Fractionation mechanism of stable isotope in evaporating water body

Under Rayleigh equilibrium condition, stable isotopic ratio in residual water increases with the decrease of the residual water proportion f exponentially, and the fractionation rate of stable isotopes is inversely proportional to temperature. However, under kinetic evaporation condition, the fi＇actionation of stable isotopes is not only related to the phase temperature but also influenced by the atmospheric humidity and the mass exchange between liquid and vapor phases. The ratio 6 in residual water will not change with f after undergoing evaporation of a long time for great relative humidity. The rate that the evaporating water body reaches isotopic steady state is mainly dependent on the relative humidity in atmosphere. The analysis shows that the actual mean linear variety rates, about -30.0, of the δ^18O in residual water versus the residual water proportion at Nagqu and Amdo stations are consistent with the simulated process under temperature of 20℃ and relative humidity of 50%. The distillation line simulated under Rayleigh equilibrium condition is analogous to the global meteoric water line （MWL） as the temperature is about 20℃. Under non-equilibrium condition, the slope and constant values of distillation line are directly proportional to temperature and relative humidity. According to the basic data, the simulated distillation line is very consistent with the actual distillation line of Qinghai Lake.

Experimental study on stable isotopic fractionation of evaporating water under varying temperature

The variation of stable isotope ratios in natural waters provides valuable information that can be used to trace water movement. Evaporation plays a crucial role in determining the variation of stable isotopes. In this paper, several evaporation experiments were conducted in order to study the stable isotopic fractionation mechanism of water and analyze the influence of different temperatures on evaporation fractionation. Three group experiments of water evaporation under different temperatures and initial isotopic values were carried out. The results show that fractionation factors of hydrogen and oxygen may increase with temperature, and the average enrichment degree of hydrogen isotope D is 3.432 times that of oxygen isotope 18O. The results also show that the isotopic composition of the initial water has little influence on water evaporation fractionation, which is mainly affected by the state variables in the evaporation process, such as temperature. This research provides experimental data for further understanding the evaporation fractionation mechanism.

Study on the mechanism of isotope fractionation in soil water during the evaporation process under equilibrium condition

In this study, with the method of vacuum extraction, two evaporative processes of soil water and free water under equilibrium condition were simulated. For each sample,water vapor was condensed by liquid nitrogen and was collected in four time intervals. From the analysis of hydrogen and oxygen isotopic compositions of the water collected at different times, it was discovered that the isotope fractionation of soil water also follows the mode, which is just the same as the evaporative process of free water. The relationship between the stable hydrogen and oxygen isotopes in residual water showed that the simulative evaporation line was close to the global meteoric water line (GMWL) under the equilibrium condition at about 20℃. Comparison of the two types of evaporative processes indicated that the isotope fractionation and evaporation velocity of soil water were only slightly modified by the Van der Waals force.

An Experimental Study of Oxygen Isotope Fractionation in the Quartz-Wolframite-Water System

Oxygen isotope fractionation was experimentally studied in the quartz-wolframite-water systemf rom 200 to 420℃.The starting wolframite was synthexized in aqueous solutions of Na2WOR·2H2O+FeCl2·4H2O or MnCl2·4H2O.The starting solutions range in salinity from 0 to 10 equivalent wt.% NaCl.Experiments were conducted in a gold-lined stainless steel autoclave,with filling degrees of about 50%.The results showed no significant difference in dquilibrium isotope fractionation between water and wolframite,ferberite and huebnerite at the same temperature(310℃）.The equilibrium oxygen isotope fractionation factors of wolframite and water tend to be equal with increasing temperature above 370℃.but to increase significantly with decreasing temperature below 370℃.

