93)Nb核磁共振 纳米氧化铌 草酸铌铵 水热 晶化机理
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Low-lying states of 92,93Nb excited in the reactions induced by the weakly-bound nucleus 6Li near the Coulomb barrier
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作者 吕翌丰 陆景彬 +22 位作者 张高龙 吴义恒 袁岑溪 傅冠健 张广鑫 黄珍 王明李 胡世鹏 孙慧斌 张焕乔 李成乾 马克岩 马英君 刘运祚 D.Testov P.R.John J.J.Valiente-Dobon A.Goasduff M.Siciliano F.Galtarossa F.Recchia D.Mengoni D.Bazzacco 《Chinese Physics C》 SCIE CAS CSCD 2019年第10期69-77,共9页
Excited states of odd-odd nucleus 92Nb and odd-A nucleus 93Nb were populated in the 6Li+ 89Y reaction with an incident energy of 34 MeV. The processes that produce 92,93Nb and can be measured by a combination of light... Excited states of odd-odd nucleus 92Nb and odd-A nucleus 93Nb were populated in the 6Li+ 89Y reaction with an incident energy of 34 MeV. The processes that produce 92,93Nb and can be measured by a combination of light charged particle and gamma ray measurements are discussed. Twenty new transitions are observed and eight new levels are constructed in 92Nb, and in addition two new transitions are added to the level scheme of 93Nb. Using shell model calculations, the low-lying structure of 92Nb is investigated and compared with the experimental results. 展开更多
关键词 weakly-bound projectile COINCIDENCE measurement level structure ODD-ODD NUCLEUS 92Nb odd-A NUCLEUS 93nb.
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46MeV/A^(12)C和^(93)Nb相互作用中线性动量转移 被引量:5
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作者 李文新 孙彤玉 +5 位作者 孙儒林 吴定清 靳根明 赵莉莉 李宗伟 秦芝 《高能物理与核物理》 CSCD 北大核心 1990年第12期1110-1116,共7页
使用离线γ能谱法测定了46MeV/A^(12)C离子和^(93)Nb相互作用中厚靶反冲射程,得到了最大线性动量转移和平均线性动量转移,和已有工作比较后指出,相应于中心碰撞的最大线性动量转移在轻靶和中重靶范围内与靶质量无关,但明显低于与^(238)... 使用离线γ能谱法测定了46MeV/A^(12)C离子和^(93)Nb相互作用中厚靶反冲射程,得到了最大线性动量转移和平均线性动量转移,和已有工作比较后指出,相应于中心碰撞的最大线性动量转移在轻靶和中重靶范围内与靶质量无关,但明显低于与^(238)U碰撞的线性动量转移.平均线性动量转移显示了与弹核和靶核不对称性的强烈依赖关系. 展开更多
关键词 46MeV/A^12C ^93nb 相互作用
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Cross-section measurement for the ^(93)Nb(n,2n)^(92g)Nb reaction at the neutron energy of 14.6 MeV by the AMS method
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作者 贺国珠 石斌 +10 位作者 何明 李振宇 刘世龙 陈雄军 阮锡超 张奇玮 樊启文 李恒 武绍勇 姜山 周祖英 《Chinese Physics C》 SCIE CAS CSCD 2018年第7期37-40,共4页
The cross-section for the 93Nb(n, 2n)92gNb reaction has been measured at the neutron energy of 14.6 MeV using neutron activation and accelerator mass spectrometry (AMS) determination of the long-lived product nucl... The cross-section for the 93Nb(n, 2n)92gNb reaction has been measured at the neutron energy of 14.6 MeV using neutron activation and accelerator mass spectrometry (AMS) determination of the long-lived product nuclide 92gNb. The neutron energy was generated from the D+T neutron source at the China Institute of Atomic Energy (CIAE). The neutron flux was monitored by measuring the activity of 92mNb produced in the competing reaction channel of 93Nb(n, 2n)92mNb. At the neutron energy of 14.6 MeV, the 93Nb(n, 2n)92gNb reaction cross-section of (736±220) mb was obtained for the first time. 展开更多
关键词 93nb(n 2n)92gNb reaction CROSS-SECTION D+T neutron source accelerator mass spectrometry
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