Mg alloys conventionally rolled often present strong basal textures that affect negatively further deformations,limiting their applications.The present research found that cross-rolling experiences in adequate conditi...Mg alloys conventionally rolled often present strong basal textures that affect negatively further deformations,limiting their applications.The present research found that cross-rolling experiences in adequate conditions can weaken those intense basal textures as a result of the interaction of deformation mechanisms and dynamic recrystallization.The effects of rolling temperature and strain rate on the microstructure and texture of an AZ31B magnesium alloy sheet generated heterogeneous microstructure where the initial basal texture was strengthened during cold cross-rolling and it was gradually weakening by the rolling reduction and the rolling temperature increases in such a way that a rather weak basal fiber was produced applying reductions higher than 15%at temperatures higher than 200℃.Their ODF functions supported the texture weakening,exhibiting a combination of two crystallographic orientations represented by{0001}<211^(-)0>and{0001}<101^(-)0>.展开更多
To improve the wear resistance and corrosion resistance of magnesium alloys, a 5 kW continuous wave CO2 laser was used to investigate the laser surface cladding on AZ31 B magnesium alloys with Al-Si/Al2O3-TiO2 composi...To improve the wear resistance and corrosion resistance of magnesium alloys, a 5 kW continuous wave CO2 laser was used to investigate the laser surface cladding on AZ31 B magnesium alloys with Al-Si/Al2O3-TiO2 composite powders. A detailed microstructure, chemical composition, and phase analysis of the composite coatings were studied by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). The laser cladding shows good metallurgical bonding with the substrate. The composite coatings are composed of Mgl7Al12, Al3Mg2, Mg2Si, Al2O3, and TiO2 phases. Compared to the average microhardness (50HV0.05) of the AZ3 1 B substrate, that of the composite coatings (230HV0.05) is improved significantly. The wear resistances of the surface layers were evaluated in detail. The results demonstrate that the wear resistances of the laser surface-modified samples are considerably improved compared to the substrate. It also show that the composite coatings exhibit better corrosion resistance than that of the substrate in 3.5wt% NaCI solution.展开更多
An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction ...An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction (XRD) was used to identify the phases. Microstructure and properties of laser melted layer of AZ31B magnesium alloy were observed or tested by means of optical microscope (OM), scanning electron microscope (SEM), micro-hardness equipment and electrochemical corrosion equipment etc. The results show that the microstructure of laser melted layer becomes finer significantly and uniform. Compared with the substrate, the content of β-Mg17 Al12 phase of melted layer decreases comparatively. Microhardness of the laser melted layer is improved to 50 -95 HV0. 05 as compared to 40 -45 HV0.05 of the AZ31B Mg alloy substrate. The results of electrochemical corrosion show that the corrosion resistance of laser surface melted layer has been improved.展开更多
At the initial rolling temperature of 250 to 400 ℃, AZ31B magnesium alloy sheets were hot rolled by four different rolling routes. Microstructures and mechanical properties of the hot-rolled magnesium alloy sheets we...At the initial rolling temperature of 250 to 400 ℃, AZ31B magnesium alloy sheets were hot rolled by four different rolling routes. Microstructures and mechanical properties of the hot-rolled magnesium alloy sheets were analyzed by optical microscope and tensile tests respectively. Based on the Hall-Petch relation, considering the average grain size and grain size distribution, the nonlinear fitting analysis between the tensile strength and average grain size was carried on, and then the prediction model of tensile strength of hot-rolled AZ31B magnesium alloy sheet was established. The results indicate that, by rolling with multi-pass cross rolling, uniform, fine and equiaxial grain microstructures can be produced, the anisotropy of hot-rolled magnesium sheet can also be effectively weakened. Strong correlation was observed between the average grain size and tensile property of the hot-rolled magnesium alloy sheet. Grain size distribution coefficient d(CV) was introduced to reflect the dispersion degree about a set of grain size data, and then the Hall-Petch relation was perfected. Ultimately, the prediction accuracy of tensile strength of multi-pass hot-rolled AZ31B magnesium alloy was improved, and the prediction of tensile property can be performed by the model.展开更多
