Orientation and Motion of Water Molecules at Air/Water Interface

Here we report a quantitative study of the orientational structure and motion of water molecule at the air/water interface. Analysis of Sum Frequency Generation （SFG） vibrational peak of the free O-H stretching band at 3700 cm^-1 in four experimental configurations showed that orientational motion of water molecule at air/water interface is libratory within a limited angular range. The free OH bond of the interracial water molecule is tilted around 33°from the interface normal and the orientational distribution or motion width is less than 15°. This picture is significantly different from the previous conclusion that the interracial water molecule orientation varies over a broad range within the ultrafast vibrational relaxation time, the only direct experimental study concluded for ultrafast and broad orient, ational motion of a liquid interface by Wei et al. （Phys. Rev. Lett. 86, 4799, （2001）） using single SFG experimental configuration.

Absolute Orientation of Molecules with Competing Hydrophilic Head Groups at the Air/Water Interface Probed with Sum Frequency Generation Vibrational Spectroscopy

The constructive or destructive spectral interference between the molecular groups oriented up and down at the interface in the sum-frequency generation （SFG） spectra provides a direct measurement of the absolute orientation of these molecular groups. This simple approach can be employed to interrogate absolute molecular orientations other than using the complex absolute phase measurement in the SFG studies. We used the -CN group in the p-cyanophenol （PCP） molecule as the internal phase standard, and we measured the phases of the SFG fields of the -CN groups in the 3,5-dimethyl-4-hydroxy-benzonitrile （35DMHBN） and 2,6-dimethyl-4-hydroxy-benzonitrile （26DMHBN） at the air/water interface by measuring the SFG spectra of the aqueous surfaces of the mixtures of the PCP, 35DMHBN, and 26DMHBN solutions. The results showed that the 35DMHBN had its -CN group pointing into the aqueous phase; while the 26DMHBN, similar to the PCP, had its -CN group pointing away from the aqueous phase. The tilt angles of the -CN group for both the 35DMHBN and 26DMHBN molecules at the air/water interface were around 25°-45° from the interface normal. These results provided insights on the understanding of the detailed balance of the competing factors, such as solvation of the polar head groups, hydrogen bonding and hydrophobic effects, etc., on influencing the absolute molecular orientation at the air/water interface.

Dynamic Study of Gemini Surfactant and Single-chain Surfactant at Air/Water Interface

Molecular dynamics (MD) simulation are used to study the properties of gemini surfactant of ethyl-α,ω-bis(dodecyldimethylammonium bromide) (C12C2C12) and dodecyl- trimethylammonium bromide (DTAB) at the air/water interface, respectively. In the two systems, the surfactant concentrations are both 28 wt. %, and other conditions are also the same. After reaching the thermodynamic equilibrium, the concentration profiles, the radial distributions functions (RDF) and the mean squared displacement (MSD) are investigated. The results reveal that the surface activity of C12C2C12 surfactant is higher than DTAB surfactant.

PIV Studies on Turbulence Structure in Air/Water Interface with Wind-Induced Water Waves

When wind appears over the free surface, water waves and turbulence are generated by an interfacial shear stress. In particular, turbulent diffusion promotes significantly mass and momentum transport beneath the interface between the water and air significantly in ocean and lakes, and thus it is very important for global environment problems to reveal such turbulence property and coherent structure. Simultaneous measurements of velocities and free-surface elevation allow us to conduct reasonably the phase analysis of the coherent structure in interfacial shear layer. Furthermore, multi-point measurements such as PIV are very powerful to detect the space-time structure of coherent motions. Therefore, in the present study, we developed a specially designed PIV system which can measure the velocity components and surface-elevation fluctuation simultaneously by using two sets of high-speed cameras to reveal the coherent structure in the interfacial shear layer.

