Characteristics and identification of weathering crust of Pennsylvanian volcanic rocks in Shixi area,Junggar Basin

Based on drill core and thin section observation,major geochemical element analysis and con-ventional well log analysis,this study summarizes the characteristics and thickness of weathering crust of Pennsylvanian volcanic rocks(Carboniferous)in Shixi area,Junggar Basin.The weathering crust is identified and divided into three types according to the petrological characteristics and well log interpretations in Shixi area,and the isopach of weathering crust is mapped.The results show that:(1)With the increase of depth,the weathering weakens,and the rocks become less fractured with decreased porosity;(2)the weathering crust of the Upper Carboniferous volcanic rocks can be divided into strongly weathered and mildly weathered layers in Shixi area;(3)the weathering crust is relatively thicker in Dinan uplift and Shixi uplift.This study provides research basis for further evaluation of Upper Carboniferous volcanic reservoir,and will benefit for well location deployment and potential oilfield development in the Shixi area.

Cenozoic Adakite-type Volcanic Rocks in Qiangtang,Tibet and Its Significance

Volcanic rocks in the study area, including dacite, trachyandesite and mugearite, belong to the intermediate-acid, high-K calc-alkaline series, and possess the characteristics of adakite. The geochemistry of the rocks shows that the rocks are characterized by SiO2>59%, enrichment in A12O3(15.09-15.64%) and Na2O (>3.6%), high Sr (649-885 μg/g) and Sc, low Y contents (<17 μg/g), depletion in HREE (Yb<1.22 μg/g), (La/Yb)N>25, Sr/Y>40, MgO<3% (Mg<0.35), weak Eu anomaly (Eu/Eu=0.84-0.94), and lack of the high field strength elements (HFSE) (Nb, Ta, Ti, etc.). The Nd and Sr isotope data (87Sr/86Sr=0.7062-0.7079, 143Nd/144Nd=0.51166-0.51253, εNd= -18.61-0.02), show that the magma resulted from partial melting (10%-40%) of newly underplated basaltic lower crust under high pressure (1-4 GPa), and the petrogenesis is obviously affected by the crust's assimilation and fractional crystallization (AFC). This research will give an insight into the uplift mechanism of the Tibetan plateau.

Geochronology and Genetic Model for Early Cretaceous Volcanic Rocks from the Southern Qiangtang Terrane,Northern Tibet,China: Constraints from U-Pb Zircon Dating, Whole-Rock Geochemical and Sr-Nd Isotopic Data

Post-collisional volcanic rocks of Mesozoic age occur in the regions adjacent to Gerze, part of the southern Qiangtang Terrane of northern Tibet, China. Geochronological, geochemical, and wholerock Sr-Nd isotopic analyses were performed on the volcanic rocks to better characterize their emplacement age and models for their origin. Laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS) U-Pb zircon analyses yielded consistent ages ranging from 123.1±0.94 Ma to 124.5±0.89 Ma for six volcanic rocks from the study area. The intermediate volcanic rocks belong to the alkaline and sub-alkaline magma series in terms of K2 O+Na2 O contents(5.9%–9.0%), and to the shoshonitic and calc-alkaline series on the basis of their high K2 O contents(1.4%–3.3%). The Gerze volcanic rocks are characterized by the enrichment of light rare earth elements [(La/Yb)N=34.9–49.5] and large–ion lithophile elements(e.g., Rb, Ba, Th, U, K, Pb, and Sr), slightly negative Eu anomalies(Eu/Eu*=0.19–0.24), and negative anomalies in high field strength elements(e.g., Nb, Ta, Hf and Ti), relative to primitive mantle. The samples show slightly elevated(87 Sr/86 Sr)i values that range from 0.7049 to 0.7057, and low εNd(t) values from-0.89 to-2.89. These results suggest that the volcanic rocks studied derived from a compositionally heterogeneous mantle source and that their parent magmas were basaltic. The more mafic, parental magmas to the Gerze volcanic rocks likely underwent fractional crystallization of clinopyroxene, hornblende, biotite, and potassium feldspar, during ascent, with little to no crustal contamination, prior to their eruption/emplacement. While these volcanic rocks exhibit geochemical signatures typical of magmas formed in a destructive plate-margin setting, it is plausible that their mantle source might also have acquired such characteristics in an earlier episode of subduction.

