The effects of Ag on the microstructure, mechanical properties, and electrical conductivity of AA2024 aluminum alloy coating were investigated. It was fabricated by friction surfacing as an additive manufacturing proc...The effects of Ag on the microstructure, mechanical properties, and electrical conductivity of AA2024 aluminum alloy coating were investigated. It was fabricated by friction surfacing as an additive manufacturing process. To carry out this investigation, Ag was added by 5.3, 10.6, and 16.0 wt.% to an AA2024 consumable rod by inserting holes in it. It was found that due to the strengthening by solid solution and the formation of precipitates and intermetallic containing Ag, the driving force for grain growth is reduced and consequently the grain size of the coating is decreased. After artificial aging heat treatment, the electrical conductivities of the coatings containing 0 and 16.0 wt.% Ag are increased by 4.15%(IACS) and decreased by 2.15%(IACS), respectively. While considering a linear relationship, it can be proposed that for a 1 wt.% Ag increase, the strength and hardness of the coating will be increased by 1.8% and 1.0%, respectively. It was established that the effect of Al6(Cu,Ag)Mg4 precipitate formation on strengthening is greater than that of Ag-rich intermetallic.展开更多
The joining of aluminum alloy sheets with thickness less than 2.0 mm is difficult via conventional frictionstir welding owing to the defects in the joint, such as root flaw, keyhole and lazy S. In the present research...The joining of aluminum alloy sheets with thickness less than 2.0 mm is difficult via conventional frictionstir welding owing to the defects in the joint, such as root flaw, keyhole and lazy S. In the present research, a newlydesigned pinless tool with involute grooves on its shoulder surface was applied to weld 1.5 mm thick AA2024-T3. Theeffects of the rotating speed and welding speed on the microstructure and mechanical properties of the joints were analyzed.The experimental results showed that the root flaw and keyhole were successfully eliminated. The lazy S wasalso eliminated under the optimized welding parameters. The maximum tensile strength of the joints was 326 MPa,which is about 74.1% that of the base material. Moreover, all the tensile samples fractured from the retreating side.Two fracture modes were observed during the tensile tests, which are related with the lazy S.展开更多
Aluminium alloy（AA） 2024 is an important engineering material due to its widespread use in the aerospace industry. However, it is very prone to corrosion attack in chloride containing media. In the present investiga...Aluminium alloy（AA） 2024 is an important engineering material due to its widespread use in the aerospace industry. However, it is very prone to corrosion attack in chloride containing media. In the present investigation, AA2024 aluminium alloy rolled plates of 5 mm in thickness were friction stir welded. Corrosion performances of the specimens were evaluated by conducting salt fog tests in Na Cl solution at different p H values, chloride ion concentrations and spraying time. In addition, an empirical relationship was established to predict the corrosion rate of friction stir welds of AA2024 aluminium alloy. A central composite rotatable design including three factors and five levels was used to minimize the number of experiments. Response surface methodology（RSM） was used to develop the relationship. The corrosion rate decreased under neutral p H conditions. The corrosion rate increased in acidic and basic conditions. It was also found that the corrosion rate decreased with the increase of spraying time, but the corrosion tended to be uniform with the increment of time and with the increase in the chloride ion concentration, and the corrosion rate increased in the salt spray corrosion test.展开更多
