Adsorbent-assisted air water harvesting(AWH)may help alleviate the current global freshwater scarcity crisis.However,the weak sorption capacity of various adsorbents and the high energy required to release water are t...Adsorbent-assisted air water harvesting(AWH)may help alleviate the current global freshwater scarcity crisis.However,the weak sorption capacity of various adsorbents and the high energy required to release water are two long-standing problems.Herein,we propose a class of green and clean adsorbent,TpPa-1@LiCl composite,whose sorption capacity is greatly improved to 0.37 and 0.80 g g^(-1)under 30%and 90%relative humidity(RH),respectively,and which has excellent stability,showing only a slight decrease(0.79%)after 10 sorp-tion–desorption cycles(1400 min).This TpPa-1@LiCl composite can reach equilibrium within 2 h and undergo complete desorption in 30 min under air mass 1.5 G irradiation.A corresponding solar-driven AWH device can complete up to 4 sorption–desorption cycles per day,with each cycle capable of collecting 0.34 g g^(-1)water without additional energy input,which implies TpPa-1@LiCl composite has the potential for achieving sorption-assisted AWH with high efficiency and rapid cycling.展开更多
During the last three decades, the introduction of new construction materials (e.g. RCC (Roller Compacted Concrete), strengthened gabions) has increased the interest for stepped channels and spillways. However stepped...During the last three decades, the introduction of new construction materials (e.g. RCC (Roller Compacted Concrete), strengthened gabions) has increased the interest for stepped channels and spillways. However stepped chute hydraulics is not simple, because of different flow regimes and importantly because of very-strong interactions between entrained air and turbu- lence. In this study, new air-water flow measurements were conducted in two large-size stepped chute facilities with two step heights in each facility to study experimental distortion caused by scale effects and the soundness of result extrapolation to pro- totypes. Experimental data included distributions of air concentration, air-water flow velocity, bubble frequency, bubble chord length and air-water flow turbulence intensity. For a Froude similitude, the results implied that scale effects were observed in both facilities, although the geometric scaling ratio was only Lr=2 in each case. The selection of the criterion for scale effects is a critical issue. For example, major differences (i.e. scale effects) were observed in terms of bubble chord sizes and turbulence levels al- though little scale effects were seen in terms of void fraction and velocity distributions. Overall the findings emphasize that physical modelling of stepped chutes based upon a Froude similitude is more sensitive to scale effects than classical smooth-invert chute studies, and this is consistent with basic dimensional analysis developed herein.展开更多
The turbulence structures near a sheared air-water interface were experimentally investigated with the hydrogen bubble visualization technique. Surface shear was imposed by an airflow over the water flow which was kep...The turbulence structures near a sheared air-water interface were experimentally investigated with the hydrogen bubble visualization technique. Surface shear was imposed by an airflow over the water flow which was kept free from surface waves. Results show that the wind shear has the main influence on coherent structures under air-water interfaces. Low- and high- speed streaks form in the region close to the interface as a result of the imposed shear stress. When a certain airflow velocity is reached, “turbulent spots” appear randomly at low-speed streaks with some characteristics of hairpin vortices. At even higher shear rates, the flow near the interface is dominated primarily by intermittent bursting events. The coherent structures observed near sheared air-water interfaces show qualitative similarities with those occurring in near-wall turbulence. However, a few distinctive phenomena were also observed, including the fluctuating thickness of the instantaneous boundary layer and vertical vortices in bursting processes, which appear to be associated with the characteristics of air-water interfaces.展开更多
The NCEP/NCAR reanalysis data are used to investigate the role of cold air and moisture characteristics during the evolution of two cases of tropical cyclones (Nanmadol and Irma) which made landfall on China in winter...The NCEP/NCAR reanalysis data are used to investigate the role of cold air and moisture characteristics during the evolution of two cases of tropical cyclones (Nanmadol and Irma) which made landfall on China in wintertime. The results are shown as follows. (1) The East Asia trough steered the cold air into the tropical ocean in early winter. The tropical cyclones moved in opposite directions with a high moving out to sea and the enhancement of the pressure gradient at the periphery played a role in maintaining and strengthening the intensity of the storms. The intrusion of weak cold air into the low levels of the tropical cyclones strengthened them by improving the cyclonic disturbance when they were still over the warm sea surface. When the cold air was strong enough and intruded into the eyes, the warm cores were damaged and stuffed before dissipation. (2) The tropical cyclones were formed in a convergence zone of moisture flux and their development could enhance the disturbance of water vapor convergence, thus strengthening the moisture convergence zone. However, when they were outside the moisture zone, the storms could not gain sufficient water vapor and became weak. There were no belts of strong moisture transportation during the wintertime tropical cyclone processes.展开更多
