An integral quality control(QC)procedure that integrates various QC methods and considers the design indexes and operational status of the instruments for the observations of drifting air-sea interface buoy was develo...An integral quality control(QC)procedure that integrates various QC methods and considers the design indexes and operational status of the instruments for the observations of drifting air-sea interface buoy was developed in the order of basic in-spection followed by targeted QC.The innovative method of combining a moving Hampel filter and local anomaly detection com-plies with statistical laws and physical processes,which guarantees the QC performance of meteorological variables.Two sets of observation data were used to verify the applicability and effectiveness of the QC procedure,and the effect was evaluated using the observations of the Kuroshio Extension Observatory buoy as the reference.The results showed that the outliers in the time series can be correctly identified and processed,and the quality of data improved significantly.The linear correlation between the quality-controlled observations and the reference increased,and the difference decreased.The correlation coefficient of wind speed before and after QC increased from 0.77 to 0.82,and the maximum absolute error decreased by approximately 2.8ms^(-1).In addition,air pressure and relative humidity were optimized by 10^(-3)–10^(-2) orders of magnitude.For the sea surface temperature,the weight of coefficients of the continuity test algorithm was optimized based on the sea area of data acquisition,which effectively expanded the applicability of the algorithm.展开更多
Coastal wetlands are hotspots for nitrogen(N)cycling,and crab burrowing is known to transform N in intertidal marsh soils.However,the underlying mechanisms remain unclear.This study conducted field experiments and use...Coastal wetlands are hotspots for nitrogen(N)cycling,and crab burrowing is known to transform N in intertidal marsh soils.However,the underlying mechanisms remain unclear.This study conducted field experiments and used indoor control test devices to investigate the seasonal response of nitrogen to crab disturbance at the sediment-water interface in coastal tidal flat wetlands.The results showed that crab disturbance exhibited significant seasonality with large seasonal differences in cave density and depth.Due to crab disturbance,nitrogen fuxes at the sediment-water interface were much greater in the box with crabs than in the box without crabs.In summer,NH-N showed a positive flux from the sediment to the overlying water,but NO2-N and NOg-N showed positive fluxes from the sediment to the overlying water only in early stages.In winter,NH-N showed a positive flux from the sediment to the overlying water,but NO-N and NO,-N both exhibited positive and negative fluxes.These results indicated that the presence of crab burrows can cause the aerobic layer to move downward by approximately 8-15 cm in summer and directly promote nitrification at the sediment surface.展开更多
Boundary conditions for momentum and vorticity have been precisely derived, paying attention to the physical meaning of each mathematical expression of terms rigorously obtained from the basic equations: Navier-Stokes...Boundary conditions for momentum and vorticity have been precisely derived, paying attention to the physical meaning of each mathematical expression of terms rigorously obtained from the basic equations: Navier-Stokes equation and the equation of vorticity transport. It has been shown first that a contribution of fluid molecules crossing over a conceptual surface moving with fluid velocity due to their fluctuating motion is essentially important to understanding transport phenomena of momentum and vorticity. A notion of surface layers, which are thin layers at both sides of an interface, has been introduced next to elucidate the transporting mechanism of momentum and vorticity from one phase to the other at an interface through which no fluid molecules are crossing over. A fact that a size of δV, in which reliable values of density, momentum, and velocity of fluid are respectively defined as a volume-averaged mass of fluid molecules, a volume-averaged momentum of fluid molecules and a mass-averaged velocity of fluid molecules, is not infinitesimal but finite has been one of the key factors leading to the boundary conditions for vorticity at an interface between two fluids. The most distinguished characteristics of the boundary conditions derived here are the zero-value conditions for a normal component of momentum flux and tangential components of vorticity flux, at an interface.展开更多
Filter-feeding shellfish are common benthos and significantly affect the biogeochemical cycle in the shallow coastal ecosystems.Ark clam Scapharca subcrenata is one of the widely cultured bivalve species in many coast...Filter-feeding shellfish are common benthos and significantly affect the biogeochemical cycle in the shallow coastal ecosystems.Ark clam Scapharca subcrenata is one of the widely cultured bivalve species in many coastal areas owing to its tremendous economic value.However,there is little information regarding the effects of the bioturbation of S.subcrenata on the fluxes of nutrient exchange in the sediment-water interface(SWI).In this regard,S.subcrenata was sampled during October 2016 to determine the effects of its bioturbation activity on the nutrient exchange flux of the SWI.The results showed that the biological activity of S.subcrenata could increase the diffusion depth and the rate of the nutrients exchange in the sediments.The bioturbation of S.subcrenata could allow the nutrients to permeate into the surface sediments at 6-10cm and increase the release rate of nutrients at the SWI.The releasing fluxes of DIN and PO43−-P in the culture area were found to be around three times higher than that in the non-cultured region.The culture of S.subcrenata has been proved to be an important contributor to nutrient exchange across the SWI in the farming area of Haizhou Bay.Nutrients exchange in the SWI contributes a part of 86%DIN,71%PO43−-P and 18%SiO32−-Si for the aquaculture farm.展开更多
