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Gas Sources of Natural Gas Hydrates in the Shenhu Drilling Area, South China Sea: Geochemical Evidence and Geological Analysis 被引量:13
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作者 ZHU Youhai HUANG Xia +1 位作者 FU Shaoying SU Pibo 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2013年第3期767-776,共10页
The Shenhu gas hydrate drilling area is located in the central Baiyun sag, Zhu I! depression, Pearl River Mouth basin, northern South China Sea. The gas compositions contained in the hydrate-bearing zones is dominated... The Shenhu gas hydrate drilling area is located in the central Baiyun sag, Zhu I! depression, Pearl River Mouth basin, northern South China Sea. The gas compositions contained in the hydrate-bearing zones is dominated by methane with content up to 99.89% and 99.91%. The carbon isotope of the methane (δ^13C1) are -56.7%0. and -60.9%0, and its hydrogen isotope (δD) are -199%0 and -180%0, respectively, indicating the methane from the microbial reduction of CO2. Based on the data of measured seafloor temperature and geothermal gradient, the gas formed hydrate reservoirs are from depths 24-1699 m below the seafloor, and main gas-generation zone is present at the depth interval of 416-1165 m. Gas-bearing zones include the Hanjiang Formation, Yuehai Formation, Wanshan Formation and Quaternary sediments. We infer that the microbial gas migrated laterally or vertically along faults (especially interlayer faults), slump structures, small-scale diapiric structures, regional sand beds and sedimentary boundaries to the hydrate stability zone, and formed natural gas hydrates in the upper Yuehai Formation and lower Wanshan Formation, probably with contribution of a little thermogenic gas from the deep sedments during this process. 展开更多
关键词 natural gas hydrate METHANE microbial gas gas source MIGRATION South China Sea
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Study of the gas sources of the Ordovician gas reservoir in the Central-Eastern Ordos Basin 被引量:3
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作者 Ji-Jun Li Zi-Wei Song +4 位作者 Chun-Lin Zhang Shuang-Fang Lu Mei-Jun Dong Shu-Ning Zhang Jun Jiang 《Petroleum Science》 SCIE CAS CSCD 2022年第3期949-962,共14页
The source of the natural gas in the Lower Paleozoic Ordovician strata in the Ordos Basin,China is a controversial issue.In the present study,the genesis and distribution characteristics of the Ordovician natural gas ... The source of the natural gas in the Lower Paleozoic Ordovician strata in the Ordos Basin,China is a controversial issue.In the present study,the genesis and distribution characteristics of the Ordovician natural gas were qualitatively investigated based on the composition of the natural gas and the hydrocarbon isotopic composition.Then,the kinetics of the carbon isotope were analyzed to determine the proportions of the gas in the Ordovician gas reservoir contributed from the Carboniferous-Permian and Ordovician strata.The results show the following.Compared to the Upper Paleozoic natural gas,the Ordovician natural gas has a large dryness coefficient.In core areas where gypsum-salt rocks are developed,the gypsum-salt rocks completely isolate the gas sources.The weathering crust of the reservoir in the fifth member of the Majiagou Formation(Ma_(5)^(1+2))originates primarily from the Upper Paleozoic coal-measure source rocks,while the Ma_(5)^(5)and the pre-salt natural gas are mainly derived from the Ordovician source rocks.In the areas where the gypsum-salt rocks are relatively well-developed,the gypsum-salt rocks isolate the gas source to some extent,the pre-salt gas reservoir is mainly derived from the Lower Paleozoic source rocks,and this contribution gradually increases with increasing depth.In the areas where the gypsum-salt rocks are not developed,the proportion of the contribution of the Upper and Lower Paleozoic source rocks to the gas source of the Ordovician gas reservoir is mainly controlled by the volume of gas generated and the other accumulation conditions,and it does not reflect the isolation effect of the gypsum-salt rocks on the gas source.The Ordovician natural gas accumulation models in the central-eastern Ordos Basin can be divided into four types according to the differences in the gas sources. 展开更多
关键词 Ordos Basin Majiagou Formation Carbon isotope kinetics Gypsum layer gas source
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Effect of Gas Sources on the Deposition of Nano-Crystalline Diamond Films Prepared by Microwave Plasma Enhanced Chemical Vapor Deposition 被引量:1
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作者 翁俊 熊礼威 +2 位作者 汪建华 满卫东 陈冠虎 《Plasma Science and Technology》 SCIE EI CAS CSCD 2010年第6期761-764,共4页
Nano-crystalline diamond (NCD) films were deposited on silicon substrates by a microwave plasma enhanced chemical vapor deposition (MPCVD) reactor in C2H5OH/H2 and CH4/H2/O2 systems, respectively, with a constant ... Nano-crystalline diamond (NCD) films were deposited on silicon substrates by a microwave plasma enhanced chemical vapor deposition (MPCVD) reactor in C2H5OH/H2 and CH4/H2/O2 systems, respectively, with a constant ratio of carbon/hydrogen/oxygen. By means of atomic force microscopy (AFM) and X-ray diffraction (XRD), it was shown that the NCD films deposited in the C2H5OH/H2 system possesses more uniform surface than that deposited in the CH4/H2/O2 system. Results from micro-Raman spectroscopy revealed that the quality of the NCD films was different even though the plasmas in the two systems contain exactly the same proportion of elements. In order to explain this phenomenon, the bond energy of forming OH groups, energy distraction in plasma and the deposition process of NCD films were studied. The experimental results and discussion indicate that for a same ratio of carbon/hydrogen/oxygen, the C2H5OH/H2 plasma was beneficial to deposit high quality NCD films with smaller average grain size and lower surface roughness. 展开更多
