A novel nano-grade organosilicon polymer:Improving airtightness of compressed air energy storage in hard rock formations

Enhancing cavern sealing is crucial for improving the efficiency of compressed air energy storage(CAES)in hard rock formations.This study introduced a novel approach using a nano-grade organosilicon polymer(NOSP)as a sealant,coupled with an air seepage evaluation model that incorporates Knudsen diffusion.Moreover,the initial coating application methods were outlined,and the advantages of using NOSP compared to other sealing materials,particularly regarding cost and construction techniques,were also examined and discussed.Experimental results indicated a significant reduction in permeability of rock specimens coated with a 7–10μm thick NOSP layer.Specifically,under a 0.5 MPa pulse pressure,the permeability decreased to less than 1 n D,and under a 4 MPa pulse pressure,it ranged between4.5×10^(-6)–5.5×10^(-6)m D,marking a 75%–80%decrease in granite permeability.The sealing efficacy of NOSP surpasses concrete and is comparable to rubber materials.The optimal viscosity for application lies between 95 and 105 KU,and the coating thickness should ideally range from 7 to 10μm,applied to substrates with less than 3%porosity.This study provides new insights into air transport and sealing mechanisms at the pore level,proposing NOSP as a cost-effective and simplified solution for CAES applications.

Comparative analysis of thermodynamic and mechanical responses between underground hydrogen storage and compressed air energy storage in lined rock caverns

Underground hydrogen storage(UHS)and compressed air energy storage(CAES)are two viable largescale energy storage technologies for mitigating the intermittency of wind and solar power.Therefore,it is meaningful to compare the properties of hydrogen and air with typical thermodynamic storage processes.This study employs a multi-physical coupling model to compare the operations of CAES and UHS,integrating gas thermodynamics within caverns,thermal conduction,and mechanical deformation around rock caverns.Gas thermodynamic responses are validated using additional simulations and the field test data.Temperature and pressure variations of air and hydrogen within rock caverns exhibit similarities under both adiabatic and diabatic simulation modes.Hydrogen reaches higher temperature and pressure following gas charging stage compared to air,and the ideal gas assumption may lead to overestimation of gas temperature and pressure.Unlike steel lining of CAES,the sealing layer(fibre-reinforced plastic FRP)in UHS is prone to deformation but can effectively mitigates stress in the sealing layer.In CAES,the first principal stress on the surface of the sealing layer and concrete lining is tensile stress,whereas UHS exhibits compressive stress in the same areas.Our present research can provide references for the selection of energy storage methods.

Design and Development of Wind-Solar Hybrid Power System with Compressed Air Energy Storage for Voltage and Frequency Regulations

The intermittent nature of wind and solar photovoltaic energy systems leads to the fluctuation of power generated due to the fact that the power output is highly dependent upon local weather conditions, which results to the load shading issue that led to the voltage and frequency instability. In additional to that, the high proportions of erratic renewable energy sources can lead to erratic frequency changes which affect the grid stability. In order to reduce this effect, the energy storage system is commonly used in most wind-solar energy systems to balance the voltage and frequency instability during load variations. One of the innovative energy storage systems is the compressed air energy storage system (CAES) for wind and solar hybrid energy system and this technology is the key focus in this research study. The aim of this research was to examine the system configuration of the CAES system through modelling and experimental approach with PID controller design for regulating the voltage and frequency under different load conditions. The essential elements and the entire system have been presented in this work as thorough modelling in the MATLAB/Simulink environment for different load conditions. The developed model was tested through an experimental workbench using the developed prototype of the compressed air storage in the Siemens Lab at DeKUT and explored the consequence of the working parameters on the system proficiency and the model accuracy. The performance of the system for the developed prototype of CAES system was validated using results from an experimental workbench with MATLAB/Simulink R2022b simulation. The modeling and experimental results, shows that the frequency fluctuation and voltage drop of the developed CAES system during load variations was governed by the I/P converter using a PID_Compact controller programed in the TIA Portal V17 software and downloaded into PLC S7 1200. Based on these results, the model can be applied as a basis for the performance assessment of the compressed air energy storage system so as to be included in current technology of wind and solar hybrid energy systems.

