Despite the great potential of cellulose wood pulp and cellulose nanofibrils as reinforcing filler in thermoplastics,its use is limited due to its tendency to form agglomerates and due to its high hydrophilic characte...Despite the great potential of cellulose wood pulp and cellulose nanofibrils as reinforcing filler in thermoplastics,its use is limited due to its tendency to form agglomerates and due to its high hydrophilic character.Here we describe fiberboard composites with high contents of wood pulp or cellulose nanofibrils,and a resin of poly(styrene-methyl-methacrylate-acrylic acid)used as water-based emulsion.Cellulose wood pulp and cellulose nanofibrils were used directly in the form of water suspensions.The method is based on the flocculation of the polymer emulsion followed by agglomeration of a mixture of the polymer emulsion and cellulose suspension,leading to the co-precipitation of the composite material,which can be easily separated from the water phase.Composites with acrylic polymer/cellulose fibers in the proportions of 75:25,50:50 and 25:75 wt%were prepared.Composites were characterized by scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FTIR),thermogravimetric analysis(TGA),dynamic mechanical analysis(DMA)and water absorption tests.SEM analysis revealed a very good dispersion of the fibers without evidence of agglomeration,which led to superior mechanical properties.These results showed the effectiveness of the methodology and the potential of cellulose wood pulp and CNF as reinforcement fillers in fiberboard composites and any other high fiber-content materials.展开更多
An acrylic acid/kaoline powder superabsorbent composite with a water absorbency of the superabsorbent composite about 1/800 was synthesized by inverse\|suspending polymerization reaction between acrylic acid monomer a...An acrylic acid/kaoline powder superabsorbent composite with a water absorbency of the superabsorbent composite about 1/800 was synthesized by inverse\|suspending polymerization reaction between acrylic acid monomer and kaoline ultrafine powder. The influence of the dispersant agent on the configuration of the products in the inverse suspension polymerization is investigated. The influences of the kaoline powder,cross\|linker,initiator,neutralization degree and the volume ratio of oil to water phase on the water absorbency of the superabsorbent composites are discussed in the paper.展开更多
A novel biopolymer-based superabsorbent hydrogel composite based on kappa-carrageenan (κC) have been prepared via graft copolymerization of acrylic acid (AA) in the presence of bentonite powder using methylenebisacry...A novel biopolymer-based superabsorbent hydrogel composite based on kappa-carrageenan (κC) have been prepared via graft copolymerization of acrylic acid (AA) in the presence of bentonite powder using methylenebisacrylamide (MBA) as a crosslinking agent and ammonium persulfate (APS) as an initiator. The hydrogel structure was confirmed using FTIR spectroscopy and the morphology of the samples was examined by scanning electron microscopy (SEM). The affecting variables onto graft polymerization (i.e. AA, MBA and APS concentration, as well as the bentonite amount) were systematically optimized to achieve a hydrogel with swelling capacity as high as possible. The results of Brunauer–Emmett–Teller (BET) analysis showed that the average pore diameter of the synthesized hydrogel was 11.5 nm. The effect of various salt media and solutions with different pHs on the swelling of the superabsorbent was also studied.展开更多
The reverse martensitic transformation of TiNi shape memory alloy fibers embedded in a pure aluminum matrix was studied in this paper. Results showed that the phase composition of the TiNi alloy fibers prior to prestr...The reverse martensitic transformation of TiNi shape memory alloy fibers embedded in a pure aluminum matrix was studied in this paper. Results showed that the phase composition of the TiNi alloy fibers prior to prestraining at the room temperature had a significant influence on the differential scanning calorimetry (DSC) results of the composites. By a comparison to the high temperature X-ray diffraction (XRD) results, it was confirmed that the martensite was divided into two groups: the self-accommodating martensite (SAM) and the preferentially oriented martensite (POM). The evolving process of the separation of martensite was discussed.展开更多
A novel TiNi/AlSi composite with high compressive strength and high damping capacity was obtained by infiltrating Al-12%Si alloy into porous TiNi alloy.It had been found that the high compressive strength (440 MPa) of...A novel TiNi/AlSi composite with high compressive strength and high damping capacity was obtained by infiltrating Al-12%Si alloy into porous TiNi alloy.It had been found that the high compressive strength (440 MPa) of TiNi/AlSi composite is due to the increase of effective carrying area after infiltrating Al-12%Si alloy,while the high damping capacity is contributed to TiNi carcass,Al-12%Si filling material and micro- slipping at the interface.展开更多