Sea spray,which comprises amounts of small ocean droplets,plays a significant role in the air-sea coupling,atmospheric and oceanic dynamics,and climate.However,it remains arduous to arrive at estimates for the efficie...Sea spray,which comprises amounts of small ocean droplets,plays a significant role in the air-sea coupling,atmospheric and oceanic dynamics,and climate.However,it remains arduous to arrive at estimates for the efficiency and accuracy of the sea spray induced air-sea heat and salt fluxes.This is because the microphysical process of sea spray evolution in the air is of extreme complexity.In this study,we iteratively calculated the sea spray induced air-sea heat and salt fluxes at various weather condition.To do so,we implemented one novel wave-steepness-dependent sea spray model into a bulk air-sea fluxes algorithm and utilized other sea spray models as comparisons.Based on the improved wave-dependent bulk turbulent algorithm,we observed that despite the negative contribution of sea spray to the sensible heat fluxes,the sea spray positively contributes to the air-sea latent heat fluxes,leading to an overall increase in the total air-sea heat fluxes.The additional heat fluxes caused by sea spray may be the missing critical process that can clarify the discrepancies observed between measured and modelled Tropical Cyclone’s development and intensification.In addition to heat fluxes,we observed that sea spray has significant impacts on the air-sea salt fluxes.As the sea salt particles are one of the main sources of the atmosphere aerosol,our results imply that sea spray could impact global and regional climate.Thus,given the significance of sea spray on the air-sea boundary layer,sea spray effects need to be considered in studies of air-sea interaction,dynamics of atmosphere and ocean.展开更多
During the Huanghai Sea Circulation and Material Flux Expedition in Spring 1996, fco_2 in surface water and atmosphere was measured. The fco2 in surface water varied in a range from 220 to 360 uatm1) while atmospheric...During the Huanghai Sea Circulation and Material Flux Expedition in Spring 1996, fco_2 in surface water and atmosphere was measured. The fco2 in surface water varied in a range from 220 to 360 uatm1) while atmospheric concentration was nearly constant at 360μatm, showing that the Huanghai Sea surface waters were undersaturated with respect to atmospheric Co during the time of investigation. A model was developed in this study in order to estimate the Co flux at the air-sea interface. The model incorporates the time-series variations of the distributions in SST (sea surface temperature), salinity, mixed-layer depth, atmospheric fco2, gas-transfer velocity, and CZCS chlorophyll concentration in the Huanghai Sea and was calibrated with the observed fco2 data. The primary parameter affecting fco2 in surface water is the variation of SST through time. The annual fluxes of Co are estimated as 0. 033 Gt C from the sea into the atmosphere and 0. 044 Gt C from the air into sea. The Huanghai Sea, thus behaves as a CO2 sink absorbing 0. 011 Gi C of CO2 a year. which.corresponds to about 0. 5 % of global oceanic absorption capacity.展开更多
Nitrogen and phosphorus contents are analyzed in the overlying waters and pore waters taken from the Changjiang Estuary and Shanghai coastal tidal flats in this study. In addition, the diffusion fluxes of nitrogen and...Nitrogen and phosphorus contents are analyzed in the overlying waters and pore waters taken from the Changjiang Estuary and Shanghai coastal tidal flats in this study. In addition, the diffusion fluxes of nitrogen and phosphorus across the sediment-water interface in tidal flats are estimated according to the nutrient concentration gradients at the interface. It has been indicated that the concentrations of ammonium, nitrite, nitrate and dissolved phosphorus in overlying waters range from 0.0082~2.56, 0.03~0.58, 0.69~5.38 and 0.035~0.53 mg/L, respectively, while 0.0025 ~ 1.35 mg/L for NH4+-N, 0. 0055 ~ 0.20mg/L for NO2--N, 0.61~1.14 mg/L for NO3--N and 0.11~0.53mg/L for DP insurface pore waters.The findings have revealed that ammonium, nitrite, nitrate and dissolved phosphorus diffusion fluxes across the sediment-water interface are between -0.024~0.99, -0.39~ -0.0019, -3.09~the source of phosphorus and an important sink for nitrogen in the waters.展开更多
To obtain carbon dioxide (CO2) flux between water-air interface of Taihu lake, monthly water samplers at 14 sites and the local meteorological data of the lake were collected and analyzed in 1998. Carbon dioxide parti...To obtain carbon dioxide (CO2) flux between water-air interface of Taihu lake, monthly water samplers at 14 sites and the local meteorological data of the lake were collected and analyzed in 1998. Carbon dioxide partial pressures (pCO2) at air-water interface in the lake were calculated using alkalinity, pH, ionic strength, active coefficient, and water temperature. The carbon fluxes at different sublakes and areas were estimated by concentration gradient between water and air in consideration of Schmidt numbers of 600 and daily mean windspeed at 10 m above water surface. The results indicated that the mean values of pCO2 in Wuli Lake, Meiliang Bay, hydrophyte area, west littoral zone, riverine mouths, and the open lake areas were 1 807.8±1 071.4 (mean±standard deviation) μatm (1atm=1.013 25×105Pa), 416.3±217.0 μatm, 576.5±758.8 μatm, 304.2±243.5 μatm, 1 933.6±1 144.7 μatm, and 448.5±202.6 μatm, respectively. Maximum and minimum pCO2 values were found in the hypertrophic (4 053.7 μatm) and the eutrophic (3.2 μatm) areas. The riverine mouth areas have the maximum fluxes (82.0±62.8 mmol/m2a). But there was no significant difference between eutrophic and mesot- rophic areas in pCO2 and the flux of CO2. The hydrophyte area, however, has the minimum (-0.58±12.9 mmol/m2a). In respect to CO2 equilibrium, input of the rivers will obviously influence inorganic carbon distribu- tion in the riverine estuary. For example, the annual mean CO2 flux in Zhihugang River estuary was 19 times of that in Meiliang Bay, although the former is only a part of the latter. The sites in the body of the lake show a clear seasonal cycle with pCO2 higher than atmospheric equilibrium in winter, and much lower than atmospheric in summer due to CO2 consumption by photosynthesis. The CO2 amount of the net annual evasion that enters the atmosphere is 28.42×104 t/a, of which those from the west littoral zone and the open lake account for 53.8% and 36.7%, respectively.展开更多
This study on the sectional and vertical distribution of dissolved oxygen (DO) and the O<sub>2</sub> fluxes acrossthe sea-air interface in East China Sea (ESC) waters shows that the waters were in stea...This study on the sectional and vertical distribution of dissolved oxygen (DO) and the O<sub>2</sub> fluxes acrossthe sea-air interface in East China Sea (ESC) waters shows that the waters were in steady state and thatthe difference of DO was great in upper and bottom waters in Apr. 1994; but that seawater mixingwas strong and the difference of DO was small in upper and bettom waters in Oct. 1994. The above con-dusions were specially obvious in continental shelf waters under 100m. The DO maximum in subsurfacelayer waters appeared only at several stations and in general the DO in the waters decreased with depth.The horizontal distributions of O<sub>2</sub> fluxes across the sea-air interface appeared in stripes in Leg 9404 whenmost regions covend were supersaturated with O<sub>2</sub>. seawater to air flux wn large, and that on section No.1was 1.594 L/m<sup>2</sup>·d. The horizontal distribution of O<sub>2</sub> fluxes across the sea-air interface appeared lumpy inLeg 9410, when most regions covered were unsaturated with O<sub>2</sub>. O<sub>2</sub> was dissolved from展开更多