The characteristics of low-speed fluid streaks occurring under sheared air-water interfaces were examined by means of hydrogen bubble visualization technique. A critical shear condition under which the streaky structu...The characteristics of low-speed fluid streaks occurring under sheared air-water interfaces were examined by means of hydrogen bubble visualization technique. A critical shear condition under which the streaky structure first appears was determined to be u(tau) approximate to 0.19 cm/s. The mean spanwise streak spacing increases with distance from the water surface owing to merging and bursting processes, and a linear relationship describing variation of non-dimensional spacing <(<lambda>+)over bar> versus y(+) was found essentially independent of shear stress on the interface. Values of <(<lambda>+)over bar>, however, are remarkably smaller than their counterparts in the near-wall region of turbulent boundary layers. Though low-speed streaks occur randomly in time and space, the streak spacing exhibits a lognormal probability distribution behavior. A tentative explanation concerning the formation of streaky structure is suggested, and the fact that <(<lambda>+)over bar> takes rather smaller values than that in wall turbulence is briefly discussed.展开更多
Degradation of the Indigo Carmine(IC) by the bipolar pulsed DBD in water-air mixture was studied. Effects of various parameters such as gas flow rate, solution conductivity, pulse repetitive rate and ect., on color re...Degradation of the Indigo Carmine(IC) by the bipolar pulsed DBD in water-air mixture was studied. Effects of various parameters such as gas flow rate, solution conductivity, pulse repetitive rate and ect., on color removal efficiency of dying wastewater were investigated. Concentrations of gas phase O 3 and aqueous phase H 2O 2 under various conditions were measured. Experimental results showed that air bubbling facilitates the breakdown of water and promotes generation of chemically active species. Color removal efficiency of IC solution can be greatly improved by the air aeration under various solution conductivities. Decolorization efficiency increases with the increase of the gas flow rate, and decreases with the increase of the initial solution conductivity. A higher pulse repetitive rate and a larger pulse capacitor C\-p are favorable for the decolorization process. Ozone and hydrogen peroxide formed decreases with the increase of initial solution conductivity. In addition, preliminary analysis of the decolorization mechanisms is given.展开更多
The development of e cient earth-abundant electrocatalysts for oxygen reduction, oxygen evolution, and hydrogen evolution reactions(ORR, OER, and HER) is important for future energy conversion and energy storage devic...The development of e cient earth-abundant electrocatalysts for oxygen reduction, oxygen evolution, and hydrogen evolution reactions(ORR, OER, and HER) is important for future energy conversion and energy storage devices, for which both rechargeable Zn–air batteries and water splitting have raised great expectations. Herein, we report a single-phase bimetallic nickel cobalt sulfide((Ni,Co)S_2) as an e cient electrocatalyst for both OER and ORR. Owing to the synergistic combination of Ni and Co, the(Ni,Co)S_2 exhibits superior electrocatalytic performance for ORR, OER, and HER in an alkaline electrolyte, and the first principle calculation results indicate that the reaction of an adsorbed O atom with a H_2O molecule to form a *OOH is the potential limiting step in the OER. Importantly, it could be utilized as an advanced air electrode material in Zn–air batteries, which shows an enhanced charge–discharge performance(charging voltage of 1.71 V and discharge voltage of 1.26 V at 2 mA cm^(-2)), large specific capacity(842 mAh g_(Zn)^(-1) at 5 mA cm^(-2)), and excellent cycling stability(480 h). Interestingly, the(Ni,Co)S_2-based Zn–air battery can e ciently power an electrochemical water-splitting unit with(Ni,Co)S_2 serving as both the electrodes. This reveals that the prepared(Ni,Co)S_2 has promising applications in future energy conversion and energy storage devices.展开更多
To obtain carbon dioxide (CO2) flux between water-air interface of Taihu lake, monthly water samplers at 14 sites and the local meteorological data of the lake were collected and analyzed in 1998. Carbon dioxide parti...To obtain carbon dioxide (CO2) flux between water-air interface of Taihu lake, monthly water samplers at 14 sites and the local meteorological data of the lake were collected and analyzed in 1998. Carbon dioxide partial pressures (pCO2) at air-water interface in the lake were calculated using alkalinity, pH, ionic strength, active coefficient, and water temperature. The carbon fluxes at different sublakes and areas were estimated by concentration gradient between water and air in consideration of Schmidt numbers of 600 and daily mean windspeed at 10 m above water surface. The results indicated that the mean values of pCO2 in Wuli Lake, Meiliang Bay, hydrophyte area, west littoral zone, riverine mouths, and the open lake areas were 1 807.8±1 071.4 (mean±standard deviation) μatm (1atm=1.013 25×105Pa), 416.3±217.0 μatm, 576.5±758.8 μatm, 304.2±243.5 μatm, 1 933.6±1 144.7 μatm, and 448.5±202.6 μatm, respectively. Maximum and minimum pCO2 values were found in the hypertrophic (4 053.7 μatm) and the eutrophic (3.2 μatm) areas. The riverine mouth areas have the maximum fluxes (82.0±62.8 mmol/m2a). But there was no significant difference between eutrophic and mesot- rophic areas in pCO2 and the flux of CO2. The hydrophyte area, however, has the minimum (-0.58±12.9 mmol/m2a). In respect to CO2 equilibrium, input of the rivers will obviously influence inorganic carbon distribu- tion in the riverine estuary. For example, the annual mean CO2 flux in Zhihugang River estuary was 19 times of that in Meiliang Bay, although the former is only a part of the latter. The sites in the body of the lake show a clear seasonal cycle with pCO2 higher than atmospheric equilibrium in winter, and much lower than atmospheric in summer due to CO2 consumption by photosynthesis. The CO2 amount of the net annual evasion that enters the atmosphere is 28.42×104 t/a, of which those from the west littoral zone and the open lake account for 53.8% and 36.7%, respectively.展开更多