A power plant for integrated waste energy recovery from liquid air energy storage and liquefied natural gas

Liquefied natural gas(LNG)is regarded as one of the cleanest fossil fuel and has experienced significant developments in recent years.The liquefaction process of natural gas is energy-intensive,while the regasification of LNG gives out a huge amount of waste energy since plenty of high grade cold energy(-160℃)from LNG is released to sea water directly in most cases,and also sometimes LNG is burned for regasification.On the other hand,liquid air energy storage(LAES)is an emerging energy storage technology for applications such as peak load shifting of power grids,which generates 30%-40%of compression heat(-200℃).Such heat could lead to energy waste if not recovered and used.The recovery of the compression heat is technically feasible but requires additional capital investment,which may not always be economically attractive.Therefore,we propose a power plant for recovering the waste cryogenic energy from LNG regasification and compression heat from the LAES.The challenge for such a power plant is the wide working temperature range between the low-temperature exergy source(-160℃)and heat source(-200℃).Nitrogen and argon are proposed as the working fluids to address the challenge.Thermodynamic analyses are carried out and the results show that the power plant could achieve a thermal efficiency of 27%and 19%and an exergy efficiency of 40%and 28%for nitrogen and argon,respectively.Here,with the nitrogen as working fluid undergoes a complete Brayton Cycle,while the argon based power plant goes through a combined Brayton and Rankine Cycle.Besides,the economic analysis shows that the payback period of this proposed system is only 2.2 years,utilizing the excess heat from a 5 MW/40 MWh LAES system.The findings suggest that the waste energy based power plant could be co-located with the LNG terminal and LAES plant,providing additional power output and reducing energy waste.

Design issues for compressed air energy storage in sealed underground cavities

Compressed air energy storage （CAES） systems represent a new technology for storing very large amount of energy. A peculiarity of the systems is that gas must be stored under a high pressure （p - 10-30 MPa）. A lined rock cavern （LRC） in the form of a tunnel or shaft can be used within this pressure range. The rock mass surrounding the opening resists the internal pressure and the lining ensures gas tightness. The present paper investigates the key aspects of technical feasibility of shallow LRC tunnels or shafts under a wide range of geotechnical conditions. Results show that the safety with respect to uplift failure of the rock mass is a necessary but not a sufficient condition for assessing feasibility. The deformation of the rock mass should also be kept sufficiently small to preserve the integrity of the lining and, especially, its tightness. If the rock is not sufficiently stiff, buckling or fatigue failure of the steel lining becomes more decisive when evaluating the feasible operating air pressure. The design of the concrete plug that seals the compressed air stored in the container is another demanding task. Numerical analyses indicate that in most cases, the stability of the rock mass under the plug loading is not a decisive factor for plug design.

Performance Analysis of Constant-Pressure Pumped Hydro Combined with Compressed Air Energy Storage System Considering Off-Design Model of Compressor

With the wide application of renewable energy, energy storage technology has become a research hotspot. In order to overcome the shortcomings of energy loss caused by compression heating in compressed air energy storage technology, a novel constant-pressure pumped hydro combined with compressed air energy storage system was proposed. To deepen the understanding of the system and make the analysis closer to reality, this paper adopted an off-design model of the compressor to calculate and analyze the effect of key parameters on system thermodynamics performance. In addition, the results of this paper were compared with previous research results, and it was found that the current efficiency considering the off-design model of compressor was generally 2% - 5% higher than the previous efficiency. With increased preset pressure or with decreased terminal pressure, both the previous efficiency and current efficiency of the system increased. The exergy destruction coefficient of the throttle valve reached 4%. System efficiency was more sensitive to changes in water pump efficiency and hydroturbine efficiency.

