Advances in methane emissions from agricultural sources:Part I.Accounting and mitigation

Methane is one of the major greenhouse gases(GHGs)and agriculture is recognized as its primary emitter.Methane accounting is a prerequisite for developing effective agriculture mitigation strategies.In this review,methane accounting methods and research status for various agricultural emission source including rice fields,animal enteric fermentation and livestock and poultry manure management were overview,and the influencing factors of each emission source were analyzed and discussed.At the same time,it analyzes the different research efforts involving agricultural methane accounting and makes recommendations based on the actual situation.Finally,mitigation strategies based on accounting results and actual situation are proposed.This review aims to provide basic data and reference for agriculture-oriented countries and regions to actively participate in climate action and carry out effective methane emission mitigation.

Agricultural non-point nitrogen pollution control function of dierent vegetation types in riparian wetlands: A case study in the Yellow River wetland in China

Riparian wetland is the major transition zone of matter, energy and information transfer between aquatic and terrestrial ecosystems and has important functions of water purification and non-point pollution control. Using the field experiment method and an isotope tracing technique, the agricultural non-point nitrogen pollution control function of different vegetation types in riparian wetland was studied in the Kouma Section of the Yellow River. The results showed that the retention of agricultural non-point nitrogen pollution by riparian wetland soil occurs mainly in top 0-10 cm layer. The amount of nitrogen retained by surface soils associated with three types of vegetation are 0.045 mg/g for Phragmites communis Trin Linn, 0.036 mg/g for Scirpus triqueter Linn, and 0.032 mg/g for Typha angustifolia Linn, which account for 59.21%, 56.25%, and 56.14% of the total nitrogen interception, respectively. Exogenous nitrogen in 0-10 cm soil layer changes more quickly than in other layers. One month after adding KISNO3 to the tested vegetation, nitrogen content was 77.78% for P communis Trin, 68.75% for T. angustifolia, and 8.33% for S. triqueter in the surface soil. After three months, nitrogen content was 93.33% for P. communis Trin, 72.22% for S. triqueter, and 37.50% for T. Angustifolia. There are large differences among vegetation communities respecting to purification of agricultural non-point nitrogen pollution. The nitrogen uptake amount decreases in the sequence： new shoots ofP. communis Trin （9.731 nag/g） 〉 old P. communis Trin （4.939 mg/g） 〉 S. triqueter （0.620 mg/g） 〉 T. angustifolia （0.186 mg/g）. Observations indicated that the presence of riparian wetlands as buffers on and adjacent to stream banks could be recommended to control agricultural non-point pollution.

Validation of an agricultural non-point source(AGNPS)pollution model for a catchment in the Jiulong River watershed,China

This study tested and evaluated the agricultural non-point source （AGNPS） model for the Wuchuan catchment, a typical agricultural area in the Jiulong River watershed, Fujian Province, China. The AGNPS model was calibrated and validated for the study area with observed data on ten storms. The data on eight storms in 2002 were used for calibration while data on two storms were used for validation of the model. Considering the lack of water quality data over a long-term series, a novel method, comparing an internal nested catchment with its surrounding catchment, was used to supplement the less long-term series data. Dual calibration and validation of the AGNPS model was obtained by this comparison. The results indicate that the correlation coefficients were 0.99 and 0.98 for runoff, 0.94 and 0.95 for the peak runoff rate of the large catchment and the small catchment, respectively, and 0.76 for the sediment of the small catchment only. Each pair of correlation coefficients is homogeneous for the same event for the two catchments. With the exception of the sediment yield and particulate phosphorus, the peak runoff rate and other nutrients were well predicted. Sensitivity analysis showed that the Soil Conservation Service curve number and rainfall quantity were the most sensitive parameters, which resulted in high output variations. Erosivity and other parameters had little influence on the hydrological and quality outputs.