It is complicated to model the acoustic field in stratified ocean for airborne aircraft,due to high speed of the source and air-to-water sound transmission.To our knowledge,there are very few papers in the open litera...It is complicated to model the acoustic field in stratified ocean for airborne aircraft,due to high speed of the source and air-to-water sound transmission.To our knowledge,there are very few papers in the open literature dealing with this complicated problem;but,in our opinion,they all require great amount of computation.We now propose a different method that requires much less computation.We improve the wavenumber integration method to model the received temporal signal for a moving source in stratified ocean and sum up in a concise form the core of our paper as follows:(A) Eq.(11) can be calculated by means of fast Chirp Z transform and the signals at all N time points are generated simultaneously;(B) direct numerical evaluation of the wavenumber integral in Eq.(4) produces large numerical errors;so it is necessary to shift the integration slightly below the real axis;(C) we compare the computation cost of direct calculation method with that of our fast calculation method;from the results presented in table 1,we can see that the fast calculation method consumes much less computation time,particularly for long duration signals;(D) for an airborne rapidly moving source,we compute the Doppler-shifted signals in shallow water and analyze their short-time Fourier transform;from Fig.1b,we can see that the received signals have multiple frequency components for a tonal source due to source motion and that each component corresponds to an arrival path.展开更多
The process of air—sea fresh water exchange is included successfully in the Global— Ocean—Atmosphere Land—System model developed at the State Key Laboratory of Atmospheric Sciences and Geophysical Fluid Dynamics (...The process of air—sea fresh water exchange is included successfully in the Global— Ocean—Atmosphere Land—System model developed at the State Key Laboratory of Atmospheric Sciences and Geophysical Fluid Dynamics (LASG). The results of the coupled integration show that the climate drift has been controlled successfully. Analyses on the responses of ocean circulation to the changes of surface fresh water or salinity forcing show that the ocean spin-up stage under flux condition for salinity is the key to the implementation of air-sea fresh water flux coupling. This study also demonstrates that the Modified—Monthly—Flux—Anomaly coupling scheme (MMFA) brought forward by Yu and Zhang (1998) is suitable not only for daily air—sea heat flux coupling but also for daily fresh water flux coupling. Key words Fresh water flux - Air-sea coupling - Thermohaline circulation This work was co-supported by the National Key Project (Grant No.96-908-02-03), the Excellent National Key Laboratory Research Project (Grant No.49823002) and Chinese Academy of Sciences (CAS) under grant “ Bai Ren Ji Hua? for “Validation of Coupled Climate Models”.展开更多
Electro-hydraulic impulse water-air mixing jet by which the quality of metal materials can be improved is described in this paper. The experimental results proved that the hardness and the micro-hardness of the surfac...Electro-hydraulic impulse water-air mixing jet by which the quality of metal materials can be improved is described in this paper. The experimental results proved that the hardness and the micro-hardness of the surface layer of metal materials can be improved with this method, for example, the microhardness of CrWMn can be increased by 35.62 percent.展开更多
The consistency of global atmospheric mass and water budget performance in 20 state-of-the-art ocean-atmosphere Coupled Model Intercomparison Project Phase 5(CMIP5) coupled models has been assessed in a historical exp...The consistency of global atmospheric mass and water budget performance in 20 state-of-the-art ocean-atmosphere Coupled Model Intercomparison Project Phase 5(CMIP5) coupled models has been assessed in a historical experiment. All the models realistically reproduce a climatological annual mean of global air mass(AM) close to the ERA-Interim AM during 1989-2005. Surprisingly, the global AM in half of the models shows nearly no seasonal variation,which does not agree with the seasonal processes of global precipitable water or water vapor, given the mass conservation constraint. To better understand the inconsistencies, we evaluated the seasonal cycles of global AM tendency and water vapor source(evaporation minus precipitation). The results suggest that the inconsistencies result from the poor balance between global AM tendency and water vapor source based on the global AM budget equation. Moreover, the cross-equatorial dry air mass flux, or hemispheric dry mass divergence, is not well represented in any of the 20 CMIP5 models, which show a poorly matched seasonal cycle and notably larger amplitude, compared with the hemispheric tendencies of dry AM in both the Northern Hemisphere and Southern Hemisphere. Pronounced erroneous estimations of tropical precipitation also occur in these models. We speculate that the large inaccuracy of precipitation and possibly evaporation in the tropics is one of the key factors for the inconsistent cross-equatorial mass flux. A reasonable cross-equatorial mass flux in well-balanced hemispheric air mass and moisture budgets remains a challenge for both reanalysis assimilation systems and climate modeling.展开更多