关键词 nano-crystalline diamond thin film chemical vapor deposition gas source ethanol
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Gas Sources of Natural Gas Hydrates in the Muli Permafrost of Qilian Mountain 被引量:1
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作者 CHENG Qingsong GONG Jianming ZHANG Min 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第6期2281-2282,共2页
The gas hydrates in the permafrost region of Qilian Mountain are characterized by low latitude, thin thickness, shallow burial depth, abundant coal seams, high contents of heavy hydrocarbons and multiple sets of sourc... The gas hydrates in the permafrost region of Qilian Mountain are characterized by low latitude, thin thickness, shallow burial depth, abundant coal seams, high contents of heavy hydrocarbons and multiple sets of source rocks. Up to date, the source of gas or the main source rocks of the Mull gas hydrates have remained unclear. 展开更多
关键词 gas sources of Natural gas Hydrates in the Muli Permafrost of Qilian Mountain ROCK
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Gas Sources for Natural Gas Hydrates in the Permafrost Region of the Qilian Mountains 被引量:1
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作者 JIANG Yubo GONG Jianming 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第5期1925-1925,共1页
Objective As a new type of gas hydrates,the natural gas hydrates in the perfost region of the Qilian Mountains are characterized by their shallow burial depth,welldeveloped coal seam,high content of heavy hydrocarbons... Objective As a new type of gas hydrates,the natural gas hydrates in the perfost region of the Qilian Mountains are characterized by their shallow burial depth,welldeveloped coal seam,high content of heavy hydrocarbons and multiple sets of mature and over-mature source rocks.Gas sources of these gas hydrates in the study area include coal-type gas and oil-type gas. 展开更多
关键词 area gas sources for Natural gas Hydrates in the Permafrost Region of the Qilian Mountains
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Oil and gas source and accumulation of Zhongqiu 1 trap in Qiulitage structural belt, Tarim Basin, NW China
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作者 LI Jian LI Jin +7 位作者 XIE Zengye WANG Chao ZHANG Haizu LIU Mancang LI Dejiang MA Wei MAO Danfeng ZENG Xu 《Petroleum Exploration and Development》 2020年第3期548-559,共12页
Well Zhongqiu 1 obtained highly productive oil-gas stream in the footwall of Zhongqiu structure, marking the strategic breakthrough of Qiulitag structural belt in the Tarim Basin. However, the oil and gas sources in Z... Well Zhongqiu 1 obtained highly productive oil-gas stream in the footwall of Zhongqiu structure, marking the strategic breakthrough of Qiulitag structural belt in the Tarim Basin. However, the oil and gas sources in Zhongqiu structural belt and the reservoir formation process in Zhongqiu 1 trap remain unclear, so study on these issues may provide important basis for the next step of oil and gas exploration and deployment in Qiulitage structural belt. In this study, a systematic correlation of oil and gas source in Well Zhongqiu 1 has been carried out. The oil in Well Zhongqiu 1 is derived from Triassic lacustrine mudstone, while the gas is a typical coal-derived gas and mainly from Jurassic coal measures. The oil charging in Well Zhongqiu 1 mainly took place during the sedimentary period from Jidike Formation to Kangcun Formation in Neogene, and the oil was mainly contributed by Triassic source rock;large-scale natural gas charging occurred in the sedimentary period of Kuqa Formation in Neogene, and the coal-derived gas generated in the late Jurassic caused large-scale gas invasion to the early Triassic crude oil reservoirs. The Zhongqiu 1 trap was formed earlier than or at the same period as the hydrocarbon generation and expulsion period of Triassic-Jurassic source rocks. Active faults provided paths for hydrocarbon migration. The source rocks-faults-traps matched well in time and space. Traps in the footwall of the Zhongqiu structural fault have similar reservoir-forming conditions with the Zhongqiu 1 trap, so they are favorable targets in the next step of exploration. 展开更多
关键词 Tarim Basin Kuqa foreland thrust belt Qiulitage structural belt oil and gas source oil and gas accumulation Zhongqiu1 trap
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China Eyes Additional Foreign Oil and Gas Sources
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作者 Ma Lianshan 《China Oil & Gas》 CAS 2013年第4期53-56,共4页