Aiming at overcoming the low plasticity of magnesium alloy at room temperature, we researched viscous warm pressure bulging(VWPB) of AZ31B magnesium alloy based on the excellent thermal stability of viscous medium u...Aiming at overcoming the low plasticity of magnesium alloy at room temperature, we researched viscous warm pressure bulging(VWPB) of AZ31B magnesium alloy based on the excellent thermal stability of viscous medium under the warm forming condition. The potential improvements of plastic deformation ability and forming quality of AZ31B magnesium alloy are expected with the aid of thermal characteristics of viscous medium. During bulging process the velocity field variation and pressure stress field distribution of viscous medium are observed at different temperatures through which the effect of temperature on the mechanical property of viscous medium and AZ31B magnesium alloy are analyzed. The results show that the formability of AZ31B magnesium alloy increases first and then decreases as the temperature increases and it is the best at 200 ℃. On the other hand, the viscous medium which can build non-uniform pressure stress field also exhibits a good flow property at elevated temperature, and it is helpful to improving the formability of AZ31B magnesium alloy.展开更多
The fatigue crack propagation rate of as-extruded AZ31B magnesium alloy was studied. Compact tension [C(T)] of the notch direction parallel (T-L), vertical (L-T), and inclined at 45o to the extrusion direction w...The fatigue crack propagation rate of as-extruded AZ31B magnesium alloy was studied. Compact tension [C(T)] of the notch direction parallel (T-L), vertical (L-T), and inclined at 45o to the extrusion direction was investigated. The experimental results indicate that the crack propagation direction is parallel to the extrusion direction for T-L and L-T specimens, whereas the specimen inclined at 45o has an angular deflection of 9° to 11° toward the extrusion direction. The T-L specimen has the fastest fatigue crack propagation rate, and the L-T specimen has the slowest rate, the fatigue crack propagation rate of the specimen inclined at 45o is between the two directions. The crack tip propagates by both transgranular and intergranular fractures. Fatigue fractures consist of cleavage plane or quasi-cleavage and are brittle fractures. The fatigue striation occurs for specimens inclined at 45o and its size is 3-15 μm.展开更多
AZ31B magnesium alloy chips were recycled by three solid-state recycling processes including cold-pressing,hot-pressing followed by hot extrusion and double extrusion.Microstructure and mechanical properties of the re...AZ31B magnesium alloy chips were recycled by three solid-state recycling processes including cold-pressing,hot-pressing followed by hot extrusion and double extrusion.Microstructure and mechanical properties of the recycled specimens and reference specimens were compared.For the recycled specimen by cold-pressing,the grains are refined to a large extent during hot extrusion due to the presence of twins and high density dislocation.The recycled specimens by hot-pressing and double extrusion do not exhibit finer grain than that the recycled specimen by cold-pressing.Consequently,higher ultimate tensile strength of the recycled specimen by hot-pressing and double extrusion is not achieved.For hot pressing process,more compact billet lowers the porosity in recycled material,so elongation to failure of the recycled specimen increases.The recycled specimen fabricated by double extrusion process shows slightly higher elongation than the reference specimen.The second extrusion makes the oxides further crush and distribute more dispersedly,and minimizes porosity,which is responsible for the improved ductility.展开更多
Superplastic deformation mechanism of AZ31B magnesium alloy sheet was investigated. Maximum elongation of 216% and strain rate sensitivity of 0.36 were obtained at 723 K and a strain rate of 1×10?3s?1. It is foun...Superplastic deformation mechanism of AZ31B magnesium alloy sheet was investigated. Maximum elongation of 216% and strain rate sensitivity of 0.36 were obtained at 723 K and a strain rate of 1×10?3s?1. It is found that dynamic recrystallization occurs at the early deformation stage, and that grain boundary sliding is the dominant deformation mode of superplastic AZ31B sheet, whose fracture is due to the growth and interlinkage of cavities nucleated at grain boundary. A cavity growth model was established, and damage characteristic parameters as well as the critical value of damage variable were identified so as to provide a theoretical ground on which the plastic forming technology of magnesium alloy sheet can be optimized.展开更多
High temperature tensile properties and microstructure evolutions of twin-roll-cast AZ31B magnesium alloy were investigated over a strain rate range from 10-3 to 1 s-1.It is suggested that the dominant deformation mec...High temperature tensile properties and microstructure evolutions of twin-roll-cast AZ31B magnesium alloy were investigated over a strain rate range from 10-3 to 1 s-1.It is suggested that the dominant deformation mechanism in the lower strain rate regimes is dislocation creep controlled by grain boundary diffusion at lower temperature and by lattice diffusion at higher temperatures,respectively.Furthermore,dislocation glide and twinning are dominant deformation mechanisms at higher strain-rate.The processing map,the effective diffusion coefficient and activation energy map of the alloy were established.The relations of microstructure evolutions to the transition temperature of dominant diffusion process,the activation energy platform and the occurrence of the full dynamic recrystallization with the maximum peak efficiency were analyzed.It is revealed that the optimum conditions for thermo-mechanical processing of the alloy are at a temperature range from 553 to 593 K,and a strain rate range from 7×10-3 to 2×10-3 s-1.展开更多
