Mass Transfer-Promoted Fe^(2+)/Fe^(3+)Circulation Steered by 3D Flow-Through Co-Catalyst System Toward Sustainable Advanced Oxidation Processes

Realizing fast and continuous generation of reactive oxygen species(ROSs)via iron-based advanced oxidation processes(AOPs)is significant in the environmental and biological fields.However,current AOPs assisted by co-catalysts still suffer from the poor mass/electron transfer and non-durable promotion effect,giving rise to the sluggish Fe^(2+)/Fe^(3+)cycle and low dynamic concentration of Fe^(2+)for ROS production.Herein,we present a three-dimensional(3D)macroscale co-catalyst functionalized with molybdenum disulfide(MoS_(2))to achieve ultra-efficient Fe^(2+)regeneration(equilibrium Fe^(2+)ratio of 82.4%)and remarkable stability(more than 20 cycles)via a circulating flow-through process.Unlike the conventional batch-type reactor,experiments and computational fluid dynamics simulations demonstrate that the optimal utilization of the 3D active area under the flow-through mode,initiated by the convectionenhanced mass/charge transfer for Fe^(2+)reduction and then strengthened by MoS_(2)-induced flow rotation for sufficient reactant mixing,is crucial for oxidant activation and subsequent ROS generation.Strikingly,the flow-through co-catalytic system with superwetting capabilities can even tackle the intricate oily wastewater stabilized by different surfactants without the loss of pollutant degradation efficiency.Our findings highlight an innovative co-catalyst system design to expand the applicability of AOPs based technology,especially in large-scale complex wastewater treatment.

UV-Based Advanced Oxidation Processes for Antibiotic Resistance Control: Efficiency, Influencing Factors, and Energy Consumption

Antibiotic resistant bacteria(ARB)with antibiotic resistance genes(ARGs)can reduce or eliminate the effectiveness of antibiotics and thus threaten human health.The United Nations Environment Programme considers antibiotic resistance the first of six emerging issues of concern.Advanced oxidation processes(AOPs)that combine ultraviolet(UV)irradiation and chemical oxidation(primarily chlorine,hydrogen peroxide,and persulfate)have attracted increasing interest as advanced water and wastewater treatment technologies.These integrated technologies have been reported to significantly elevate the efficiencies of ARB inactivation and ARG degradation compared with direct UV irradiation or chemical oxidation alone due to the generation of multiple reactive species.In this study,the performance and underlying mechanisms of UV/chlorine,UV/hydrogen peroxide,and UV/persulfate processes for controlling ARB and ARGs were reviewed based on recent studies.Factors affecting the process-specific efficiency in controlling ARB and ARGs were discussed,including biotic factors,oxidant dose,UV fluence,pH,and water matrix properties.In addition,the cost-effectiveness of the UV-based AOPs was evaluated using the concept of electrical energy per order.The UV/chlorine process exhibited a higher efficiency with lower energy consumption than other UV-based AOPs in the wastewater matrix,indicating its potential for ARB inactivation and ARG degradation in wastewater treatment.Further studies are required to address the trade-off between toxic byproduct formation and the energy efficiency of the UV/chlorine process in real wastewater to facilitate its optimization and application in the control of ARB and ARGs.

Application of Spectral Angle Mapper Classification to Discriminate Hydrothermal Alteration in Southwest Birjand, Iran, Using Advanced Spaceborne Thermal Emission and Reflection Radiometer Image Processing

The purpose of this study is to evaluate the Spectral Angle Mapper （SAM） classification method for determining the optimum threshold （maximum spectral angle） to unveil the hydrothermal mineral assemblages related to mineral deposits. The study area indicates good potential for Cu-Au porphyry, epithermal gold deposits and hydrothermal alteration well developed in arid and semiarid climates, which makes this region significant for Advanced Spaceborne Thermal Emission and Reflection Radiometer （ASTER） image processing analysis. Given that achieving an acceptable mineral mapping requires knowing the alteration patterns, petrochemistry and petrogenesis of the igneous rocks while considering the effect of weathering, overprinting of supergene alteration, overprinting of hypogene alteration and host rock spectral mixing, SAM classification was implemented for argillic, sericitic, propylitic, alunitization, silicification and iron oxide zones of six previously known mineral deposits： Maherabad, a Cu-Au porphyry system; Sheikhabad, an upper part of Cu-Au porphyry system; Khoonik, an Intrusion related Au system; Barmazid, a low sulfidation epithermal system; Khopik, a Cu-Au porphyry system; and Hanish, an epithermal Au system. Thus, the investigation showed that although the whole alteration zones are affected by mixing, it is also possible to produce a favorable hydrothermal mineral map by such complementary data as petrology, petrochemistry and alteration patterns.