China is expanding its scope in looking for energy resources in foreign assets,participating actively in the international oil and gas market to ensure the domestic supply driven by economic growth.In mid-November 201... China is expanding its scope in looking for energy resources in foreign assets,participating actively in the international oil and gas market to ensure the domestic supply driven by economic growth.In mid-November 2013,Sinopec Group,the country’s largest refiner,announced it has officially completed the acquisition of one-third of Apache Corp.’s Egypt oil and gas business.On Aug 30,Sinopec and Apache had launched a global strategic partnership,with the 展开更多
关键词 LNG China Eyes Additional Foreign Oil and gas sources US THAN
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Sinian gas sources and effectiveness of primary gas-bearing system in Sichuan Basin, SW China 被引量:2
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作者 ZHAO Wenzhi XIE Zengye +4 位作者 WANG Xiaomei SHEN Anjiang WEI Guoqi WANG Zecheng WANG Kun 《Petroleum Exploration and Development》 CSCD 2021年第6期1260-1270,共11页
Based on correlation between geochemical characteristics of Sinian and Cambrian source rocks and discovered gas reservoirs,paleoand the analysis on geological conditions of reservoir formation,the sources of natural g... Based on correlation between geochemical characteristics of Sinian and Cambrian source rocks and discovered gas reservoirs,paleoand the analysis on geological conditions of reservoir formation,the sources of natural gas in the Sinian of Sichuan Basin have been discussed to sort out the contribution of Sinian source rocks to the gas reservoirs and effectiveness of Sinian primary gas-bearing system.Through the analysis of natural gas composition,carbon and hydrogen isotopes and effectiveness of Sinian accumulation assemblages,it is concluded that:(1)The natural gas derived from the Sinian source rock is characterized by low ethane content,heavy ethane carbon isotope and light methane hydrogen isotope,and obviously different from the gas generated by the Cambrian source rock.(2)The gas reservoirs discovered in Sinian Dengying Formation are sourced by Sinian and Cambrian source rocks,and the Sinian source rock contributes different proportions to the gas in the 4th member and the 2nd member of the Dengying Formation,specifically,39%and 55%to the 4th member in marginal zone and intra-platform,54%and 68%to the 2th member in the marginal zone and intra-platform respectively.(3)The effectiveness of the Sinian primary gas-bearing system depends on the gas generating effectiveness of the source kitchen,reservoir and combination of gas accumulation elements.For high-over mature marine source rocks at the Ro of less than 3.5%,besides gas generated from the thermal cracking of liquid hydrocarbon,the kerogen still has some gas generation potential by thermal degradation.In addition,the Sinian microbial dolomite still preserves relatively good-quality reservoirs despite large burial depths,which match well with other basic conditions for gas accumulation in central Sichuan paleo-uplift,increasing the possibility of Sinian primary gas-bearing system.The research results confirm that the Sinian primary gas-bearing system is likely to form large-scale accumulation. 展开更多
关键词 natural gas carbon isotope hydrogen isotope geochemical characteristics gas and source rock correlation Sinian System primary gas-bearing system Sichuan Basin
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Gas source of the Middle Jurassic Shaximiao Formation in the Zhongjiang large gas field of Western Sichuan Depression:Constraints from geochemical characteristics of light hydrocarbons
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作者 Xiaoqi Wu Jun Yang +4 位作者 Ping Wang Huaji Li Yingbin Chen Chunhua Ni Huasheng Zeng 《Energy Geoscience》 EI 2024年第2期141-151,共11页
The Zhongjiang gas field is a typical large gas field in terrigenous strata of the Western Sichuan Depression.It remains debatable which member of the Upper Triassic Xujiahe Formation served as the source rocks and ho... The Zhongjiang gas field is a typical large gas field in terrigenous strata of the Western Sichuan Depression.It remains debatable which member of the Upper Triassic Xujiahe Formation served as the source rocks and how significant the member contributed to the gas accumulations in the Zhongjiang gas field.In this study,we analyzed the essential characteristics of the Lower Jurassic source rocks and the geochemical features of light hydrocarbons in natural gas from the 2nd(T3χ^(2))and 4th members(T3χ^(4))of the Upper Triassic Xujiahe Formation(T3χ),as well as the Middle Jurassic Shaximiao(J2s)and Qianfoya(J2q)formations.Based on this,we explored the sources of the natural gas in the Zhongjiang gas field and determined the natural gas migration patterns and their effects on the properties of light hydrocarbons in the natural gas.The results indicate that the Lower Jurassic lacustrine source rocks of the Zhongjiang gas field contain humic organic matter,with vitrinite reflectance(R_(0))values ranging from 0.86%to 0.98%.Samples meeting the criterion for effective source rocks[total organic carbon(TOC)content≥0.75%]exhibited an average TOC content of merely 1.02%,suggesting significantly lower hydrocarbon generation potential than source rocks in the underlying T3x,which show higher thermal maturity and TOC contents.For natural gas samples from T3χ^(2),T3χ^(4),J2s,and J2q reservoirs,their C_(5-7)iso-alkane content was significantly higher than their n-alkane content,and their methylcyclohexane(MCH)index ranged from 