Study on Control Countermeasures of Agricultural Non-point Source Pollution in Lakeside Belt of Poyang Lake——Taking Duchang Section in the Lower Reaches of Poyang Lake as Example

[Objective] The aim was to study the control countermeasures of agricultural non-point source pollution in lakeside belt of Poyang Lake.[Method] The current situation of water quality of Poyang Lake was analyzed firstly,then the causes of agricultural non-point source pollution in Duchang section of Poyang Lake were studied,finally corresponding control countermeasures were put forward.[Result] Agricultural non-point source pollution in Duchang section of Poyang Lake was mainly related to the rapid development of pearl industry and livestock industry,aggravated soil erosion and excessive utilization of fertilizer.Based on analysis of current environmental situation and bearing capability of resources in Poyang Lake basin,agricultural non-point source pollution would be controlled through the reduction of external source pollution load,restoration of river wetland and construction of aquatic ecosystem.After the primary implementation of agricultural non-point source pollution control project,the amount of agricultural non-point source pollution in demonstration plot was reduced,and the quality of effluent met the first Class (Class A) of state Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB18918-2002).Meanwhile,biodiversity index in river wetland increased by about 30%,so the pollution load entering Poyang Lake was decreased.[Conclusion] The study could provide technology integration and demonstration for the environmental remediation in lakeside belt of Poyang Lake.

Agricultural Non-point Source Pollution in China:Evaluation,Convergence Characteristics and Spatial Effects

In this study,an inventory analysis approach was used to investigate the intensity of agricultural non-point source pollution(ANSP)and its spatial convergence at national and provincial levels in China from 1999 to 2017.On this basis,spatial factors affecting ANSP were explored by constructing a spatial econometric model.The results indicate that:1)The intensity of China's ANSP emission showed an overall upward trend and an obvious spatial difference,with the values being high in the eastern and central regions and relatively low in the western region.2)Significant spatial agglomeration was shown in China's ANSP intensity,and the agglomeration effect was increasing gradually.3)In the convergence analysis,a spatial lag model was found applicable for interpretation of the ANSP intensity,with the convergence rate being accelerated after considering the spatial factors but slower than that of regional economic growth.4)The spatial factors affecting the ANSP intensity are shown to be reduced by improving agricultural infrastructure investment,labor-force quality,and crop production ratio,while the expansion of agricultural economy scale and precipitation and runoff have positive impact on ANSP in the study region.However,agricultural research and development(R&D)investment showed no direct significant effect on the ANSP intensity.Meanwhile,improving the quality of the labor force would significantly reduce the ANSP intensity in the surrounding areas,while the precipitation and runoff would significantly increase the pollution of neighboring regions.This research has laid a theoretical basis for formulation and optimization of ANSP prevention strategies in China and related regions.

Impact of nutrient losses from agricultural lands on nutrient stocks in Dianshan Lake in Shanghai, China

Abstract： The water quality of Dianshan Lake in Shanghai Municipality, China, is impacted by nutrient losses from agricultural lands around the lake. In this study, nine types of agricultural land use were monitored in 2010 and 2011, and a correlation analysis between nutrient losses from agricultural non-point sources （NPS） and nutrient stocks in the lake was conducted over monthly and seasonal time periods. The results indicate that the monthly average concentration of total nitrogen （TN） ranged from 1.41 to 7.34 mg/L in 2010 and from 1.52 to 5.90 mg/L in 2011, while the monthly average concentration of total phosphorous （TP） ranged from 0.11 to 0.26 mg/L in 2010 and from 0.13 to 0.30 mg/L in 2011. The annual loss of TN from agricultural NPS was 195.55 tons in 2010 and 208.40 tons in 2011. The cultivation of water oat made the largest contribution to the loss of TN. The annual loss of TP was 44.58 tons in 2010 and 48.12 tons in 2011, and multi-vegetable cultivation made the largest contribution to the loss of TP. The results of correlation analysis show that the monthly stocks of TN and TP in the lake have a positive correlation with the monthly losses of TN and TP from agricultural NPS. According to the seasonal data, the stocks of TN and TP in the lake both have a much stronger correlation with the losses of TN and TP from agricultural NPS in summer than in other seasons. Agricultural NPS pollution control should be the main focus for the water resource conservation in this area.