Given the nonuse of TiO2 nanoparticles as the reinforcement of AA2024 alloy in fabricating composites by ex-situ casting methods,it was decided to process the AA2024−xTiO2(np)(x=0,0.5 and 1 vol.%)nanocomposites by emp...Given the nonuse of TiO2 nanoparticles as the reinforcement of AA2024 alloy in fabricating composites by ex-situ casting methods,it was decided to process the AA2024−xTiO2(np)(x=0,0.5 and 1 vol.%)nanocomposites by employing the stir casting method.The structural properties of the produced samples were then investigated by optical microscopy and scanning electron microscopy;their mechanical properties were also addressed by hardness and tensile tests.The results showed that adding 1 vol.%TiO2 nanoparticles reduced the grain size and dendrite arm spacing by about 66%and 31%,respectively.Also,hardness,ultimate tensile strength,yield strength,and elongation of AA2024−1vol.%TiO2(np)composite were increased by about 25%,28%,4%and 163%,respectively,as compared to those of the monolithic component.The agglomerations of nanoparticles in the structure of nanocomposites were found to be a factor weakening the strength against the strengthening mechanisms.Some agglomerations of nanoparticles in the matrix were detected on the fractured surfaces of the tension test specimens.展开更多
In the present study,the effect of reduction of cutting fluid consumption on the surface quality and tool wear was studied.Mathematical models were developed to predict the surface roughness using response surface met...In the present study,the effect of reduction of cutting fluid consumption on the surface quality and tool wear was studied.Mathematical models were developed to predict the surface roughness using response surface methodology(RSM).Analysis of variance(ANOVA)was used to investigate the significance of the developed regression models.The results showed that the coefficient of determination values(R^2)for the developed models was 97.46%for dry,89.32%for flood mode(FM),and 99.44%for MQL,showing the high accuracy of fitted models.Also,under the minimum quantity lubrication(MQL)condition,the surface roughness improved by 23%−44%and 19%−41%compared with dry and FM,respectively,and the SEM images of machined surface proved the statement.The prepared SEM images of tool rake face also showed a considerable decrease in adhesion wear.Built-up edge and built-up layer were the two main products of the adhesion wear,and energy-dispersive X-ray spectroscopy(EDX)analysis of specific points on the tool faces helped to discover the chemical compositions of adhered materials.By changing dry and FM to MQL mode,dominant mechanism of tool wear in machining aluminum alloy was significantly decreased.Breakage wear that led to early failure of cutting edge was also controlled by MQL technique.展开更多
The effect of non-isothermal aging treatment on microstructure and mechanical properties of in-situ AA2024−Al_(3)NiCu composite fabricated by the stir casting process was examined.The Al_(3)NiCu intermetallic was crea...The effect of non-isothermal aging treatment on microstructure and mechanical properties of in-situ AA2024−Al_(3)NiCu composite fabricated by the stir casting process was examined.The Al_(3)NiCu intermetallic was created by adding 3 wt.%nickel powder during stir casting and homogenization treatment at 500℃ for 24 h after casting.The microstructural results obtained using optical and scanning electron microscope indicate that,after non-isothermal aging treatment,the S-Al_(2)CuMg precipitates become finer,forming a poor zone of this precipitate in the area between the dendrites.Also,adding nickel during stir casting reduces the precipitation rate and the contribution of S-Al_(2)CuMg precipitates in strengthening composite during non-isothermal aging.The maximum hardness,ultimate tensile strength,and toughness achieved in the 3 wt.%nickel-containing sample after non-isothermal aging at 250℃ are(121.30±4.21)HV,(221.67±8.31)MPa,and(1.67±0.08)MJ/m^(3),respectively.The maximum hardness and ultimate tensile strength of AA2024−Al_(3)NiCu composite are decreased by 6%and 4%,respectively,compared to those of nickel-free AA2024 aluminum alloy.展开更多
The extruded plate of powder metallurgy AA2024 aluminum alloy was successfully solid-state joined by friction stir welding(FSW) to demonstrate potential applications in the aerospace and automotive industries. For det...The extruded plate of powder metallurgy AA2024 aluminum alloy was successfully solid-state joined by friction stir welding(FSW) to demonstrate potential applications in the aerospace and automotive industries. For determining the optimal processing parameters of FSW, the microstructure, mechanical properties, and fracture behavior of FSW joints were evaluated. When the processing parameters were optimized with 2000 r/min rotation speed and100 mm/min traverse speed, high quality welds were achieved. The ultimate tensile strength yield strength and elongation of the joint can reach 415 MPa(85% of the base metal strength), 282 MPa, and 9.5%, respectively. The hardness of the joint gradually decreased from the alloy matrix to the heat-affected zone. The lowest strength and hardness appeared near the heat-affected zone because of the over-aging caused by heat flow from repeated stirring during FSW. The average grain size of the stir zone(2.15 μm) was smaller than that of the base metal(4.43 μm) and the heat-affected zone(5.03 μm), whose grains had <110> preferred orientation.展开更多