It has long been recognized that the evolution of marine storms may be strongly affected by the flux transfer processes over the ocean. High winds in a storm can generate large amounts of spray, which can modify the t...It has long been recognized that the evolution of marine storms may be strongly affected by the flux transfer processes over the ocean. High winds in a storm can generate large amounts of spray, which can modify the transfer of momentum, heat, and moisture across the air-sea interface. However, the role of sea spray and air-sea processes in western Pacific typhoons has remained elusive. In this study, the impact of sea spray on air-sea fluxes and the evolution of a typhoon over the western Pacific is investigated using a coupled atmosphere-sea-spray modeling system. Through the case study of the recent Typhoon Fengshen from 2002, we found that: (1) Sea spray can cause a significant latent heat flux increase of up to 40% of the interfacial fluxes in the typhoon; (2) Taking into account the effects of sea spray, the intensity of the modeled typhoon can be increased by 30% in the 10-m wind speed, which may greatly improve estimates of storm maximum intensity and, to some extent, improve the simulations of overall storm structure in the atmospheric model; (3) The effects of sea spray are mainly focused over the high wind regions around the storm center and are mainly felt in the lower part of the troposphere.展开更多
The distributions of partial pressure of carbon dioxide (pCO2) in the surface waters of the Changjiang River Estuary and adjacent Hangzhou Bay were examined in the summer of 2010. Surface water pCO2 ranged from 751-...The distributions of partial pressure of carbon dioxide (pCO2) in the surface waters of the Changjiang River Estuary and adjacent Hangzhou Bay were examined in the summer of 2010. Surface water pCO2 ranged from 751-2 095/zatm (1 atm=101 325 Pa) in the inner estuary, 177-1 036/zatm in the outer estuary, and 498-1 166 μatm in Hangzhou Bay. Overall, surface pCO2 behaved conservatively during the estuary mixing. In the inner estuary, surface pCO2 was relatively high due to urbanized pollution and a high respiration rate. The lowest pCO2 was observed in the outer estuary, which was apparently induced by a phytoplankton bloom because the dissolved oxygen and chlorophyll a were very high. The Changjiang River Estuary was a significant source of atmospheric CO2 and the degassing fluxes were estimated as 0-230 mmol/(m2.d) [61 mmol/(m2.d) on average] in the inner estuary. In contrast, the outer estuary acted as a CO2 sink.展开更多
A singular value decomposition (SVD) analysis is carried out to reveal the relationship between the interannual variation of track and intensity of the western North Pacific tropical cyclones (WNPTCs) in the tropi...A singular value decomposition (SVD) analysis is carried out to reveal the relationship between the interannual variation of track and intensity of the western North Pacific tropical cyclones (WNPTCs) in the tropical cyclone (TC) active season (July–November) and the global net air-sea heat flux (Q net ) in the preceding season (April–June). For this purpose, a tropical cyclone track and intensity function (TIF) is defined by a combination of accumulated cyclone energy (ACE) index and a cyclone track density function. The SVD analysis reveals that the first mode is responsible for the positive correlation between the upward heat flux in the tropical central Pacific and the increased activity of western North Pacific (WNP) TIF, the second mode for the positive correlation between the upward heat flux in the North Indian Ocean and the northeastward track shift of WNPTCs and the third mode for the negative correlation between the upward heat flux in mid-latitude central Pacific and the northwest displacement of the WNP TC-active center. This suggests that Q net anomalies in some key regions have a substantial remote impact on the WNP TC activity.展开更多
With the data observed from the Second SCS Air-Sea Flux Experiment on the Xisha air-sea flux research tower, the radiation budget, latent, sensible heat fluxes and net oceanic heat budgets were caculated before and af...With the data observed from the Second SCS Air-Sea Flux Experiment on the Xisha air-sea flux research tower, the radiation budget, latent, sensible heat fluxes and net oceanic heat budgets were caculated before and after summer monsoon onset. It is discovered that, after summer monsoon onset, there are considerable changes in air-sea fluxes, especially in latent heat fluxes and net oceanic heat budget. Furthermore, the analyzed results of five synoptic stages are compared. And the characteristics of the flux transfer during different stages around onset of South China Sea monsoon are discussed. The flux change shows that there is an oceanic heat accumulating process during the pre-onset and the break period, as same as oceanic heat losing process during the onset period. Moreover, latent fluxes, the water vapor moving to the continent, even the rainfall appearance in Chinese Mainland also can be influenced by southwester. Comparing Xisha fluxes with those obtained from the Indian Ocean and the western Pacific Ocean, their differences may be observed. It is the reason why SSTs can keep stable over the South China Sea while they decrease quickly over the Arabian Sea and the Bay of Bengal after monsoon onset.展开更多
The ESMD method can be seen as a new alternate of the well-known Hilbert-Huang transform (HHT) for non-steady data processing. It is good at finding the optimal adaptive global mean fitting curve, which is superior to...The ESMD method can be seen as a new alternate of the well-known Hilbert-Huang transform (HHT) for non-steady data processing. It is good at finding the optimal adaptive global mean fitting curve, which is superior to the common least-square method and running-mean approach. Take the air-sea momentum flux investigation as an example, only when the non-turbulent wind components is well extracted, can the remainder signal be seen as actual oscillations caused by turbulence. With the aid of —5/3 power law for the turbulence, a mode-filtering approach based on ESMD decomposition is developed here. The test on observational data indicates that this approach is very feasible and it may greatly reduce the error caused by the non-turbulent components.展开更多