The air bag deformation data were obtained by high-speed dynamic videos experiments. Based on gas–liquid flow VOF model, dynamic mesh technique and deformation data, numerical simulations for different structure mode...The air bag deformation data were obtained by high-speed dynamic videos experiments. Based on gas–liquid flow VOF model, dynamic mesh technique and deformation data, numerical simulations for different structure models were achieved, and the law of water motion and influencing factors were analyzed.The results show that the flow in the length direction of the jig is smooth, and second pulsation appears in the separation time and forms the secondary separation. The installation position of screen and the number of air bags have a great influence on the uniformity of flow and velocity. The screen height cannot be too low to avoid forming the unstable flow. At the same time, the screen height cannot be too high, otherwise water velocity will be too small and was unable to provide enough power. At the height of 1.4m,velocity unevenness is minimum and the best uniform flow can be obtained. Compared with double air bags, there are the following features of single air bag: water flow is not smooth, the time achieving the maximum velocity is too long, maximum velocity is smaller, and overall effect is worse than double air bags.展开更多
In order to investigate whether an air–water plasma jet is beneficial to improve the efficiency of inactivation, a series of experiments were done using a ring-needle plasma jet. The water content in the working gas...In order to investigate whether an air–water plasma jet is beneficial to improve the efficiency of inactivation, a series of experiments were done using a ring-needle plasma jet. The water content in the working gas(air) was accurately measured based on the Karl Fischer method. The effects of water on the production of OH(A;Σ;–X;Π;) and O(3p;P–3s;S) were also studied by optical emission spectroscopy. The results show that the water content is in the range of 2.53–9.58 mg l;, depending on the gas/water mixture ratio. The production of OH(A;Σ;–X;Π;) rises with the increase of water content, whereas the O(3p;P–3s;S) shows a declining tendency with higher water content. The sterilization experiments indicate that this air–water plasma jet inactivates the P. digitatum spores very effectively and its efficiency rises with the increase of the water content. It is possible that OH(A;Σ;–X;Π;) is a more effective species in inactivation than O(3p;P–3s;S) and the water content benefit the spore germination inhibition through rising the OH(A;Σ;–X;Π;) production. The maximum of the inactivation efficacy is up to 93% when the applied voltage is -6.75 kV and the water content is 9.58 mg l;.展开更多
Results of environmental radioactivity monitoring around Qinshan Nuclear Power Plant (QNPP) are reported in this paper. From 1992 to 2005, concentrations of 90Sr, 137Cs and 3H in terrestrial freshwater are (4.4±1...Results of environmental radioactivity monitoring around Qinshan Nuclear Power Plant (QNPP) are reported in this paper. From 1992 to 2005, concentrations of 90Sr, 137Cs and 3H in terrestrial freshwater are (4.4±1.7) mBq·L-1, (0.3±0.1) mBq·L-1 and (1.6±0.5) Bq·L-1, respectively, and (2.8±2.4) Bq·L-1 of 3H in rainwater. Concentrations of 90Sr, 137Cs and 3H in the seawater samples collected from sea area nearby QNPP are (5.4±4.1) mBq·L-1, (0.7±0.2) mBq·L-1 and (1.0±0.5) Bq·L-1, respectively. Concentrations of 90Sr, 137Cs and 3H in the total waste water discharged from NPP-I are (4.0±1.8) m Bq·L-1, (1.0±0.5) mBq·L-1 and (2.8±2.2) Bq·L-1, respectively, and (1.4±0.4) Bq·L-1 of 3H in seawater sampled from No.1 outlet. Atomspheric 3H concentration in 1993~2005 at two monitoring sites is (78.9±96.3) and (64.2±40.2) mBq·m-3, respectively, with an increasing trend after 2003. Atmospheric 14C concentrations at the two sites are in the same levels as the background and data of the reference site.展开更多
Gas turbine (GT) power plants operating in arid climates suffer a decrease in output power during the hot summer months because of the high specific volume of air drawn by the compressor. Cooling the air intake to the...Gas turbine (GT) power plants operating in arid climates suffer a decrease in output power during the hot summer months because of the high specific volume of air drawn by the compressor. Cooling the air intake to the compressor has been widely used to mitigate this shortcoming. Energy and exergy analysis of a GT Brayton cycle coupled to a refrigeration air cooling unit shows a promise for increasing the output power with a little decrease in thermal efficiency. A thermo-economics algorithm is developed to estimate the economic feasibility of the cooling system. The analysis is applied to an open cycle, HITACHI-FS7001B GT plant at the industrial city of Yanbu (Latitude 24o 05” N and longitude 38o E) by the Red Sea in the Kingdom of Saudi Arabia. Result show that the enhancement in output power depends on the degree of chilling the air intake to the compressor (a 12 - 22 K decrease is achieved). For this case study, maximum power gain ratio (PGR) is 15.46% (average of 12.25%), at an insignificant decrease in thermal efficiency. The second law analysis show that the exergetic power gain ratio drops to an average 8.5%. The cost of adding the air cooling system is also investigated and a cost function is derived that incorporates time-dependent meteorological data, operation characteristics of the GT and the air intake cooling system and other relevant parameters such as interest rate, lifetime, and operation and maintenance costs. The profit of adding the air cooling system is calculated for different electricity tariff.展开更多
基金supported by the Hainan Provincial Joint Project of Sanya Yazhou Bay Science and Technology City(No.520LH053)the National Natural Science Foundation of China(12174298)+3 种基金the National Natural Science Foundation of Shenzhen City(No.JCYJ20210324135002007)Guangdong Basic and Applied Basic Research Foundation(No.2023A1515010130)the Fundamental Research Funds for the Cornell University(No.2021Szvup104)the 111 Project(No.B18038).
