In this study, we developed a strategy for using the Scoggins procedure in the synthesis of acetamidines as novel C02-triggered switchable surfactants via acetimidates by effectively tuning the chemical equilibrium. T...In this study, we developed a strategy for using the Scoggins procedure in the synthesis of acetamidines as novel C02-triggered switchable surfactants via acetimidates by effectively tuning the chemical equilibrium. The as-synthesized N'-alkyl-N,Ndiethylacetamidines exhibit excellent CO_2/N_2 switchability and their bicarbonate salts have the ability to emulsify oil-water mixtures.展开更多
基金supported by the China National Petroleum Corporation (RIPED-2017-JS-87)
文摘In this study, we developed a strategy for using the Scoggins procedure in the synthesis of acetamidines as novel C02-triggered switchable surfactants via acetimidates by effectively tuning the chemical equilibrium. The as-synthesized N'-alkyl-N,Ndiethylacetamidines exhibit excellent CO_2/N_2 switchability and their bicarbonate salts have the ability to emulsify oil-water mixtures.