Oxygen Isotopic Fractionation in the Kaolinite-Water System during the Synthetic Process

Oxygen isotope fractionation is studied during the synthesis of kaolinite under controlled conditions of temperature and time. Equilibrium conditions have been established and its relationship with temperature has been studied. Kaolinite was hydrothermally precipitated starting from non-crystalline aluminosilicate gels. The amount of kaolinite obtained increases up to a limited constant value and in all cases coexists with the amorphous starting gels. It can be seen that the data obtained at 48 hours of synthesis can be considered as quasi-equilibrium, since the total isotopic equilibrium has not been reached, only the sample obtained at 24 hours should be discarded for studies in equilibrium. This would allow us, with the samples obtained at 720 hours, to try to establish a relationship between isotopic fractionation and temperature, provided that we know the water in equilibrium with the synthesized kaolinite. Two equations have been obtained that show correlation coefficients with a high statistical significance.

Simulations of Stable Isotopic Fractionation in Mixed Cloud in Middle Latitudes-Taking the Precipitation at Urumqi as an Example

The introduced mathematical model takes into account the role of the kinetic fractionation effect in a supersaturation environment at the ice surface as liquid and solid phases coexist in mixed cloud. Using the model, the temperature effect of stable isotopes in precipitation is simulated under different cooling conditions. The rate of change of δ18O against temperature in the process of wet adiabatic cooling is smaller than in the process of isobaric cooling under the same humidity. The increasing supersaturation ratio at the ice surface, Si, leads to the strengthening of the kinetic fractionation effect. The kinetic fractionation function makes the synthesis fractionation factor decreased and the change of δ18O with temperature flatted, compared with that in the equilibrium state. The simulated results show that the slope parameter b and the intercept d of the meteoric water line (MWL), 6D = bδ18O+d, in wet adiabatic cooling are both greater than those in isobaric cooling. The global MWL lies between the two MWLs simulated under wet adiabatic and isobaric cooling processes, respectively. The magnitudes of 6 and d are directly proportional to Si. The greater the Si, the stronger the kinetic fractionation effect, and thus the greater the 6 and d, and vice versa. However, 6 and d have low sensitivity to the liquid-water contents in the cloud. Using the kinetic fractionation model, the variation of stable isotopes in precipitation at Uriimqi is simulated. The simulated stable isotopic ratio vs temperature and the SD vs δ18O curves are very consistent with the actual regressions and MWL at Uriimqi, respectively.

Distribution of various aluminum fractions in surface water of the Le An River

Total concentration and fractions of aluminum in water samples collected from the Le An River were determined by PCV complex colorimetry. Taking advantage of developed empirical models combined with nonlinear multivariate statistical technique, concentration of aluminum adsorbed by suspended particles, i.e. [Al ads ] was regressed with concentration of monomeric aluminum,i.e.[Al mono ], pH and turbidity. However, aluminum strongly bound with humic substances, i.e.[Al org ] was universally too low to detected in this experiment, and at least, it may be partially related with much lower DOC level along the Le An River.

Simulation of the Fate of Faecal Bacteria in Estuarine and Coastal Waters Based on A Fractionated Sediment Transport Model

A two-dimensional depth-integrated numerical model is refined in this paper to simulate the hydrodynamics, graded sediment transport process and the fate of faecal bacteria in estuarine and coastal waters. The sediment mixture is divided into several fractions according to the grain size. A bed evolution model is adopted to simulate the processes of the bed elevation change and sediment grain size sorting. The faecal bacteria transport equation includes enhanced source and sink terms to represent bacterial kinetic transformation and disappearance or reappearance due to sediment deposition or re-suspension. A novel partition ratio and dynamic decay rates of faecal bacteria are adopted in the numerical model. The model has been applied to the turbid water environment in the Bristol Channel and Severn estuary, UK. The predictions by the present model are compared with field data and those by non-fractionated model.

Hydrogen and Oxygen Isotope Fractionation Mechanism in the Hydrothermal System and Its Geologic Significance

The geochemical behaviors of hydrogen and oxygen isotopes in the hydrothermal system and their inher-ent relationship with the water / rock exchange are discussed in this paper In addition to the temperature con-ditions, the effective W / R ratio is another factor controlling the changes in H and O isotope compositions ofthe altered rock and hydrothermal water. Besides, the application and geological significance of the water-rockexchange theory are also discussed in the light of the H and O isotope compositions and their variation charac-teristics of the mineralizing hydrothermal water and altered rocks from several mineral deposits. Finally, abrief evolutional model of H and O istotope compositions of meteoric and magmatic hydrothermal waters in ahydrothermal system is given.

