An air-silica microstructure optical fiber based on the anti-resonant reflecting optical waveguide （ARROW） principle was used to develop a spectral absorption gas sensor. The ARROW fiber has an air core and an air c...An air-silica microstructure optical fiber based on the anti-resonant reflecting optical waveguide （ARROW） principle was used to develop a spectral absorption gas sensor. The ARROW fiber has an air core and an air cladding layer. An ARROW fiber with a length of 725mm was used to construct a sensing system to detect acetylene gas. The gas was injected into the fiber from one end of the fiber. The transmission spectra were collected using an optical spectrum analyzer. The results indicate that the system can detect the gas of different concentrations and has the good system linearity. The response time of the system is about 200 s.展开更多
Solvothermal reaction of 3-aminoisonicotinic acid（Haina） and Cu（NO_3）_2·2.5H_2O gave a novel twodimensional（2D） microporous metal–organic framework, [Cu（aina）_2（DMF）]·DMF（1, DMF = N,N-dimethylfor...Solvothermal reaction of 3-aminoisonicotinic acid（Haina） and Cu（NO_3）_2·2.5H_2O gave a novel twodimensional（2D） microporous metal–organic framework, [Cu（aina）_2（DMF）]·DMF（1, DMF = N,N-dimethylformamide）. Single-crystal X-ray crystallographic study of compound 1 revealed that Cu（II）ions are linked by ainaàligands forming square grid-like layers, which stack together via multiple hydrogen bonding interactions. The solvent-free framework of 1a displayed considerable porosity（void = 46.5%） with one-dimensional（1D） open channels（4.7 ？ ？ 4.8 ？） functionalized by amino groups.Gas sorption measurements of 1 revealed selective carbon dioxide（CO_2） and acetylene（C_2H_2） adsorption over methane（CH_4） and nitrogen（N_2） at ambient temperature.展开更多
基金This work was supported by the Major Program of the National Natural Science Foundation of China （Grant No. 61290311）.
文摘An air-silica microstructure optical fiber based on the anti-resonant reflecting optical waveguide （ARROW） principle was used to develop a spectral absorption gas sensor. The ARROW fiber has an air core and an air cladding layer. An ARROW fiber with a length of 725mm was used to construct a sensing system to detect acetylene gas. The gas was injected into the fiber from one end of the fiber. The transmission spectra were collected using an optical spectrum analyzer. The results indicate that the system can detect the gas of different concentrations and has the good system linearity. The response time of the system is about 200 s.
基金supported by the grant AX-1593(JCGZ)and AX1730(BC)from the Welch Foundation
文摘Solvothermal reaction of 3-aminoisonicotinic acid（Haina） and Cu（NO_3）_2·2.5H_2O gave a novel twodimensional（2D） microporous metal–organic framework, [Cu（aina）_2（DMF）]·DMF（1, DMF = N,N-dimethylformamide）. Single-crystal X-ray crystallographic study of compound 1 revealed that Cu（II）ions are linked by ainaàligands forming square grid-like layers, which stack together via multiple hydrogen bonding interactions. The solvent-free framework of 1a displayed considerable porosity（void = 46.5%） with one-dimensional（1D） open channels（4.7 ？ ？ 4.8 ？） functionalized by amino groups.Gas sorption measurements of 1 revealed selective carbon dioxide（CO_2） and acetylene（C_2H_2） adsorption over methane（CH_4） and nitrogen（N_2） at ambient temperature.