In this research, a series of wood-based panels were produced by using wood chips [beech (Fagus Sylvatica L.) and Scotch pine (Pinus sylvestris L.)] as wastes of wood-working workshops and acrylic fibers as wastes of ...In this research, a series of wood-based panels were produced by using wood chips [beech (Fagus Sylvatica L.) and Scotch pine (Pinus sylvestris L.)] as wastes of wood-working workshops and acrylic fibers as wastes of textiles factory. Four kinds of different panels (Eltapan I, II, III and IV) were obtained by mixing these components in different composition (0%, 25% and 50%). Some physical and mechanical properties of the samples taken from these panels were determined in accordance with ASTM D1037-12 and ASTM-C 1113. The values were compared to properties of industrially produced chipboard. As a result, the textile fibers used as additive material reduced density, thermal conductivity and bending resistance of wood panel and increased dimensional stability of wood panel.展开更多
A series of poly(2-ethylhexyl acrylate-co-acrylic acid)s(P(2-EHA-co-AA))s with different mole contents of 2-ethylhexyl acrylate(2-EHA) were synthesized through free radical copolymerization in ethanol for investigatin...A series of poly(2-ethylhexyl acrylate-co-acrylic acid)s(P(2-EHA-co-AA))s with different mole contents of 2-ethylhexyl acrylate(2-EHA) were synthesized through free radical copolymerization in ethanol for investigating the influences of copolymer composition upon the performance such as apparent viscosity,film behaviors,and adhesion to fibers for warp sizing.The content of 2-EHA was varied from 80% to 40%.The adhesion was estimated by measuring tensile strength and work-to-break of impregnated roving.The film behaviors were evaluated in terms of breaking strength,breaking elongation,work-to-break,and flex-fatigue resistance.It was observed that the viscosity,adhesion,and film behaviors of the copolymers strongly depended on the content of 2-EHA.Excessively increasing or decreasing the content of 2-EHA units incorporated into the copolymeric chains reduces the serviceability of P(2-EHA-co-AA) in warp sizing.The adhesion and film behaviors of the copolymer reach their maximal values at mole content of 50% simultaneously.Therefore,the copolymer used as sizing agent should be synthesized under equal mole of 2-EHA and AA in monomer formulation.展开更多
Purpose: The study investigated the impact of dietary habits, specifically soda, milk kefir, water kefir, almond milk, and distilled water (control) consumption, on the microhardness of gingiva-coloured composite and ...Purpose: The study investigated the impact of dietary habits, specifically soda, milk kefir, water kefir, almond milk, and distilled water (control) consumption, on the microhardness of gingiva-coloured composite and acrylic denture bases. Methods: Materials included gingiva-coloured composite (Fusion Universal G1), acrylic (Imicryl), and subdivided Procryla group. Subgroups comprised 15 and 30-minute heat polymerized (Pro15, Pro30), and 1 wt% (Pro1Z) and 3 wt% (Pro3Z) zirconium added groups. Immersed in beverages for 1, 7, and 14 days, pH and microhardness were assessed. SEM examined random samples. Statistical analysis used repeated measures ANOVA, and post hoc tests (p Results: The gingiva-coloured composites displayed noteworthy time-associated microhardness changes (p 0.05). Despite variable pH levels in beverages, no substantial group interaction effects were observed (p > 0.05). Initial microhardness rankings shifted after a 14-day immersion. Conclusions: Gingiva-coloured composite exhibited the highest microhardness pre- and post-immersion, followed by Procryla30 and Imicryl groups. .展开更多
文摘Despite the great potential of cellulose wood pulp and cellulose nanofibrils as reinforcing filler in thermoplastics,its use is limited due to its tendency to form agglomerates and due to its high hydrophilic character.Here we describe fiberboard composites with high contents of wood pulp or cellulose nanofibrils,and a resin of poly(styrene-methyl-methacrylate-acrylic acid)used as water-based emulsion.Cellulose wood pulp and cellulose nanofibrils were used directly in the form of water suspensions.The method is based on the flocculation of the polymer emulsion followed by agglomeration of a mixture of the polymer emulsion and cellulose suspension,leading to the co-precipitation of the composite material,which can be easily separated from the water phase.Composites with acrylic polymer/cellulose fibers in the proportions of 75:25,50:50 and 25:75 wt%were prepared.Composites were characterized by scanning electron microscopy(SEM),Fourier transform infrared spectroscopy(FTIR),thermogravimetric analysis(TGA),dynamic mechanical analysis(DMA)and water absorption tests.SEM analysis revealed a very good dispersion of the fibers without evidence of agglomeration,which led to superior mechanical properties.These results showed the effectiveness of the methodology and the potential of cellulose wood pulp and CNF as reinforcement fillers in fiberboard composites and any other high fiber-content materials.
文摘An acrylic acid/kaoline powder superabsorbent composite with a water absorbency of the superabsorbent composite about 1/800 was synthesized by inverse\|suspending polymerization reaction between acrylic acid monomer and kaoline ultrafine powder. The influence of the dispersant agent on the configuration of the products in the inverse suspension polymerization is investigated. The influences of the kaoline powder,cross\|linker,initiator,neutralization degree and the volume ratio of oil to water phase on the water absorbency of the superabsorbent composites are discussed in the paper.