文摘Adsorbent-assisted air water harvesting(AWH)may help alleviate the current global freshwater scarcity crisis.However,the weak sorption capacity of various adsorbents and the high energy required to release water are two long-standing problems.Herein,we propose a class of green and clean adsorbent,TpPa-1@LiCl composite,whose sorption capacity is greatly improved to 0.37 and 0.80 g g^(-1)under 30%and 90%relative humidity(RH),respectively,and which has excellent stability,showing only a slight decrease(0.79%)after 10 sorp-tion–desorption cycles(1400 min).This TpPa-1@LiCl composite can reach equilibrium within 2 h and undergo complete desorption in 30 min under air mass 1.5 G irradiation.A corresponding solar-driven AWH device can complete up to 4 sorption–desorption cycles per day,with each cycle capable of collecting 0.34 g g^(-1)water without additional energy input,which implies TpPa-1@LiCl composite has the potential for achieving sorption-assisted AWH with high efficiency and rapid cycling.
基金Project supported by the National Council for Science and Tech-nology of Mexico (CONACYT)
文摘During the last three decades, the introduction of new construction materials (e.g. RCC (Roller Compacted Concrete), strengthened gabions) has increased the interest for stepped channels and spillways. However stepped chute hydraulics is not simple, because of different flow regimes and importantly because of very-strong interactions between entrained air and turbu- lence. In this study, new air-water flow measurements were conducted in two large-size stepped chute facilities with two step heights in each facility to study experimental distortion caused by scale effects and the soundness of result extrapolation to pro- totypes. Experimental data included distributions of air concentration, air-water flow velocity, bubble frequency, bubble chord length and air-water flow turbulence intensity. For a Froude similitude, the results implied that scale effects were observed in both facilities, although the geometric scaling ratio was only Lr=2 in each case. The selection of the criterion for scale effects is a critical issue. For example, major differences (i.e. scale effects) were observed in terms of bubble chord sizes and turbulence levels al- though little scale effects were seen in terms of void fraction and velocity distributions. Overall the findings emphasize that physical modelling of stepped chutes based upon a Froude similitude is more sensitive to scale effects than classical smooth-invert chute studies, and this is consistent with basic dimensional analysis developed herein.
基金The project supported by the National Natural Science Foundation of China (Grant No.19672070)
文摘The turbulence structures near a sheared air-water interface were experimentally investigated with the hydrogen bubble visualization technique. Surface shear was imposed by an airflow over the water flow which was kept free from surface waves. Results show that the wind shear has the main influence on coherent structures under air-water interfaces. Low- and high- speed streaks form in the region close to the interface as a result of the imposed shear stress. When a certain airflow velocity is reached, “turbulent spots” appear randomly at low-speed streaks with some characteristics of hairpin vortices. At even higher shear rates, the flow near the interface is dominated primarily by intermittent bursting events. The coherent structures observed near sheared air-water interfaces show qualitative similarities with those occurring in near-wall turbulence. However, a few distinctive phenomena were also observed, including the fluctuating thickness of the instantaneous boundary layer and vertical vortices in bursting processes, which appear to be associated with the characteristics of air-water interfaces.
基金National Development and Plan for Key Foundamental Research (2009CB421505)11th National Five-Year Plan for Science Support (2006BAC02B)+1 种基金National Natural Science Foundation (40775058)Natural Science Foundation of Guangxi (2010GXNSFA013010)
文摘The NCEP/NCAR reanalysis data are used to investigate the role of cold air and moisture characteristics during the evolution of two cases of tropical cyclones (Nanmadol and Irma) which made landfall on China in wintertime. The results are shown as follows. (1) The East Asia trough steered the cold air into the tropical ocean in early winter. The tropical cyclones moved in opposite directions with a high moving out to sea and the enhancement of the pressure gradient at the periphery played a role in maintaining and strengthening the intensity of the storms. The intrusion of weak cold air into the low levels of the tropical cyclones strengthened them by improving the cyclonic disturbance when they were still over the warm sea surface. When the cold air was strong enough and intruded into the eyes, the warm cores were damaged and stuffed before dissipation. (2) The tropical cyclones were formed in a convergence zone of moisture flux and their development could enhance the disturbance of water vapor convergence, thus strengthening the moisture convergence zone. However, when they were outside the moisture zone, the storms could not gain sufficient water vapor and became weak. There were no belts of strong moisture transportation during the wintertime tropical cyclone processes.