The Inception of Jungian Advanced Motor Processing (JAMP) —A 21st Century Approach to Treating Trauma

Jungian Advanced Motor Processing (JAMP) is a mode of treatment developed in May of 2020 by Dr. Lahab Al-Samarrai during the COVID-19 pandemic. Dr. Al-Samarrai had many students who reported increased anxiety, negative thoughts, fearful thoughts, and self-defeating thoughts. These students needed symptom relief more quickly than conventional talk therapy typically provides. Dr. Al-Samarrai developed a treatment modality incorporating light, bilateral audible beats, and positive affirmations. So far, more than 100 subjects have undergone JAMP, and this paper is a case study of one such subject. The research currently being compiled on JAMP, the subject of a future paper, to date shows positive improvement after receiving 5 - 6 sessions, and demonstrated decreases in both somatic symptoms and post-traumatic symptoms ranging from 45 - 55 percent. This paper will share the following: 1) Description of the underlying theoretical components supporting the treatment;2) Description of the treatment;3) Discussion of the case of Grace and her experience with JAMP.

The First Pacific Rim International Conference on Advanced Materials and Processing

The First Pacific Rim International Confer-ence on Advanced Materials and Processing(PRICM-1)organized by The Chinese Society ofMetals(CSM),and co-sponsored by the Japan In-stitute of Metals(JIM),the Korean Institute ofMetals(KIM)and The Mineral,Metals & Materi-als Society of the United States(TMS),was held inShangri-La Hotel,Hangzhou,China on June24-27,1992.It was the first large international conference

Preliminary Announcement for the 1st Pacific Rim International Conference on Advanced Materials and Processing(PRICM-1)

The Joint Conference Organizing Committee of The Chinese Society of Metals(CSM),The Japan Insti-tute of Metals(JIM),The Korean Institute of Metals(KIM)and The Minerals,Metals & Materials Society(TMS)announces The First Pacific Rim International Conference on Advanced Materials and Processing(PRICM-1)which will be held in Hangzhou,China,in the last week of June,1992 lasting about four days.It is agreed that the PRICM-1 will be organized by The Chinese Society of Metals.

South China University of fechnology Advanced Metallic Materials Research and Processing Technology Center

A dvanced Metallic Materials Research and Processing Technology Center was found in December 1998. As a unit under The College of Mechanical Engineering, the Center is an expansion of the former Cast and Composite Materials Research Group, which was found in the early eighties of last century. The Center is focusing in the basic and applied research, and development of advanced metallic materials and their processing technology. It also functions as an organization

Advances of embedded resistive random access memory in industrial manufacturing and its potential applications

Embedded memory,which heavily relies on the manufacturing process,has been widely adopted in various industrial applications.As the field of embedded memory continues to evolve,innovative strategies are emerging to enhance performance.Among them,resistive random access memory(RRAM)has gained significant attention due to its numerousadvantages over traditional memory devices,including high speed(<1 ns),high density(4 F^(2)·n^(-1)),high scalability(~nm),and low power consumption(~pJ).This review focuses on the recent progress of embedded RRAM in industrial manufacturing and its potentialapplications.It provides a brief introduction to the concepts and advantages of RRAM,discusses the key factors that impact its industrial manufacturing,and presents the commercial progress driven by cutting-edge nanotechnology,which has been pursued by manysemiconductor giants.Additionally,it highlights the adoption of embedded RRAM in emerging applications within the realm of the Internet of Things and future intelligent computing,with a particular emphasis on its role in neuromorphic computing.Finally,the review discusses thecurrent challenges and provides insights into the prospects of embedded RRAM in the era of big data and artificial intelligence.