Performance Evaluation of Compressed Air Energy Storage Using TRNSYS

The appreciable economic growth in some of the developing countries like India in the recent years, towards providing energy security causes large environmental impact. Renewable Energy （RE） is being seen as one of the important means to meet the growing power needs of the economy while enhancing energy security and providing opportunities for mitigating greenhouse gas emissions. However, RE sources are highly intermittent in nature. The variability of these sources has led to concerns regarding the reliability of an electric grid that derives a large fraction of its energy from these sources as well as the cost of reliably integrating large amounts of variable generation into the electric grid. Hence at this juncture, it is necessary to explore the benefits of suitable Energy storage technologies. Compressed air energy storage （CAES） is a commercial, utility-scale technology that provides long-duration energy storage with fast ramp rates and good part-load operation. It is a promising storage technology for balancing the large-scale penetration of renewable energies, such as wind and solar power, into electric grids. Considering the potential of CAES storage, the present work, a thermodynamic model is developed with suitable assumptions and the simulation analysis is performed using transient system simulation （TRNSYS） v17 software. The system performanee is compared by considering the recovery during the heat of compression using a thermal storage system and without considering the heat recovery. The overall turnaround efficiency of the system without considering the thermal energy storage （TES） system is 57 % and with TES system the efficiency is increased to 70%.

Design Strategy of Diagonal Compressors in Compressed Air Energy Storage System

As a kind of large-scale physical energy storage,compressed air energy storage(CAES)plays an important role in the construction of more efficient energy system based on renewable energy in the future.Compared with traditional industrial compressors,the compressor of CAES has higher off-design performance requirements.From the perspective of design,it needs to pay attention not only to the performance of the design point,but also to the performance of all the stable working range.However,from the previous literature,no diagonal compressor was used in CAES which can meet the requirements,which also reflects the design program can be further improved.Therefore,this paper studies the design strategy of high efficient diagonal compressor for large-scale CAES,and gives the complete strategy algorithms used for different program modules.The pressure ratio,isentropic efficiency and stable working range are comprehensively considered.In the design process,the criteria for the key parameters of the diagonal flow angle of the diagonal compressor are given for the first time.The results show that the isentropic efficiency at the design point is 92.7%,the total pressure ratio is1.97,and the stable working range exceeds 20%,which meets the design requirements of the compressor for CAES and exceeds the overall performance of the previous compressors in the entire working range.

Comparative Analysis of Diagonal and Centrifugal Compressors with Synergy Theory in Compressed Air Energy Storage System

Energy storage technology is an essential part of the efficient energy system.Compressed air energy storage(CAES)is considered to be one of the most promising large-scale physical energy storage technologies.It is favored because of its low-cost,long-life,environmentally friendly and low-carbon characteristics.The compressor is the core component of CAES,and the performance is critical to the overall system efficiency.That importance is not only reflected in the design point,but also in the continuous efficient operation under variable working conditions.The diagonal compressor is currently the focus of the developing large-scale CAES because of its stronger flow capacity compared with traditional centrifugal compressors.And the diagonal compressor has the higher single stage pressure ratio compared with axial compressors.In this paper,the full three dimensional numerical simulation technologies with synergy theory are used to compare and analyze the internal flow characteristics.The performance of the centrifugal and diagonal impellers that are optimized under the same requirements for large-scale CAES has been analyzed.The relationship between the internal flow characteristics and performance of the centrifugal and diagonal impellers with the change of mass flow rates and total inlet temperature is given qualitatively and quantitatively.Where the cosine value of the synergy angle is high,the local flow loss is large.The smaller proportion of the positive area is the pursuit of design.Through comparative analysis,it is concluded that the internal flow and performance changes of centrifugal and diagonal impellers are different.The results confirm the superiority and feasibility of the off-design performance of the diagonal compressor applied to the developing large-scale CAES.

Conception of a new 4-quadrant hydrogen compressed air energy storage power plant with an integrated electrolyzer

A hydrogen compressed air energy storage power plant with an integrated electrolyzer is ideal for large-scale,long-term energy storage because of the emission-free operation and the possibility to offer multiple ancillary services on the German energy market.This paper defines analyzes such a storage concept and conducts an extensive comparison with four additional storage concepts based on various criteria.The results show that the combination of storing compressed air and hydrogen offers a higher efficiency than storing only hydrogen and lower specific investment costs than storing only compressed air.This result is confirmed with analysis of the optimal sizing of each power plant component for simultaneous participation on multiple energy markets with a linear optimization dispatch mode.The hydrogen compressed air energy storage(HCAES)power plant can utilize more revenue possibilities than a hydrogen energy storage because of the higher round-trip efficiency and the combination of the air compressor and the integrated electrolyzer during charging mode.The integration of the electrolyzer,however,offers a couple of challenges itself because of the highly flexible operation mode.A new concept for the controllable 24-pulse diode-thyristor rectifier of the electrolyzer is presented,that uses mostly common components while offering little to no grid harmonics and a long lifetime.The flexible integrated electrolyzer allows for the 4-quadrant operation of the storage power plant.