Risk Prevention and Control for Agricultural Non-Point Source Pollution Based on the Process of Pressure-Transformation-Absorption in Chongqing, China

According to China’s second national survey of pollution sources, the contribution of agricultural non-point sources(ANS) to water pollution is still high. Risk prevention and control are the main means to control costs and improve the efficiency of ANS, but most studies directly take pollution load as the risk standard, leading to a considerable misjudgment of the actual pollution risk. To objectively reflect the risk of agricultural non-point source pollution(ANSP) in Chongqing, China, we investigated the influences of initial source input, intermediate transformation, and terminal absorption of pollutants via literature research and the Delphi method and built a PTA(pressure kinetic energy, transformation kinetic energy, and absorption kinetic energy) model that covers 12 factors, with the support of geographical information system(GIS) technology. The terrain factor calculation results and the calculation results of other factors were optimized by Python tools to reduce human error and workload. Via centroid migration analysis and Kernel density analysis, the risk level, spatial aggregation degree, and key prevention and control regions could be accurately determined. There was a positive correlation between the water quality of the rivers in Chongqing and the risk assessment results of different periods, indirectly reflecting the reliability of the assessment results by the proposed model. There was an obvious tendency for the low-risk regions transforming into high-risk regions. The proportion of high-risk regions and extremely high-risk regions increased from 17.82% and 16.63%in 2000 to 18.10% and 16.76% in 2015, respectively. And the risk level in the main urban areas was significantly higher than that in the southeastern and northeastern areas of Chongqing. The centroids of all grades of risky areas presented a successive distribution from west to east, and the centroids of high-risk and extremely high-risk regions shifted eastward. From 2000 to 2015, the centroids of highrisk and extremely high-risk regions moved 4.63 km(1.68°) and 4.48 km(12.08°) east by north, respectively. The kernel density analysis results showed that the high-risk regions were mainly concentrated in the main urban areas and that the distribution of agglomeration areas overall displayed a transition trend from contiguous distribution to decentralized concentration. The risk levels of the regions with a high proportion of cultivated land and artificial surface were significantly increased, and the occupation of cultivated land in the process of urbanization promoted the movement of the centroids of high-risk and extremely high-risk regions. The identification of key areas for risk prevention and control provides data scientific basis for the development of prevention and control strategies.

Effects of Rainfall Change on Agricultural Non-point Source Pollution in Liangping County

[Objective] The study aimed to discuss the impact of rainfall change on agricultural non-point source pollution in Uangping County. E Method ] Based on daily precipitation data of Liangping from 1955 to 2011, changes of precipitation and frequency of heavy rain in Uangping during a year were analyzed firstly, and then the risk of surface runoff caused by rainfall to agricultural non-point source pollution was studied, finally chan- ging trends of annual average precipitation and frequency during 1955 -2011 were discussed using Mann-Kendal method. [ Result] Total precipitati- on of heavy rain in Liangping mainly concentrated from late May to early September, especially in eady and middle July as well as early September. Meanwhile, fertilizer and pesticide were applied to main crops in Liangping in the periods above, so agricultural non-point source pollution became more serious. In recent 57 years, annual average precipitation and frequency of heavy rain in Liangping showed an increasing trend respectively, and surface runoff rose with the increase of the precipitation, thereby probably enlarging agricultural pollution area. [ Conclusion] The research could provide a theoretical basis and technical support for the control of agricultural non-point source pollution.

Agricultural Non-point Source Pollution in Drinking Water Conservation Area of the Hongfeng Lake in Guiyang City

On the basis of investigating rural population, land types, livestock and poultry breeding scale in drinking water conservation area of the Hongfeng Lake in Guiyang City, as well as the urban domestic pol utant discharge coefficient, livestock and poultry excretion coefficient, nitrogen fertilizer and phosphate fertilizer loss rate in the first national pollution source survey, this paper tried to explore current situation of agricultural non-point source pollution, and provide scientific support for the pollution control. The results showed that in the drinking water conservation area of the Hongfeng lake in 2013, contribution rate of pollution sources to the water pollution in the Hongfeng Lake followed the sequence "livestock and poultry breeding > rural life > farmland fertilizer". Among all agricultural non-point source pollutants, livestock and poultry breeding pollutants were major pollution sources, with a contribution rate to CODCr, TP and NH3-N in water above 50%; rural domestic pollutants were also important pollution sources, its contribution rate to CODCr and NH3-N was 43.49% and 46.69%, respectively; contribution rate of farmland fertilizer pollutants to TN and TP was 33.76% and 27.71%, respectively, higher than that of rural domestic pollutants(25.87% and 6.75%). Therefore, the control of non-point source pollution within the drinking water conservation area should be enhanced, so as to control the pollution from the source.