Maximizing Irrigation Water Productivity by Optimizing Leaching Fraction

The importance of maximizing irrigation water productivity is increasing as the water resources still decreasing and deteriorating due to environmental interactions. An optimal irrigation water depth （including leaching water depth） was estimated in order to maximize water unit volume productivity by using the optimal leaching fraction （LF）, which is calculated by the new proposed model--unit yield ratio （UYR%） and irrigation depth ratio （IDP）. A computer program was constructed to apply this model for several crops irrigated by two water resources--river and well. The water salinity of river was 1.1 dS/m and the well salinity was 3.85 dS/m. The results showed that there is an optimal leaching requirement （LR） value for each crop irrigated by any water resource. The maximum UYR% of the alfalfa irrigated by saline well water was 58.45% with the optimal LF = 0.4, while the maximum UYR% of the bean irrigated by river water was 78.58% with the optimal LR = 0.2. The optimal LF is saving water by increasing the productivity of irrigation water unit volume, especially when using saline irrigation water, for example, an increase of IDP for alfalfa by only 20%, followed by an increase of UYR% about 47.5% （from 12% to 57%） by increasing LF from 0.1 to 0.3.

Flow Characteristics of Crude Oil with High Water Fraction during Non-heating Gathering and Transportation

In order to ensure the safety of the non-heating gathering and transportation processes for high water fraction crude oil,the effect of temperature,water fraction,and flow rate on the flow characteristics of crude oil with high water fraction was studied in a flow experimental system of the X Oilfield.Four distinct flow patterns were identified by the photographic and local sampling techniques.Especially,three new flow patterns were found to occur below the pour point of crude oil,including EW/O&W stratified flow with gel deposition,EW/O&W intermittent flow with gel deposition,and water single-phase flow with gel deposition.Moreover,two characteristic temperatures,at which the change rate of pressure drop had changed obviously,were found during the change of pressure drop.The characteristic temperature of the first congestion of gel deposition in the pipeline was determined to be the safe temperature for the non-heating gathering and transportation of high water cut crude oil,while the pressure drop reached the peak at this temperature.An empirical formula for the safe temperature was established for oil-water flow with high water fraction/low fluid production rate.The results can serve as a guide for the safe operation of the non-heating gathering and transportation of crude oil in high water fraction oilfields.

Changes in Soil Hot-Water Extractable C,N and P Fractions During Vegetative Restoration in Zhifanggou Watershed on the Loess Plateau

The study was conducted in Zhifanggou Watershed,Shaanxi Province,China,to evaluate the effect of different vegetation types on hot-water extractable C,N and P fractions,with the aim to determine whether hot-water extractable fractions could be used as indicators of soil quality change in Loess Plateau.The six vegetation types established in 1975 were（i） Robinia pseudoacacia L.,（ii） Caragana korshinkii Kom.,（iii） Pinus tabulaeformis Carr.,（iv） P.tabulaeformis-Amorpha fruticosa L.,（v） R.pseudoacacia-A.fruticosa,and（vi） grassland.A cropped hillslope plot and a Platycladus orientalis L.native forest plot were used as references.The results indicated that the conversion of native forest to cropland resulted in a significant decline in the hot-water extractable C,N and P fractions.Hot-water extractable C,N,and P increased when cultivated land was revegetated,but after 30 years the amount of hot-water extractable C,N,and P in revegetated fields was still much lower compared to native forest.Hot-water extractable fractions increased more under mixed-forest than under pure-forest stands.Furthermore,there was a significant correlation between the hot-water extractable fractions and soil chemical and microbiological properties.The results showed that hot-water extractable fractions could be used as indicators of soil quality change on the Loess Plateau.