Evaluation of Air-Kerma and Absorbed Dose to Water for External Radiotherapy Beam Using Ionization Chamber

Radiotherapy is the most widely applied oncologic treatment modality utilizing ionizing radiation. A high degree of accuracy, reliability and reproducibility is required for a successful treatment outcome. Measurement using ionization chamber is a prerequisite for absorbed dose determination for external beam radiotherapy. Calibration coefficient is expressed in terms of air kerma and absorbed dose to water traceable to Secondary Standards Dosimetry Laboratory. The objective of this work was to evaluate the level of accuracy of ionization chamber used for clinical radiotherapy beam determination. Measurement and accuracy determination were carried out according to IAEA TRS 398 protocol. Clinical farmers type ionization chamber measurement and National Reference standard from Secondary Standards Dosimetry Laboratory were both exposed to cobalt-60 beam and measurement results compared under the same environmental conditions. The accuracy level between National Reference Standard and clinical radiotherapy standard was found to be −1.92% and −2.02% for air kerma and absorbed dose to water respectively. To minimize the effect of error and maximize therapeutic dose during treatment in order to achieve required clinical outcome, calibration factor was determined for air kerma (Nk) as 49.7 mGy/nC and absorbed dose to water ND, as 52.9 mGy/nC. The study established that radiotherapy beam measurement chain is prone to errors. Hence there is a need to independently verify the accuracy of radiation dose to ensure precision of dose delivery. The errors must be accounted for during clinical planning by factoring in calibration factor to minimize the systematic errors during treatment, and thereby providing enough room to achieve ±5% dose delivery to tumor target as recommended by ICRU.

具有时滞效应的air2stream河流水温模型及应用研究

高精度河流水温模型对于深入了解水温的时空变化特征和河流生态修复具有重要意义。基于数据驱动的air2stream模型在保证预测精度的同时,避免了计算的复杂性,已成为河流水温模拟常用的模型。由于水的热惯性及水文条件等的影响,河流水温变化往往显著滞后于气温变化,而air2stream原模型并未考虑滞后效应,导致该模型在流量未知情况下实际精度偏低。为解决该问题,采用气温-水温皮尔逊相关系数计算时滞天数,构建具有时滞的air2stream新模型,进一步根据长江中下游地区两个监测站的多年实测数据验证新模型的有效性和稳定性。结果表明:新模型在不引进额外观测数据的条件下具有更高精度且性能更稳定。相比原模型,在两个监测站新模型的均方根误差分别降低约4.29%和5.85%。新模型具有精度高、水文要素需求少的特点,可为长江中下游的水环境影响评价和生态保护提供依据。

In situ Observation of the Photochromism in the Langmuir Monolayer of a Non-typical Amphiphilic Spiropyran Derivative at the Air/Water Interface

In situ photochromic process in the monolayer of a photochromic spiropyran derivative without long alkyl chain, was investigated. The photochromism at the air/water interface under different surface pressures was studied by surface pressure area isotherms, surface pressure time curves, area time curves and Brewster angle microscopy. Both forms of the compound were found to form monolayers at the air/water interface although it does not have long alkyl chain. A large area expansion in the monolayer corresponding to a zero th order reaction was found at the initial stage of the UV light irradiation. A series of dynamic investigations revealed that at high pressure after phase transition in the monolayer, the surface pressure changes greatly under alternative irradiation of UV and visible light. An obvious morphological change accompanying with the photochromism was observed in situ .

Development and Experimental Study of Air Source Heat Pump Water Heater

The principle and development prospect of air source heat pump water heat were introduced,as well as the designation of condenser (storage water tank),experimental study on installations was also carried out.The results showed that air source heat pump water heater was superior to conventional system.Under the operation of cooling and heating,heat pump comprehensive utilization equipment could improve heating performance,reduce energy consumption,and recycle condensing heat to provide hot water.

Application of Air Floatation in Water Quality Maintenance of Ecolandscape Pool in Zhongxing Mangrove Bay

The invasion of various pollutant sources and lack of water circulation may easily lead to the eutrophication and deteriorated water quality of the landscape water system.This study focuses on the application of air floatation method in water quality maintenance with the eco-landscape pool of Zhongxing Mangrove Bay as the study object,so as to provide a scheme for maintaining the water quality of artificial lakes.

Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy

In this investigation, the adsorption of benzonitrile at the air/water interface was addressed using vibrational sum-frequency spectroscopy. Using ppp and ssp polarization combinations, the authors detected the symmetric stretching mode of the cyano (CN) group and calculated the orientation of benzonitrile at the interface. In addition, the adsorption isotherm was determined in terms of the hyperpolarizability element by varying the bulk benzonitrile concentration. The adsorption energy was obtained from fitting this isotherm. This work will add to our understanding of chemical processes relevant to retention, degradation, and photolysis of benzonitriles in the environment.

AN EXPERIMENTAL STUDY ON TURBULENT COHERENT STRUCTURES NEAR A SHEARED AIR-WATER INTERFACE

The turbulence structures near a sheared air-water interface were experimentally investigated with the hydrogen bubble visualization technique. Surface shear was imposed by an airflow over the water flow which was kept free from surface waves. Results show that the wind shear has the main influence on coherent structures under air-water interfaces. Low- and high- speed streaks form in the region close to the interface as a result of the imposed shear stress. When a certain airflow velocity is reached, “turbulent spots” appear randomly at low-speed streaks with some characteristics of hairpin vortices. At even higher shear rates, the flow near the interface is dominated primarily by intermittent bursting events. The coherent structures observed near sheared air-water interfaces show qualitative similarities with those occurring in near-wall turbulence. However, a few distinctive phenomena were also observed, including the fluctuating thickness of the instantaneous boundary layer and vertical vortices in bursting processes, which appear to be associated with the characteristics of air-water interfaces.

SOME CHARACTERISTICS OF LOW-SPEED STREAKS UNDER SHEARED AIR-WATER INTERFACES

The characteristics of low-speed fluid streaks occurring under sheared air-water interfaces were examined by means of hydrogen bubble visualization technique. A critical shear condition under which the streaky structure first appears was determined to be u(tau) approximate to 0.19 cm/s. The mean spanwise streak spacing increases with distance from the water surface owing to merging and bursting processes, and a linear relationship describing variation of non-dimensional spacing <(<lambda>+)over bar> versus y(+) was found essentially independent of shear stress on the interface. Values of <(<lambda>+)over bar>, however, are remarkably smaller than their counterparts in the near-wall region of turbulent boundary layers. Though low-speed streaks occur randomly in time and space, the streak spacing exhibits a lognormal probability distribution behavior. A tentative explanation concerning the formation of streaky structure is suggested, and the fact that <(<lambda>+)over bar> takes rather smaller values than that in wall turbulence is briefly discussed.

Plasma induced degradation of Indigo Carmine by bipolar pulsed dielectric barrier discharge(DBD) in the water-air mixture

Degradation of the Indigo Carmine(IC) by the bipolar pulsed DBD in water-air mixture was studied. Effects of various parameters such as gas flow rate, solution conductivity, pulse repetitive rate and ect., on color removal efficiency of dying wastewater were investigated. Concentrations of gas phase O 3 and aqueous phase H 2O 2 under various conditions were measured. Experimental results showed that air bubbling facilitates the breakdown of water and promotes generation of chemically active species. Color removal efficiency of IC solution can be greatly improved by the air aeration under various solution conductivities. Decolorization efficiency increases with the increase of the gas flow rate, and decreases with the increase of the initial solution conductivity. A higher pulse repetitive rate and a larger pulse capacitor C\-p are favorable for the decolorization process. Ozone and hydrogen peroxide formed decreases with the increase of initial solution conductivity. In addition, preliminary analysis of the decolorization mechanisms is given.