Impact of social capital on farmers' response to different policies for controlling agricultural non-point source pollution

Chinese society in rural areas is typically a geographically and genetically related society.Scattered farmers can be connected to form small groups through their social capital,which can affect farmers' agricultural activities in the process of controlling agricultural Non-point Source pollution.An ordered Logit model can be built to analyze the effects of social capital to farmers' responsive willingness to different measurements of controlling agricultural NPS pollution by using survey data in Shaanxi Province.This paper characterizes farmers' social capital in three dimensions:social trust,social participation and social network.The results indicated that farmers' social capital significantly affects farmers' response to different policies.When governments construct and implement policies to control agricultural NPS pollution,the effects of social capital need to be considered at same time with the effects of governmental supervision,market and education measurements.

Isotopic characteristics and source analysis of atmospheric ammonia during agricultural periods in the Xichuan area of the Danjiangkou Reservoir

Nitrogen deposition is an important means of exogenous nitrogen input in reservoir water.Agricultural activities around the reservoir lead to a sharp increase in the concentration of ammonia in the atmosphere,which poses a threat to the reservoir water body.Clarifying the contribution of agricultural ammonia release to atmospheric NH_(x)(gaseous NH_(3)and particulate NH_(4)^(+)),in the reservoir area can provide a theoretical foundation for local reactive nitrogen control.We collected atmospheric NH_(3)and NH_(4)^(+)samples during the agricultural periods and analyzed the isotopic characteristics of atmospheric NH_(x)and the contribution rates of different ammonia sources in the Xichuan area of the Danjiangkou Reservoir.The results showed that the initialδ~(15)N values of NH_(3)(-30.0‰to–7.2‰)and particulate NH_(4)^(+)(–33‰to+4.9‰for finer and coarser particles,respectively)are different,and their contribution ratios from dissimilar ammonia sources are also different,among which NH_(4)^(+)is more susceptible to meteorological factors.However,since the atmospheric NH_(x)in the Xichuan area is mainly gaseous NH_(3),the final sources of atmospheric ammonia nitrogen source depend on gaseous NH_(3).Agricultural sources(59%-74%)were the main NH_(3)sources in this area.Among them,the fertilizer use emission was dominant;it had the highest contribution rate in summer during the agricultural period and a more prominent impact in areas with less human interference.Reasonable regulation of the application of high-ammonia releasing fertilizer,especially during the agricultural period in summer,is an effective way to reduce the threat of atmospheric ammonia to water health.

Source analysis of dissolved heavy metals in the Shaying River Basin,China

Over the years,the Shaying River Basin has experienced frequent instances of river pollution.The presence of numerous critical pollutant discharge enterprises and sewage-treatment plants in the vicinity of the Shaying River has transformed it a major tributary with relatively serious pollution challenge within the upper reaches of Huaihe River Basin.To study the sources of manganese(Mn),chromium(Cr),nickel(Ni),arsenic(As),cadmium(Cd)and lead(Pb)in Shaying River water,123 sets of surface water samples were collected from 41 sampling points across the entire basin during three distinct phases from 2019 to 2020,encompassing normal water period,dry season and wet season.The primary origins of heavy metals in river water were determined by analyzing the heavy metal contents in urban sewage wastewater,industrial sewage wastewater,groundwater,mine water,and the heavy metal contributions from agricultural non-point source pollution.The analytical findings reveal that Mn primarily originates from shallow groundwater used for agricultural irrigation,While Cr mainly is primarily sourced from urban sewage treatment plant effluents,coal washing wastewater,tannery wastewater,and industrial discharge related to metal processing and manufacturing.Ni is mainly contributed by urban sewage treatment plant effluents and industrial wastewater streams associated with machinery manufacturing and metal processing.Cd primarily linked to industrial wastewater,particularly from machinery manufacturing and metal processing facilities,while Pb is predominantly associated with urban sewage treatment plant effluents and wastewater generated in Pb processing and recycling wastewater.These research provides a crucial foundation for addressing the prevention and control of dissolved heavy metals at their sources in the Shaying River.

西南涌流域农业面源污染状况分析(英文)

Taking Xinan River basin as research object,the status of agricultural non-point source pollution was analyzed based on field survey,as well as the effect of fertilizer and pesticide leaching and runoff,livestock and poultry breeding and rural domestic pollution on non-point source TN and TP.At last,some technical countermeasures of controlling non-point source pollution were put forward according to the characteristics of agricultural non-point source pollution in Xinan River basin.