基金This work was supported by Chines Academy of Scieuces(No.CMS-cx200305),National Natural Science Foundation of China(NSFC No.20425309,No.20573117)and Chinese Ministry of Science and Technology (M0ST No.G1999075305).
基金The project supported by the National Natural Science Foundation of China (19672070)
文摘The characteristics of low-speed fluid streaks occurring under sheared air-water interfaces were examined by means of hydrogen bubble visualization technique. A critical shear condition under which the streaky structure first appears was determined to be u(tau) approximate to 0.19 cm/s. The mean spanwise streak spacing increases with distance from the water surface owing to merging and bursting processes, and a linear relationship describing variation of non-dimensional spacing <(<lambda>+)over bar> versus y(+) was found essentially independent of shear stress on the interface. Values of <(<lambda>+)over bar>, however, are remarkably smaller than their counterparts in the near-wall region of turbulent boundary layers. Though low-speed streaks occur randomly in time and space, the streak spacing exhibits a lognormal probability distribution behavior. A tentative explanation concerning the formation of streaky structure is suggested, and the fact that <(<lambda>+)over bar> takes rather smaller values than that in wall turbulence is briefly discussed.
文摘Degradation of the Indigo Carmine(IC) by the bipolar pulsed DBD in water-air mixture was studied. Effects of various parameters such as gas flow rate, solution conductivity, pulse repetitive rate and ect., on color removal efficiency of dying wastewater were investigated. Concentrations of gas phase O 3 and aqueous phase H 2O 2 under various conditions were measured. Experimental results showed that air bubbling facilitates the breakdown of water and promotes generation of chemically active species. Color removal efficiency of IC solution can be greatly improved by the air aeration under various solution conductivities. Decolorization efficiency increases with the increase of the gas flow rate, and decreases with the increase of the initial solution conductivity. A higher pulse repetitive rate and a larger pulse capacitor C\-p are favorable for the decolorization process. Ozone and hydrogen peroxide formed decreases with the increase of initial solution conductivity. In addition, preliminary analysis of the decolorization mechanisms is given.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11474137 and 11674143)Program for Changjiang Scholars and Innovative Research Team in University (IRT 16R35)+1 种基金the Fundamental Research Funds for the Central Universities (Grant Nos. LZUMMM2018017, lzujbky-2018-121)the support of Ministry of Education (MOE2016-T2-2-138,Singapore),for research conducted at the National University of Singapore
文摘The development of e cient earth-abundant electrocatalysts for oxygen reduction, oxygen evolution, and hydrogen evolution reactions(ORR, OER, and HER) is important for future energy conversion and energy storage devices, for which both rechargeable Zn–air batteries and water splitting have raised great expectations. Herein, we report a single-phase bimetallic nickel cobalt sulfide((Ni,Co)S_2) as an e cient electrocatalyst for both OER and ORR. Owing to the synergistic combination of Ni and Co, the(Ni,Co)S_2 exhibits superior electrocatalytic performance for ORR, OER, and HER in an alkaline electrolyte, and the first principle calculation results indicate that the reaction of an adsorbed O atom with a H_2O molecule to form a *OOH is the potential limiting step in the OER. Importantly, it could be utilized as an advanced air electrode material in Zn–air batteries, which shows an enhanced charge–discharge performance(charging voltage of 1.71 V and discharge voltage of 1.26 V at 2 mA cm^(-2)), large specific capacity(842 mAh g_(Zn)^(-1) at 5 mA cm^(-2)), and excellent cycling stability(480 h). Interestingly, the(Ni,Co)S_2-based Zn–air battery can e ciently power an electrochemical water-splitting unit with(Ni,Co)S_2 serving as both the electrodes. This reveals that the prepared(Ni,Co)S_2 has promising applications in future energy conversion and energy storage devices.
基金This research was supported by the Knowledge Innovation Project of Chinese Academy of Sciences (KZCX1-SW-01-15) and (KZCX1- SW-12)
文摘To obtain carbon dioxide (CO2) flux between water-air interface of Taihu lake, monthly water samplers at 14 sites and the local meteorological data of the lake were collected and analyzed in 1998. Carbon dioxide partial pressures (pCO2) at air-water interface in the lake were calculated using alkalinity, pH, ionic strength, active coefficient, and water temperature. The carbon fluxes at different sublakes and areas were estimated by concentration gradient between water and air in consideration of Schmidt numbers of 600 and daily mean windspeed at 10 m above water surface. The results indicated that the mean values of pCO2 in Wuli Lake, Meiliang Bay, hydrophyte area, west littoral zone, riverine mouths, and the open lake areas were 1 807.8±1 071.4 (mean±standard deviation) μatm (1atm=1.013 25×105Pa), 416.3±217.0 μatm, 576.5±758.8 μatm, 304.2±243.5 μatm, 1 933.6±1 144.7 μatm, and 448.5±202.6 μatm, respectively. Maximum and minimum pCO2 values were found in the hypertrophic (4 053.7 μatm) and the eutrophic (3.2 μatm) areas. The riverine mouth areas have the maximum fluxes (82.0±62.8 mmol/m2a). But there was no significant difference between eutrophic and mesot- rophic areas in pCO2 and the flux of CO2. The hydrophyte area, however, has the minimum (-0.58±12.9 mmol/m2a). In respect to CO2 equilibrium, input of the rivers will obviously influence inorganic carbon distribu- tion in the riverine estuary. For example, the annual mean CO2 flux in Zhihugang River estuary was 19 times of that in Meiliang Bay, although the former is only a part of the latter. The sites in the body of the lake show a clear seasonal cycle with pCO2 higher than atmospheric equilibrium in winter, and much lower than atmospheric in summer due to CO2 consumption by photosynthesis. The CO2 amount of the net annual evasion that enters the atmosphere is 28.42×104 t/a, of which those from the west littoral zone and the open lake account for 53.8% and 36.7%, respectively.
