A_3BGa_3Si_2O_(14)类晶体的旋光特性研究

报道了La3Ga5SiO14(LGS)同构物掺杂性改进后,用提拉法生长出A3BGa3Si2O14(A=Ca2+,Sr2+;B=Nb5+,Ta5+)系列的4种晶体。此类稀土晶体均为单轴晶,属三方晶系,32点群。采用改造过的分光光度计研究了这类晶体的透过率、旋光角、旋光率色散,并与LGS进行了比较。透射率光谱显示,ABGS类晶体在大于294 nm的可见光谱区和红外区是透明的,透过率均大于LGS。偏振光透过率曲线显示这类晶体自然旋光率较大,结果表明,这4种晶体的旋光率均大于LGS,其中SNGS旋光为最大,在波长0.30μm处,ρ=240.75(°).mm-1;在0.633μm处,ρ=34.73(°).mm-1。根据实验结果计算了这类晶体的波尔兹曼系数,与文献结果吻合很好。

Ca_3NbGa_3Si_2O_(14)晶体光学和热学特性的研究

用提拉法成功地生长了一种具有La3Ga5SiO14(LGS)结构的Ca3NbGa3Si2O14(CNGS)单晶;用X-射线粉末衍射证明了其具有单一相且同LGS同构的单晶结构;DSC实验表明CNGS单晶的熔点为1349.9°C。在293.15～403.15K间测得垂直于z方向的热膨胀系数为1.7×10-6/K,而在283.15和433.15K的温度范围内z方向的热膨胀几乎不变。在300.42K测得晶体的比热为0.763J/mol·K;并在190～3200nm间测其透过谱。

Ca_3NbGa_3Si_2O_(14)晶体的BAW传播特性

本文计算了沿Ca3NbGa3Si2O14(CNGS)晶体的x、y和z方向传播的声体波(BAW)的声速,绘制了yz、xy和xz面传播的慢速度分布曲线。这些结果对CNGS晶体在压电器件的设计、开发及利用方面具有一定的理论指导意义。

Study on Optical Activities of A3BGa3Si2O14 Crystals

Four crystals with the general formula of A3BGa3Si2O14 （A = Ca^2＋, Sr^2＋; B=Nb^5＋ , Ta^5＋） grown by using the Czoehralsky technique were reported. They are all uniaxial and belong to 32 point group. Their transmission, rotatory angle and specific rotation dispersion were investigated by speetrophotometer and compared with LGS. The transmission spectra show that they are transparent in the visible wavelength region beyond 294 nm and infrared region, and their transmission are all larger than that of LGS.The transmission spectra between parallel polasizers show that they have large optical activities which are larger than that of LGS. Of the four crystals, Sr3NbGa3Si2O14 has the largest optical activity ： 240.75 （°）·mm^-1 at 0.30 μm wavelength, 34.73 （°） ·mm^-1 at 0. 633 μm wavelength. The Bohzmann＇s coefficients of these crystals were calculated, which were in good agreement with earlier measurement in other reference.