Estimation of runoff and sediment yield in the Redrock Creek watershed using AnnAGNPS and GIS

Sediment has been identified as a significant threat to water quality and channel clogging that in turn may lead to river flooding. With the increasing awareness of the impairment from sediment to water bodies in a watershed, identifying the locations of the major sediment sources and reducing the sediment through management practices will be important for an effective watershed management. The annualized agricultural non-point source pollution(AnnAGNPS) model and newly developed GIS interface for it were applied in a small agricultural watershed, Redrock Creek watershed, Kansas, in this pilot study for exploring the effectiveness of using this model as a management tool. The calibrated model appropriately simulated monthly runoff and sediment yield through the practices in this study and potentially suggested the ways of sediment reduction through evaluating the changes of land use and field operation in the model for the purpose of watershed management.

Control division of agricultural non-point source pollution at medium-sized watershed scale in Southeast China

This paper presents the study carried out for controlling agricultural non-point source pollution(NSP)in a medium-sized watershed covering 1.47×10^(4) km^(2) in Southeast China using quantitative analysis coupled with geographic information system(GIS),universal soil loss equation(USLE),soil conservation service-curve number(SCS-CN),nutrient loss equations,and annualized agricultural nonpoint source model(AnnAGNPS).Based on the quantitative results derived from GIS and environmental models,five control division units were generated for NSP control in Jiulong River watershed,namely,controlling unit for soil losses,controlling unit for livestock breeding and soil losses,controlling unit for excessive fertilizer use and livestock breeding,controlling unit for soil losses and fertilizer use,and controlling unit for excessive fertilizer use and soil losses.This study proved that integrating GIS with environmental models can be adopted to efficiently evaluate major sources and contributors of NSP,and identify the critical source areas of NSP,which enables adjusting measures to local conditions by further control division units developed through such study for control and management of water quality degradation induced by NSP in the Jiulong River watershed.

Simultaneous degradation of sulfadiazine and dissolved organic matter based on low-impact development facilities

Sulfadiazine(SD)is a common antibiotic administered to treat bacterial infections in livestock,and its fate andmigration are greatly affected by dissolved organicmatter(DOM).The soil infiltration system[a typical low-impact development(LID)facility]can significantly alterDOMproperties during runoff pollution,thus affecting the complexation of SDwithDOM.Here,the binding characteristics of different DOM components and SD in the soil infiltration system were explored using spectroscopic techniques(excitation–emission matrices,parallel factor analysis,and synchronous fluorescence spectroscopy).Combined with the weakening of DOM fluorescence intensity and 78.63%reduction in mean SD concentration following treatment,synchronous degradation may have occurred.The binding sequence of SD and DOM fluorophores was further explored using two-dimensional correlation spectroscopy.Effluent DOM showed greater sensitivity to SD and more binding sites than influent DOM.Moreover,hydrophobic protein-like substances exhibited higher log K_(M) values than other fluorescent components,indicating that protein-like components play significant roles in SD complexation.The soil percolation system improved the complexation stability and binding sequence of fulvic-like substances.Thus,SD–DOM can be intercepted and degraded using LID facilities to reduce the risk of SD in aquatic environments.

FULL TIME-SPACE GOVERNANCE STRATEGY AND TECHNOLOGY FOR CROPLAND NON-POINT POLLUTION CONTROL IN CHINA

Ensuring food safety while reducing agricultural non-point source pollution is quite challenging,especially in developing and underdeveloped countries.Effective systematic strategies and comprehensive technologies need to be developed for agricultural non-point source pollution control at the watershed scale to improve surface water quality.In this review,a proposal is made for a full time-space governance strategy that prioritizes source management followed by endpoint water pollution control.The 4R chain technology system is specifically reviewed,including source reduction,process retention,nutrient reuse and water restoration.The 4R chain technology system with the full time-space governance strategy was applied at the scale of an administrative village and proved to be a feasible solution for reducing agricultural non-point source pollution in China.In the future,a monitoring system needs to be established to trace N and P transport.Additionally,new smart fertilizer and intelligent equipment need to be developed,and relevant governance standards and supportive policies need to be set to enhance the efficacy of agricultural non-point source pollution control.