文摘It is complicated to model the acoustic field in stratified ocean for airborne aircraft,due to high speed of the source and air-to-water sound transmission.To our knowledge,there are very few papers in the open literature dealing with this complicated problem;but,in our opinion,they all require great amount of computation.We now propose a different method that requires much less computation.We improve the wavenumber integration method to model the received temporal signal for a moving source in stratified ocean and sum up in a concise form the core of our paper as follows:(A) Eq.(11) can be calculated by means of fast Chirp Z transform and the signals at all N time points are generated simultaneously;(B) direct numerical evaluation of the wavenumber integral in Eq.(4) produces large numerical errors;so it is necessary to shift the integration slightly below the real axis;(C) we compare the computation cost of direct calculation method with that of our fast calculation method;from the results presented in table 1,we can see that the fast calculation method consumes much less computation time,particularly for long duration signals;(D) for an airborne rapidly moving source,we compute the Doppler-shifted signals in shallow water and analyze their short-time Fourier transform;from Fig.1b,we can see that the received signals have multiple frequency components for a tonal source due to source motion and that each component corresponds to an arrival path.
文摘The process of air—sea fresh water exchange is included successfully in the Global— Ocean—Atmosphere Land—System model developed at the State Key Laboratory of Atmospheric Sciences and Geophysical Fluid Dynamics (LASG). The results of the coupled integration show that the climate drift has been controlled successfully. Analyses on the responses of ocean circulation to the changes of surface fresh water or salinity forcing show that the ocean spin-up stage under flux condition for salinity is the key to the implementation of air-sea fresh water flux coupling. This study also demonstrates that the Modified—Monthly—Flux—Anomaly coupling scheme (MMFA) brought forward by Yu and Zhang (1998) is suitable not only for daily air—sea heat flux coupling but also for daily fresh water flux coupling. Key words Fresh water flux - Air-sea coupling - Thermohaline circulation This work was co-supported by the National Key Project (Grant No.96-908-02-03), the Excellent National Key Laboratory Research Project (Grant No.49823002) and Chinese Academy of Sciences (CAS) under grant “ Bai Ren Ji Hua? for “Validation of Coupled Climate Models”.
基金This work was supported by the National Natural Science Foundation of China(No.598740337)
文摘Electro-hydraulic impulse water-air mixing jet by which the quality of metal materials can be improved is described in this paper. The experimental results proved that the hardness and the micro-hardness of the surface layer of metal materials can be improved with this method, for example, the microhardness of CrWMn can be increased by 35.62 percent.
基金Natural Science Foundation of Jiangsu Province grant(BK2012465)National Natural Science Foundation of China(41205065,41475045,41005046)+1 种基金National Basic Research Program of China(2010CB428602)Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institution
文摘The consistency of global atmospheric mass and water budget performance in 20 state-of-the-art ocean-atmosphere Coupled Model Intercomparison Project Phase 5(CMIP5) coupled models has been assessed in a historical experiment. All the models realistically reproduce a climatological annual mean of global air mass(AM) close to the ERA-Interim AM during 1989-2005. Surprisingly, the global AM in half of the models shows nearly no seasonal variation,which does not agree with the seasonal processes of global precipitable water or water vapor, given the mass conservation constraint. To better understand the inconsistencies, we evaluated the seasonal cycles of global AM tendency and water vapor source(evaporation minus precipitation). The results suggest that the inconsistencies result from the poor balance between global AM tendency and water vapor source based on the global AM budget equation. Moreover, the cross-equatorial dry air mass flux, or hemispheric dry mass divergence, is not well represented in any of the 20 CMIP5 models, which show a poorly matched seasonal cycle and notably larger amplitude, compared with the hemispheric tendencies of dry AM in both the Northern Hemisphere and Southern Hemisphere. Pronounced erroneous estimations of tropical precipitation also occur in these models. We speculate that the large inaccuracy of precipitation and possibly evaporation in the tropics is one of the key factors for the inconsistent cross-equatorial mass flux. A reasonable cross-equatorial mass flux in well-balanced hemispheric air mass and moisture budgets remains a challenge for both reanalysis assimilation systems and climate modeling.