Cenozoic volcanic rocks in the Belog Co area, Qiangtang, northern Tibet, China: Petrochemical evidence for partial melting of the mantle-crust transition zone

Neogene volcanic rocks in the Belog Co area, Qiangtang, northern Tibet, are represented by a typical intermediate-basic and intermediate alkaline rock association, with latite-trachyte as the main rock type. The results of chemical analysis are: SiO2=52%–62%, Al2O3>15%, Na2O/K2O>1 and MgO<3.30%. In addition, the volcanic rocks are LREE-enriched with LREE/HREE=10–13, (La/Yb)N=15–19, and show a weak negative Eu anomaly with δEu=0.71–0.89. The close relationship between Mg# and SiO2 and the co-variation of the magmatophile elements and ultra-magmatophile elements such as La/Sm-La and Cr-Tb indicate that this association of volcanic rocks is the product of comagmatic fractional crystallization. The rock association type and lower Sm/Yb values (Sm/Yb=3.23–3.97) imply that this association of volcanic rocks should have originated from partial melting of spinel lherzolite in the lithospheric mantle. On the other hand, the weak negative Eu anomaly and relative depletion in Nb, Ta and Ti reflect the features of terrigenous magma. So the Neogene Belog Co alkaline volcanic rocks should be the result of partial melting of the special crust-mantle transition zone on the Qinghai-Tibet Plateau.

PETROLOGY AND GEOCHEMISTRY OF CENOZOIC VOLCANIC ROCKS FROM THE CENTRE OF QIANGTANG,TIBET

The Cenozoic volcanic rocks in Qinghai—Tibetan plateau mainly occur in Qiangtang, Kunlun,Kokshili and eastern Tibet to the north of Bangong\|Nujiang suture. The study area locates in the centre of Qiangtang (N34°00′\|34°50′;E87°30′\|89°00′),where is nearly a blank area of geological work.Thirteen pieces of samples from Hehulin,Luanqingshan,Bandaohu and Donghu show that the K\|Ar ages of the Cenozoic volcanic rocks range from 32 6 to 44 1Ma, which are elder than the Cenozoic volcanic rocks from Kunlun,Kokshili and eastern Tibet.There are two types of occurrence for the volcanic rocks: volcanic lava and sub\|volcanic rock. The lava is dark grey, light purple or dark purple and unconformably covers up on the Jurassic,which interbeds with purplish red tertiary sandstone and pebble\|bearing sandstone and contains a small amount of phenocrysts (andesine,pyroxene,amphibole and biotite). three craters and four volcanic necks have been found in this area. The sub\|volcanic rocks expose as volcanic necks with appearance of isolated peaks,which intrude into Jurassic. The rocks,appearing grey white to light grey, have trachytic texture with the phenocrysts of plagioclase,biotite and amphibole. Besides above rocks,there are some lamprophyre dikes intruding into grey white tertiary lacustrine algal limestone in this area with its length up to 2km and width 3m. The rocks appear dark grey or dark green and contain the phenocrysts of pyroxene,orthoclase,biotite,olivine,and leucitite.

THE EARLY UPLIFT IN NORTHERN TIBETAN PLATEAU: EVIDENCE FROM THE STUDY ON CENOZOIC VOLCANIC ROCKS IN QIANGTANG REGION

Cenozoic volcanic rocks, forming a series of volcanic rocks platform or highland on different sub\|volcanic rocks belt, had distributed widely in northern Qinghai—Tibet plateau, and characterized by potassinm\|rich lavas which main petrologic types are latidacite and latite. The petrogenesis of volcanic rocks in northern Tibetan plateau had been well\|studied, and thought they play an important role to uplift of Tibetan plateau. Based on the study of lithochemistry and isotopic age determination of the rocks in Qiangtang area, which is the most southern and earliest volcanic rocks belt of Cenozoic volcanic rocks, I contribute another view here to the early uplift of Tibetan plateau. Cenozoic volcanic rocks in Qiangtang region, thickness of the rocks are from 200 to 1000m in different area, belong to shoshonite and high\|K calc\|alkaline series, highly enrich alkaline specially enrich potassinm, large\|ion lithophytes elements (Rb,Sr,Ba,and Th), LREE and deplete high\|field strength elements (Ta,Er,Hf,and Ti). Chondrite\|normalized REE pattern of volcanic rocks show an absence of significant Eu anomaly, and indicate that the volcanic source was plagioclase\|free and probably resulted from melting in lower crust or upper mantle. Cenozoic volcanic rocks in Qiangtang region are similar petrologic and geochemical characteristics to that have been reported in more northern Hoh Xil and Kunlun area in Tibetan plateau. The age scope of volcanic rocks in Qiangtang area were from 44.1～32.6Ma, among which the age mainly were 44.1～42.5Ma, which belong to mid\|Eocene epoch to primary Oligocene epoch, and could be classified into four out pouring periods, according to the potassium\|argon age dating. The study on lithochemistry and age of the rocks in Qiangtang area suggest that Intracontinental subduction southward Qiangtang tectonic belt plays an important role to Cenozoic volcanism, and imply that the convective removal of the thicked lithosphere, which formed at the collision mountain\|building processes, are responsible for the formation of Cenozoic volcanic rocks, the earliest uplift of Tibetan plateau. and regional extension in Qiangtang area.