Hot forming with synchronous cooling(HFSC)is a novel technique for heat-treatable,high-strength aluminum alloys,which allows the alloys to acquire good formability,negligible springback,rapid processing and better mec...Hot forming with synchronous cooling(HFSC)is a novel technique for heat-treatable,high-strength aluminum alloys,which allows the alloys to acquire good formability,negligible springback,rapid processing and better mechanical properties.However,the deformation behavior and microstructure evolution of the alloys during HFSC are complex and need to be studied due to the temperature and strain rate effects.Uniaxial tensile tests in a temperature range of 250—450℃and a strain rate range of 0.01—1 s-1 for AA2024-H18 aluminum alloy sheet are conducted with a Gleeble-3500 Thermal-Mechanical Simulation Tester.And based on metallography observation and analysis,AA2024-H18 aluminum alloy sheet in HSFC process exhibits hardening and dynamic recovery behaviors within the temperature range of 250—450 ℃.Strain rate shows different effects on ductility at different temperatures.Compared with traditional warm/hot forming methods,AA2024-H18 aluminum alloy achieves a better work-hardening result through HFSC operations,which promises an improved formability at elevated temperature and thus good mechanical properties of final part.After HSFC operations,the microstructure of the specimens is composed of elongated static recrystallization grain.展开更多
The objectives of this study were to produce ultrafine-grained(UFG) AA2024 aluminum alloy by cryorolling followed by aging and to evaluate its corrosion behavior. Solutionized samples were cryorolled to ~85% reduction...The objectives of this study were to produce ultrafine-grained(UFG) AA2024 aluminum alloy by cryorolling followed by aging and to evaluate its corrosion behavior. Solutionized samples were cryorolled to ~85% reduction in thickness. Subsequent aging resulted in a UFG structure with finer precipitates of Al_2CuMg in the cryorolled alloy. The(1) solutionized and(2) solutionized and cryorolled samples were uniformly aged at 160°C/24 h and were designated as CGPA and CRPA, respectively; these samples were subsequently subjected to corrosion studies. Potentiodynamic polarization studies in 3.5 wt% NaCl solution indicated an increase in corrosion potential and a decrease in corrosion current density for CRPA compared to CGPA. In the case of CRPA, electrochemical impedance spectroscopic studies indicated the presence of two complex passive oxide layers with a higher charge transfer resistance and lower mass loss during intergranular corrosion tests. The improved corrosion resistance of CRPA was mainly attributed to its UFG structure, uniform distribution of fine precipitates, and absence of coarse grain-boundary precipitation and associated precipitate-free zones as compared with the CGPA alloy.展开更多
zirconia-based nanostructured coatings were deposited on AA2024 to improve the corrosion resistance properties. Three different nanostructured coatings, namely, zirconia–benzotriazole, zirconia–alumina–benzotriazol...zirconia-based nanostructured coatings were deposited on AA2024 to improve the corrosion resistance properties. Three different nanostructured coatings, namely, zirconia–benzotriazole, zirconia–alumina–benzotriazole, and zirconia–yttria–benzotriazole, were applied on AA2024 via a sol–gel method using the dip-coating technique. Next, the coatings were annealed at 150°C after each dipping period. The phases and morphologies of the coatings were investigated using grazing incidence X-ray diffraction(GIXRD), Fourier transform infrared spectroscopy(FT-IR), field emission scanning electron microscopy(FESEM), and atomic force microscopy(AFM). The corrosion properties were evaluated using electrochemical methods, including polarization and