Fabrication of pollution-free coal gangue-based catalytic material utilizing ferrous chloride as activator for efficient peroxymonosulfate activation

Novel coal gangue-based persulfate catalyst(CG-FeCl_(2))was successfully synthesized by the means of calcinating under nitrogen atmosphere with the addition of ferrous chloride tetrahydrate(FeCl_(2)·_(4)H_(2)O).The phase transformation of the prepared materials and gas products during the heating process are thoroughly investigated.It is suggested that ferrous chloride participated in the phase transformation and formed Si-O-Fe bonds.And the main gaseous products are H_(2)O,H_(2),and HCl during the heating process.Besides,the ability of CG-FeCl_(2) to activate peroxymonosulfate(PMS)for catalytic degradation of polycyclic aromatic hydrocarbons(PAHs)and phenol was deeply studied.More than 95%of naphthyl,phenanthrene and phenol were removed under optimizied conditions.In addition,1O_(2),·OH,and SO_(4)·−were involved in the CG-FeCl_(2)/PMS system from the free radical scavenging experiment,where 1O_(2) played a major role during the oxidation process.Furthermore,CG-FeCl_(2)/PMS system exhibited superior stability in a relatively wide pH range and the presence of common anion from related degradation experiments.Overall,the novel CG-FeCl_(2) is an efficient and environmentally friendly catalyst,displaying potential application prospect in the field of PAHs and phenol-contaminated wastewater treatment.

Simultaneous Degradation, Dehalogenation, and Detoxification of Halogenated Antibiotics by Carbon Dioxide Radical Anions

Despite the extensive application of advanced oxidation processes(AOPs)in water treatment,the efficiency of AOPs in eliminating various emerging contaminants such as halogenated antibiotics is constrained by a number of factors.Halogen moieties exhibit strong resistance to oxidative radicals,affecting the dehalogenation and detoxification efficiencies.To address these limitations of AOPs,advanced reduction processes(ARPs)have been proposed.Herein,a novel nucleophilic reductant—namely,the carbon dioxide radical anion(CO_(2)^(·-))—is introduced for the simultaneous degradation,dehalogenation,and detoxification of florfenicol(FF),a typical halogenated antibiotic.The results demonstrate that FF is completely eliminated by CO_(2)^(·-),with approximately 100%of Cland 46%of Freleased after 120 min of treatment.Simultaneous detoxification is observed,which exhibits a linear response to the release of free inorganic halogen ions(R^(2)=0.97,p<0.01).The formation of halogen-free products is the primary reason for the superior detoxification performance of this method,in comparison with conventional hydroxyl-radical-based AOPs.Products identification and density functional theory(DFT)calculations reveal the underlying dehalogenation mechanism,in which the chlorine moiety of FF is more susceptible than other moieties to nucleophilic attack by CO_(2)^(·-).Moreover,CO_(2)^(·-)-based ARPs exhibit superior dehalogenation efficiencies(>75%)in degrading a series of halogenated antibiotics,including chloramphenicol(CAP),thiamphenicol(THA),diclofenac(DLF),triclosan(TCS),and ciprofloxacin(CIP).The system shows high tolerance to the pH of the solution and the presence of natural water constituents,and demonstrates an excellent degradation performance in actual groundwater,indicating the strong application potential of CO_(2)^(·-)-based ARPs in real life.Overall,this study elucidates the feasibility of CO_(2)^(·-)for the simultaneous degradation,dehalogenation,and detoxification of halogenated antibiotics and provides a promising method for their regulation during water or wastewater treatment.

Photocatalytic ozonation-based degradation of phenol by ZnO—TiO_(2)nanocomposites in spinning disk reactor

Spinning disk reactor(SDR)has emerged as a novel process intensification photocatalytic reactor,and it has higher mass transfer efficiency and photon utilization for the degradation of toxic organic pollutants by advanced oxidation processes(AOPs).In this study,ZnO—TiO_(2)nanocomposites were prepared by solgel method,and coated on the disk of SDR by impregnation-pull-drying-calcination method.The performance of catalyst was characterized by X-ray diffraction,scanning electron microscope,X-ray photoelectron spectroscopy,photoluminescence and ultraviolet—visible diffuse reflectance spectroscopy.Photocatalytic ozonation in SDR was used to remove phenol,and various factors on degradation effect were studied in detail.The results showed that the rate of degradation and mineralization reached 100%and 83.4%under UV light irradiation after 50 min,compared with photocatalysis and ozonation,the removal rate increased by 69.3%and 34.7%,and mineralization rate increased by 56.7%and 62.9%,which indicated that the coupling of photocatalysis and ozonation had a synergistic effect.The radical capture experiments demonstrated that the active species such as photogenerated holes(h^(+)),hydroxyl radicals(·OH),superoxide radical(·O_(2)-)were responsible for phenol degradation,and·OH played a leading role in the degradation process,while h+and·O_(2)^(-)played a non-leading role.