A flux system deployed on a moored buoy has been described, which is capable of directly estimating the airsea fluxes after removing the contamination in the signal due to buoy motion. A triple loop fitting method has...A flux system deployed on a moored buoy has been described, which is capable of directly estimating the airsea fluxes after removing the contamination in the signal due to buoy motion. A triple loop fitting method has been demonstrated for determining the three angular offsets between measurement axes of the sonic anemometer and motion pack. The data collected in an experiment in the Northern Huanghai Sea is used to correct the three sonic anemometer measurements of turbulent wind for buoy motion. The effective removal of wave-scale motion from the spectra and cospectra are demonstrated. Estimates of along-wind momentum flux, sensible heat flux and latent heat flux calculated by the eddy correlation method based on data obtained by sonic anemometer 81000V are shown to be in the same trend and scale with those determined by the bulk aerodynamic method after motion correction. The motion correction not only greatly improve the estimation of the momentum flux but also has a great impact on the calculated sensible heat flux.展开更多
The 3rd Chinese National Arctic Research Expedition (CHINARE-Arctic III) was carried out from July to September in 2008. The partial pressure of CO2 (pCO2) in the atmosphere and in surface seawater were determined...The 3rd Chinese National Arctic Research Expedition (CHINARE-Arctic III) was carried out from July to September in 2008. The partial pressure of CO2 (pCO2) in the atmosphere and in surface seawater were determined in the Bering Sea during luly 11-27, 2008, and a large number of seawater samples were taken for total alkalinity (TA) and total dissolved inorganic carbon (DIC) analysis. The distributions of CO2 parameters in the Bering Sea and their controlling factors were discussed. The pCO2 values in surface seawater presented a drastic variation from 148 to 563 laatm (1 μatm = 1.013 25× 10-1Pa). The lowest pCOz values were observed near the Bering Sea shelf break while the highest pCO2 existed at the western Bering Strait. The Bering Sea generally acts as a net sink for atmospheric CO2 in summer. The air-sea CO2 fluxes in the Bering Sea shelf, slope, and basin were estimated at -9.4, -16.3, and -5.1 mmol/(m2.d), respectively. The annual uptake of CO2 was about 34 Tg C in the Bering Sea.展开更多
Precise measurements of the CO2 gas transfer across the air-sea interface provide a better under- standing of the global carbon cycle. The air-sea CO2 fluxes are obtained by the eddy covariance method and the bulk met...Precise measurements of the CO2 gas transfer across the air-sea interface provide a better under- standing of the global carbon cycle. The air-sea CO2 fluxes are obtained by the eddy covariance method and the bulk method from a buoy observation in the northern Huanghai sea. The effects of buoy motion on flux calculated by the eddy covariance method are demonstrated. The research shows that a motion correction can improve the correlation coefficient between the C02 fluxes esti- mated from two different levels. Without the CO2-H20 cross-correlation correction which is termed as PKT correction, the air-sea CO2 fluxes estimated by eddy covariance method using the motion corrected data are nearly an order of magnitude larger than those estimated by the bulk method. After the CO2-H20 cross-correlation correction, some eddy covariance CO2 fluxes indeed become closer to the bulk CO2 flux, whereas some are overcorrected which are in response to small water vapor flux.展开更多
The measurement of atmospheric O_(2)concentrations and related oxygen budget have been used to estimate terrestrial and oceanic carbon uptake.However,a discrepancy remains in assessments of O_(2)exchange between ocean...The measurement of atmospheric O_(2)concentrations and related oxygen budget have been used to estimate terrestrial and oceanic carbon uptake.However,a discrepancy remains in assessments of O_(2)exchange between ocean and atmosphere(i.e.air-sea O_(2)flux),which is one of the major contributors to uncertainties in the O_(2)-based estimations of the carbon uptake.Here,we explore the variability of air-sea O_(2)flux with the use of outputs from Coupled Model Intercomparison Project phase 6(CMIP6).The simulated air-sea O_(2)flux exhibits an obvious warming-induced upward trend(~1.49 Tmol yr−2)since the mid-1980s,accompanied by a strong decadal variability dominated by oceanic climate modes.We subsequently revise the O_(2)-based carbon uptakes in response to this changing air-sea O_(2)flux.Our results show that,for the 1990−2000 period,the averaged net ocean and land sinks are 2.10±0.43 and 1.14±0.52 GtC yr−1 respectively,overall consistent with estimates derived by the Global Carbon Project(GCP).An enhanced carbon uptake is found in both land and ocean after year 2000,reflecting the modification of carbon cycle under human activities.Results derived from CMIP5 simulations also investigated in the study allow for comparisons from which we can see the vital importance of oxygen dataset on carbon uptake estimations.展开更多
Indian Central Water (ICW) and Subantarctic Mode Water (SAMW) formation rates are estimated from two air-sea flux products, the Comprehensive Ocean-Atmosphere Data Set (COADS) and the Southampton Oceanography Ce...Indian Central Water (ICW) and Subantarctic Mode Water (SAMW) formation rates are estimated from two air-sea flux products, the Comprehensive Ocean-Atmosphere Data Set (COADS) and the Southampton Oceanography Centre (SOC) climatology. The ICW formation is estimated to be 8 Sv (1 Sv = 106m3·s-1 ) from both products, with more contributions from freshwater flux. From the COADS product, the SAMW formation rate is estimated to be 31 Sv in the potential density range of 26.5-26.9σθ, with also a significant contribution from freshwater flux. However, the SAMW formation rate estimated from the SOC product is much smaller, which may be due to bias of the SOC heat flux. Poorer quality of the flux products in the Southern Ocean may also contribute to the difference.展开更多
基金supported by the Natural Resources Development Special Fund Project of Jiangsu Province(No.JSZRHYKJ202009)the Taishan Scholar Funds(No.tsqn 201812022)+2 种基金the Fundamental Research Funds for the Central Universities(No.202072001)the Guangxi Key Laboratory of Marine Disaster in the Beibu Gulf,Beibu Gulf University(No.2021KF03)the National Natural Science Foundation of China(No.42176020).