electrochemical impedance techniques in 3.5 wt% NaCl solution. The obtained results confirm the formation of homogeneous and crack free zirconia-benzotriazole-based nanostructured coatings. The average roughness values for zirconia-benzotriazole, zirconia-alumina-benzotriazole, and zirconia-yttria-benzotriazole nanostructured coatings were 30, 8, and 6 nm, respectively. The presence of alumina as a stabilizer on zirconia coating was found to have a beneficial impact on the stability of the corrosion resistance for different immersion times. In fact, the addition of alumina resulted in the dominance of the healing behavior in competition with the corrosion process of zirconia-benzotriazole nanostructured coating.展开更多
Cerium malate (CeMal) was tested as a corrosion inhibitor for AA2024-T3 in this work. Corrosion inhibition on bare AA2024-T3 indicated that the inhibiting effect was a result of the synergistic effect of cerium cation...Cerium malate (CeMal) was tested as a corrosion inhibitor for AA2024-T3 in this work. Corrosion inhibition on bare AA2024-T3 indicated that the inhibiting effect was a result of the synergistic effect of cerium cations and maleic anions. The corrosion of AA2024-T3 was stagnated by greatly reducing the corrosion current when CeMal was present in NaCl solutions. CeMal was adsorbed on the surface of AA2024-T3 forming a protective film in the initial stage. Then, cerium cations transformed to cerium oxide/hydroxides, precipitating on the cathode sites to inhibit the further corrosion. The electrochemical impedance spectra results of the sol-gel coatings proved that CeMal was an effective corrosion inhibitor in the sol-gel coatings to provide corrosion protection for AA2024-T3.展开更多
Microstructure and mechanical properties of AA2024 after severe plastic deformation （SPD） and non-isothermal annealing were investigated. The non-isothermal treatment was carried out on the severely deformed AA2024,...Microstructure and mechanical properties of AA2024 after severe plastic deformation （SPD） and non-isothermal annealing were investigated. The non-isothermal treatment was carried out on the severely deformed AA2024, and the interaction between restoration and precipitation phenomena was investigated. Differential scanning calorimetry, hardness and shear punch tests illustrate that static recovery and dissolution of GPB zones/Cu-Mg co-clusters occur concurrently through non-isothermal annealing. Scanning electron microscope and electron backscatter diffraction illustrate that non-isothermal annealing of deformed AA2024 up to 250 ℃ promotes the particle-free regions and also particle stimulated nucleation. Results show that through heating with the rate of 10 ℃/min up to 250 ℃, the ultimate shear strength and the hardness are maximum due to the presence of S＇/S phases which have been detected during non-isothermal differential scanning calorimetry experiment. Also, recrystallization phenomenon occurs in temperature range which includes the dissolution of S＇/S phases. The concurrent recrystallization and dissolution of S＇/S phase at 380 ℃ have been verified by differential scanning calorimetry, mechanical properties, and optical microscope.展开更多
基金funding support of Babol Noshirvani University of Technology,Iran,through Grant Program No.BNUT/370167/99。
文摘The effects of Ag on the microstructure, mechanical properties, and electrical conductivity of AA2024 aluminum alloy coating were investigated. It was fabricated by friction surfacing as an additive manufacturing process. To carry out this investigation, Ag was added by 5.3, 10.6, and 16.0 wt.% to an AA2024 consumable rod by inserting holes in it. It was found that due to the strengthening by solid solution and the formation of precipitates and intermetallic containing Ag, the driving force for grain growth is reduced and consequently the grain size of the coating is decreased. After artificial aging heat treatment, the electrical conductivities of the coatings containing 0 and 16.0 wt.% Ag are increased by 4.15%(IACS) and decreased by 2.15%(IACS), respectively. While considering a linear relationship, it can be proposed that for a 1 wt.% Ag increase, the strength and hardness of the coating will be increased by 1.8% and 1.0%, respectively. It was established that the effect of Al6(Cu,Ag)Mg4 precipitate formation on strengthening is greater than that of Ag-rich intermetallic.