Preparation of Co/S co-doped carbon catalysts for excellent methylene blue degradation

S and Co co-doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)degradation.The effects of two different mixing routes were identified on the MB degradation performance.Particularly,the catalyst obtained by the alcohol solvent evaporation(MOF-AEP)mixing route could degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectroscopy revealed that the Co-S content of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of Co for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to cobalt in the form of Co-S bond(-2.86 eV).Thus,the C-S-C sites might provide more contributions to activate PMS compared with Co-S.Furthermore,the degradation parameters,including pH and MOF-AEP dosage,were investigated.Finally,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the secondary one in degrading MB.

Application of advanced oxidation processes for removing salicylic acid from synthetic wastewaters

In this study,advanced oxidation processes(AOPs) such as anodic oxidation(AO),UV/H_2O_2 and Fenton processes(FP) were investigated for the degradation of salicylic acid(SA) in lab-scale experiments.Boron-doped diamond(BDD) film electrodes using Ta as substrates were employed for AO of SA.In the case of FP and UV/H_2O_2,most favorable experimental conditions were determined for each process and these were used for comparing with AO process.The study showed that the FP was the most effective process under aci...

Chemical oxygen demand reduction in coffee wastewater through chemical flocculation and advanced oxidation processes

The removal of the natural organic matter present in coffee processing wastewater through chemical coagulation-flocculation and advanced oxidation processes （AOP） had been studied. The effectiveness of the removal of natural organic matter using commercial flocculants and UV/H202, UV/O3 and UV/H2O2/O3 processes was determined under acidic conditions. For each of these processes, different operational conditions were explored to optimize the treatment efficiency of the coffee wastewater. Coffee wastewater is characterized by a high chemical oxygen demand （COD） and low total suspended solids. The outcomes of coffee wastewater treatment using coagulation-flocculation and photodegradation processes were assessed in terms of reduction of COD, color, and turbidity. It was found that a reduction in COD of 67% could be realized when the coffee wastewater was treated by chemical coagulation-flocculation with lime and coagulant T-1. When coffee wastewater was treated by coagulation-flocculation in combination with UV/H2O2, a COD reduction of 86% was achieved, although only after prolonged UV irradiation. Of the three advanced oxidation processes considered, UV/H2O2, UV/O3 and UV/H2O2/O3, we found that the treatment with UV/H2O2/O3 was the most effective, with an efficiency of color, turbidity and further COD removal of 87%, when applied to the flocculated coffee wastewater.

Degradation of Organic Pollutants by the Advanced Oxidation Processes

A kinetic model has been developed for the degradation of organic pollutants concerning with hydroperoxide ion as the initial step for generation of hydroxyl radical and its subsequent reaction mechanisms. Rate equations were derived for depletion of ozone and pollutants in the peroxone oxidation process using ozone and hydrogen peroxide as combined oxidants. Kinetic data obtained experimentally from the hydrogen peroxide-ozone reaction and peroxone oxidation of nitrobenzene were analyzed by using the proposed rate equations.

Fine analysis on advanced detection of transient electromagnetic method

Fault fracture zones and water-bearing bodies in front of the driving head are the main disasters in mine laneways,thus it is important to perform their advanced detection and prediction in advance in order to provide reliable technical support for the excavation.Based on the electromagnetic induction theory,we analyzed the characteristics of primary and secondary fields with a positive and negative wave form of current,proposed the fine processing of the advanced detection with variation rate of apparent resistivity and introduced in detail the computational formulae and procedures.The result of physical simulation experiments illustrate that the tectonic interface of modules can be judged by first-order rate of apparent resistivity with a boundary error of 5%,and the position of water body determined by the fine analysis method agrees well with the result of borehole drilling.This shows that in terms of distinguishing structure and aqueous anomalies,the first-order rate of apparent resistivity is more sensitive than the secondorder rate of apparent resistivity.However,some remaining problems are suggested for future solutions.