Response of antioxidase in viscera of Pagrosuma Major larvae to water soluble fraction of hydrocarbons in No.0 diesel oil

Pagrosomus major larvae were exposed to the water soluble fraction of hydrocarbon in No.0 diesel oil (corresponding to No.2 fuel oil) at concentrations of 0, 0 17, 1.22 and 8 82 mg/L for up to 15 days. Larvae were sampled on days 9 and l5 of the experiment. Supernatants of viscera tissue extractions were assayed for biochemical response in terms of oxidative stress superoxide dismutase(SOD), activity of selenium dependant glutathione peroxidase(Se GPx) and catalase(Ca), and the concentration of reduced glutathione(GSH). On day 9 of exposure, statistically significant dose related increases in Se GPx and SOD activity, and GSH concentration were observed in all cases except for Se GPx activity under the highest dosage of hydrocarbon. However, on day l5 of exposure, a similar dose related response was only observed for Se GPx activity. GSH concentration decreased and SOD activity showed no statistical difference as compared to controls. However, a significant decrease in compared to day 9 Se GPx activity and GSH concentration, in contrast to increase SOD activity at day 15 as indicates an accelerated accumulation of H 2O 2 and potential oxidative damage under long term exposure of larvae to hydrocarbons. No statistical changes were observed in Ca activity throughout the experiment, possibly owing to the high efficiency of Se GPx. A recovery experiment was performed on indicating that the response of antioxidants measured tending to return to their control levels. These results prove the function of the antioxidant defense system of the larvae to the water soluble fraction of hydrocarbons in No.0 diesel oil.

Effects of Annealing and Removal of the Water-Soluble Fraction of Dry-Milled Rice Flour on the Texture of Cooked Rice Noodles

Rice noodles were prepared using dry-milled rice flours, which were treated by annealing and removing the water-soluble fraction to improve the quality of noodles without using chemical additives. The combined treatment (TC) with annealing and water-soluble fraction removal decreased the cooking losses for Goamibyeo but not for Chenmaai and Milyang260, which had soft kernels and contained less damaged starch than the hard kernel rice after milling. TC significantly reduced the hardness and adhesiveness of cooked noodles, and increased the cohesiveness according to the texture profile analysis. A sensory evaluation detected an increase in mouth feel firmness and elasticity of cooked TC noodles. These results indicate that annealing at room temperature for 3 h followed by the removal of the water-soluble fraction is effective for reducing the cooking losses and improving the textural properties of noodles made from rice flour with high starch damage.

Numerical Solution of the Rotating Shallow Water Flows with Topography Using the Fractional Steps Method

The two-dimensional nonlinear shallow water equations in the presence of Coriolis force and bottom topography are solved numerically using the fractional steps method. The fractional steps method consists of splitting the multi-dimensional matrix inversion problem into an equivalent one dimensional problem which is successively integrated in every direction along the characteristics using the Riemann invariant associated with the cubic spline interpolation. The height and the velocity field of the shallow water equations over irregular bottom are discretized on a fixed Eulerian grid and time-stepped using the fractional steps method. Effects of the Coriolis force and the bottom topography for particular initial flows on the velocity components and the free surface elevation have been studied and the results are plotted.

Biomarker responses in the bivalve Chlamys farreri to the water-soluble fraction of crude oil