基金Supported by the Fok Ying-Tong Education Foundation for Young Teachers in the Higher Education Institutions of China(No.131052)+6 种基金
the Fundamental Research Funds for the Central Universities(No.3102014JC02010404)
the Research Fund of the State Key Laboratory of Solidification Processing(No.108-QP-2014)
the Graduate Starting Seed Fund of Northwestern Polytechnical University(No.Z2013019)
the “111” Project(No.B08040)
文摘The joining of aluminum alloy sheets with thickness less than 2.0 mm is difficult via conventional frictionstir welding owing to the defects in the joint, such as root flaw, keyhole and lazy S. In the present research, a newlydesigned pinless tool with involute grooves on its shoulder surface was applied to weld 1.5 mm thick AA2024-T3. Theeffects of the rotating speed and welding speed on the microstructure and mechanical properties of the joints were analyzed.The experimental results showed that the root flaw and keyhole were successfully eliminated. The lazy S wasalso eliminated under the optimized welding parameters. The maximum tensile strength of the joints was 326 MPa,which is about 74.1% that of the base material. Moreover, all the tensile samples fractured from the retreating side.Two fracture modes were observed during the tensile tests, which are related with the lazy S.
文摘Aluminium alloy（AA） 2024 is an important engineering material due to its widespread use in the aerospace industry. However, it is very prone to corrosion attack in chloride containing media. In the present investigation, AA2024 aluminium alloy rolled plates of 5 mm in thickness were friction stir welded. Corrosion performances of the specimens were evaluated by conducting salt fog tests in Na Cl solution at different p H values, chloride ion concentrations and spraying time. In addition, an empirical relationship was established to predict the corrosion rate of friction stir welds of AA2024 aluminium alloy. A central composite rotatable design including three factors and five levels was used to minimize the number of experiments. Response surface methodology（RSM） was used to develop the relationship. The corrosion rate decreased under neutral p H conditions. The corrosion rate increased in acidic and basic conditions. It was also found that the corrosion rate decreased with the increase of spraying time, but the corrosion tended to be uniform with the increment of time and with the increase in the chloride ion concentration, and the corrosion rate increased in the salt spray corrosion test.
文摘Given the nonuse of TiO2 nanoparticles as the reinforcement of AA2024 alloy in fabricating composites by ex-situ casting methods,it was decided to process the AA2024−xTiO2(np)(x=0,0.5 and 1 vol.%)nanocomposites by employing the stir casting method.The structural properties of the produced samples were then investigated by optical microscopy and scanning electron microscopy;their mechanical properties were also addressed by hardness and tensile tests.The results showed that adding 1 vol.%TiO2 nanoparticles reduced the grain size and dendrite arm spacing by about 66%and 31%,respectively.Also,hardness,ultimate tensile strength,yield strength,and elongation of AA2024−1vol.%TiO2(np)composite were increased by about 25%,28%,4%and 163%,respectively,as compared to those of the monolithic component.The agglomerations of nanoparticles in the structure of nanocomposites were found to be a factor weakening the strength against the strengthening mechanisms.Some agglomerations of nanoparticles in the matrix were detected on the fractured surfaces of the tension test specimens.
文摘In the present study,the effect of reduction of cutting fluid consumption on the surface quality and tool wear was studied.Mathematical models were developed to predict the surface roughness using response surface methodology(RSM).Analysis of variance(ANOVA)was used to investigate the significance of the developed regression models.The results showed that the coefficient of determination values(R^2)for the developed models was 97.46%for dry,89.32%for flood mode(FM),and 99.44%for MQL,showing the high accuracy of fitted models.Also,under the minimum quantity lubrication(MQL)condition,the surface roughness improved by 23%−44%and 19%−41%compared with dry and FM,respectively,and the SEM images of machined surface proved the statement.The prepared SEM images of tool rake face also showed a considerable decrease in adhesion wear.Built-up edge and built-up layer were the two main products of the adhesion wear,and energy-dispersive X-ray spectroscopy(EDX)analysis of specific points on the tool faces helped to discover the chemical compositions of adhered materials.By changing dry and FM to MQL mode,dominant mechanism of tool wear in machining aluminum alloy was significantly decreased.Breakage wear that led to early failure of cutting edge was also controlled by MQL technique.