59.0%to 77.3%,indicating the predominance of methylcyclohexane in C_(7)light hydrocarbons.As indicated by the origin identification and gas-source correlation based on the geochemical features of light hydrocarbons,the natural gas in the Zhongjiang gas field is typical coal-derived gas.The gas from the primary pay zone of the Shaximiao Formation,with significantly high K_(1),(P_(2)+N_(2))/C_(7),and P_(3)/C_(7)values,predominantly originated from the 5th member of the T3x and migrated in the free phase,with a small amount possibly sourced from the Lower Jurassic source rocks.The dissolution and adsorption during gas migration led to a decrease in the aromatic content in C_(6-7)light hydrocarbons and an increase in the isoheptane values.Therefore,their effects must be considered when determining the gas origin and thermal maturity based on the aromatic content in C_(6-7) light hydrocarbons and iso-heptane values. 展开更多
关键词 Zhongjiang gas field source rock Origin of natural gas Light hydrocarbon geochemistry Natural gas migration
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Neutronics analysis of a subcritical blanket system driven by a gas dynamic trap-based fusion neutron source for ^(99)Mo production 被引量:2
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作者 Hou-Hua Xiong Qiu-Sun Zeng +5 位作者 Yun-Cheng Han Lei Ren Isaac Kwasi Baidoo Ni Chen Zheng-Kui Zeng Xiao-Yu Wang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第4期14-25,共12页
Gamma-emitting radionuclide ^(99m)Tc is globally used for the diagnosis of various pathological conditions owing to its ideal single-photon emission computed tomography (SPECT) characteristics.However,the short half-l... Gamma-emitting radionuclide ^(99m)Tc is globally used for the diagnosis of various pathological conditions owing to its ideal single-photon emission computed tomography (SPECT) characteristics.However,the short half-life of ^(99m)Tc (T_(1/2)=6 h)makes it difficult to store or transport.Thus,the production of ^(99m)Tc is tied to its parent radionuclide ^(99)Mo (T_(1/2)=66 h).The major production paths are based on accelerators and research reactors.The reactor process presents the potential for nuclear proliferation owing to its use of highly enriched uranium (HEU).Accelerator-based methods tend to use deuterium–tritium(D–T) neutron sources but are hindered by the high cost of tritium and its challenging operation.In this study,a new ^(99)Mo production design was developed based on a deuterium–deuterium (D–D) gas dynamic trap fusion neutron source (GDT-FNS) and a subcritical blanket system (SBS) assembly with a low-enriched uranium (LEU) solution.GDT-FNS can provide a relatively high-neutron intensity,which is one of the advantages of ^(99)Mo production.We provide a Monte Carlo-based neutronics analysis covering the calculation of the subcritical multiplication factor (k_(s)) of the SBS,optimization design for the reflector,shielding layer,and ^(99)Mo production capacity.Other calculations,including the neutron flux and nuclear heating distributions,are also provided for an overall evaluation of the production system.The results demonstrated that the SBS meets the nuclear critical safety design requirement (k_(s)<0.97) and maintained a high ^(99)Mo production capacity.The proposed system can generate approximately 157 Ci ^(99)Mo for a stable 24 h operation with a neutron intensity of 1×10^(14) n/s,which can meet 50%of China’s demand in 2025. 展开更多
关键词 gas dynamic trap Fusion neutron source Molybdenum-99 Low-enriched uranium Subcritical blanket system
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Evaluation of the oil and gas preservation conditions, source rocks, and hydrocarbongenerating potential of the Qiangtang Basin: New evidence from the scientific drilling project 被引量:2
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作者 Li-jun Shen Jian-yong Zhang +4 位作者 Shao-yun Xiong Jian Wang Xiu-gen Fu Bo Zheng Zhong-wei Wang 《China Geology》 CAS CSCD 2023年第2期187-207,共21页
The Qiangtang Basin of the Tibetan Plateau,located in the eastern Tethys tectonic domain,is the largest new marine petroliferous region for exploration in China.The scientific drilling project consisting primarily of ... The Qiangtang Basin of the Tibetan Plateau,located in the eastern Tethys tectonic domain,is the largest new marine petroliferous region for exploration in China.The scientific drilling project consisting primarily of well QK-1 and its supporting shallow boreholes for geological surveys(also referred to as the Project)completed in recent years contributes to a series of new discoveries and insights into the oil and gas preservation conditions and source rock evaluation of the Qiangtang Basin.These findings differ from previous views that the Qiangtang Basin has poor oil and gas preservation conditions and lacks high-quality source rocks.As revealed by well QK-1 and its supporting shallow boreholes in the Project,the Qiangtang Basin hosts two sets of high-quality regional seals,namely an anhydrite layer in the Quemo Co Formation and the gypsum-bearing mudstones in the Xiali Formation.Moreover,the Qiangtang Basin has favorable oil and gas preservation conditions,as verified by the comprehensive study of the sealing capacity of seals,basin structure,tectonic uplift,magmatic activity,and groundwater motion.Furthermore,the shallow boreholes have also revealed that the Qiangtang Basin has high-quality hydrocarbon source rocks in the Upper Triassic Bagong Formation,which are thick and widely distributed according to the geological and geophysical data.In addition,the petroleum geological conditions,such as the type,abundance,and thermal evolution of organic matter,indicate that the Qiangtang Basin has great hydrocarbon-generating potential. 展开更多