To investigate the effect of the water soluble fraction of crude oil(WSF) on marine bivalves, the scallop C hlamys farreri was exposed to three WSF concentrations(0.18 mg/L, 0.32 mg/L, and 0.51 mg/L, respectively) in seawater. Petroleum hydrocarbon contents in scallops and a suite of enzymes [7-Ethoxyresorufin-O-deethylase(EROD), aryl hydrocarbon hydroxylase(AHH), glutathione S-transferase(GST), and glutathione peroxidase(GPx)] in gills and digestive glands were monitored over 10 days. The results revealed that WSF affected the activity of the four enzymes in the gills and digestive glands. EROD activity in the gills was significantly induced in most individuals of the three test groups, while in the digestive gland it was significantly induced in the low-concentration group within 4 days but was inhibited in the middle- and high-concentration groups on days 1, 4, and 10. AHH activity in the gills of all treatment groups was significantly induced on day 1. In the digestive gland, AHH activity was induced in most individuals from the treatment groups. In all treatment groups, GST activity was significantly inhibited from days 2 to 10 in the gills and was induced after day 4 in the digestive gland. GPx activity in the gills was significantly inhibited throughout the exposure period in all treatment groups. There was no overall significant difference in GPx activity in the digestive gland between the control and treatment groups. Our results also revealed that petroleum hydrocarbon concentrations in the tissues increased linearly with exposure time. EROD activity in the digestive gland and GST and GPx activity in the gill tissue were negatively correlated with petroleum hydrocarbon body burden. These enzymes play important roles in detoxification and can act as potential biomarkers for monitoring petroleum hydrocarbon contaminants in the marine environment.

Phosphorus Fractions in Water and Sediment and Their Correlations in Hengshui Lake, China

Sediment is a principal reservoir which accumulates and releases the pollutants. It is an important way of nutrients releasing from pore water of sediments to overlying water across the sediment-water interface. Five sampling sites were selected in the Hengshui Lake. Overlying water and sediments were collected in each of them. The phosphorus fractions and their relationships were analyzed. The results showed that the change of the total phosphorus （TP） in sediment was similar to that of the total dissolved phosphorus （TDP） and soluble orthophosphate （PO4^3-） in pore water. The concentrations of PO4^3- in pore water were higher than those in overlying water, reflecting a possible diffuse trend for PO4^3-P in the five zones of Hengshui Lake. It is indicated that phosphorus and other nutrients will be transferred from sediment to pore water and then to overlying water, which can lead to lake eutrophication.

Water Profile over an Ogee-Shaped Crest and the Reynolds Fractional Equations

Weir crest must have the correct shape in the concave side of an ogee-shaped crest to diminish erosion. This shape can be obtained using an approximation of the fractional Reynolds equations when the water interacts with the surface. A model is introduced for the Reynolds stresses complemented with a closure relation of fractional origin. A power type solution is obtained for the main velocity and stress. Velocity profile is found based on the assumption of a steady flow and the energy conservation equation. A Froude number and the cubic equation of the weir are built. The dimensionless upstream velocity head is also determined which allow graphically showing the exponent and coefficient of the water-profile over an ogee-shaped crest. It is possible to estimate the occupied-space index trough an exponents＇ ratio of profile over the velocity head.

Pulsed laser interference patterning of transition-metal carbides for stable alkaline water electrolysis kinetics

We investigated the role of metal atomization and solvent decomposition into reductive species and carbon clusters in the phase formation of transition-metal carbides(TMCs;namely,Co_(3)C,Fe_(3)C,TiC,and MoC)by pulsed laser ablation of Co,Fe,Ti,and Mo metals in acetone.The interaction between carbon s-p-orbitals and metal d-orbitals causes a redistribution of valence structure through charge transfer,leading to the formation of surface defects as observed by X-ray photoelectron spectroscopy.These defects influence the evolved TMCs,making them effective for hydrogen and oxygen evolution reactions(HER and OER)in an alkaline medium.Co_(3)C with more oxygen affinity promoted CoO(OH)intermediates,and the electrochemical surface oxidation to Co_(3)O_(4)was captured via in situ/operando electrochemical Raman probes,increasing the number of active sites for OER activity.MoC with more d-vacancies exhibits strong hydrogen binding,promoting HER kinetics,whereas Fe_(3)C and TiC with more defect states to trap charge carriers may hinder both OER and HER activities.The results show that the assembled membrane-less electrolyzer with Co_(3)C∥Co_(3)C and MoC∥MoC electrodes requires~2.01 and 1.99 V,respectively,to deliver a 10 mA cm−2 with excellent electrochemical and structural stability.In addition,the ascertained pulsed laser synthesis mechanism and unit-cell packing relations will open up sustainable pathways for obtaining highly stable electrocatalysts for electrolyzers.