Increasing Coal-Fired Power Plant Operational Flexibility by Integrating Solar Thermal Energy and Compressed Air Energy Storage System

This paper proposed a novel integrated system with solar energy,thermal energy storage(TES),coal-fired power plant(CFPP),and compressed air energy storage(CAES)system to improve the operational flexibility of the CFPP.A portion of the solar energy is adopted for preheating the boiler’s feedwater,and another portion is stored in the TES for the CAES discharging process.Condensate water from the CFPP condenser is used for cooling compressed air during the CAES charging process.The thermodynamic performance of the integrated system under different load conditions is studied.The system operations in a typical day are simulated with EBSILON software.The system enables daily coal saving of 9.88 t and reduces CO_(2)emission by 27.95 t compared with the original CFPP at 100%load.Under partial load conditions,the system enables maximum coal saving of 10.29 t and maximum CO_(2)emission reduction of 29.11 t at 75%load.The system has maximum peak shaving depth of 9.42%under 40%load condition.The potential of the system participating ancillary service is also discussed.It is found that the integration of solar thermal system and CAES system can bring significant ancillary service revenue to a conventional CFPP.

Efficiency Analysis of an Arrayed Liquid Piston Isothermal Air Compression System for Compressed Air Energy Storage

Compressed air energy storage(CAES)is an important technology in the development of renewable energy.The main advantages of CAES are its high energy capacity and environmental friendliness.One of the main challenges is its low energy density,meaning a natural cavern is required for air storage.High-pressure air compression can effectively solve the problem.A liquid piston gas compressor facilitates high-pressure compression,and efficient convective heat transfer can significantly reduce the compression energy consumption during air compression.In this paper,a near isothermal compression method is proposed to increase the surface area and heat exchange by using multiple tube bundles in parallel in the compression chamber in order to obtain high-pressure air using liquid-driven compression.Air compression with a compression ratio of 6.25:1 is achieved by reducing the tube diameter and increasing the parallel tube number while keeping the compression chamber cross-sectional area constant in order to obtain a high-pressure air of 5 MPa.The performances of this system are analyzed when different numbers of tubes are applied.A system compression efficiency of 93.0%and an expansion efficiency of 92.9%can be achieved when 1000 tubes are applied at a 1 minute period.A new approach is provided in this study to achieve high efficiency and high pressure compressed air energy storage.

Development and technology status of energy storage in depleted gas reservoirs

Utilizing energy storage in depleted oil and gas reservoirs can improve productivity while reducing power costs and is one of the best ways to achieve synergistic development of"Carbon Peak–Carbon Neutral"and"Underground Resource Utiliza-tion".Starting from the development of Compressed Air Energy Storage(CAES)technology,the site selection of CAES in depleted gas and oil reservoirs,the evolution mechanism of reservoir dynamic sealing,and the high-flow CAES and injection technology are summarized.It focuses on analyzing the characteristics,key equipment,reservoir construction,application scenarios and cost analysis of CAES projects,and sorting out the technical key points and existing difficulties.The devel-opment trend of CAES technology is proposed,and the future development path is scrutinized to provide reference for the research of CAES projects in depleted oil and gas reservoirs.

