The possibility to produce advanced alumina and zirconia ceramics by the electroconsolidation method is studied. The technological parameters of Al2O3 and ZrO2 （3 mass% Y2O3 ） production were developed and optimized...The possibility to produce advanced alumina and zirconia ceramics by the electroconsolidation method is studied. The technological parameters of Al2O3 and ZrO2 （3 mass% Y2O3 ） production were developed and optimized. Electroconsolidated alumina and zirconia ceramics have higher values of properties in comparison with ordinary sintered samples in air. Advanced proper- ties of electroconsolidated ceramics are defined by homo- geneous, ultradense and fine-crystalline structure that was formed due to the effect to consolidate the materials to high density for a shortest time.展开更多
Joining of ZrO_2 (containing 8% (mol fraction) Y_2O_3,as the composition used in oxygen sensors) to 95Al_2O_3 (widely used at elevated temperature) in green state was described using polymer/layered silicate (PLS) nan...Joining of ZrO_2 (containing 8% (mol fraction) Y_2O_3,as the composition used in oxygen sensors) to 95Al_2O_3 (widely used at elevated temperature) in green state was described using polymer/layered silicate (PLS) nanocomposites contained slurry,without applied pressure. Microstructure of the joined section was investigated. The effects of interlayer and PLS on joining qualities were analysed. The results show that interface cracks are easily produced because of mismatch of both thermal expansion and/or sintering shrinkage between joined samples. With an optimized condition of joining layer composition and solid contents,a fine joint could be obtained without obvious cracks,pores and other defects. This process is suitable for joining of various kinds of advanced ceramics.展开更多
Ce-ZrO2 and ZrO2/CePO4 ceramic system was joined in the green body by using mixed powder. Three kinds of systems are discussed. The microstructure and bending strengths of the joint were investigated and it is found t...Ce-ZrO2 and ZrO2/CePO4 ceramic system was joined in the green body by using mixed powder. Three kinds of systems are discussed. The microstructure and bending strengths of the joint were investigated and it is found that the Ce-ZrO2 and 30%CePO4/ZrO2 ceramics can be well joined in the green body. A joint with high mechanical property and good microstructure can be obtained after sintering without applied pressure. Complexly shaped ceramic components can be created by the technique of green state joining. A new way to produce them is provided and the cost is reduced due to the simplicity of the process.展开更多
文摘The possibility to produce advanced alumina and zirconia ceramics by the electroconsolidation method is studied. The technological parameters of Al2O3 and ZrO2 （3 mass% Y2O3 ） production were developed and optimized. Electroconsolidated alumina and zirconia ceramics have higher values of properties in comparison with ordinary sintered samples in air. Advanced proper- ties of electroconsolidated ceramics are defined by homo- geneous, ultradense and fine-crystalline structure that was formed due to the effect to consolidate the materials to high density for a shortest time.
文摘Joining of ZrO_2 (containing 8% (mol fraction) Y_2O_3,as the composition used in oxygen sensors) to 95Al_2O_3 (widely used at elevated temperature) in green state was described using polymer/layered silicate (PLS) nanocomposites contained slurry,without applied pressure. Microstructure of the joined section was investigated. The effects of interlayer and PLS on joining qualities were analysed. The results show that interface cracks are easily produced because of mismatch of both thermal expansion and/or sintering shrinkage between joined samples. With an optimized condition of joining layer composition and solid contents,a fine joint could be obtained without obvious cracks,pores and other defects. This process is suitable for joining of various kinds of advanced ceramics.
文摘Ce-ZrO2 and ZrO2/CePO4 ceramic system was joined in the green body by using mixed powder. Three kinds of systems are discussed. The microstructure and bending strengths of the joint were investigated and it is found that the Ce-ZrO2 and 30%CePO4/ZrO2 ceramics can be well joined in the green body. A joint with high mechanical property and good microstructure can be obtained after sintering without applied pressure. Complexly shaped ceramic components can be created by the technique of green state joining. A new way to produce them is provided and the cost is reduced due to the simplicity of the process.
