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硫酸铝和蔗糖合成ALN纳米粉实验研究
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作者 赵民 王宗英 孙旭东 《机械设计与制造》 2004年第5期104-105,共2页
利用硫酸铝和蔗糖合成ALN纳米粉,通过X射线衍射仪对实验产物进行物相分析,以确定产物的物相组成。采用PhilipsEM420分析电子显微镜观察ALN颗粒粒度为50nm,同时对合成机理进行了研究。通过实验结果表明该方法可行。
关键词 硫酸铝 aln纳米粉 工艺
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在NH_3-C_3H_8混合气氛下通过还原-氮化γ-Al_2O_3合成制备AlN纳米粉
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作者 冯海霞 《耐火与石灰》 2007年第5期32-35,共4页
以NH3和C3H8作为反应气体,通过还原-氮化γ-Al2O3可合成制得AlN纳米粉。我们已经通过分析确认:通过NH3和C3H8的混合气流,在1100℃~1400℃保温120min的条件下通过气相还原-氮化γ-Al2O3制得的合成产物中确实存在AlN相,而且在1100℃保温1... 以NH3和C3H8作为反应气体,通过还原-氮化γ-Al2O3可合成制得AlN纳米粉。我们已经通过分析确认:通过NH3和C3H8的混合气流,在1100℃~1400℃保温120min的条件下通过气相还原-氮化γ-Al2O3制得的合成产物中确实存在AlN相,而且在1100℃保温120min后合成制得的产物中还包含未反应的γ-Al2O3。Al核磁共振的图谱显示:产物中的Al-N键随反应温度的提高而增强:[AlO4]四面体比[AlO6]八面体的谐振先削弱,这表明γ-Al2O3中的[AlO4]四面体比[AlO6]八面体更易氮化,基于这一点,可在低温条件下从γ-Al2O3中直接制得AlN纳米粒子。通过气相还原-氮化γ-Al2O3制得AlN纳米粒子的原因是:一方面因为反应温度足够低限制了晶粒生长;另一方面也因为γ-Al2O3只含有[AlO6]一种配位体,而γ-Al2O3则包含两种配位多面体结构即[AlO4]和[AlO6]。 展开更多
关键词 还原-氧化 合成 aln纳米粉 配位体
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Structural and mechanical properties of CuZr/AlN nanocomposites 被引量:1
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作者 谷曼 吴玉程 +1 位作者 焦明华 黄新民 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第2期380-384,共5页
Powder metallurgy method was used to prepare copper alloy nanocomposites (CuZr/AlN) with high strength and conductivity. Optical microscopy, high-resolution transmission electron microscopy and other methods were ad... Powder metallurgy method was used to prepare copper alloy nanocomposites (CuZr/AlN) with high strength and conductivity. Optical microscopy, high-resolution transmission electron microscopy and other methods were adopted to study the impact of different sintering technologies on the structural and mechanical properties as well as the impact of solution and aging treatments on the mechanical properties of CuZr/AlN. The result shows that the specimen has a dense structure, and the size of the crystal grain is around 0.2 μm. The Brinell hardness of the specimen increases with the increase in re-pressing pressure and sintering temperature. The Brinell hardness of specimen also increases with the increase in zirconium content. However, above 0.5%(mass fraction) of zirconium content, the Brinell hardness of the nanocomposites is reduced. The buckling strength of the specimens increases with the increase in re-pressing pressure and sintering temperature. The buckling strength is the highest when the zirconium content is 0.5%. The Brinell hardness is lower after solution and aging treatments at 900 ℃. The Brinell hardness of the CuZr/AlN series specimen after the aging treatment at 500 ℃ or 600 ℃ increases. The specimen was also over aged at 700 ℃. 展开更多
关键词 CuZr/aln nanocomposites powder metallurgy mechanical properties
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