AZ31B magnesium alloy was subjected to friction stir welding with various welding parameters. The equivalent Young's moduli of the friction stir welded samples and the base material were obtained by the three-poin...AZ31B magnesium alloy was subjected to friction stir welding with various welding parameters. The equivalent Young's moduli of the friction stir welded samples and the base material were obtained by the three-point method, and their transverse rigidities were obtained as well. Furthermore, the sound transmission characteristics of those samples were experimentally studied by four-microphone impedance tube method. The experimental results indicate that the transverse rigidities of the friction stir welded samples were only 79%, 83% and 92% of those of the base material, respectively. The sound transmission losses of the processed samples were also lower, which was largely due to the reduction of transverse rigidities induced by the decrease of equivalent Young's moduli.展开更多
The deformation behavior of AZ31B magnesium alloy as extruded under hot compression conditions was characterized in the temperature range of 200400℃ and strain rate range of 0.0011s^-1. The processing maps were o...The deformation behavior of AZ31B magnesium alloy as extruded under hot compression conditions was characterized in the temperature range of 200400℃ and strain rate range of 0.0011s^-1. The processing maps were obtained at different strains. The results show that the map exhibits flow instabilities as two domains. The domain at beyond 300℃ and strain rate of 1s^-1 appears with a peak efficiency of power dissipation about 56% occurring. This domain is expected to happen in a hot process, such as hot rolling, hot extrusion and hot forging. There is high efficiency of power dissipation at temperature beyond 350℃ and strain rate 0.001s^-1.Such domains suggest the occurrence of superplastic deformation.展开更多
A V/Ce conversion coating was deposited in the surface of AZ31B magnesium alloy in a solution containing vanadate and cerium nitrate.The coating composition and morphology were examined.The conversion coating appears ...A V/Ce conversion coating was deposited in the surface of AZ31B magnesium alloy in a solution containing vanadate and cerium nitrate.The coating composition and morphology were examined.The conversion coating appears to consist of a thin and cracked coating with a scattering of spherical particles.The corrosion behavior of the substrate and conversion coating was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS).Compared with AZ31B magnesium alloy,the corrosion current density of the conversion coating is decreased by two orders of magnitude.The total impedance of the V/Ce conversion coating rise to 1.6×10^(3)Ω·cm^(2)in contrast with2.2×10^(2)Ω·cm^(2)of the bare AZ31B.In addition,the electrical conductivity of the coating was assessed by conductivity meter and Mott-Schottky measurement.The results reveal a high dependence of the conductivity of the coating on the semiconductor properties of the phase compositions.展开更多
A fluoride conversion coating was successfully prepared on AZ31B magnesium alloy by chemical reaction in hydrofluoric acid. Morphologies, composition, bonding strength, corrosion properties, in vitro cytotoxicity and ...A fluoride conversion coating was successfully prepared on AZ31B magnesium alloy by chemical reaction in hydrofluoric acid. Morphologies, composition, bonding strength, corrosion properties, in vitro cytotoxicity and antibacterial properties of the coating were investigated, respectively. The scanning electron microscopy observations revealed a dense coating with some irregular pores. The thin-film X-ray diffraction analysis indicated that the coating was mainly composed of MgO and MgF2. The electrochemical impedance spectroscopy results showed that the fluoride conversion coating significantly improved the corrosion resistance of AZ31B. The hydroxyapatite formed on the surface of the fluoride coated AZ31 B after being immersed in the simulated blood plasma indicated the good bioactivity of the material. The in vitro cytotoxicity test showed that the fluoride coated AZ31B alloy was not toxic to BMMSCs (human bone marrow-derived mesenchymal stem cells). It was also found that the fluoride coated AZ31 B alloy had antibacterial capability.展开更多
The AZ31B magnesium alloy sheet added with 0.5 wt.% Ce was welded with friction stir welding(FSW).The microstructures and mechanical properties of the welded joint were investigated.The results showed that the microst...The AZ31B magnesium alloy sheet added with 0.5 wt.% Ce was welded with friction stir welding(FSW).The microstructures and mechanical properties of the welded joint were investigated.The results showed that the microstructures in the weld nugget zone were uniform and with small equiaxed grains.The grains in the heat-affected zone and the thermo-mechanical affected zone were coarser than those in the base metal zone and the weld nugget zone.The ultimate tensile strength of AZ31B magnesium alloy added with 0.5...展开更多
基金supported by CAPES-(Coordenação de Aperfeiçoamento de Pessoal de Nível Su-perior),process no.PNPD20130250-22001018034P4.