关键词 Scientific drilling project Oil and gas preservation source rock Quemo Co Formation Oil and gas exploration engineering Qiangtang Basin Tibet
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Optimization of sensor deployment sequences for hazardous gas leakage monitoring and source term estimation
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作者 Jikai Dong Bing Wang +3 位作者 Xinjie Wang Chenxi Cao Shikuan Chen Wenli Du 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第4期169-179,共11页
Nowadays, chemical safety has attracted considerable attention, and chemical gas leakage monitoring and source term estimation(STE) have become hot spots. However, few studies have focused on sensor layouts in scenari... Nowadays, chemical safety has attracted considerable attention, and chemical gas leakage monitoring and source term estimation(STE) have become hot spots. However, few studies have focused on sensor layouts in scenarios with multiple potential leakage sources and wind conditions, and studies on the risk information(RI) detection and prioritization order of sensors have not been performed. In this work, the monitoring area of a chemical factory is divided into multiple rectangles with a uniform mesh. The RI value of each grid node is calculated on the basis of the occurrence probability and normalized concentrations of each leakage scenario. A high RI value indicates that a sensor at a grid node has a high chance of detecting gas concentrations in different leakage scenarios. This situation is beneficial for leakage monitoring and STE. The methods of similarity redundancy detection and the maximization of sensor RI detection are applied to determine the sequence of sensor locations. This study reveals that the RI detection of the optimal sensor layout with eight sensors exceeds that of the typical layout with 12 sensors. In addition, STE with the optimized placement sequence of the sensor layout is numerically simulated. The statistical results of each scenario with various numbers of sensors reveal that STE is affected by sensor number and scenarios(leakage locations and winds). In most scenarios, appropriate STE results can be retained under the optimal sensor layout even with four sensors. Eight or more sensors are advised to improve the performance of STE in all scenarios. Moreover, the reliability of the STE results in each scenario can be known in advance with a specific number of sensors. Such information thus provides a reference for emergency rescue. 展开更多
关键词 gas leakage source term estimation Sensor layout Risk information Numerical simulation OPTIMIZATION
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Geochemical prerequisites for the formation of oil and gas accumulation zones in the South Turgay basin,Kazakhstan
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作者 Rima Kopbosynkyzy Madisheva Vassiliy Sergeevich Portnov +3 位作者 Gulmadina Bulatovna Amangeldiyeva Akmaral Bakhytbekovna Demeuova Yessimkhan Sherekhanovich Seitkhaziyev Dulat Kalimovich Azhgaliev 《Acta Geochimica》 EI CAS CSCD 2024年第3期520-534,共15页
This study predicts favorable oil and gas source-rock formation conditions in the Aryskum Depression of the South Turgay Basin,Kazakhstan.This study assesses the thermal maturity and characteristics of organic matter ... This study predicts favorable oil and gas source-rock formation conditions in the Aryskum Depression of the South Turgay Basin,Kazakhstan.This study assesses the thermal maturity and characteristics of organic matter by determining its environmental conditions using data from geochemical analysis of core(pyrolysis)and oil(biomarkers and carbon isotopic compositions)samples.According to the geochemical parameters obtained by pyrolysis,the oil generation potential of the original rocks of most studied samples varies from poor to rich.The facies–genetic organic matter is predominantly humic and less frequently humus–sapropel,indicating organic matter accumulation in the studied samples were under moderately reducing conditions(kerogenⅢand Ⅱ types)and coastal–marine environments(kerogen typeⅠ).The carbon isotopic compositions of oils derived from the Jurassic deposits of the Aryskum Depression also indicate the sapropelic and mixed humic–sapropelic type of organic matter(kerogenⅡandⅠ).Biomarker analysis of oils indicates original organic matter formation in an anoxic environment. 展开更多
关键词 South Turgay Basin Oil and gas potential source rock Organic matter KEROGEN
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Gas hydrate accumulation associated with fluid escape structure in the western margin of South China Sea
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作者 Taotao YANG Lin LI +4 位作者 Yintao LU Kaiqi YU Zhili YANG Xuefeng WANG Wei LI 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2023年第3期947-958,共12页