文摘An integral quality control(QC)procedure that integrates various QC methods and considers the design indexes and operational status of the instruments for the observations of drifting air-sea interface buoy was developed in the order of basic in-spection followed by targeted QC.The innovative method of combining a moving Hampel filter and local anomaly detection com-plies with statistical laws and physical processes,which guarantees the QC performance of meteorological variables.Two sets of observation data were used to verify the applicability and effectiveness of the QC procedure,and the effect was evaluated using the observations of the Kuroshio Extension Observatory buoy as the reference.The results showed that the outliers in the time series can be correctly identified and processed,and the quality of data improved significantly.The linear correlation between the quality-controlled observations and the reference increased,and the difference decreased.The correlation coefficient of wind speed before and after QC increased from 0.77 to 0.82,and the maximum absolute error decreased by approximately 2.8ms^(-1).In addition,air pressure and relative humidity were optimized by 10^(-3)–10^(-2) orders of magnitude.For the sea surface temperature,the weight of coefficients of the continuity test algorithm was optimized based on the sea area of data acquisition,which effectively expanded the applicability of the algorithm.
基金supported by the National Natural Science Foundation of China(Grant No.52271273)the Open Foundation of the Key Laboratory of Ministry of Education for Coastal Disaster and Protection(Grant No.Z202201)。
文摘Coastal wetlands are hotspots for nitrogen(N)cycling,and crab burrowing is known to transform N in intertidal marsh soils.However,the underlying mechanisms remain unclear.This study conducted field experiments and used indoor control test devices to investigate the seasonal response of nitrogen to crab disturbance at the sediment-water interface in coastal tidal flat wetlands.The results showed that crab disturbance exhibited significant seasonality with large seasonal differences in cave density and depth.Due to crab disturbance,nitrogen fuxes at the sediment-water interface were much greater in the box with crabs than in the box without crabs.In summer,NH-N showed a positive flux from the sediment to the overlying water,but NO2-N and NOg-N showed positive fluxes from the sediment to the overlying water only in early stages.In winter,NH-N showed a positive flux from the sediment to the overlying water,but NO-N and NO,-N both exhibited positive and negative fluxes.These results indicated that the presence of crab burrows can cause the aerobic layer to move downward by approximately 8-15 cm in summer and directly promote nitrification at the sediment surface.
文摘Boundary conditions for momentum and vorticity have been precisely derived, paying attention to the physical meaning of each mathematical expression of terms rigorously obtained from the basic equations: Navier-Stokes equation and the equation of vorticity transport. It has been shown first that a contribution of fluid molecules crossing over a conceptual surface moving with fluid velocity due to their fluctuating motion is essentially important to understanding transport phenomena of momentum and vorticity. A notion of surface layers, which are thin layers at both sides of an interface, has been introduced next to elucidate the transporting mechanism of momentum and vorticity from one phase to the other at an interface through which no fluid molecules are crossing over. A fact that a size of δV, in which reliable values of density, momentum, and velocity of fluid are respectively defined as a volume-averaged mass of fluid molecules, a volume-averaged momentum of fluid molecules and a mass-averaged velocity of fluid molecules, is not infinitesimal but finite has been one of the key factors leading to the boundary conditions for vorticity at an interface between two fluids. The most distinguished characteristics of the boundary conditions derived here are the zero-value conditions for a normal component of momentum flux and tangential components of vorticity flux, at an interface.
基金supported by the Young Orient Scholars Programme of Shanghaithe Doctoral Scientific Research Starting Foundation of Shanghai Ocean University+2 种基金the Shanghai Special Research Fund for Training College’s Young Teachersthe Fund for Ministry of Agriculture Readjusting the Industrial Structure: Sea Farming Demonstration Project of Haizhou Bay in Jiangsu Province (Nos. D-8006-12-0018, D8006-15-8014)the Special Fund for Agro-Scientific Research in the Public Interest (No. 201303047)
文摘Filter-feeding shellfish are common benthos and significantly affect the biogeochemical cycle in the shallow coastal ecosystems.Ark clam Scapharca subcrenata is one of the widely cultured bivalve species in many coastal areas owing to its tremendous economic value.However,there is little information regarding the effects of the bioturbation of S.subcrenata on the fluxes of nutrient exchange in the sediment-water interface(SWI).In this regard,S.subcrenata was sampled during October 2016 to determine the effects of its bioturbation activity on the nutrient exchange flux of the SWI.The results showed that the biological activity of S.subcrenata could increase the diffusion depth and the rate of the nutrients exchange in the sediments.The bioturbation of S.subcrenata could allow the nutrients to permeate into the surface sediments at 6-10cm and increase the release rate of nutrients at the SWI.The releasing fluxes of DIN and PO43−-P in the culture area were found to be around three times higher than that in the non-cultured region.The culture of S.subcrenata has been proved to be an important contributor to nutrient exchange across the SWI in the farming area of Haizhou Bay.Nutrients exchange in the SWI contributes a part of 86%DIN,71%PO43−-P and 18%SiO32−-Si for the aquaculture farm.
基金The support of the US Office of Naval Research Global under contract No.N62909-20-1-2080.