Bimetallic Nickel Cobalt Sulfide as E cient Electrocatalyst for Zn–Air Battery and Water Splitting

The development of e cient earth-abundant electrocatalysts for oxygen reduction, oxygen evolution, and hydrogen evolution reactions(ORR, OER, and HER) is important for future energy conversion and energy storage devices, for which both rechargeable Zn–air batteries and water splitting have raised great expectations. Herein, we report a single-phase bimetallic nickel cobalt sulfide((Ni,Co)S_2) as an e cient electrocatalyst for both OER and ORR. Owing to the synergistic combination of Ni and Co, the(Ni,Co)S_2 exhibits superior electrocatalytic performance for ORR, OER, and HER in an alkaline electrolyte, and the first principle calculation results indicate that the reaction of an adsorbed O atom with a H_2O molecule to form a *OOH is the potential limiting step in the OER. Importantly, it could be utilized as an advanced air electrode material in Zn–air batteries, which shows an enhanced charge–discharge performance(charging voltage of 1.71 V and discharge voltage of 1.26 V at 2 mA cm^(-2)), large specific capacity(842 mAh g_(Zn)^(-1) at 5 mA cm^(-2)), and excellent cycling stability(480 h). Interestingly, the(Ni,Co)S_2-based Zn–air battery can e ciently power an electrochemical water-splitting unit with(Ni,Co)S_2 serving as both the electrodes. This reveals that the prepared(Ni,Co)S_2 has promising applications in future energy conversion and energy storage devices.

Modeling the Underwater Acoustic Field Excited by an Airborne Rapidly Moving Source Using Wavenumber Integration

It is complicated to model the acoustic field in stratified ocean for airborne aircraft,due to high speed of the source and air-to-water sound transmission.To our knowledge,there are very few papers in the open literature dealing with this complicated problem;but,in our opinion,they all require great amount of computation.We now propose a different method that requires much less computation.We improve the wavenumber integration method to model the received temporal signal for a moving source in stratified ocean and sum up in a concise form the core of our paper as follows:(A) Eq.(11) can be calculated by means of fast Chirp Z transform and the signals at all N time points are generated simultaneously;(B) direct numerical evaluation of the wavenumber integral in Eq.(4) produces large numerical errors;so it is necessary to shift the integration slightly below the real axis;(C) we compare the computation cost of direct calculation method with that of our fast calculation method;from the results presented in table 1,we can see that the fast calculation method consumes much less computation time,particularly for long duration signals;(D) for an airborne rapidly moving source,we compute the Doppler-shifted signals in shallow water and analyze their short-time Fourier transform;from Fig.1b,we can see that the received signals have multiple frequency components for a tonal source due to source motion and that each component corresponds to an arrival path.

Response of IAP/LASG GOALS Model to the Coupling of Air-Sea Fresh Water Exchange

The process of air—sea fresh water exchange is included successfully in the Global— Ocean—Atmosphere Land—System model developed at the State Key Laboratory of Atmospheric Sciences and Geophysical Fluid Dynamics (LASG). The results of the coupled integration show that the climate drift has been controlled successfully. Analyses on the responses of ocean circulation to the changes of surface fresh water or salinity forcing show that the ocean spin-up stage under flux condition for salinity is the key to the implementation of air-sea fresh water flux coupling. This study also demonstrates that the Modified—Monthly—Flux—Anomaly coupling scheme (MMFA) brought forward by Yu and Zhang (1998) is suitable not only for daily air—sea heat flux coupling but also for daily fresh water flux coupling. Key words Fresh water flux - Air-sea coupling - Thermohaline circulation This work was co-supported by the National Key Project (Grant No.96-908-02-03), the Excellent National Key Laboratory Research Project (Grant No.49823002) and Chinese Academy of Sciences (CAS) under grant “ Bai Ren Ji Hua? for “Validation of Coupled Climate Models”.

Water-Air Mixing Jet Produced by Electro-hydraulic Impulse Technology Strengthening the Quality of Surface of Metal Materials

Electro-hydraulic impulse water-air mixing jet by which the quality of metal materials can be improved is described in this paper. The experimental results proved that the hardness and the micro-hardness of the surface layer of metal materials can be improved with this method, for example, the microhardness of CrWMn can be increased by 35.62 percent.

