The hybrid battery integrating a typical Zn redox battery and a Zn-air battery is a promising green technology for energy storage,and the cathode integrating the redox reaction and electrocatalytic oxygen reduction is...The hybrid battery integrating a typical Zn redox battery and a Zn-air battery is a promising green technology for energy storage,and the cathode integrating the redox reaction and electrocatalytic oxygen reduction is a key point for efficient electrochemical energy conversion.Herein,we report a scalable strategy to fabricate nanoporous Ag2 Al internetallic compound as a self-standing cathode for the hybrid Zn battery.The abundant surface oxygen species,the Ag-Al intermetallic interaction and the npAg_(2)Al@AgAlOx interface cooperatively contributed to the catalytic ORR activity.The electrode endows efficient catalytic oxygen reduction(a Tafel slope of 38.0 mV/dec and an onset potential of 0.998 V)and regulated redox activity as compared with Ag.The nanoporous channels allow efficient ion transport,interface charge exchange and gas molecular diffusion.Significantly,the assembled hybrid Zn-Ag_(2) Al/air battery delivers a high capacity of 3.23 mAh/cm^(2) as compared with recent reports.As far as we know,this is the first exploration for the electrochemical property of Ag2 Al,and it would inspire more exploration in developing multifunctional materials and robust hybrid batteries for practical applications.展开更多
基金supported by the National Natural Science Foundation of China(No.51771072 and No.51901076)the Youth 1000 Talent Program of China,the Natural Science Foundation of Hunan Province(No.2019JJ50051)+1 种基金the Fundamental Research Funds for the Central Universitiesthe project support from State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body in Hunan University(No.71865007)。
文摘The hybrid battery integrating a typical Zn redox battery and a Zn-air battery is a promising green technology for energy storage,and the cathode integrating the redox reaction and electrocatalytic oxygen reduction is a key point for efficient electrochemical energy conversion.Herein,we report a scalable strategy to fabricate nanoporous Ag2 Al internetallic compound as a self-standing cathode for the hybrid Zn battery.The abundant surface oxygen species,the Ag-Al intermetallic interaction and the npAg_(2)Al@AgAlOx interface cooperatively contributed to the catalytic ORR activity.The electrode endows efficient catalytic oxygen reduction(a Tafel slope of 38.0 mV/dec and an onset potential of 0.998 V)and regulated redox activity as compared with Ag.The nanoporous channels allow efficient ion transport,interface charge exchange and gas molecular diffusion.Significantly,the assembled hybrid Zn-Ag_(2) Al/air battery delivers a high capacity of 3.23 mAh/cm^(2) as compared with recent reports.As far as we know,this is the first exploration for the electrochemical property of Ag2 Al,and it would inspire more exploration in developing multifunctional materials and robust hybrid batteries for practical applications.