Gas hydrates have been found in the western continental margin of South China Sea,which are revealed by widespread bottom simulating reflectors(BSRs)imaged from a three-dimensional(3D)seismic volume near the Guangle c... Gas hydrates have been found in the western continental margin of South China Sea,which are revealed by widespread bottom simulating reflectors(BSRs)imaged from a three-dimensional(3D)seismic volume near the Guangle carbonate platform in the western South China Sea.Fluid-escape structures(faults and gas chimneys)are originated below BSR were distinguished.A comprehensive model in three-level structure was proposed to depict the gas hydrate accumulation in the study area.In Level 1,regional major faults and gas chimneys provide the first pathways of upward migration of gas near basement.In Level 2,pervasive polygonal faults in carbonate layer promote the migration of gas.In Level 3,gases sourced from near-basement accumulate within shallow sediment layers and form gas hydrate above the unit with faults once appropriate temperature and pressure occur.The gas hydrates in the study area are mainly in microbial origin,and their accumulation occurs only when fluid-escape structures align in all the three levels.The proposed model of the gas hydrate accumulation in western SCS margin provides new insights for further studies in this poorly studied area. 展开更多
关键词 gas hydrate fluid-escape structures gas sources bottom simulating reflector(BSR) South
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Kinetics and model of gas generation of source rocks in the deepwater area, Qiongdongnan Basin 被引量:3
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作者 HUANG Baojia HUANG Hao +2 位作者 WANG Zhenfeng HUANG Yiwen SUN Zhipeng 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2015年第4期11-18,共8页
In order to investigate the hydrocarbon generation process and gas potentials of source rocks in deepwater area of the Qiongdongnan Basin, kinetic parameters of gas generation (activation energy distribution and freq... In order to investigate the hydrocarbon generation process and gas potentials of source rocks in deepwater area of the Qiongdongnan Basin, kinetic parameters of gas generation (activation energy distribution and frequency factor) of the Yacheng Formation source rocks (coal and neritic mudstones) was determined by thermal simulation experiments in the closed system and the specific KINETICS Software. The results show that the activation energy (Ea) distribution of C1–C5 generation ranges from 50 to 74 kcal/mol with a frequency factor of 2.4×1015 s–1 for the neritic mudstone and the Ea distribution of C1–C5 generation ranges from 49 to 73 kcal/mol with a frequency factor of 8.92×1013 s–1 for the coal. On the basis of these kinetic parameters and combined with the data of sedimentary burial and paleothermal histories, the gas generation model of the Yacheng Formation source rocks closer to geological condition was worked out, indicating its main gas generation stage at Ro (vitrinite reflectance) of 1.25%–2.8%. Meanwhile, the gas generation process of the source rocks of different structural locations (central part, southern slope and south low uplift) in the Lingshui Sag was simulated. Among them, the gas generation of the Yacheng Formation source rocks in the central part and the southern slope of the sag entered the main gas window at 10 and 5 Ma respectively and the peak gas generation in the southern slope occurred at 3 Ma. The very late peak gas generation and the relatively large gas potential indices (GPI:20×10^8–60×10^8 m^3/km^2) would provide favorable conditions for the accumulation of large natural gas reserves in the deepwater area. 展开更多
关键词 Yacheng Formation source rock gas generation kinetics gas generation model deepwater area Qiongdongnan Basin
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Hydrocarbon Generation and Expulsion of the Upper Triassic T3x5Source Rocks in the Western Sichuan Depression: Assessment for Unconventional Natural Gas 被引量:3
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作者 GUO Yingchun SONG Yan +3 位作者 PANG Xiongqi WANG Youwei YANG Keming LI Boyuan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2015年第1期175-186,共12页
Tight-sand gas in the Jurassic and shale gas within the fifth member of Xujiahe Formation (T3xs) in the Western Sichuan Basin (WSD) are currently regarded as the most prolific emerging unconventional gas plays in ... Tight-sand gas in the Jurassic and shale gas within the fifth member of Xujiahe Formation (T3xs) in the Western Sichuan Basin (WSD) are currently regarded as the most prolific emerging unconventional gas plays in China. This study conducted a conventional evaluation of T3x5 source rocks in the WSD, and investigated their hydrocarbon generation and expulsion characteristics, including intensity, efficiency and amount. The results show that, the T3x5 source rocks are thick (generally 〉200 m), and have a high total organic content (TOC), ranging from 2.5 to 4.5 wt%. It is thus indivative of a great hydrocarbon generation potential when they underwent high thermal evolution (Ro〉1.2%) in the area. In addition, an improved method of hydrocarbon generation potential is applied, indicating that the source rocks reached a hydrocarbon expulsion threshold with vitrinite reflectance (Ro) reaching 1.06%. and that the comprehensive hydrocarbon expulsion efficiency is about 60%. The amount of hydrocarbon generation and expulsion from Tax5 source rocks is 3.14x10^10 t and 1.86x10^10 t, respectively, with a residual amount of 1.28x10^10t within them. Continuous-type tight-sand gas is predicted to have developed in the Jurassic in the Chengdu Sag of the WSD because of the good source-reservoir configuration; the Jurassic sandstone reservoirs are tight, and the gas expelled from the T3xs source rocks migrates for very short distances vertically and horizontally. The amount of gas accumulation in the Jurassic reservoirs derived from T3x5 source rocks is up to 9.3x10s t. Geological resources of shale gas are up to 1.05x10TM t. Small differences between the amounts calculated by the volumetric method and those obtained by hydrocarbon generation potential method may be due to other gas accumulations present within interbedded sands associated with gas shales. 展开更多