文摘Sea spray,which comprises amounts of small ocean droplets,plays a significant role in the air-sea coupling,atmospheric and oceanic dynamics,and climate.However,it remains arduous to arrive at estimates for the efficiency and accuracy of the sea spray induced air-sea heat and salt fluxes.This is because the microphysical process of sea spray evolution in the air is of extreme complexity.In this study,we iteratively calculated the sea spray induced air-sea heat and salt fluxes at various weather condition.To do so,we implemented one novel wave-steepness-dependent sea spray model into a bulk air-sea fluxes algorithm and utilized other sea spray models as comparisons.Based on the improved wave-dependent bulk turbulent algorithm,we observed that despite the negative contribution of sea spray to the sensible heat fluxes,the sea spray positively contributes to the air-sea latent heat fluxes,leading to an overall increase in the total air-sea heat fluxes.The additional heat fluxes caused by sea spray may be the missing critical process that can clarify the discrepancies observed between measured and modelled Tropical Cyclone’s development and intensification.In addition to heat fluxes,we observed that sea spray has significant impacts on the air-sea salt fluxes.As the sea salt particles are one of the main sources of the atmosphere aerosol,our results imply that sea spray could impact global and regional climate.Thus,given the significance of sea spray on the air-sea boundary layer,sea spray effects need to be considered in studies of air-sea interaction,dynamics of atmosphere and ocean.
文摘During the Huanghai Sea Circulation and Material Flux Expedition in Spring 1996, fco_2 in surface water and atmosphere was measured. The fco2 in surface water varied in a range from 220 to 360 uatm1) while atmospheric concentration was nearly constant at 360μatm, showing that the Huanghai Sea surface waters were undersaturated with respect to atmospheric Co during the time of investigation. A model was developed in this study in order to estimate the Co flux at the air-sea interface. The model incorporates the time-series variations of the distributions in SST (sea surface temperature), salinity, mixed-layer depth, atmospheric fco2, gas-transfer velocity, and CZCS chlorophyll concentration in the Huanghai Sea and was calibrated with the observed fco2 data. The primary parameter affecting fco2 in surface water is the variation of SST through time. The annual fluxes of Co are estimated as 0. 033 Gt C from the sea into the atmosphere and 0. 044 Gt C from the air into sea. The Huanghai Sea, thus behaves as a CO2 sink absorbing 0. 011 Gi C of CO2 a year. which.corresponds to about 0. 5 % of global oceanic absorption capacity.
基金The work is supported by the National Natural Science Foundation of China(Grant Nos.430100203 and 49801018)the Foundation for University Key Teachers by the Ministry of Education of China.
文摘Nitrogen and phosphorus contents are analyzed in the overlying waters and pore waters taken from the Changjiang Estuary and Shanghai coastal tidal flats in this study. In addition, the diffusion fluxes of nitrogen and phosphorus across the sediment-water interface in tidal flats are estimated according to the nutrient concentration gradients at the interface. It has been indicated that the concentrations of ammonium, nitrite, nitrate and dissolved phosphorus in overlying waters range from 0.0082~2.56, 0.03~0.58, 0.69~5.38 and 0.035~0.53 mg/L, respectively, while 0.0025 ~ 1.35 mg/L for NH4+-N, 0. 0055 ~ 0.20mg/L for NO2--N, 0.61~1.14 mg/L for NO3--N and 0.11~0.53mg/L for DP insurface pore waters.The findings have revealed that ammonium, nitrite, nitrate and dissolved phosphorus diffusion fluxes across the sediment-water interface are between -0.024~0.99, -0.39~ -0.0019, -3.09~the source of phosphorus and an important sink for nitrogen in the waters.
基金This research was supported by the Knowledge Innovation Project of Chinese Academy of Sciences (KZCX1-SW-01-15) and (KZCX1- SW-12)
文摘To obtain carbon dioxide (CO2) flux between water-air interface of Taihu lake, monthly water samplers at 14 sites and the local meteorological data of the lake were collected and analyzed in 1998. Carbon dioxide partial pressures (pCO2) at air-water interface in the lake were calculated using alkalinity, pH, ionic strength, active coefficient, and water temperature. The carbon fluxes at different sublakes and areas were estimated by concentration gradient between water and air in consideration of Schmidt numbers of 600 and daily mean windspeed at 10 m above water surface. The results indicated that the mean values of pCO2 in Wuli Lake, Meiliang Bay, hydrophyte area, west littoral zone, riverine mouths, and the open lake areas were 1 807.8±1 071.4 (mean±standard deviation) μatm (1atm=1.013 25×105Pa), 416.3±217.0 μatm, 576.5±758.8 μatm, 304.2±243.5 μatm, 1 933.6±1 144.7 μatm, and 448.5±202.6 μatm, respectively. Maximum and minimum pCO2 values were found in the hypertrophic (4 053.7 μatm) and the eutrophic (3.2 μatm) areas. The riverine mouth areas have the maximum fluxes (82.0±62.8 mmol/m2a). But there was no significant difference between eutrophic and mesot- rophic areas in pCO2 and the flux of CO2. The hydrophyte area, however, has the minimum (-0.58±12.9 mmol/m2a). In respect to CO2 equilibrium, input of the rivers will obviously influence inorganic carbon distribu- tion in the riverine estuary. For example, the annual mean CO2 flux in Zhihugang River estuary was 19 times of that in Meiliang Bay, although the former is only a part of the latter. The sites in the body of the lake show a clear seasonal cycle with pCO2 higher than atmospheric equilibrium in winter, and much lower than atmospheric in summer due to CO2 consumption by photosynthesis. The CO2 amount of the net annual evasion that enters the atmosphere is 28.42×104 t/a, of which those from the west littoral zone and the open lake account for 53.8% and 36.7%, respectively.