Air tightness of compressed air storage energy caverns with polymer sealing layer subjected to various air pressures

During the operation of compressed air storage energy system,the rapid change of air pressure in a cavern will cause drastic changes in air density and permeability coefficient of sealing layer.To calculate and properly evaluate air tightness of polymer sealing caverns,the air-pressure-related air density and permeability must be considered.In this context,the high-pressure air penetration in the polymer sealing layer is studied in consideration of thermodynamic change of the cavern structure during the system operation.The air tightness model of compressed air storage energy caverns is then established.In the model,the permeability coefficient and air density of sealing layer vary with air pressure,and the effectiveness of the model is verified by field data in two test caverns.Finally,a compressed air storage energy cavern is taken as an example to understand the air tightness.The air leakage rate in the caverns is larger than that using air-pressure-independent permeability coefficient and air density,which is constant and small in the previous leakage rate calculation.Under the operating pressure of 4.5-10 MPa,the daily air leakage in the compressed air storage energy cavern of Yungang Mine with high polymer butyl rubber as the sealing material is 0.62%,which can meet the sealing requirements of compressed air storage energy caverns.The air tightness of the polymer sealing cavern is mainly affected by the cavern operating pressure,injected air temperature,cavern radius,and sealing layer thickness.The cavern air leakage rate will be decreased to reduce the cavern operating pressure the injection air temperature,or the cavern radius and sealing layer thickness will be increased.

The carbon dioxide removal potential of Liquid Air Energy Storage: A high-level technical and economic appraisal

Liquid Air Energy Storage(LAES)is at pilot scale.Air cooling and liquefaction stores energy;reheating revaporises the air at pressure,powering a turbine or engine(Ameel et al.,2013).Liquefaction requires water&CO2 removal,preventing ice fouling.This paper proposes subsequent geological storage of this CO2–offering a novel Carbon Dioxide Removal(CDR)by-product,for the energy storage industry.It additionally assesses the scale constraint and economic opportunity offered by implementing this CDR approach.Similarly,established Compressed Air Energy Storage(CAES)uses air compression and subsequent expansion.CAES could also add CO2 scrubbing and subsequent storage,at extra cost.CAES stores fewer joules per kilogram of air than LAES–potentially scrubbing more CO2 per joule stored.Operational LAES/CAES technologies cannot offer full-scale CDR this century(Stocker et al.,2014),yet they could offer around 4%of projected CO2 disposals for LAES and<25%for current-technology CAES.LAES CDR could reach trillion-dollar scale this century(20 billion USD/year,to first order).A larger,less certain commercial CDR opportunity exists for modified conventional CAES,due to additional equipment requirements.CDR may be commercially critical for LAES/CAES usage growth,and the necessary infrastructure may influence plant scaling and placement.A suggested design for low-pressure CAES theoretically offers global-scale CDR potential within a century(ignoring siting constraints)–but this must be costed against competing CDR and energy storage technologies.

Design and engineering implementation of non-supplementary fired compressed air energy storage system: TICC-500

The integration and accommodation of the wind and solar energy pose great challenges on today’s power system operation due to the intermittent nature and volatility of the wind and solar resources.High efficient large-scale electrical energy storage is one of the most effective and economical solutions to those problems.After the comprehensive review of the existing storage technologies,this paper proposes an overall design scheme for the Non-supplementary Fired Compressed Air Energy Storage(NFCAES)system,including system design,modeling and efficiency assessment,as well as protection and control.Especially,the design principles of the multistage regenerative,i.e.heat recovery system which is used to fully recycle and utilize the waste heat from compression are provided,so as the overall system efficiency evaluation method.This paper theoretically ascertains the storage decoupling rules in the potential and internal energy of molecular compressed air and reveals the conversion mechanism of gas,heat,power,electricity and other forms of energy.On this basis,a 500-k W physical simulation system of CAES system(TICC-500,Tsinghua-IPCCAS-CEPRI-CAES)is built,which passed a system-wide 420-k W load power generation test with less pollution and zero carbon emissions.Besides,the multi-form energy conversion of multi-stage regenerative CAES and storage efficiency is verified,especially its incomparable superiority in solving the uncertainty problem in wind and solar power generation.Finally,the propaganda and application scenario of the CAES system in China is introduced.