关键词 source rocks evaluation hydrocarbon generation and expulsion tight-sand gas shale gas resource assessment Upper Triassic Western Sichuan Depression
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“Exploring petroleum inside source kitchen”: Connotation and prospects of source rock oil and gas 被引量:5
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作者 YANG Zhi ZOU Caineng 《Petroleum Exploration and Development》 2019年第1期181-193,共13页
Based on the transitional background of the global energy structure, exploration and development of unconventional oil and gas, and investigation of key basins, the unconventional oil and gas resources are divided int... Based on the transitional background of the global energy structure, exploration and development of unconventional oil and gas, and investigation of key basins, the unconventional oil and gas resources are divided into three types: source rock oil and gas, tight oil and gas, and retention and accumulated oil and gas. Source rock oil and gas resources are the global strategic supplies of oil and gas, the key resource components in the second 150-year life cycle of the future petroleum industry, and the primary targets for "exploring petroleum inside source kitchen". The geological connotation of source rock oil and gas was proposed, and the models of source rock oil and gas generation, expulsion and accumulation were built, and five source rock oil and gas generation sections were identified, which may determine the actual resource potential under available technical conditions. The formation mechanism of the "sweet sections" was investigated, that is, shale oil is mainly accumulated in the shale section that is close to the oil generation section and has higher porosity and permeability, while the "sweet sections" of coal-bed methane(CBM) and shale gas have self-contained source and reservoir and they are absorbed in coal seams or retained in the organic-rich black shale section, so evaluation and selection of good "sweet areas(sections)" is the key to "exploring petroleum inside source kitchen". Source rock oil and gas resources have a great potential and will experience a substantial growth for over ten world-class large "coexistence basins" of conventional-unconventional oil and gas in the future following North America, and also will be the primary contributor to oil stable development and the growth point of natural gas production in China, with expected contribution of 15% and 30% to oil and gas, respectively, in 2030. Challenges in source rock oil and gas development should be paid more attention to, theoretical innovation is strongly recommended, and a development pilot zone can be established to strengthen technology and promote national support. The source rock oil and gas geology is the latest progress of the "source control theory" at the stage of unconventional oil and gas. It will provide a new theoretical basis for the new journey of the upstream business in the post-industry age. 展开更多
关键词 source rock OIL and gas SHALE gas SHALE OIL coal-bed methane SWEET section SWEET area source control theory man-made OIL and gas reservoir UNCONVENTIONAL OIL and gas revolution large“coexistence basins”of conventional-unconventional OIL and gas
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Source of nutrient substrates for microbes in deep biosphere and characteristics of biogenic gas source rock 被引量:2
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作者 SHUAI YanHua ZHANG ShuiChang +1 位作者 CHEN JianPing SU AiGuo 《Science China Earth Sciences》 SCIE EI CAS 2010年第8期1163-1168,共6页
To understand the biogas formation in geological basins, the present work investigated the reactive organic matter in sediments of the Sanhu depression of Qaidam Basin, a prolific region of biogenic gases with a prove... To understand the biogas formation in geological basins, the present work investigated the reactive organic matter in sediments of the Sanhu depression of Qaidam Basin, a prolific region of biogenic gases with a proved reserve of 300 bil steres. The ROC (reactive organic carbon) was obtained by ultrasonic extraction from sediment samples in the solution of 6 mol/L HCl and 5% K2SO4. To investigate the effect of early diagenesis, parts of the samples were heated at 80°C before extraction. The results showed that the ROC content at a constant temperature decreased with increasing burial depths, which should be attributed to the microbial consumption. For the same sample, the ROC content heated at 80°C was dramatically higher than the unheated. The increment of the ROC content for some samples was as high as 200% in the experiment. The