Petrogenesis of high-Mg# Cenozoic volcanic rocks of southern Qiangtang area, Tibetan Plateau： geochemical and Sr-Nd isotopic evidence

The Nadingcuo volcanic rock suite is the most volmninous Cenozoic volcanic suite in the southern Qiangtang area of the northern Tibetan Plateau. These high-K calc-alkaline volcanic rocks were formed between 36 and 34 Ma, characterized by high Mg# values, high concentrations of TiO2 and P205, 87Sr/S6Sr ratios of 0. 704682--0. 706 112, and aNd（t） values of - 1.2 to 1.6. There is a lack of reasonable explanations for sour- cing and origin of magmas that formed the rocks with high Mg# values and TiO2 and P2O5 enrichments, which makes the previous research results still controversial. This study reviews the geochemical characteristics of Nadingcuo volcanic rocks and the data we have newly found in our fieldwork. We give some new interpretation to the magmatic evolution of the basaltic magmas in the discussed area dominated by fractional crystallization. The geochemistry of trachyandesite and trachyte units in the studied area is indicative of formation from mantle- derived magmas that mixed with crustal materials. The high values of Mg# and TiO2 and P205 enrichment in these units are evident to show the mixing between mantle-derived magmas with -30-40 wt.% rhyolitic melt or assimilation of a similar amount of felsic rocks. The geochemistry of basaltic rocks in the area also suggests that the Nadingcuo basalts may have been derived from an ocean island basalt （OIB） -type source that contained and was mixed with ancient mantle wedge derived material, indicating that a 36-34 Ma asthenospheric upwelling e- vent in the Qiangtang area may relate to the northward subduction of Indian lithospheric mantle and the south- ward subduction of Asian lithospherie mantle. This upwelling of asthenospherie material was centered in the southern Qiangtang area between 36 and 34 Ma, while the northward movement of the Indian Craton caused this upwelling mantle flow to continuously migrate northward, resulting in the current centering of this upwelling in the Hoh Xil-Kunlun region.

Early Triassic Silicic Volcanics of South China:Petrogenesis and Constraints on the Geodynamic Evolution of the Paleo-Tethys Ocean Region

The only occurrence of Lower Triassic silicic volcanic rocks within the South China Block is in the Qinzhou Bay area of Guangxi Province.LA-ICP-MS zircon U-Pb dating reveals that volcanic rocks of the Beisi and Banba formations formed between 248.8±1.6 and 246.5±1.3 Ma,coeval with peraluminous granites of the Qinzhou Bay Granitic Complex.The studied rhyolites and dacites are characterized by high SiO_(2),K_(2)O,and Al_(2)O_(3),and low MgO,CaO,and P_(2)O_(5) contents and are classified as high-K calc-alkaline S-type rocks,with A/CNK=0.98-1.19.The volcanic rocks are depleted in high field strength elements,e.g.,Nb,Ta,Ti,and P,and enriched in large ion lithophile elements,e.g.,Rb,K,Sr,and Ba.Although the analyzed volcanic rocks have extremely enriched zircon Hf isotopic compositions(ε_(Hf)(t)=-29.1 to-6.9),source discrimination indicators and high calculated Ti-in-zircon temperatures(798-835℃)reveal that magma derived from enriched lithospheric mantle not only provided a heat source for anatectic melting of the metasedimentary protoliths but was also an endmember component of the S-type silicic magma.The studied early Triassic volcanics are inferred to have formed immediately before closure of the Paleo-Tethys Ocean in this region,as the associated subduction would have generated an extensional setting in which the mantle-derived upwelling and volcanic activity occurred.