文摘A novel biopolymer-based superabsorbent hydrogel composite based on kappa-carrageenan (κC) have been prepared via graft copolymerization of acrylic acid (AA) in the presence of bentonite powder using methylenebisacrylamide (MBA) as a crosslinking agent and ammonium persulfate (APS) as an initiator. The hydrogel structure was confirmed using FTIR spectroscopy and the morphology of the samples was examined by scanning electron microscopy (SEM). The affecting variables onto graft polymerization (i.e. AA, MBA and APS concentration, as well as the bentonite amount) were systematically optimized to achieve a hydrogel with swelling capacity as high as possible. The results of Brunauer–Emmett–Teller (BET) analysis showed that the average pore diameter of the synthesized hydrogel was 11.5 nm. The effect of various salt media and solutions with different pHs on the swelling of the superabsorbent was also studied.
基金the National Natural Science Foundation of China under grant No. 59731030.
文摘The reverse martensitic transformation of TiNi shape memory alloy fibers embedded in a pure aluminum matrix was studied in this paper. Results showed that the phase composition of the TiNi alloy fibers prior to prestraining at the room temperature had a significant influence on the differential scanning calorimetry (DSC) results of the composites. By a comparison to the high temperature X-ray diffraction (XRD) results, it was confirmed that the martensite was divided into two groups: the self-accommodating martensite (SAM) and the preferentially oriented martensite (POM). The evolving process of the separation of martensite was discussed.
文摘A novel TiNi/AlSi composite with high compressive strength and high damping capacity was obtained by infiltrating Al-12%Si alloy into porous TiNi alloy.It had been found that the high compressive strength (440 MPa) of TiNi/AlSi composite is due to the increase of effective carrying area after infiltrating Al-12%Si alloy,while the high damping capacity is contributed to TiNi carcass,Al-12%Si filling material and micro- slipping at the interface.
文摘In this research, a series of wood-based panels were produced by using wood chips [beech (Fagus Sylvatica L.) and Scotch pine (Pinus sylvestris L.)] as wastes of wood-working workshops and acrylic fibers as wastes of textiles factory. Four kinds of different panels (Eltapan I, II, III and IV) were obtained by mixing these components in different composition (0%, 25% and 50%). Some physical and mechanical properties of the samples taken from these panels were determined in accordance with ASTM D1037-12 and ASTM-C 1113. The values were compared to properties of industrially produced chipboard. As a result, the textile fibers used as additive material reduced density, thermal conductivity and bending resistance of wood panel and increased dimensional stability of wood panel.
基金Open Project Program of Key Laboratory of Eco-Textiles,Ministry of Education,China(No.KLET0617)
文摘A series of poly(2-ethylhexyl acrylate-co-acrylic acid)s(P(2-EHA-co-AA))s with different mole contents of 2-ethylhexyl acrylate(2-EHA) were synthesized through free radical copolymerization in ethanol for investigating the influences of copolymer composition upon the performance such as apparent viscosity,film behaviors,and adhesion to fibers for warp sizing.The content of 2-EHA was varied from 80% to 40%.The adhesion was estimated by measuring tensile strength and work-to-break of impregnated roving.The film behaviors were evaluated in terms of breaking strength,breaking elongation,work-to-break,and flex-fatigue resistance.It was observed that the viscosity,adhesion,and film behaviors of the copolymers strongly depended on the content of 2-EHA.Excessively increasing or decreasing the content of 2-EHA units incorporated into the copolymeric chains reduces the serviceability of P(2-EHA-co-AA) in warp sizing.The adhesion and film behaviors of the copolymer reach their maximal values at mole content of 50% simultaneously.Therefore,the copolymer used as sizing agent should be synthesized under equal mole of 2-EHA and AA in monomer formulation.
文摘Purpose: The study investigated the impact of dietary habits, specifically soda, milk kefir, water kefir, almond milk, and distilled water (control) consumption, on the microhardness of gingiva-coloured composite and acrylic denture bases. Methods: Materials included gingiva-coloured composite (Fusion Universal G1), acrylic (Imicryl), and subdivided Procryla group. Subgroups comprised 15 and 30-minute heat polymerized (Pro15, Pro30), and 1 wt% (Pro1Z) and 3 wt% (Pro3Z) zirconium added groups. Immersed in beverages for 1, 7, and 14 days, pH and microhardness were assessed. SEM examined random samples. Statistical analysis used repeated measures ANOVA, and post hoc tests (p Results: The gingiva-coloured composites displayed noteworthy time-associated microhardness changes (p 0.05). Despite variable pH levels in beverages, no substantial group interaction effects were observed (p > 0.05). Initial microhardness rankings shifted after a 14-day immersion. Conclusions: Gingiva-coloured composite exhibited the highest microhardness pre- and post-immersion, followed by Procryla30 and Imicryl groups. .
