Samples of fog water collected in the area of Guangzhou during February, March and April of 2005 are used in this work to study the chemical composition of fog water in polluting fog there. Three typical episodes of p...Samples of fog water collected in the area of Guangzhou during February, March and April of 2005 are used in this work to study the chemical composition of fog water in polluting fog there. Three typical episodes of polluting fog are analyzed in terms of ionic concentration and their possible sources. It is found that the concentration of various ions in fog water is much higher than those in rainwater. Fog not only blocks visual range but contains liquid particles that result in high degree of pollution and are very harmful to human health. SO4= is the anion with the highest concentration in fog water, followed by NO3-. For the cation, Ca++ and NH4+ are the highest in concentration. It is then known that rainwater is more acidic than fog water, indicating that ionic concentration of fog water is much higher than that of rainwater, but there are much more buffering materials in fog water, like NH4+ and Ca++. There is significant enrichment of Ca++, SO4=, and Mg++ in fog water. In the Guangzhou area, fog water from polluting fog is mainly influenced continental environment and human activity. The episodes of serious fog pollution during the time have immediate relationships with the presence of abundant water vapor and large amount of polluting aerosol particles.展开更多
We conducted a three-month field experiment focusing on the physical and chemical characteristics of fog in a tropical rainforest in Xishuangbanna,Southwest China,in the winter of 2019.In general,the fog would form at...We conducted a three-month field experiment focusing on the physical and chemical characteristics of fog in a tropical rainforest in Xishuangbanna,Southwest China,in the winter of 2019.In general,the fog would form at midnight and persist because of the increased long-wave radiative cooling combined with the high relative humidity,gentle breeze,and a relatively low aerosol number concentration in the forest;the fog would dissipate before noon due to the increasing turbulence near the surface.This diurnal cycle is typical for radiation fog.The microphysical fog properties included a relatively low number concentration of the fog droplet,large droplet size,high liquid water content,narrow droplet number-size distribution,and high supersaturation.The chemical properties showed that the fog water was slightly alkaline with low electrical conductivity,whereas the highest proportions of anions and cations therein were Cl^(−)and Ca^(2+),respectively;the chemical components were enriched in small fog droplets.In addition,we indirectly calculated the fog supersaturation according to theκ-Köhler theory.We found that condensation broadens the droplet number-size distribution at relatively low supersaturation,which is positively correlated with the fog-droplet number concentration and negatively correlated with the droplet mean-volume diameter;this affects the key microphysical processes of fog.展开更多
基金Natural Science Foundation of China (40375002, 40418008, 40775011, U0733004)Project 863 (2006AA06A306, 2006AA06A308)+3 种基金National Basic Research Program of China (973 Program):2005CB422207Natural Science Foundation of Guangdong Province (033029)Project of Key Scientific Research of Guangdong Province (2004A30401002, 2005B32601011)Project of Applied Fundamental Research of Guangzhou (2004J1-0021)
文摘Samples of fog water collected in the area of Guangzhou during February, March and April of 2005 are used in this work to study the chemical composition of fog water in polluting fog there. Three typical episodes of polluting fog are analyzed in terms of ionic concentration and their possible sources. It is found that the concentration of various ions in fog water is much higher than those in rainwater. Fog not only blocks visual range but contains liquid particles that result in high degree of pollution and are very harmful to human health. SO4= is the anion with the highest concentration in fog water, followed by NO3-. For the cation, Ca++ and NH4+ are the highest in concentration. It is then known that rainwater is more acidic than fog water, indicating that ionic concentration of fog water is much higher than that of rainwater, but there are much more buffering materials in fog water, like NH4+ and Ca++. There is significant enrichment of Ca++, SO4=, and Mg++ in fog water. In the Guangzhou area, fog water from polluting fog is mainly influenced continental environment and human activity. The episodes of serious fog pollution during the time have immediate relationships with the presence of abundant water vapor and large amount of polluting aerosol particles.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.41775134,41822504,41675136,and 41671209)the Innovative Project of Postgraduates in Jiangsu Province(Grant Nos.KYCX20_0920).
文摘We conducted a three-month field experiment focusing on the physical and chemical characteristics of fog in a tropical rainforest in Xishuangbanna,Southwest China,in the winter of 2019.In general,the fog would form at midnight and persist because of the increased long-wave radiative cooling combined with the high relative humidity,gentle breeze,and a relatively low aerosol number concentration in the forest;the fog would dissipate before noon due to the increasing turbulence near the surface.This diurnal cycle is typical for radiation fog.The microphysical fog properties included a relatively low number concentration of the fog droplet,large droplet size,high liquid water content,narrow droplet number-size distribution,and high supersaturation.The chemical properties showed that the fog water was slightly alkaline with low electrical conductivity,whereas the highest proportions of anions and cations therein were Cl^(−)and Ca^(2+),respectively;the chemical components were enriched in small fog droplets.In addition,we indirectly calculated the fog supersaturation according to theκ-Köhler theory.We found that condensation broadens the droplet number-size distribution at relatively low supersaturation,which is positively correlated with the fog-droplet number concentration and negatively correlated with the droplet mean-volume diameter;this affects the key microphysical processes of fog.