Zircon U-Pb age of the volcanic rock from the Huoshiling Formation in the Yingtai Fault Depression, Songliao Basin, China

1. Objective The Songliao Basin is a superposed basin filled with two layers. The lower layer is characterized by a fault-bounded volcanogenic succession comprising of intercalated volcanic,pyroclastic and epiclastic rocks. The upper layer is composed of normal sedimentary rocks. The Huoshiling Formation is the earliest volcanic stratum in the Songliao Basin. The report of geological age of it was rare, because of the lack of credible dating samples.

Paleoproterozoic volcanic rocks in the southern margin of the North China Craton, central China:Implications for the Columbia supercontinent

The volcanic rocks of the Xiong’er Group are situated in the southern margin of the North China Craton(NCC).Research on the Xiong er Group is important to understand the tectonic evolution of the NCC and the Columbia supercontinent during the Paleoproterozoic.In this study,to constrain the age of the Xiong’er volcanic rocks and identify its tectonic environment,we report zircon LA-ICP-MS data with Hf isotope,whole-rock major and trace element compositions and Sr-Nd-Pb-Hf isotopes of the volcanic rocks of the Xiong’er Group.The Xiong’er volcanic rocks mainly consist of basaltic andesite,andesite.dacite and rhyolite,with minor basalt.Our new sets of data combined with those from previous studies indicate that Xiong’er volcanism should have lasted from 1827 Ma to 1746 Ma as the major phase of the volcanism.These volcanics have extremely low MgO.Cr and Ni contents,are enriched in LREEs and LILEs but depleted in HFSEs(Nb,Ta,and Ti),similar to arc-related volcanic rocks.They are characterized by negative zirconεHft values of-17.4 to 8.8,whole-rock initial 87Sr/86Sr values of 0.7023 to 0.7177 andεNd(t)values of-10.9 to 6.4.and Pb isotopes(206Pb/204Pb=14.366-16.431,207Pb/204Pb=15.106-15.371,208Pb/204Pb=32.455-37.422).The available elemental and Sr-Nd-Pb-Hf isotope data suggest that the Xiong’er volcanic rocks were sourced from a mantle contaminated by continental crust.The volcanic rocks of the Xiong’er Group might have been generated by high-degree partial melting of a lithospheric mantle that was originally modified by oceanic subduction in the Archean.Thus,we suggest that the subduction-modified lithospheric mantle occurred in an extensional setting during the breakup of the Columbia supercontinent in the Late Paleoproterozoic,rather than in an arc setting.

Chronology and Geochemistry of Mesozoic Volcanic Rocks in the Linjiang Area,Jilin Province and their Tectonic Implications

Zircon U-Pb ages and geochemical analytical results are presented for the volcanic rocks of the Naozhigou, Ergulazi, and Sidaogou Formations in the Linjiang area, southeastern Jilin Province to constrain the nature of magma source and their tectonic settings. The Naozhigou Formation is composed mainly of andesite and rhyolite and its weighted mean ^206pb/^238U age for 13 zircon grains is 222±1 Ma. The Ergulazi Formation consists of basaltic andesite, basaltic trachyandesite, and andesite, and six grains give a weighted mean ^206pb/^238U age of 131±4 Ma. The Sidaogou Formation consists mainly of trachyandesite and rhyolite, and six zircon grains yield a weighted mean ^206pb/^238U age of 113±4 Ma. The volcanic rocks have SIO2=60.24%-77.46%, MGO=0.36%-1.29% （Mg#=0.32-0.40） for the Naozhigou Formation, SIO2=51.60%-59.32%, MGO=3.70%-5.54% （Mg#=0.50-0.60） for the Ergulazi Formation, and SIO2=58.28%-76.32%, MGO=0.07%-1.20% （Mg#=0.14-0.46） for the Sidaogou Formation. The trace element analytical results indicate that these volcanic rocks are characterized by enrichment in light rare earth elements （LREEs） and large ion lithophile elements （LILEs）, relative depletion in heavy rare earth elements （HREEs） and high field strength elements （HFSEs, Nb, Ta, and Ti）, and negative Eu anomalies. Compared with the primitive mantle, the Mesozoic volcanic rocks in the Linjiang area have relatively high initial ^87Sr/^86Sr ratios （0.7053-0.7083） and low εNd（t） values （-8.38 to -2.43）, and display an EMⅡ trend. The late Triassic magma for the Naozhigou Formation could be derived from partial melting of a newly accretional crust with the minor involvement of the North China Craton basement and formed under an extensional environment after the collision of the Yangtze Craton and the North China Craton. The Early Cretaceous volcanic rocks for the Ergulazi and Sidaogou Formations could be formed under the tectonic setting of an active continental margin related to the westward subduction of the Izanagi plate.