文摘The effect of non-isothermal aging treatment on microstructure and mechanical properties of in-situ AA2024−Al_(3)NiCu composite fabricated by the stir casting process was examined.The Al_(3)NiCu intermetallic was created by adding 3 wt.%nickel powder during stir casting and homogenization treatment at 500℃ for 24 h after casting.The microstructural results obtained using optical and scanning electron microscope indicate that,after non-isothermal aging treatment,the S-Al_(2)CuMg precipitates become finer,forming a poor zone of this precipitate in the area between the dendrites.Also,adding nickel during stir casting reduces the precipitation rate and the contribution of S-Al_(2)CuMg precipitates in strengthening composite during non-isothermal aging.The maximum hardness,ultimate tensile strength,and toughness achieved in the 3 wt.%nickel-containing sample after non-isothermal aging at 250℃ are(121.30±4.21)HV,(221.67±8.31)MPa,and(1.67±0.08)MJ/m^(3),respectively.The maximum hardness and ultimate tensile strength of AA2024−Al_(3)NiCu composite are decreased by 6%and 4%,respectively,compared to those of nickel-free AA2024 aluminum alloy.
基金Project(92066205) supported by the National Natural Science Foundation of ChinaProject(JCKY61420052008)supported by the National Defense Science and Technology Key Laboratory Foundation,China+2 种基金Project(311021013)supported by Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai),ChinaProject(FRF-MP-20-52) supported by the Fundamental Research Funds for the Central Universities,ChinaProject(075-15-2021-612) support from the Government of the Russian Federation。
文摘The extruded plate of powder metallurgy AA2024 aluminum alloy was successfully solid-state joined by friction stir welding(FSW) to demonstrate potential applications in the aerospace and automotive industries. For determining the optimal processing parameters of FSW, the microstructure, mechanical properties, and fracture behavior of FSW joints were evaluated. When the processing parameters were optimized with 2000 r/min rotation speed and100 mm/min traverse speed, high quality welds were achieved. The ultimate tensile strength yield strength and elongation of the joint can reach 415 MPa(85% of the base metal strength), 282 MPa, and 9.5%, respectively. The hardness of the joint gradually decreased from the alloy matrix to the heat-affected zone. The lowest strength and hardness appeared near the heat-affected zone because of the over-aging caused by heat flow from repeated stirring during FSW. The average grain size of the stir zone(2.15 μm) was smaller than that of the base metal(4.43 μm) and the heat-affected zone(5.03 μm), whose grains had <110> preferred orientation.
基金supported by the National Natural Science Foundation of China(No.51175252)
文摘Hot forming with synchronous cooling(HFSC)is a novel technique for heat-treatable,high-strength aluminum alloys,which allows the alloys to acquire good formability,negligible springback,rapid processing and better mechanical properties.However,the deformation behavior and microstructure evolution of the alloys during HFSC are complex and need to be studied due to the temperature and strain rate effects.Uniaxial tensile tests in a temperature range of 250—450℃and a strain rate range of 0.01—1 s-1 for AA2024-H18 aluminum alloy sheet are conducted with a Gleeble-3500 Thermal-Mechanical Simulation Tester.And based on metallography observation and analysis,AA2024-H18 aluminum alloy sheet in HSFC process exhibits hardening and dynamic recovery behaviors within the temperature range of 250—450 ℃.Strain rate shows different effects on ductility at different temperatures.Compared with traditional warm/hot forming methods,AA2024-H18 aluminum alloy achieves a better work-hardening result through HFSC operations,which promises an improved formability at elevated temperature and thus good mechanical properties of final part.After HSFC operations,the microstructure of the specimens is composed of elongated static recrystallization grain.