文摘Mg alloys conventionally rolled often present strong basal textures that affect negatively further deformations,limiting their applications.The present research found that cross-rolling experiences in adequate conditions can weaken those intense basal textures as a result of the interaction of deformation mechanisms and dynamic recrystallization.The effects of rolling temperature and strain rate on the microstructure and texture of an AZ31B magnesium alloy sheet generated heterogeneous microstructure where the initial basal texture was strengthened during cold cross-rolling and it was gradually weakening by the rolling reduction and the rolling temperature increases in such a way that a rather weak basal fiber was produced applying reductions higher than 15%at temperatures higher than 200℃.Their ODF functions supported the texture weakening,exhibiting a combination of two crystallographic orientations represented by{0001}<211^(-)0>and{0001}<101^(-)0>.
基金Funded by the national Natural Science Foundation of China (No. 51075293)the Foundation for Development of Science and Technology of Taiyuan University of Technology,China(No.K201014)
文摘To improve the wear resistance and corrosion resistance of magnesium alloys, a 5 kW continuous wave CO2 laser was used to investigate the laser surface cladding on AZ31 B magnesium alloys with Al-Si/Al2O3-TiO2 composite powders. A detailed microstructure, chemical composition, and phase analysis of the composite coatings were studied by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). The laser cladding shows good metallurgical bonding with the substrate. The composite coatings are composed of Mgl7Al12, Al3Mg2, Mg2Si, Al2O3, and TiO2 phases. Compared to the average microhardness (50HV0.05) of the AZ3 1 B substrate, that of the composite coatings (230HV0.05) is improved significantly. The wear resistances of the surface layers were evaluated in detail. The results demonstrate that the wear resistances of the laser surface-modified samples are considerably improved compared to the substrate. It also show that the composite coatings exhibit better corrosion resistance than that of the substrate in 3.5wt% NaCI solution.
基金The research is supported by the Shanxi Natural Science Foundation (No. 2008011044).
文摘An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction (XRD) was used to identify the phases. Microstructure and properties of laser melted layer of AZ31B magnesium alloy were observed or tested by means of optical microscope (OM), scanning electron microscope (SEM), micro-hardness equipment and electrochemical corrosion equipment etc. The results show that the microstructure of laser melted layer becomes finer significantly and uniform. Compared with the substrate, the content of β-Mg17 Al12 phase of melted layer decreases comparatively. Microhardness of the laser melted layer is improved to 50 -95 HV0. 05 as compared to 40 -45 HV0.05 of the AZ31B Mg alloy substrate. The results of electrochemical corrosion show that the corrosion resistance of laser surface melted layer has been improved.
基金Funded by the National Natural Science Foundation of China(No.U1510131)the Key Research and Development Projects of Shanxi Province(No.201603D121010)+1 种基金the Science and Technology Project of Jincheng City(No.20155010)the Project of Young Scholar of Shanxi Province and the Leading Talent Project of Innovative Entrepreneurial Team of Jiangsu Province and the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi(TYAL)
文摘At the initial rolling temperature of 250 to 400 ℃, AZ31B magnesium alloy sheets were hot rolled by four different rolling routes. Microstructures and mechanical properties of the hot-rolled magnesium alloy sheets were analyzed by optical microscope and tensile tests respectively. Based on the Hall-Petch relation, considering the average grain size and grain size distribution, the nonlinear fitting analysis between the tensile strength and average grain size was carried on, and then the prediction model of tensile strength of hot-rolled AZ31B magnesium alloy sheet was established. The results indicate that, by rolling with multi-pass cross rolling, uniform, fine and equiaxial grain microstructures can be produced, the anisotropy of hot-rolled magnesium sheet can also be effectively weakened. Strong correlation was observed between the average grain size and tensile property of the hot-rolled magnesium alloy sheet. Grain size distribution coefficient d(CV) was introduced to reflect the dispersion degree about a set of grain size data, and then the Hall-Petch relation was perfected. Ultimately, the prediction accuracy of tensile strength of multi-pass hot-rolled AZ31B magnesium alloy was improved, and the prediction of tensile property can be performed by the model.
