Ag3PO4/Ag/Ag2Mo2O7 composite photocatalyst was successfully prepared via an in situ precipitation method. The as-prepared Ag3PO4/Ag/Ag2Mo2O7 nanocomposite included Ag3PO4 nanoparticles （NPs） as well as Ag NPs assemb...Ag3PO4/Ag/Ag2Mo2O7 composite photocatalyst was successfully prepared via an in situ precipitation method. The as-prepared Ag3PO4/Ag/Ag2Mo2O7 nanocomposite included Ag3PO4 nanoparticles （NPs） as well as Ag NPs assembling on the surface of Ag2Mo2O7 nanowires. Under visible light irradiation （λ〉420 nm）, the Ag3PO4/Ag/Ag2Mo2O7 com- posite degraded rhodamine B （Rh B） efficiently and showed much higher photocatalytic efficiency than pure AgaPO4, Ag2Mo2O7, or Ag3PO4/Ag2Mo2O7. It was elucidated that the excellent photocatalytic performance of Ag3PO4/Ag/Ag2Mo2O7 for the degradation of Rh B under visible light could be ascribed to the high specific surface area, the extended absorption in the visible light region resulting from the Ag3PO4/Ag loading, and the effi- cient separation of photogenerated electrons and holes through the ternary heterostrucure composed of Ag3PO4, Ag and Ag2Mo2O7.展开更多
Ag3PO4 is widely used in the field of photocatalysis because of its unique activity. However, photocorrosion limits its practical application. Therefore, it is very urgent to find a solution to improve the light corro...Ag3PO4 is widely used in the field of photocatalysis because of its unique activity. However, photocorrosion limits its practical application. Therefore, it is very urgent to find a solution to improve the light corrosion resistance of Ag3PO4. Herein, the Z-scheme WO3(H2O)0.333/Ag3PO4 composites are successfully prepared through microwave hydrothermal and simple stirring. The WO3(H2O)0.333/Ag3PO4 composites are characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and UV-Vis spectroscopy. In the degradation of organic pollutants, WO3(H2O)0.333/Ag3PO4 composites exhibit excellent performance under visible light. This is mainly attributed to the synergy of WO3(H2O)0.333 and Ag3PO4. Especially, the photocatalytic activity of 15%WO3(H2O)0.333/Ag3PO4 is the highest, and the methylene blue can be completely degraded in 4 min. In addition, the stability of the composites is also greatly enhanced. After five cycles of testing, the photocatalytic activity of 15%WO3(H2O)0.333/Ag3PO4 is not obviously decreased. However, the degradation efficiency of Ag3PO4 was only 20.2%. This indicates that adding WO3(H2O)0.333 can significantly improve the photoetching resistance of Ag3PO4. Finally, Z-scheme photocatalytic mechanism is investigated.展开更多
基金supported by the Natural Science Foundation of Hebei Province,China(B2014209182)Youth Foundation of Hebei Education Department,China(QN2014045)College Students'Innovative Entrepreneurial Training Plan Program of North China University of Science and Technology,China(X2015117)~~
文摘水热法结合原位沉淀法成功制备新型磁性溴化银/磷酸银/铁酸锌(AgBr/Ag_3PO_4/ZnFe_2O_4)复合催化剂,并通过X射线衍射、能量色散X射线、场发射扫描电子显微镜、透射电子显微镜和紫外-可见漫反射光谱对其晶相结构、组成、形貌及吸光性能进行了表征。在可见光照射下,所制备的AgBr/Ag_3PO_4/ZnFe_2O_4复合催化剂光催化降解罗丹明B(RhB)的活性优于Ag_3PO_4/ZnFe_2O_4、AgBr/ZnFe_2O_4和P25 TiO_2。在酸性和碱性溶液中,AgBr/Ag_3PO_4/ZnFe_2O_4光催化剂呈现出优良光催化性能。在AgBr/Ag_3PO_4/ZnFe_2O_4体系中,光催化降解Rh B的速率随着反应体系温度的升高而增大,由阿伦尼乌斯方程计算获得反应体系活化能为31.9 k J?mol^(-1)。AgBr/Ag_3PO_4/ZnFe_2O_4复合材料优异的可见光催化活性归因于光生电荷的有效分离,所产生的超氧自由基和空穴是Rh B降解的主要活性物种。
基金supported by the National Natural Science Foundation of China(No.21407059,No.21576112,No.21407064,and No.21607051)the Science Development Project of Jiangsu Province(BK20140527)+1 种基金the Science and Technology Research Project of the Department of Education of Jilin Province(No.2015220)the Open Subject of the State Key Laboratory of Rare Earth Resource Utilization(RERU2017011)
文摘Ag3PO4/Ag/Ag2Mo2O7 composite photocatalyst was successfully prepared via an in situ precipitation method. The as-prepared Ag3PO4/Ag/Ag2Mo2O7 nanocomposite included Ag3PO4 nanoparticles （NPs） as well as Ag NPs assembling on the surface of Ag2Mo2O7 nanowires. Under visible light irradiation （λ〉420 nm）, the Ag3PO4/Ag/Ag2Mo2O7 com- posite degraded rhodamine B （Rh B） efficiently and showed much higher photocatalytic efficiency than pure AgaPO4, Ag2Mo2O7, or Ag3PO4/Ag2Mo2O7. It was elucidated that the excellent photocatalytic performance of Ag3PO4/Ag/Ag2Mo2O7 for the degradation of Rh B under visible light could be ascribed to the high specific surface area, the extended absorption in the visible light region resulting from the Ag3PO4/Ag loading, and the effi- cient separation of photogenerated electrons and holes through the ternary heterostrucure composed of Ag3PO4, Ag and Ag2Mo2O7.
基金supported by the National Natural Science Foundation of China(51572103 and 51502106)the Distinguished Young Scholar of Anhui Province(1808085J14)+2 种基金the Foundation for Young Talents in College of Anhui Province(gxyqZD2017051)the Key Foundation of Educational Commission of Anhui Province(KJ2016SD53)the Innovation Team of Design and Application of Advanced Energetic Materials(KJ2015TD003)~~
文摘Ag3PO4 is widely used in the field of photocatalysis because of its unique activity. However, photocorrosion limits its practical application. Therefore, it is very urgent to find a solution to improve the light corrosion resistance of Ag3PO4. Herein, the Z-scheme WO3(H2O)0.333/Ag3PO4 composites are successfully prepared through microwave hydrothermal and simple stirring. The WO3(H2O)0.333/Ag3PO4 composites are characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and UV-Vis spectroscopy. In the degradation of organic pollutants, WO3(H2O)0.333/Ag3PO4 composites exhibit excellent performance under visible light. This is mainly attributed to the synergy of WO3(H2O)0.333 and Ag3PO4. Especially, the photocatalytic activity of 15%WO3(H2O)0.333/Ag3PO4 is the highest, and the methylene blue can be completely degraded in 4 min. In addition, the stability of the composites is also greatly enhanced. After five cycles of testing, the photocatalytic activity of 15%WO3(H2O)0.333/Ag3PO4 is not obviously decreased. However, the degradation efficiency of Ag3PO4 was only 20.2%. This indicates that adding WO3(H2O)0.333 can significantly improve the photoetching resistance of Ag3PO4. Finally, Z-scheme photocatalytic mechanism is investigated.