Slaughterhouse Wastewater Characterization and Treatment: An Economic and Public Health Necessity of the Meat Processing Industry in Ontario, Canada

The characteristics of the slaughterhouse effluents and current wastewater treatment practices in the province of Ontario, Canada are analyzed. Meat processing plants are found to produce large amounts of wastewater due to the slaughtering process and cleaning of their facilities. Furthermore, the composition of the wastewater varies according to the type and number of animals slaughtered and the water requirements of the process. However, the slaughterhouse wastewater usually contains high levels of organics and nutrients. Several slaughterhouses in Ontario discharge their wastewater into the municipal sewer system after primary pretreatment at the meat processing plant. Therefore, due to the high-strength characteristics of the slaughterhouse effluents, an extensive treatment for a safe discharge into the environment is required. Thus, the combination of biological processes and advanced oxidation technologies for slaughterhouse wastewater treatment is evaluated in this study. Results show that the application of combined biological and advanced oxidation processes is recommended for on-site slaughterhouse wastewater treatment.

Problems and Strategies in Applications of Advanced Process Control in China

Advanced Process Control （APC） is necessary for oil refining and chemical process in China, but some problems have emerged in the application of APC techniques in this field. This paper discusses the conditions of APC application concerning process design, distributed control system （DCS） choice and regular control. It analyzes the problems and strategies in APC application. Some suggestions are proposed for the enterprise to benefit from APC application.

O_(3) based advanced oxidation for ibuprofen degradation

The degradation of the anti-inflammatory ibuprofen(IBP)was evaluated by several advanced oxidation processes.IBP was treated by single ozonation and oxidation with hydrogen peroxide(H_(2)O_(2)),as well as a combination of these treatments.In order to improve the efficiency,the presence of catalysts such as original carbon nanotubes,labelled as CNT,and iron oxide supported on carbon nanotubes,named as Fe/CNT sample,was considered.The evolution of IBP degradation,mineralization and toxicity of the solutions was assessed.The formation of intermediates was also monitored.In the non-catalytic processes,IBP was faster removed by single ozonation,whereas no significant total organic carbon(TOC)removal was achieved.Oxidation with H_(2)O_(2) did not present satisfactory results.When ozone and H_(2)O_(2) were combined,a higher mineralization was attained(70%after 180 min of reaction).On the other hand,in the catalytic processes,this combined process allowed the fastest IBP degradation.In terms of mineralization degree,the presence of Fe/CNT increases the removal rate in the first hour of reaction,achieving a TOC removal of 85%.Four compounds were detected as by-products.All treated solutions presented lower toxicity than the initial solution,suggesting that the released intermediates during applied processes are less toxic.

Acid precipitation coupled membrane-dispersion advanced oxidation process(MAOP)to treat crystallization mother liquor of pulp wastewater

Treatment to crystallization mother liquor containing high concentration of organic and inorganic substances is a challenge in zero liquid discharge of industrial wastewater.Acid precipitation coupled membrane-dispersion advanced oxidation process(MAOP)was proposed for organics degradation before salt crystallization by evaporation.With acid-MAOP treatment CODCrin mother liquor of pulping wastewater was eliminated by 55.2%from ultrahigh initial concentration up to 12,500 mg·L^-1.The decolorization rate was 96.5%.Recovered salt was mainly NaCl(83.3 wt%)having whiteness 50 brighter than industrial baysalt of whiteness 45.The oxidation conditions were optimized as CO3=0.11 g·L^-1 and CH2O2=2.0 g·L^-1 with dispersing rate 0.53 ml·min^-1 for 100 min reaction toward acidified liquor of p H=2.Acidification has notably improved evaporation efficiency during crystallization.Addition of H2O2 made through membrane dispersion has eliminated hydroxyl radical"quench effect"and enhanced the degradation capacity,in particular,the breakage of carbon-chloride bonds(of both aliphatic and aromatic).As a result,the proposed coupling method has improved organic pollutant reduction so as the purity of salt from the wastewater mixture which can facilitate water and salt recycling in industry.