文摘This study on the sectional and vertical distribution of dissolved oxygen (DO) and the O<sub>2</sub> fluxes acrossthe sea-air interface in East China Sea (ESC) waters shows that the waters were in steady state and thatthe difference of DO was great in upper and bottom waters in Apr. 1994; but that seawater mixingwas strong and the difference of DO was small in upper and bettom waters in Oct. 1994. The above con-dusions were specially obvious in continental shelf waters under 100m. The DO maximum in subsurfacelayer waters appeared only at several stations and in general the DO in the waters decreased with depth.The horizontal distributions of O<sub>2</sub> fluxes across the sea-air interface appeared in stripes in Leg 9404 whenmost regions covend were supersaturated with O<sub>2</sub>. seawater to air flux wn large, and that on section No.1was 1.594 L/m<sup>2</sup>·d. The horizontal distribution of O<sub>2</sub> fluxes across the sea-air interface appeared lumpy inLeg 9410, when most regions covered were unsaturated with O<sub>2</sub>. O<sub>2</sub> was dissolved from
文摘It has long been recognized that the evolution of marine storms may be strongly affected by the flux transfer processes over the ocean. High winds in a storm can generate large amounts of spray, which can modify the transfer of momentum, heat, and moisture across the air-sea interface. However, the role of sea spray and air-sea processes in western Pacific typhoons has remained elusive. In this study, the impact of sea spray on air-sea fluxes and the evolution of a typhoon over the western Pacific is investigated using a coupled atmosphere-sea-spray modeling system. Through the case study of the recent Typhoon Fengshen from 2002, we found that: (1) Sea spray can cause a significant latent heat flux increase of up to 40% of the interfacial fluxes in the typhoon; (2) Taking into account the effects of sea spray, the intensity of the modeled typhoon can be increased by 30% in the 10-m wind speed, which may greatly improve estimates of storm maximum intensity and, to some extent, improve the simulations of overall storm structure in the atmospheric model; (3) The effects of sea spray are mainly focused over the high wind regions around the storm center and are mainly felt in the lower part of the troposphere.
基金The Marine Public Welfare Project of China under contract Nos200805029,200905012,200905025,and 201005034the Scientific Research Fund of the Second Institute of Oceanography,SOA under contract Nos JG0821 and JG1021
文摘The distributions of partial pressure of carbon dioxide (pCO2) in the surface waters of the Changjiang River Estuary and adjacent Hangzhou Bay were examined in the summer of 2010. Surface water pCO2 ranged from 751-2 095/zatm (1 atm=101 325 Pa) in the inner estuary, 177-1 036/zatm in the outer estuary, and 498-1 166 μatm in Hangzhou Bay. Overall, surface pCO2 behaved conservatively during the estuary mixing. In the inner estuary, surface pCO2 was relatively high due to urbanized pollution and a high respiration rate. The lowest pCO2 was observed in the outer estuary, which was apparently induced by a phytoplankton bloom because the dissolved oxygen and chlorophyll a were very high. The Changjiang River Estuary was a significant source of atmospheric CO2 and the degassing fluxes were estimated as 0-230 mmol/(m2.d) [61 mmol/(m2.d) on average] in the inner estuary. In contrast, the outer estuary acted as a CO2 sink.
基金The National Key Basic Research Program of China under Grant No.2009CB421404the National Natural Science Foundation of China-Regional Cooperation Project under Grant No.40921160379+1 种基金the National Natural Science foundation of China under Grant No.40730951the Fundamental Research Funds for the Central Universities under Grant No.11lgjc10
文摘A singular value decomposition (SVD) analysis is carried out to reveal the relationship between the interannual variation of track and intensity of the western North Pacific tropical cyclones (WNPTCs) in the tropical cyclone (TC) active season (July–November) and the global net air-sea heat flux (Q net ) in the preceding season (April–June). For this purpose, a tropical cyclone track and intensity function (TIF) is defined by a combination of accumulated cyclone energy (ACE) index and a cyclone track density function. The SVD analysis reveals that the first mode is responsible for the positive correlation between the upward heat flux in the tropical central Pacific and the increased activity of western North Pacific (WNP) TIF, the second mode for the positive correlation between the upward heat flux in the North Indian Ocean and the northeastward track shift of WNPTCs and the third mode for the negative correlation between the upward heat flux in mid-latitude central Pacific and the northwest displacement of the WNP TC-active center. This suggests that Q net anomalies in some key regions have a substantial remote impact on the WNP TC activity.
基金National Natural Science Foundation of China under contract No. 40075003The Prior Study of State Key Project for Basic Research "East Asian Monsoon Experiment".
文摘With the data observed from the Second SCS Air-Sea Flux Experiment on the Xisha air-sea flux research tower, the radiation budget, latent, sensible heat fluxes and net oceanic heat budgets were caculated before and after summer monsoon onset. It is discovered that, after summer monsoon onset, there are considerable changes in air-sea fluxes, especially in latent heat fluxes and net oceanic heat budget. Furthermore, the analyzed results of five synoptic stages are compared. And the characteristics of the flux transfer during different stages around onset of South China Sea monsoon are discussed. The flux change shows that there is an oceanic heat accumulating process during the pre-onset and the break period, as same as oceanic heat losing process during the onset period. Moreover, latent fluxes, the water vapor moving to the continent, even the rainfall appearance in Chinese Mainland also can be influenced by southwester. Comparing Xisha fluxes with those obtained from the Indian Ocean and the western Pacific Ocean, their differences may be observed. It is the reason why SSTs can keep stable over the South China Sea while they decrease quickly over the Arabian Sea and the Bay of Bengal after monsoon onset.
文摘The ESMD method can be seen as a new alternate of the well-known Hilbert-Huang transform (HHT) for non-steady data processing. It is good at finding the optimal adaptive global mean fitting curve, which is superior to the common least-square method and running-mean approach. Take the air-sea momentum flux investigation as an example, only when the non-turbulent wind components is well extracted, can the remainder signal be seen as actual oscillations caused by turbulence. With the aid of —5/3 power law for the turbulence, a mode-filtering approach based on ESMD decomposition is developed here. The test on observational data indicates that this approach is very feasible and it may greatly reduce the error caused by the non-turbulent components.
