高温超导材料Ag-Mg合金包套力学性能研究

高温超导材料Bi-2212在4.2K具有优异的磁场载流性能,是高场应用的首选材料之一。然而,其塑性差、对应变敏感的特性阻碍了其在实际中的应用。测试了Ag、Ag-Mg合金以及以Ag-Mg合金作为包套的Bi-2212导线在不同温度下的机械性能,结果表明使用Ag-Mg合金做包套可以有效提高Bi-2212线材机械性能,是确保Bi-2212实际应用的有效手段。

Microstructure and mechanical properties of extruded Mg-8.5Gd-2.3Y-1.8Ag-0.4Zr alloy

The microstructure, age hardening behavior and mechanical properties of an Mg-8.5Gd-2.3Y-1.8Ag-0.4Zr alloy prepared by casting and hot extrusion techniques were investigated. The solution-treated （T4 temper） alloys were extruded at 400, 450 and 500 °C with an extrusion ratio of 10：1, respectively. Optimized mechanical properties were obtained by extrusion at 400 °C followed by T5 treatment under the combined effects of grain refinement and precipitation strengthening. The alloy exhibits a grain size of about 5.0 μm, initial and peak microhardness of HV 109 and HV 129, respectively. The tensile yield strength, ultimate tensile strength and elongation at room temperature are 391 MPa, 430 MPa and 5.2%, respectively.

Effect of solid solution treatment on in vitro degradation rate of as-extruded Mg-Zn-Ag alloys

The degradation behaviors of the as-extruded and solution treated Mg-3Zn-xAg(x=0,1,3,mass fraction,%)alloys,as well as as-extruded pure Mg,have been investigated by immersion tests in simulated body fluid(SBF)at37°C.The as-extruded Mg-Zn(-Ag)alloys contained Mg51Zn20and Ag17Mg54.While the quasi-single phase Mg-Zn(-Ag)alloys were obtained by solution treatment at400°C for8h.The quasi-single phase Mg-Zn(-Ag)alloys showed lower degradation rate and more homogeneous degradation than corresponding as-extruded Mg alloys.Degradation rate of solid-solution treated Mg-3Zn-1Ag and Mg-3Zn-3Ag was approximately half that of corresponding as-extruded Mg alloy.Moreover,the degradation rate of solid-solution treated Mg-3Zn and Mg-3Zn-1Ag was equivalent to that of as-extruded pure Mg.However,heterogeneous degradation also occurred in quasi-single phase Mg-Zn-Ag alloys,compared to pure Mg.So,preparing complete single-phase Mg alloys could be a potential and feasible way to improve the corrosion resistance.

High cyclic fatigue performance of Al-Cu-Mg-Ag alloy under T6 and T840 conditions

High cyclic fatigue(HCF)behavior of an AA2139alloy belonging to Al-Cu-Mg-Ag system in T6and T840conditionswas examined.The T840treatment involving cold rolling with a40%reduction prior to peak ageing provides an increase in tensilestrength compared with the T6condition.However,fatigue lifetime for two material conditions was nearly the same since there isweak effect of thermomechanical processing on micro-mechanisms of crack initiation and growth.

Effects of trace Ag on precipitation behavior and mechanical properties of extruded Mg−Gd−Y−Zr alloys

The effects of trace Ag element on the precipitation behaviors and mechanical properties of the Mg−7.5Gd−1.5Y−0.4Zr(wt.%)alloy by means of tensile test,X-ray diffractometry,scanning electron microscopy,electron backscattered diffractometry,and scanning transmission electron microscopy.There is an unusual texture(á0001ñ//extrusion direction)in the extruded Mg−Gd−Y−Zr alloys containing 0.5 wt.%Ag.During the aging periods at 225℃,the addition of the trace Ag does not form new precipitates,just accelerates aging kinetics,and refinesβ′precipitates,thereby increasing the number density of theβ′precipitates by Ag-clusters.Moreover,the Mg−Gd−Y−Zr alloy containing 0.5 wt.%Ag shows the most excellent synergy of strength and plasticity(408 MPa of ultimate tensile strength,265 MPa of yield strength,and 12.9%of elongation to failure)after peak-aging.

Microstructure,mechanical properties and corrosion behavior of quaternary Mg−1Zn−0.2Ca−xAg alloy wires applied as degradable anastomotic nails

The microstructure,mechanical properties and corrosion behavior of quaternary degradable Mg−1Zn−0.2Ca−xAg(x=1,2,4 wt.%)alloy wires,intended as anastomotic nails,were investigated.It was found that these Ag-containing alloy wires mainly consist of Mg matrix and Ag17Mg54 phase,characterized by SEM,EDS,XRD and TEM.Tensile and knotting tests results demonstrate the superior mechanical properties of these alloy wires.Especially,Mg−1Zn−0.2Ca−4Ag alloy exhibits the highest mechanical properties,i.e.an ultimate tensile strength of 334 MPa and an elongation of 8.6%.Moreover,with increasing Ag content,the corrosion rates of these alloy wires remarkably increase due to the formation of more micro-galvanic coupling between Mg matrix and Ag17Mg54 phase,shown by mass loss and scanning Kelvin probe force microscopy(SKPFM)results.The present alloy can be completely degraded within 28 d,satisfying the property requirements of anastomotic nails.

Corrosion behaviour of Mg−Gd−Y−Zn−Ag alloy components with different sizes after cooling

The corrosion behaviour of Mg−6Gd−3Y−1Zn−0.3Ag(wt.%)alloy components with different sizes after cooling was investigated.The alloys in the small components(SC)cooled fast,which were composed ofα-Mg matrix and coarse long-period stacking ordered(LPSO)phases.The alloys in the large components(LC)cooled slowly,and there were thin lamellar LPSO phases precipitating inside the grains,except forα-Mg matrix and coarse LPSO phases.The hydrogen evolution test revealed that the corrosion rate of LC sample was higher than that of SC sample.Electrochemical impedance spectroscopy(EIS)test showed that the surface film on LC alloys provided worse protection.The corrosion morphologies indicated that the precipitation of the thin lamellar LPSO phases in LC sample caused severe micro-galvanic corrosion,which accelerated the rupture of the surface film.