The temporal-spatial distribution and seasonal variation of the precipitation acidity in Guangxi Province were statistically analyzed by means of the data from 2003 to 2008 in 10 Stations of Acid Rain Observation in t...The temporal-spatial distribution and seasonal variation of the precipitation acidity in Guangxi Province were statistically analyzed by means of the data from 2003 to 2008 in 10 Stations of Acid Rain Observation in the province and the data from 1996 to 2008 in two Monitoring Spots in Nanning and Baise,respectively.The results showed that annual average pH value of precipitation was <5.6 based on the analysis of the data from 10 Stations of Acid Rain Observation in the province,among which,the data from 5 stations indicated that annual average pH value of precipitation was <4.5.Thus,it can be thought that the serious acid rain had appeared in the province.There was an obvious seasonal variation in the extent of the acidity in precipitation and the acidity of precipitation in spring and winter was heavier than that in summer and autumn.展开更多
The variation characteristics of acid rain and the relationship between the formation of acid rain and meteorological conditions were analyzed based on the observation data and meteorological records collected from ac...The variation characteristics of acid rain and the relationship between the formation of acid rain and meteorological conditions were analyzed based on the observation data and meteorological records collected from acid rain observation station in Dalian over 2006-2009.The results showed that Dalian was one of the regions with strong acid rain in northern China,with the frequency of 66% and pH value of 3.49.The acidity was the strongest in fall and weakest in spring;and the maximum and minimum frequencies were in summer and in winter respectively.Frequency of acid rain was inversely proportional to wind speed and concentration of inhalable particles in Dalian;acid rain occurred easily in foggy weather due to the steady stratification and abundant moisture;continuous precipitation did not mean the reduction of acidic material in the air,and the rainfall with increased acidity in the second day accounted for 42% in continuous precipitation cases.展开更多
Based on the rainfall monitoring data and high altitude meteorological data,the present situation of acid rain pollution in Nanchang City was analyzed and the forming factors of acid rain were revealed. The results sh...Based on the rainfall monitoring data and high altitude meteorological data,the present situation of acid rain pollution in Nanchang City was analyzed and the forming factors of acid rain were revealed. The results showed that acid rain in Nanchang had the characteristics of high acidity and frequency,and the pH value of rainfall reduced in recent years,belonging to sulfuric acid type,and the most serious acid rain pollution appeared in autumn and winter. The pH value of rainfall went up with the improvement of rainfall grade,and the increase of rainfall quantity had diluting effect on the rainfall acidity. High altitude meteorological conditions affected acid rain obviously,when the upper wind velocity was below 7 m/s,the frequency of acid rain was higher and its pH value was lower,with serious acid rain pollution,and it showed that upper wind had diluting effect on the horizontal transport of pollutants. The frequency of acid rain became higher with stronger inversion intensity. Moreover,the surrounding industrial areas had obvious effect on the formation of acid rain. Unstable meteorological conditions were beneficial to the horizontal and vertical diffusion of pollution in the lower atmosphere,reducing the effect of induced-acidity pollutants on a region.展开更多
A series of extraction equilibrium experiments for aminobenzoic acid with di(2-ethylhexyl)phosphoric acid (D2EHPA) dissolved in n-octane or 1-octanol was carried out. The effects of aminobenzoic acid concentration,D2E...A series of extraction equilibrium experiments for aminobenzoic acid with di(2-ethylhexyl)phosphoric acid (D2EHPA) dissolved in n-octane or 1-octanol was carried out. The effects of aminobenzoic acid concentration,D2EHPA concentration and pH on the distribution ratio were discussed in detail. The infrared spectra of the organic phase loaded with solute illustrated that pH had little effect on the structure of the complex formed. There proceed ion association and cation-exchange.reaction in the extraction. An expression of the equilibrium distribution was proposed.展开更多
文摘The temporal-spatial distribution and seasonal variation of the precipitation acidity in Guangxi Province were statistically analyzed by means of the data from 2003 to 2008 in 10 Stations of Acid Rain Observation in the province and the data from 1996 to 2008 in two Monitoring Spots in Nanning and Baise,respectively.The results showed that annual average pH value of precipitation was <5.6 based on the analysis of the data from 10 Stations of Acid Rain Observation in the province,among which,the data from 5 stations indicated that annual average pH value of precipitation was <4.5.Thus,it can be thought that the serious acid rain had appeared in the province.There was an obvious seasonal variation in the extent of the acidity in precipitation and the acidity of precipitation in spring and winter was heavier than that in summer and autumn.
基金Supported by Scientific Research Special Fund for Public Welfare Industry (Meteorology) (GYHY20080620)
文摘The variation characteristics of acid rain and the relationship between the formation of acid rain and meteorological conditions were analyzed based on the observation data and meteorological records collected from acid rain observation station in Dalian over 2006-2009.The results showed that Dalian was one of the regions with strong acid rain in northern China,with the frequency of 66% and pH value of 3.49.The acidity was the strongest in fall and weakest in spring;and the maximum and minimum frequencies were in summer and in winter respectively.Frequency of acid rain was inversely proportional to wind speed and concentration of inhalable particles in Dalian;acid rain occurred easily in foggy weather due to the steady stratification and abundant moisture;continuous precipitation did not mean the reduction of acidic material in the air,and the rainfall with increased acidity in the second day accounted for 42% in continuous precipitation cases.
基金Supported by Major Project of Chinese National Program for Fundamental Research and Development("973" Program)(2005CB42- 208)Meteorological Science and Technology Innovation Foundation of Jiangxi Province,China(2006KJC-X1006)
文摘Based on the rainfall monitoring data and high altitude meteorological data,the present situation of acid rain pollution in Nanchang City was analyzed and the forming factors of acid rain were revealed. The results showed that acid rain in Nanchang had the characteristics of high acidity and frequency,and the pH value of rainfall reduced in recent years,belonging to sulfuric acid type,and the most serious acid rain pollution appeared in autumn and winter. The pH value of rainfall went up with the improvement of rainfall grade,and the increase of rainfall quantity had diluting effect on the rainfall acidity. High altitude meteorological conditions affected acid rain obviously,when the upper wind velocity was below 7 m/s,the frequency of acid rain was higher and its pH value was lower,with serious acid rain pollution,and it showed that upper wind had diluting effect on the horizontal transport of pollutants. The frequency of acid rain became higher with stronger inversion intensity. Moreover,the surrounding industrial areas had obvious effect on the formation of acid rain. Unstable meteorological conditions were beneficial to the horizontal and vertical diffusion of pollution in the lower atmosphere,reducing the effect of induced-acidity pollutants on a region.
文摘A series of extraction equilibrium experiments for aminobenzoic acid with di(2-ethylhexyl)phosphoric acid (D2EHPA) dissolved in n-octane or 1-octanol was carried out. The effects of aminobenzoic acid concentration,D2EHPA concentration and pH on the distribution ratio were discussed in detail. The infrared spectra of the organic phase loaded with solute illustrated that pH had little effect on the structure of the complex formed. There proceed ion association and cation-exchange.reaction in the extraction. An expression of the equilibrium distribution was proposed.