Geochemistry of Mesoproterozoic Volcanic Rocks in the Western Kunlun Mountains: Evidence for Plate Tectonic Evolution

Mesoproterozoic volcanic rocks occurring in the north of the western Kunlun Mountains can be divided into two groups. The first group (north belt) is an reversely-evolved bimodal series. Petrochemistry shows that the alkalinity of the rocks decreases from early to late: alkaline→calc-alkaline→tholeiite, and geochemistry proves that the volcanic rocks were formed in rifting tectonic systems. The sedimentary facies shows characteristics of back-arc basins. The second (south belt) group, which occurs to the south of Yutian-Minfeng-Cele, is composed of calc-alkaline island arc (basaltic) andesite and minor rhyolite. The space distribution, age and geochemistry of the two volcanite groups indicate that they were formed in a back-arc basin (the first group) and an island arc (the second group) respectively and indicate the plate evolution during the Mesoproterozoic. The orogeny took place at -1.05 Ga, which was coeval with the Grenville orogeny. This study has provided important geological data for exploring the position of the Paleo-Tarim plate in the Rodinia super-continent.

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang,China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios （0.18-0.57）, implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer （LA-ICP-MS） indicate that the ^206Pb/^238U ages of zircons from andesite range within 105- 106 Ma, yielding a weighted mean age of 105.5±0.8 Ma （n=14）, and that ^206pb/^238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma （n =13）. The volcanic rocks from the Snifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% （Mg^#= 45-53）, and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements （LILE） and lightrare-earth elements （LREE）, depletion in heavy rare earth elements （HREE） and high field strength elements （HFSE） （e.g., Nb, Ta, Ti）, and low initial ^87Sr/^86Sr ratios （0.7041-0.7057） and positive εNd（t） ValUes （0.39-4.08）, implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.

Neoproterozoic Volcanic Rocks in the Southern Quruqtagh of Northwest China:Geochemistry,Zircon Geochronology and Tectonic Implications

The Early Neoproterozoic Beiyixi Formation volcanic rocks of the southern Quruqtagh comprise mainly of a suite of tholeiitic basalts, alkaline andesites, and calc-alkaline rhyolites. The rhyolites are characterized by variably fractionated enrichment in light rare earth elements （LREE） and fiat in heavy rare earth elements （HREE）, and strongly negative Eu anomalies. Compared to the rhyolites, the andesites also exhibit enrichment in LREE and flat HREE （chondrite-normalized values of La/Yb,and La/Sm are 13.30-41.09, 3.18-6.89 respectively）. Their rare earth element patterns display minor negative Eu anomalies. Both of them exhibit coherent patterns with strongly to moderately negative anomalies of Nb, Zr, Ti, and Hf on spider diagrams. Two rhyolite and one andesite magmatic zircons with defined oscillatory zoning yielded weighted mean 206pb/23Su ages of 743 ± 7 Ma, 741±2 Ma, and 7274 Ma. These ages are interpreted to represent the timing of volcanic eruptions. According to geochemistry and rock type, these volcanic rocks formed within a continental island-arc environment following subduction of the oceanic crust during the Early Neoproterozoic period.