DISCREPANCY OF THE GLOBAL AIR MASS AND WATER BUDGETS AMONG 20 CMIP5 CLIMATE MODELS

The consistency of global atmospheric mass and water budget performance in 20 state-of-the-art ocean-atmosphere Coupled Model Intercomparison Project Phase 5(CMIP5) coupled models has been assessed in a historical experiment. All the models realistically reproduce a climatological annual mean of global air mass(AM) close to the ERA-Interim AM during 1989-2005. Surprisingly, the global AM in half of the models shows nearly no seasonal variation,which does not agree with the seasonal processes of global precipitable water or water vapor, given the mass conservation constraint. To better understand the inconsistencies, we evaluated the seasonal cycles of global AM tendency and water vapor source(evaporation minus precipitation). The results suggest that the inconsistencies result from the poor balance between global AM tendency and water vapor source based on the global AM budget equation. Moreover, the cross-equatorial dry air mass flux, or hemispheric dry mass divergence, is not well represented in any of the 20 CMIP5 models, which show a poorly matched seasonal cycle and notably larger amplitude, compared with the hemispheric tendencies of dry AM in both the Northern Hemisphere and Southern Hemisphere. Pronounced erroneous estimations of tropical precipitation also occur in these models. We speculate that the large inaccuracy of precipitation and possibly evaporation in the tropics is one of the key factors for the inconsistent cross-equatorial mass flux. A reasonable cross-equatorial mass flux in well-balanced hemispheric air mass and moisture budgets remains a challenge for both reanalysis assimilation systems and climate modeling.

Radioactivity monitoring in environmental water and air around QNPP

Results of environmental radioactivity monitoring around Qinshan Nuclear Power Plant (QNPP) are reported in this paper. From 1992 to 2005, concentrations of 90Sr, 137Cs and 3H in terrestrial freshwater are (4.4±1.7) mBq·L-1, (0.3±0.1) mBq·L-1 and (1.6±0.5) Bq·L-1, respectively, and (2.8±2.4) Bq·L-1 of 3H in rainwater. Concentrations of 90Sr, 137Cs and 3H in the seawater samples collected from sea area nearby QNPP are (5.4±4.1) mBq·L-1, (0.7±0.2) mBq·L-1 and (1.0±0.5) Bq·L-1, respectively. Concentrations of 90Sr, 137Cs and 3H in the total waste water discharged from NPP-I are (4.0±1.8) m Bq·L-1, (1.0±0.5) mBq·L-1 and (2.8±2.2) Bq·L-1, respectively, and (1.4±0.4) Bq·L-1 of 3H in seawater sampled from No.1 outlet. Atomspheric 3H concentration in 1993～2005 at two monitoring sites is (78.9±96.3) and (64.2±40.2) mBq·m-3, respectively, with an increasing trend after 2003. Atmospheric 14C concentrations at the two sites are in the same levels as the background and data of the reference site.

Energy, Exergy and Thermoeconomics Analysis of Water Chiller Cooler for Gas Turbines Intake Air Cooling

Gas turbine (GT) power plants operating in arid climates suffer a decrease in output power during the hot summer months because of the high specific volume of air drawn by the compressor. Cooling the air intake to the compressor has been widely used to mitigate this shortcoming. Energy and exergy analysis of a GT Brayton cycle coupled to a refrigeration air cooling unit shows a promise for increasing the output power with a little decrease in thermal efficiency. A thermo-economics algorithm is developed to estimate the economic feasibility of the cooling system. The analysis is applied to an open cycle, HITACHI-FS7001B GT plant at the industrial city of Yanbu (Latitude 24o 05” N and longitude 38o E) by the Red Sea in the Kingdom of Saudi Arabia. Result show that the enhancement in output power depends on the degree of chilling the air intake to the compressor (a 12 - 22 K decrease is achieved). For this case study, maximum power gain ratio (PGR) is 15.46% (average of 12.25%), at an insignificant decrease in thermal efficiency. The second law analysis show that the exergetic power gain ratio drops to an average 8.5%. The cost of adding the air cooling system is also investigated and a cost function is derived that incorporates time-dependent meteorological data, operation characteristics of the GT and the air intake cooling system and other relevant parameters such as interest rate, lifetime, and operation and maintenance costs. The profit of adding the air cooling system is calculated for different electricity tariff.