基金Funded by the National Natural Science Foundation of China(No.51575364)the Natural Science Foundation of Liaoning Province(No.2013024014)
文摘Aiming at overcoming the low plasticity of magnesium alloy at room temperature, we researched viscous warm pressure bulging(VWPB) of AZ31B magnesium alloy based on the excellent thermal stability of viscous medium under the warm forming condition. The potential improvements of plastic deformation ability and forming quality of AZ31B magnesium alloy are expected with the aid of thermal characteristics of viscous medium. During bulging process the velocity field variation and pressure stress field distribution of viscous medium are observed at different temperatures through which the effect of temperature on the mechanical property of viscous medium and AZ31B magnesium alloy are analyzed. The results show that the formability of AZ31B magnesium alloy increases first and then decreases as the temperature increases and it is the best at 200 ℃. On the other hand, the viscous medium which can build non-uniform pressure stress field also exhibits a good flow property at elevated temperature, and it is helpful to improving the formability of AZ31B magnesium alloy.
基金Funded by the National Natural Science Foundation of China(No. 50675148)
文摘The fatigue crack propagation rate of as-extruded AZ31B magnesium alloy was studied. Compact tension [C(T)] of the notch direction parallel (T-L), vertical (L-T), and inclined at 45o to the extrusion direction was investigated. The experimental results indicate that the crack propagation direction is parallel to the extrusion direction for T-L and L-T specimens, whereas the specimen inclined at 45o has an angular deflection of 9° to 11° toward the extrusion direction. The T-L specimen has the fastest fatigue crack propagation rate, and the L-T specimen has the slowest rate, the fatigue crack propagation rate of the specimen inclined at 45o is between the two directions. The crack tip propagates by both transgranular and intergranular fractures. Fatigue fractures consist of cleavage plane or quasi-cleavage and are brittle fractures. The fatigue striation occurs for specimens inclined at 45o and its size is 3-15 μm.
基金Projects(50674038,50974048) supported by the National Natural Science Foundation of ChinaProject(11541347) supported by the Educational Office of Heilongjiang Province,China
文摘AZ31B magnesium alloy chips were recycled by three solid-state recycling processes including cold-pressing,hot-pressing followed by hot extrusion and double extrusion.Microstructure and mechanical properties of the recycled specimens and reference specimens were compared.For the recycled specimen by cold-pressing,the grains are refined to a large extent during hot extrusion due to the presence of twins and high density dislocation.The recycled specimens by hot-pressing and double extrusion do not exhibit finer grain than that the recycled specimen by cold-pressing.Consequently,higher ultimate tensile strength of the recycled specimen by hot-pressing and double extrusion is not achieved.For hot pressing process,more compact billet lowers the porosity in recycled material,so elongation to failure of the recycled specimen increases.The recycled specimen fabricated by double extrusion process shows slightly higher elongation than the reference specimen.The second extrusion makes the oxides further crush and distribute more dispersedly,and minimizes porosity,which is responsible for the improved ductility.
基金Project(2001AA331050-3) supported by the Hi-tech Research Program of China
文摘Superplastic deformation mechanism of AZ31B magnesium alloy sheet was investigated. Maximum elongation of 216% and strain rate sensitivity of 0.36 were obtained at 723 K and a strain rate of 1×10?3s?1. It is found that dynamic recrystallization occurs at the early deformation stage, and that grain boundary sliding is the dominant deformation mode of superplastic AZ31B sheet, whose fracture is due to the growth and interlinkage of cavities nucleated at grain boundary. A cavity growth model was established, and damage characteristic parameters as well as the critical value of damage variable were identified so as to provide a theoretical ground on which the plastic forming technology of magnesium alloy sheet can be optimized.
基金Project(3093024) supported by the Natural Science Foundation of Beijing, China Project(2007XM035) supported by the Science Foundation of Beijing Jiaotong University
文摘High temperature tensile properties and microstructure evolutions of twin-roll-cast AZ31B magnesium alloy were investigated over a strain rate range from 10-3 to 1 s-1.It is suggested that the dominant deformation mechanism in the lower strain rate regimes is dislocation creep controlled by grain boundary diffusion at lower temperature and by lattice diffusion at higher temperatures,respectively.Furthermore,dislocation glide and twinning are dominant deformation mechanisms at higher strain-rate.The processing map,the effective diffusion coefficient and activation energy map of the alloy were established.The relations of microstructure evolutions to the transition temperature of dominant diffusion process,the activation energy platform and the occurrence of the full dynamic recrystallization with the maximum peak efficiency were analyzed.It is revealed that the optimum conditions for thermo-mechanical processing of the alloy are at a temperature range from 553 to 593 K,and a strain rate range from 7×10-3 to 2×10-3 s-1.