Geochemical and isotopic characteristics of volcanic rocks from the northern East China Sea shelf margin and the Okinawa Trough

Volcanic rocks both from the northern East China Sea （NECS） shelf margin and the northern Okinawa Trough are subalkaline less aluminous,and lower in High Field Strength Elements （HFSE）.These rocks are higher in Large Ion Lithophile Elements （LILE）,thorium and uranium contents,positive lead anomalies,negative Nb-Ta anomalies,and enrichment in Light Rare Earth Elements （LREE）.Basalts from the NECS shelf margin are akin to Indian Ocean Mid-Ocean Ridge Basalt （MORB）,and rhyolites from the northern Okinawa Trough have the highest 207 Pb/ 204 Pb and 208 Pb/ 204 Pb ratios.The NECS shelf margin basalts have lower 87 Sr/ 86 Sr ratios,ε N d and σ 18 O than the northern Okinawa Trough silicic rocks.According to 40 K– 40 Ar isotopic ages of basalts from the NECS shelf margin,rifting of the Okinawa Trough may have been active since at least 3.65–3.86 Ma.The origin of the NECS shelf margin basalt can be explained by the interaction of melt derived from Indian Ocean MORB-like mantle with enriched subcontinental lithosphere.The basalts from both sides of the Okinawa Trough may have a similar origin during the initial rifting of the Okinawa Trough,and the formation of basaltic magmas closely relates to the thinning of continental crust.The source of the formation of the northern Okinawa Trough silicic rocks was different from that of the middle Okinawa Trough,which could have been generated by the interaction of basaltic melt with an enriched crustal component.From the Ryukyu island arc to East China,the Cenozoic basalts have apparently increasing trends of MgO contents and ratios of LREE to Heavy Rare Earth Elements （HREE）,suggesting that the trace element variabilities of basalts may have been influenced by the subduction of the Philippine Sea plate,and that the effects of subduction of the Philippine Sea plate on the chemical composition of basaltic melts have had a decreasing effect from the Ryukyu island arc to East China.

U-Pb Dating of Volcanic Rocks and Granites along the Wuyishan Belt:Constraints on Timing of Late Mesozoic Tectonic Events in Southeast China

Five volcanic rock samples and two granite samples taken from the volcanic basins in western Fujian and southern Jiangxi were dated by using the zircon laser albation-inductively coupled plasma mass spectrometry U-Pb method. Together with previously dated ages, the dates obtained provide important constraints on the timing of late Mesozoic tectonic events in SE China. The volcanic rock samples yield ages of 183.1±3.5 Ma, ca. 141 Ma to 135.8±1.1 Ma, 100.4±1.5 to 97.6±1.1 Ma, confirming three episodes of late Mesozoic volcanic activities, which peaked at 180±5 Ma, 140±5 Ma and 100±5 Ma, respectively, along the Wuyishan belt. Moreover, based on field investigations of these volcano-sedimentary basins, we have recognized two compressional tectonic events along this belt. The early one was characterized by Upper Triassic to Middle Jurassic NNE-trending folds that were intruded by late Jurassic granites; and the late one caused the Lower Cretaceous volcano-sedimentary layer to be tilted. The dated age 152.9±1.4 Ma of the granitic samples from the Hetian granitic pluton in the Changting Basin and that from the Baishiding granitic pluton, 100.2±1.8 Ma, in the Jianning Basin, give the upper boundaries of these two tectonic events respectively. Hence, the late Mesozoic tectonic evolution of SE China was alternated between extension and compression.

Geodynamic Background of Intracontinental Cenozoic Alkaline Volcanic Rocks in Laojiezi, Western Yangtze Craton: Constraints from Sr-Nd-Hf-O Isotopes