文摘The objectives of this study were to produce ultrafine-grained(UFG) AA2024 aluminum alloy by cryorolling followed by aging and to evaluate its corrosion behavior. Solutionized samples were cryorolled to ~85% reduction in thickness. Subsequent aging resulted in a UFG structure with finer precipitates of Al_2CuMg in the cryorolled alloy. The(1) solutionized and(2) solutionized and cryorolled samples were uniformly aged at 160°C/24 h and were designated as CGPA and CRPA, respectively; these samples were subsequently subjected to corrosion studies. Potentiodynamic polarization studies in 3.5 wt% NaCl solution indicated an increase in corrosion potential and a decrease in corrosion current density for CRPA compared to CGPA. In the case of CRPA, electrochemical impedance spectroscopic studies indicated the presence of two complex passive oxide layers with a higher charge transfer resistance and lower mass loss during intergranular corrosion tests. The improved corrosion resistance of CRPA was mainly attributed to its UFG structure, uniform distribution of fine precipitates, and absence of coarse grain-boundary precipitation and associated precipitate-free zones as compared with the CGPA alloy.
文摘zirconia-based nanostructured coatings were deposited on AA2024 to improve the corrosion resistance properties. Three different nanostructured coatings, namely, zirconia–benzotriazole, zirconia–alumina–benzotriazole, and zirconia–yttria–benzotriazole, were applied on AA2024 via a sol–gel method using the dip-coating technique. Next, the coatings were annealed at 150°C after each dipping period. The phases and morphologies of the coatings were investigated using grazing incidence X-ray diffraction(GIXRD), Fourier transform infrared spectroscopy(FT-IR), field emission scanning electron microscopy(FESEM), and atomic force microscopy(AFM). The corrosion properties were evaluated using electrochemical methods, including polarization and electrochemical impedance techniques in 3.5 wt% NaCl solution. The obtained results confirm the formation of homogeneous and crack free zirconia-benzotriazole-based nanostructured coatings. The average roughness values for zirconia-benzotriazole, zirconia-alumina-benzotriazole, and zirconia-yttria-benzotriazole nanostructured coatings were 30, 8, and 6 nm, respectively. The presence of alumina as a stabilizer on zirconia coating was found to have a beneficial impact on the stability of the corrosion resistance for different immersion times. In fact, the addition of alumina resulted in the dominance of the healing behavior in competition with the corrosion process of zirconia-benzotriazole nanostructured coating.
基金financial support from the National Natural Science Foundation of China (Grant Nos. 51571202 and 51001109)
文摘Cerium malate (CeMal) was tested as a corrosion inhibitor for AA2024-T3 in this work. Corrosion inhibition on bare AA2024-T3 indicated that the inhibiting effect was a result of the synergistic effect of cerium cations and maleic anions. The corrosion of AA2024-T3 was stagnated by greatly reducing the corrosion current when CeMal was present in NaCl solutions. CeMal was adsorbed on the surface of AA2024-T3 forming a protective film in the initial stage. Then, cerium cations transformed to cerium oxide/hydroxides, precipitating on the cathode sites to inhibit the further corrosion. The electrochemical impedance spectra results of the sol-gel coatings proved that CeMal was an effective corrosion inhibitor in the sol-gel coatings to provide corrosion protection for AA2024-T3.
基金research board of Sharif University of Technology for the financial support and the provision of the research facilities used in this work
文摘Microstructure and mechanical properties of AA2024 after severe plastic deformation （SPD） and non-isothermal annealing were investigated. The non-isothermal treatment was carried out on the severely deformed AA2024, and the interaction between restoration and precipitation phenomena was investigated. Differential scanning calorimetry, hardness and shear punch tests illustrate that static recovery and dissolution of GPB zones/Cu-Mg co-clusters occur concurrently through non-isothermal annealing. Scanning electron microscope and electron backscatter diffraction illustrate that non-isothermal annealing of deformed AA2024 up to 250 ℃ promotes the particle-free regions and also particle stimulated nucleation. Results show that through heating with the rate of 10 ℃/min up to 250 ℃, the ultimate shear strength and the hardness are maximum due to the presence of S＇/S phases which have been detected during non-isothermal differential scanning calorimetry experiment. Also, recrystallization phenomenon occurs in temperature range which includes the dissolution of S＇/S phases. The concurrent recrystallization and dissolution of S＇/S phase at 380 ℃ have been verified by differential scanning calorimetry, mechanical properties, and optical microscope.