dramatically increasing ROC by thermal action should be the major nutrient substrate for the deep biospheres in most geological basins. There is a positive correlation between the reactive organic carbon (ROC) and the traditional insoluble organic carbon (TOC), not only for its absolute content of the ROC, but also for the 'ROC' produced in thermal action, all of these are clearly related with TOC. These data showed that higher abundance of organic matter can contribute more to the reactive organic matter, and is more favorable to the formation of biogenic gases. In the Sanhu depression of Qaidam Basin, more than 85% of the biogenic gas reserves occur in the lower layers (K5-K13) with a relatively high abundance of organic matter. The exploration has provided further evidence that deposits with higher abundance of organic matter are effective biogas source rocks. 展开更多
关键词 BIOGENIC gasES gas source rock Qaidam Basin reactive organic MATTER TOC
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Downhole Microseismic Source Location Based on a Multi-Dimensional DIRECT Algorithm for Unconventional Oil and Gas Reservoir Exploration 被引量:2
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作者 YIN Qifeng TAO Pengfei +3 位作者 ZHENG Shuo HE Qing AN Yanfei GUO Quanshi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2019年第3期718-730,共13页
Downhole microseismic data has the significant advantages of high signal-to-noise ratio and well-developed P and S waves and the core component of microseismic monitoring is microseismic event location associated with... Downhole microseismic data has the significant advantages of high signal-to-noise ratio and well-developed P and S waves and the core component of microseismic monitoring is microseismic event location associated with hydraulic fracturing in a relatively high confidence level and accuracy.In this study,we present a multidimensional DIRECT inversion method for microseismic locations and applicability tests over modeling data based on a downhole microseismic monitoring system.Synthetic tests inidcate that the objective function of locations can be defined as a multi-dimensional matrix space by employing the global optimization DIRECT algorithm,because it can be run without the initial value and objective function derivation,and the discretely scattered objective points lead to an expeditious contraction of objective functions in each dimension.This study shows that the DIRECT algorithm can be extensively applied in real downhole microseismic monitoring data from hydraulic fracturing completions.Therefore,the methodology,based on a multidimensional DIRECT algorithm,can provide significant high accuracy and convergent efficiency as well as robust computation for interpretable spatiotemporal microseismic evolution,which is more suitable for real-time processing of a large amount of downhole microseismic monitoring data. 展开更多
关键词 UNCONVENTIONAL oil and gas RESERVOIR DOWNHOLE microseismic monitoring source LOCATION DIRECT algorithm
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Origin and Source of Deep Natural Gas in Nanpu sag, Bohai Bay Basin, China 被引量:3
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作者 ZHU Guangyou WANG Zhengjun +5 位作者 WANG Yongjun ZHAO Jie DONG Yuexia WANG Kai LIU Yongchang WANG Jianwei 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2013年第4期1081-1096,共16页
Natural gas exploration in Nanpu sag, Bohai Bay Basin, has achieved breakthroughs in recent years, and a number of natural gas and condensate wells with high yield have been found in several structures in the beach ar... Natural gas exploration in Nanpu sag, Bohai Bay Basin, has achieved breakthroughs in recent years, and a number of natural gas and condensate wells with high yield have been found in several structures in the beach area. Daily gas production of single wells is up to 170,000 m3, and high-yield wells are mainly distributed in?the Nanpu No. 1 structural belt.?Studies have shown that these natural gases are mainly hydrocarbon gases, with methane content about 80% to 90% and ethane 6%-9%, so they are mainly wet gas; and non-hydrocarbons are at a low level.?Carbon isotopes of methane range from -42‰ to -36‰, and ethane from -28‰ to -26‰. Calculated maturity based on the relationship between δ13C and Ro of natural gas, the gases are equivalent to those generated from organic matter when Ro is 1.0%-1.7% (mainly 1.25%-1.32%). The natural gas is oil-type gas generated from the source rocks at mature to high mature stage, associated with condensate, so carbon isotopes of the gases are heavier. Natural gas in the Nanpu No.1 structural belt is mainly associated gas with condensate. The analysis of the origin and source of natural gas and condensate, combined with the monomer hydrocarbon carbon isotopes and biomarker, indicated that the main source rocks in the Nanpu No.1 structural belt were Es3 (the lower member of the Shahejie Formation), followed by Es1 (the upper member of the Shahejie Formation).?The high-mature hydrocarbons from source rocks in the deep sag mainly migrated through deep inherited faults into shallow traps and accumulated to form oil and gas pools. Therefore, there is a great potential for exploring gas in deep layers. 展开更多
关键词 Deep layer Natural gas CONDENSATE source rocks Shahejie Formation Nanpu sag Bohai Bay Basin
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