基金Supported by the National Technology Research and Development Program in the 12th Five-Year Plan of China(No.2011BAE22B05)Canada-China-USA Collaborative Research and Development Project(No.2011DFA50900)
文摘AZ31B magnesium alloy was subjected to friction stir welding with various welding parameters. The equivalent Young's moduli of the friction stir welded samples and the base material were obtained by the three-point method, and their transverse rigidities were obtained as well. Furthermore, the sound transmission characteristics of those samples were experimentally studied by four-microphone impedance tube method. The experimental results indicate that the transverse rigidities of the friction stir welded samples were only 79%, 83% and 92% of those of the base material, respectively. The sound transmission losses of the processed samples were also lower, which was largely due to the reduction of transverse rigidities induced by the decrease of equivalent Young's moduli.
基金Project(2001AA351050) supported by the National High-Tech Research and Development Programof China
文摘The deformation behavior of AZ31B magnesium alloy as extruded under hot compression conditions was characterized in the temperature range of 200400℃ and strain rate range of 0.0011s^-1. The processing maps were obtained at different strains. The results show that the map exhibits flow instabilities as two domains. The domain at beyond 300℃ and strain rate of 1s^-1 appears with a peak efficiency of power dissipation about 56% occurring. This domain is expected to happen in a hot process, such as hot rolling, hot extrusion and hot forging. There is high efficiency of power dissipation at temperature beyond 350℃ and strain rate 0.001s^-1.Such domains suggest the occurrence of superplastic deformation.
基金financially supported by the National Key Research and Development Program of China (Nos. 2016YFB0301105 and 2017YFB0702100)。
文摘A V/Ce conversion coating was deposited in the surface of AZ31B magnesium alloy in a solution containing vanadate and cerium nitrate.The coating composition and morphology were examined.The conversion coating appears to consist of a thin and cracked coating with a scattering of spherical particles.The corrosion behavior of the substrate and conversion coating was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS).Compared with AZ31B magnesium alloy,the corrosion current density of the conversion coating is decreased by two orders of magnitude.The total impedance of the V/Ce conversion coating rise to 1.6×10^(3)Ω·cm^(2)in contrast with2.2×10^(2)Ω·cm^(2)of the bare AZ31B.In addition,the electrical conductivity of the coating was assessed by conductivity meter and Mott-Schottky measurement.The results reveal a high dependence of the conductivity of the coating on the semiconductor properties of the phase compositions.
基金the financial support of the National Basic Research Program of China(973 Program,No.2012CB619101)the Basic Application Research of Yunnan Province(No. KKSA201151053)
文摘A fluoride conversion coating was successfully prepared on AZ31B magnesium alloy by chemical reaction in hydrofluoric acid. Morphologies, composition, bonding strength, corrosion properties, in vitro cytotoxicity and antibacterial properties of the coating were investigated, respectively. The scanning electron microscopy observations revealed a dense coating with some irregular pores. The thin-film X-ray diffraction analysis indicated that the coating was mainly composed of MgO and MgF2. The electrochemical impedance spectroscopy results showed that the fluoride conversion coating significantly improved the corrosion resistance of AZ31B. The hydroxyapatite formed on the surface of the fluoride coated AZ31 B after being immersed in the simulated blood plasma indicated the good bioactivity of the material. The in vitro cytotoxicity test showed that the fluoride coated AZ31B alloy was not toxic to BMMSCs (human bone marrow-derived mesenchymal stem cells). It was also found that the fluoride coated AZ31 B alloy had antibacterial capability.
基金supported by the Support Plans for Science and Technology of Changchun City (2007KZ07)the Program for New Century Excellent Talents in University985 project of Jilin University
文摘The AZ31B magnesium alloy sheet added with 0.5 wt.% Ce was welded with friction stir welding(FSW).The microstructures and mechanical properties of the welded joint were investigated.The results showed that the microstructures in the weld nugget zone were uniform and with small equiaxed grains.The grains in the heat-affected zone and the thermo-mechanical affected zone were coarser than those in the base metal zone and the weld nugget zone.The ultimate tensile strength of AZ31B magnesium alloy added with 0.5...