The film diffusion mass-transfer process of adsorption of phenol on macroporous polystyrene resin was investigated in detail In order to revise the Boyd film diffusion kinetics equation, the out-surface structure of t...The film diffusion mass-transfer process of adsorption of phenol on macroporous polystyrene resin was investigated in detail In order to revise the Boyd film diffusion kinetics equation, the out-surface structure of the macroporous resin and that of gel-type ion-exchange resin was compared and the new film diffusion equation was also suggested. These results showed that the film diffusion was influenced by porosity of the macroporous resin greatly, which differed from the film diffusion behavior of ion-exchange resin obviously.展开更多
The isothermal adsorption of dyes on a variety of sisal based activated carbonfibers (SACFs), and the influence of PH and temperature on absorption are discussedin this paper The results indicate that the adsorption o...The isothermal adsorption of dyes on a variety of sisal based activated carbonfibers (SACFs), and the influence of PH and temperature on absorption are discussedin this paper The results indicate that the adsorption of methylene blue, crystal violetand Eriochrome blue black R on SACFs shows type I isotherms and can be describedby the Langnuir equation or the Freudlich equation. The acidity of solution hasgreatly ifluence over the adeorption amounts of methylene blue, crystal violet andEriochrome blue black R. As PHs of the solutions were adjusted to increase ordecrease from the original acidity of the solution (4. 7. 4. ) and 4. 0 for methylene blue,crystal violet and Eriochrome blue black R. respectively), the amounts of dyesadsorbed on SACFs increased. The adsorption temperature (in the range of 25~50℃)exerts little influence on the adsorption amount of methylene blue, crystal violet andfluorescein. For azo dyes (Eriochrome blue black R and Eriochrome black T), howeverthe absorption amount increases slightly with the elevation of temperature.展开更多
文摘The film diffusion mass-transfer process of adsorption of phenol on macroporous polystyrene resin was investigated in detail In order to revise the Boyd film diffusion kinetics equation, the out-surface structure of the macroporous resin and that of gel-type ion-exchange resin was compared and the new film diffusion equation was also suggested. These results showed that the film diffusion was influenced by porosity of the macroporous resin greatly, which differed from the film diffusion behavior of ion-exchange resin obviously.
文摘The isothermal adsorption of dyes on a variety of sisal based activated carbonfibers (SACFs), and the influence of PH and temperature on absorption are discussedin this paper The results indicate that the adsorption of methylene blue, crystal violetand Eriochrome blue black R on SACFs shows type I isotherms and can be describedby the Langnuir equation or the Freudlich equation. The acidity of solution hasgreatly ifluence over the adeorption amounts of methylene blue, crystal violet andEriochrome blue black R. As PHs of the solutions were adjusted to increase ordecrease from the original acidity of the solution (4. 7. 4. ) and 4. 0 for methylene blue,crystal violet and Eriochrome blue black R. respectively), the amounts of dyesadsorbed on SACFs increased. The adsorption temperature (in the range of 25~50℃)exerts little influence on the adsorption amount of methylene blue, crystal violet andfluorescein. For azo dyes (Eriochrome blue black R and Eriochrome black T), howeverthe absorption amount increases slightly with the elevation of temperature.