基金provided by the Project of National Scientific and Technical Supporting Programs Funded of China(No.2012BAB13B03)
文摘The air bag deformation data were obtained by high-speed dynamic videos experiments. Based on gas–liquid flow VOF model, dynamic mesh technique and deformation data, numerical simulations for different structure models were achieved, and the law of water motion and influencing factors were analyzed.The results show that the flow in the length direction of the jig is smooth, and second pulsation appears in the separation time and forms the secondary separation. The installation position of screen and the number of air bags have a great influence on the uniformity of flow and velocity. The screen height cannot be too low to avoid forming the unstable flow. At the same time, the screen height cannot be too high, otherwise water velocity will be too small and was unable to provide enough power. At the height of 1.4m,velocity unevenness is minimum and the best uniform flow can be obtained. Compared with double air bags, there are the following features of single air bag: water flow is not smooth, the time achieving the maximum velocity is too long, maximum velocity is smaller, and overall effect is worse than double air bags.
基金The authors gratefully acknowledge financial support from Key Technologies R&D Program Foundation of China(02BA312B07)the National Natural Science Foundation of China(No.20303011)Natural Science Foundation of Shandong Province(Y 2001 B08).
基金supported by National Natural Science Foundation of China (NSFC) under Grants No. 51407020National Key Technology Research and Development Program of the Ministry of Science and Technology of China under Grants No. 2014BAC13B05Visiting Scholarship of State Key Laboratory of Power Transmission Equipment & System Security and New Technology (Chongqing University) No. 2007DA10512716404
文摘In order to investigate whether an air–water plasma jet is beneficial to improve the efficiency of inactivation, a series of experiments were done using a ring-needle plasma jet. The water content in the working gas(air) was accurately measured based on the Karl Fischer method. The effects of water on the production of OH(A;Σ;–X;Π;) and O(3p;P–3s;S) were also studied by optical emission spectroscopy. The results show that the water content is in the range of 2.53–9.58 mg l;, depending on the gas/water mixture ratio. The production of OH(A;Σ;–X;Π;) rises with the increase of water content, whereas the O(3p;P–3s;S) shows a declining tendency with higher water content. The sterilization experiments indicate that this air–water plasma jet inactivates the P. digitatum spores very effectively and its efficiency rises with the increase of the water content. It is possible that OH(A;Σ;–X;Π;) is a more effective species in inactivation than O(3p;P–3s;S) and the water content benefit the spore germination inhibition through rising the OH(A;Σ;–X;Π;) production. The maximum of the inactivation efficacy is up to 93% when the applied voltage is -6.75 kV and the water content is 9.58 mg l;.
文摘Results of environmental radioactivity monitoring around Qinshan Nuclear Power Plant (QNPP) are reported in this paper. From 1992 to 2005, concentrations of 90Sr, 137Cs and 3H in terrestrial freshwater are (4.4±1.7) mBq·L-1, (0.3±0.1) mBq·L-1 and (1.6±0.5) Bq·L-1, respectively, and (2.8±2.4) Bq·L-1 of 3H in rainwater. Concentrations of 90Sr, 137Cs and 3H in the seawater samples collected from sea area nearby QNPP are (5.4±4.1) mBq·L-1, (0.7±0.2) mBq·L-1 and (1.0±0.5) Bq·L-1, respectively. Concentrations of 90Sr, 137Cs and 3H in the total waste water discharged from NPP-I are (4.0±1.8) m Bq·L-1, (1.0±0.5) mBq·L-1 and (2.8±2.2) Bq·L-1, respectively, and (1.4±0.4) Bq·L-1 of 3H in seawater sampled from No.1 outlet. Atomspheric 3H concentration in 1993~2005 at two monitoring sites is (78.9±96.3) and (64.2±40.2) mBq·m-3, respectively, with an increasing trend after 2003. Atmospheric 14C concentrations at the two sites are in the same levels as the background and data of the reference site.
文摘Gas turbine (GT) power plants operating in arid climates suffer a decrease in output power during the hot summer months because of the high specific volume of air drawn by the compressor. Cooling the air intake to the compressor has been widely used to mitigate this shortcoming. Energy and exergy analysis of a GT Brayton cycle coupled to a refrigeration air cooling unit shows a promise for increasing the output power with a little decrease in thermal efficiency. A thermo-economics algorithm is developed to estimate the economic feasibility of the cooling system. The analysis is applied to an open cycle, HITACHI-FS7001B GT plant at the industrial city of Yanbu (Latitude 24o 05” N and longitude 38o E) by the Red Sea in the Kingdom of Saudi Arabia. Result show that the enhancement in output power depends on the degree of chilling the air intake to the compressor (a 12 - 22 K decrease is achieved). For this case study, maximum power gain ratio (PGR) is 15.46% (average of 12.25%), at an insignificant decrease in thermal efficiency. The second law analysis show that the exergetic power gain ratio drops to an average 8.5%. The cost of adding the air cooling system is also investigated and a cost function is derived that incorporates time-dependent meteorological data, operation characteristics of the GT and the air intake cooling system and other relevant parameters such as interest rate, lifetime, and operation and maintenance costs. The profit of adding the air cooling system is calculated for different electricity tariff.