基金The National Basic Research Program of China under contract No. 2011CB403501the Fund for Creative Research Groups by NSFC of China under contract No. 40821004+1 种基金the Knowledge Innovation Programs of the Chinese Academy of Sciences under contract No. KZCX2-YW-Q07-02the High-Tech Research and Development Program (863 Program) of China under contract No. 2006AA09A309
文摘A flux system deployed on a moored buoy has been described, which is capable of directly estimating the airsea fluxes after removing the contamination in the signal due to buoy motion. A triple loop fitting method has been demonstrated for determining the three angular offsets between measurement axes of the sonic anemometer and motion pack. The data collected in an experiment in the Northern Huanghai Sea is used to correct the three sonic anemometer measurements of turbulent wind for buoy motion. The effective removal of wave-scale motion from the spectra and cospectra are demonstrated. Estimates of along-wind momentum flux, sensible heat flux and latent heat flux calculated by the eddy correlation method based on data obtained by sonic anemometer 81000V are shown to be in the same trend and scale with those determined by the bulk aerodynamic method after motion correction. The motion correction not only greatly improve the estimation of the momentum flux but also has a great impact on the calculated sensible heat flux.
基金The National Natural Science Foundation of China (NSFC) under contract Nos 40976116 and 40531007the Fujian Science Foundation under contract No.2009J06025+3 种基金the SOA Youth Foundation Grant under contract No.2012538the Chinese Projects for Investigations and Assessments of the Arctic and Antarctic under contract Nos CHINARE2012: 01-04, 02-01, 03-04, 04-03, 04-04, and CHINARE2013: 01-04, 02-01, 03-04, 04-03, 04-04the Chinese International Cooperation Projects under contract Nos IC201114, IC201201, IC201308, and HC120601the Scientific Research Foundation of Third Institute of Oceanography, SOA under contract Nos 2012006 and 2014006
文摘The 3rd Chinese National Arctic Research Expedition (CHINARE-Arctic III) was carried out from July to September in 2008. The partial pressure of CO2 (pCO2) in the atmosphere and in surface seawater were determined in the Bering Sea during luly 11-27, 2008, and a large number of seawater samples were taken for total alkalinity (TA) and total dissolved inorganic carbon (DIC) analysis. The distributions of CO2 parameters in the Bering Sea and their controlling factors were discussed. The pCO2 values in surface seawater presented a drastic variation from 148 to 563 laatm (1 μatm = 1.013 25× 10-1Pa). The lowest pCOz values were observed near the Bering Sea shelf break while the highest pCO2 existed at the western Bering Strait. The Bering Sea generally acts as a net sink for atmospheric CO2 in summer. The air-sea CO2 fluxes in the Bering Sea shelf, slope, and basin were estimated at -9.4, -16.3, and -5.1 mmol/(m2.d), respectively. The annual uptake of CO2 was about 34 Tg C in the Bering Sea.
基金The National Basic Research Program of China under contract No. 2011CB403501the Public Science and Technology Research Funds Projects of Ocean of the State oceanic Administration of China under contract No. 200905012-9+1 种基金the Fund for Creative Research Groups by the National Natural Science Foundation of China under contract No. 41121064the Open Research Foundation for the key Laboratory of Ocean Circulation and Waves.Institute of Oceanology,Chinese Academy of Sciences of China under contract No.KLOCAW1207
文摘Precise measurements of the CO2 gas transfer across the air-sea interface provide a better under- standing of the global carbon cycle. The air-sea CO2 fluxes are obtained by the eddy covariance method and the bulk method from a buoy observation in the northern Huanghai sea. The effects of buoy motion on flux calculated by the eddy covariance method are demonstrated. The research shows that a motion correction can improve the correlation coefficient between the C02 fluxes esti- mated from two different levels. Without the CO2-H20 cross-correlation correction which is termed as PKT correction, the air-sea CO2 fluxes estimated by eddy covariance method using the motion corrected data are nearly an order of magnitude larger than those estimated by the bulk method. After the CO2-H20 cross-correlation correction, some eddy covariance CO2 fluxes indeed become closer to the bulk CO2 flux, whereas some are overcorrected which are in response to small water vapor flux.
基金the World Climate Recruitment Programme’s (WCRP) Working Group on Coupled Modelling (WGCM)the Global Organization for Earth System Science Portals (GO-ESSP)+2 种基金jointly supported by the National Science Foundation of China (Grant Nos. 41991231, 91937302)the China 111 project (Grant No. B13045)supported by Supercomputing Center of Lanzhou University
文摘The measurement of atmospheric O_(2)concentrations and related oxygen budget have been used to estimate terrestrial and oceanic carbon uptake.However,a discrepancy remains in assessments of O_(2)exchange between ocean and atmosphere(i.e.air-sea O_(2)flux),which is one of the major contributors to uncertainties in the O_(2)-based estimations of the carbon uptake.Here,we explore the variability of air-sea O_(2)flux with the use of outputs from Coupled Model Intercomparison Project phase 6(CMIP6).The simulated air-sea O_(2)flux exhibits an obvious warming-induced upward trend(~1.49 Tmol yr−2)since the mid-1980s,accompanied by a strong decadal variability dominated by oceanic climate modes.We subsequently revise the O_(2)-based carbon uptakes in response to this changing air-sea O_(2)flux.Our results show that,for the 1990−2000 period,the averaged net ocean and land sinks are 2.10±0.43 and 1.14±0.52 GtC yr−1 respectively,overall consistent with estimates derived by the Global Carbon Project(GCP).An enhanced carbon uptake is found in both land and ocean after year 2000,reflecting the modification of carbon cycle under human activities.Results derived from CMIP5 simulations also investigated in the study allow for comparisons from which we can see the vital importance of oxygen dataset on carbon uptake estimations.
文摘Indian Central Water (ICW) and Subantarctic Mode Water (SAMW) formation rates are estimated from two air-sea flux products, the Comprehensive Ocean-Atmosphere Data Set (COADS) and the Southampton Oceanography Centre (SOC) climatology. The ICW formation is estimated to be 8 Sv (1 Sv = 106m3·s-1 ) from both products, with more contributions from freshwater flux. From the COADS product, the SAMW formation rate is estimated to be 31 Sv in the potential density range of 26.5-26.9σθ, with also a significant contribution from freshwater flux. However, the SAMW formation rate estimated from the SOC product is much smaller, which may be due to bias of the SOC heat flux. Poorer quality of the flux products in the Southern Ocean may also contribute to the difference.