The Laojiezi alkaline volcanic rocks, which are located in the intraplate region of the Yangtze craton, coincide with the formation of the Jinshajiang-Ailaoshan-Red River alkaline rock belt. Although this belt has been widely studied by geologists because of its porphyry-related Pb-Ag-Au polymetallic deposit and geotectonic location, the material sources of this belt are still debate. Whole-rock analyses show that these rocks have high total alkali contents(3.73–11.08 wt%), and their aluminum saturation index(ASI) values widely vary from 0.82 to 3.07, which comprise a metaluminous-peraluminous magma series. These rocks are characterized by high K(K2 O/Na2 O>1) and low Ti and Mg contents; enrichment in large-ion lithophile elements, such as Rb, Ba, K and light rare earth elements; and depletion in high field strength elements, such as Ta, Nb, P, and Ti. These rocks exhibit moderate Eu(Eu/Eu*=0.86–1.04) and Ce(Ce/Ce*=0.63–0.96) anomalies. Their(87 Sr/86 Sr)i, εNd(t), zircon εHf(t) and δ18 O values range from 0.70839 to 0.71013, from-10.16 to-12.45, from-19.6 to-5.8, and from 5.69‰ to 8.54‰, respectively, and their Nd and Hf two-stage model ages(TDM2) are 1.67–1.86 Ga and 1.27–2.02 Ga, respectively. These data reflect the primary partial melting of Paleoproterozoic to Mesoproterozoic lower crust with minor residual continental lithospheric mantle and supracrustal metasediments. The lithosphere was likely thickened along the southeastern margin of the Tibetan Plateau following the Indian-Asian continentcontinent collision(65–41 Ma). During the post-collision phase(36–16 Ma), the transition from a compressional to extensional setting triggered the convective removal of the over-thickened CLM beneath the Yangtze craton, which led to the upwelling of asthenospheric materials. This process created alkali-rich and high-K magma through the partial melting of the thickened lower crust. Magma that carried Cu-Au-Pb-Ag minerals was emplaced by strike-slip motion along the E-to W-or ENE-to WSWtrending tectonically weak zone, finally forming an alkaline porphyry Cu-Au-Pb-Ag polymetallic deposit.

Discovery and Significance of High CH_4 Primary Fluid Inclusions in Reservoir Volcanic Rocks of the Songliao Basin,NE China

Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that： （1） up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; （2） high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; （3） in gas reservoirs of such abiotic methane （〉80%） and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; （4） a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.

Zircon SHRIMP U–Pb age of Late Jurassic OIB-type volcanic rocks from the Tethyan Himalaya: constraints on the initial activity time of the Kerguelen mantle plume

This work presents zircon U–Pb age and wholerock geochemical data for the volcanic rocks from the Lakang Formation in the southeastern Tethyan Himalaya and represents the initial activity of the Kerguelen mantle plume. SHRIMP U–Pb dating of zircons from the volcanic rocks yielded a ^(206) Pb/^(238) U age of 147 ± 2 Ma that reflects the time of Late Jurassic magmatism. Whole rock analyses of major and trace elements show that the volcanic rocks are characterized by high content of Ti O_2(2.62 wt%–4.25 wt%) and P_2O_5(0.38 wt%–0.68 wt%), highly fractionated in LREE/HREE [(La/Yb)N= 5.35–8.31] with no obvious anomaly of Eu, and HFSE enrichment with no obvious anomaly of Nb and Ta, which are similar to those of ocean island basalts and tholeiitic basaltic andesites indicating a mantle plume origin. The Kerguelen mantle plume produced a massive amount of magmatic rocks from Early Cretaceous to the present, which widely dispersed from their original localities of emplacement due to the changing motions of the Antarctic, Australian, and Indian plates. However, our new geochronological and geochemical results indicate that the Kerguelen mantle plume started from the Late Jurassic. Furthermore, we suggest that the Kerguelen mantle plume may played a significant role in the breakup of eastern Gondwanaland according to the available geochronological, geochemical and paleomagnetic data.

Development features of volcanic rocks of the Yingcheng Formation and their relationship with fault structure in the Xujiaweizi Fault Depression,Songliao Basin,China

The Xujiaweizi Fault Depression is located in the northern Songliao Basin,Northeast China.The exploration results show that the most favorable natural gas reservoirs are in the volcanic rocks of the Yingcheng Formation（K 1 yc）.Based on seismic interpretation,drill cores and the results of previous research,we analyzed the distribution of faults and the thickness of volcanic rocks in different periods of K 1 yc,and studied the relationship of volcanic activities and main faults.Volcanic rocks were formed in the Yingcheng period when the magma erupted along pre-existing fault zones.The volcanic activities strongly eroded the faults during the eruption process,which resulted in the structural traces in the seismic section being diffuse and unclear.The tectonic activities weakened in the study area in the depression stage.The analysis of seismic interpretation,thin section microscopy and drill cores revealed that a large number of fractures generated in the volcanic rocks were affected by later continued weak tectonic activities,which greatly improved the physical properties of volcanic reservoirs,and made the volcanic rocks of K 1 yc be favorable natural gas reservoirs.The above conclusions provide the basis to better understand the relationship of the volcanic rock distribution and faults,the mechanism of volcanic eruption and the formation of natural gas reservoirs in volcanic rocks.