Optimal dispatch of zero-carbon-emission micro Energy Internet integrated with non-supplementary fired compressed air energy storage system

To utilize heat and electricity in a clean and integrated manner,a zero-carbon-emission micro Energy Internet(ZCE-MEI) architecture is proposed by incorporating non-supplementary fired compressed air energy storage(NSF-CAES) hub.A typical ZCE-MEI combining power distribution network(PDN) and district heating network(DHN) with NSF-CAES is considered in this paper.NSF-CAES hub is formulated to take the thermal dynamic and pressure behavior into account to enhance dispatch flexibility.A modified Dist Flow model is utilized to allow several discrete and continuous reactive power compensators to maintain voltage quality of PDN.Optimal operation of the ZCE-MEI is firstly modeled as a mixed integer nonlinear programming(MINLP).Several transformations and simplifications are taken to convert the problem as a mixed integer linear programming(MILP)which can be effectively solved by CPLEX.A typical test system composed of a NSF-CAES hub,a 33-bus PDN,and an 8-node DHN is adopted to verify the effectiveness of the proposed ZCE-MEI in terms of reducing operation cost and wind curtailment.

Optimization of Operation Strategies for a Combined Cooling, Heating and Power System based on Adiabatic Compressed Air Energy Storage

The fluctuations of renewable energy and various energy demands are crucial issues for the optimal design and operation of combined cooling,heating and power(CCHP)system.In this paper,a novel CCHP system is simulated with advanced adiabatic compressed air energy storage(AA-CAES)technology as a join to connect with wind energy generation and an internal-combustion engine(ICE).The capital cost of utilities,energy cost,environmental protection cost and primary energy savings ratio(P E S R)are used as system performance indicators.To fulfill the cooling,heating and power requirements of a district and consider the thermal-electric coupling of ICE and AA-CAES in CCHP system,three operation strategies are established to schedule the dispatch of AA-CAES and ICE:ICE priority operation strategy,CAES priority operation strategy and simultaneous operation strategy.Each strategy leads the operation load of AA-CAES or ICE to improve the energy supply efficiency of the system.Moreover,to minimize comprehensive costs and maximize the P E S R,a novel optimization algorithm based on intelligent updating multi-objective differential evolution(MODE)is proposed to solve the optimization model.Considering the multi-interface characteristic and active management ability of the ICE and AA-CAES,the economic benefits and energy efficiency of the three operation strategies are compared by the simulation with the same system configuration.On a typical summer day,the simultaneous strategy is the best solution as the total cost is 3643 USD and the P E S R is 66.1%,while on a typical winter day,the ICE priority strategy is the best solution as the total cost is 4529 USD and the P E S R is 64.4%.The proposed methodology provides the CCHP based AA-CAES system with a better optimized operation.

Review and prospect of compressed air energy storage system

As an effective approach of implementing power load shifting,fostering the accommodation of renewable energy,such as the wind and solar generation,energy storage technique is playing an important role in the smart grid and energy internet.Compressed air energy storage(CAES) is a promising energy storage technology due to its cleanness,high efficiency,low cost,and long service life.This paper surveys state-of-the-art technologies of CAES,and makes endeavors to demonstrate the fundamental principles,classifications and operation modes of CAES.Critical subsystems of CAES are elaborated exhaustively.The application prospects and further research directions are summarized to promote the popularization of CAES in smart grid and energy internet.

Lowering the cost of large-scale energy storage:High temperature adiabatic compressed air energy storage

Compressed air energy storage is an energy storage technology with strong potential to play a significant role in balancing energy on transmission networks,owing to its use of mature technologies and low cost per unit of storage capacity.Adiabatic compressed air energy storage(A-CAES)systems typically compress air from ambient temperature in the charge phase and expand the air back to ambient temperature in the discharge phase.This papers explores the use of an innovative operating scheme for an A-CAES system aimed at lowering the total cost of the system for a given exergy storage capacity.The configuration proposed considers preheating of the air before compression which increases the fraction of the total exergy that is stored in the fom of high-grade heat in comparison to existing designs in which the main exergy storage medium is the compressed air itself.Storing a high fraction of the total exergy as heat allows reducing the capacity of costly pressure stores in the system and replacing it with cheaper thermal energy stores.Additionally,a configuration that integrates a system based on the aforementioned concept with solar thermal power or low-medium grade waste heat is introduced and thoroughly discussed.