The key parameters of the adhesive layer of a reinforcing patch are of great significance and affect the ability to suppress crack propagation in an Al–Li alloy patch-reinforced structure.This paper proposes a method...The key parameters of the adhesive layer of a reinforcing patch are of great significance and affect the ability to suppress crack propagation in an Al–Li alloy patch-reinforced structure.This paper proposes a method to determine the key parameters of the adhesive layer of adhesively bonded joints in the Al–Li alloy patch-reinforced structure.A zero-thickness cohesive zone model(CZM)was selected to simulate the adhesive layer’s fracture process,and an orthogonal simulation was designed to compare against the test results.A three-dimensional progressive damage model of an Al–Li alloy patch-reinforced structure with single-lap adhesively bonded joints was developed.The simulation’s results closely agree with the test results,demonstrating that this method of determining the key parameters is likely accurate.The results also verify the correctness of the cohesive strength and fracture energy,the two key parameters of the cohesive zone model.The model can accurately predict the strength and fracture process of adhesively bonded joints,and can be used in research to suppress crack propagation in Al–Li alloy patch-reinforced structures.展开更多
The samples consisting of 100nm Al or Ag film on optical glass substrate were irradiated by a beam of Xe 5×10<sup>15</sup> to 2×10<sup>16</sup> cm<sup>-2</sup> with energy...The samples consisting of 100nm Al or Ag film on optical glass substrate were irradiated by a beam of Xe 5×10<sup>15</sup> to 2×10<sup>16</sup> cm<sup>-2</sup> with energy 320 keV. The adhesion of films on substrates was tested by Xe<sup>+</sup> irradiation. Optical character was measured by spectrophotometer. The ion mixing amount was measured by RBS. The results showed that after ion irradiating the adhesion of the film on the glass is enhanced. The adherent strength is greater than 10 kg/cm<sup>2</sup>. The thermal stability of the films is good. The irradiated film is more optically efficient, the surface is smooth and rendered more corrosion resistance. The mechanism of the film adhesion was discussed.展开更多
The regulation of the burning rate pressure exponent for the ammonium perchlorate/hydroxylterminated polybutadiene/aluminum(AP/HTPB/Al)composite propellants under high pressures is a crucial step for its application i...The regulation of the burning rate pressure exponent for the ammonium perchlorate/hydroxylterminated polybutadiene/aluminum(AP/HTPB/Al)composite propellants under high pressures is a crucial step for its application in high-pressure solid rocket motors.In this work,the combustion characteristics of AP/HTPB/Al composite propellants containing ferrocene-based catalysts were investigated,including the burning rate,thermal behavior,the local heat transfer,and temperature profile in the range of 7-28 MPa.The results showed that the exponent breaks were still observed in the propellants after the addition of positive catalysts(Ce-Fc-MOF),the burning rate inhibitor((Ferrocenylmethyl)trimethylammonium bromide,Fc Br)and the mixture of Fc Br/catocene(GFP).However,the characteristic pressure has increased,and the exponent decreased from 1.14 to 0.66,0.55,and 0.48 when the addition of Ce-FcMOF,Fc Br and Fc Br/GFP in the propellants.In addition,the temperature in the first decomposition stage was increased by 7.50℃ and 11.40℃ for the AP/Fc Br mixture and the AP/Fc Br/GFP mixture,respectively,compared to the pure AP.On the other hand,the temperature in the second decomposition stage decreased by 48.30℃ and 81.70℃ for AP/Fc Br and AP/Fc Br/GFP mixtures,respectively.It was also found that Fc Br might generate ammonia to cover the AP surface.In this case,a reaction between the methyl in Fc Br and perchloric acid caused more ammonia to appear at the AP surface,resulting in the suppression of ammonia desorption.In addition,the coarse AP particles on the quenched surface were of a concave shape relative to the binder matrix under low and high pressures when the catalysts were added.In the process,the decline at the AP/HTPB interface was only exhibited in the propellant with the addition of Ce-Fc-MOF.The ratio of the gas-phase temperature gradient of the propellants containing catalysts was reduced significantly below and above the characteristic pressure,rather than 3.6 times of the difference in the blank propellant.Overall,the obtained results demonstrated that the pressure exponent could be effectively regulated and controlled by adjusting the propellant local heat and mass transfer under high and low pressures.展开更多
基金Project(51575535)supported by the National Natural Science Foundation of ChinaProject(2015CX002)supported by the Innovation-driven Plan in Central South University,China+2 种基金Project(zzyjkt2013-09B)supported by the Fund of the State Key Laboratory of High Performance Manufacturing,ChinaProject(2017zzts638)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(2016RS2015)supported by the Scientific and Technological Leading Talent Projects of Hunan Province,China
文摘The key parameters of the adhesive layer of a reinforcing patch are of great significance and affect the ability to suppress crack propagation in an Al–Li alloy patch-reinforced structure.This paper proposes a method to determine the key parameters of the adhesive layer of adhesively bonded joints in the Al–Li alloy patch-reinforced structure.A zero-thickness cohesive zone model(CZM)was selected to simulate the adhesive layer’s fracture process,and an orthogonal simulation was designed to compare against the test results.A three-dimensional progressive damage model of an Al–Li alloy patch-reinforced structure with single-lap adhesively bonded joints was developed.The simulation’s results closely agree with the test results,demonstrating that this method of determining the key parameters is likely accurate.The results also verify the correctness of the cohesive strength and fracture energy,the two key parameters of the cohesive zone model.The model can accurately predict the strength and fracture process of adhesively bonded joints,and can be used in research to suppress crack propagation in Al–Li alloy patch-reinforced structures.
文摘The samples consisting of 100nm Al or Ag film on optical glass substrate were irradiated by a beam of Xe 5×10<sup>15</sup> to 2×10<sup>16</sup> cm<sup>-2</sup> with energy 320 keV. The adhesion of films on substrates was tested by Xe<sup>+</sup> irradiation. Optical character was measured by spectrophotometer. The ion mixing amount was measured by RBS. The results showed that after ion irradiating the adhesion of the film on the glass is enhanced. The adherent strength is greater than 10 kg/cm<sup>2</sup>. The thermal stability of the films is good. The irradiated film is more optically efficient, the surface is smooth and rendered more corrosion resistance. The mechanism of the film adhesion was discussed.
基金the support of the National Natural Science Foundation of China grant number 51776175。
文摘The regulation of the burning rate pressure exponent for the ammonium perchlorate/hydroxylterminated polybutadiene/aluminum(AP/HTPB/Al)composite propellants under high pressures is a crucial step for its application in high-pressure solid rocket motors.In this work,the combustion characteristics of AP/HTPB/Al composite propellants containing ferrocene-based catalysts were investigated,including the burning rate,thermal behavior,the local heat transfer,and temperature profile in the range of 7-28 MPa.The results showed that the exponent breaks were still observed in the propellants after the addition of positive catalysts(Ce-Fc-MOF),the burning rate inhibitor((Ferrocenylmethyl)trimethylammonium bromide,Fc Br)and the mixture of Fc Br/catocene(GFP).However,the characteristic pressure has increased,and the exponent decreased from 1.14 to 0.66,0.55,and 0.48 when the addition of Ce-FcMOF,Fc Br and Fc Br/GFP in the propellants.In addition,the temperature in the first decomposition stage was increased by 7.50℃ and 11.40℃ for the AP/Fc Br mixture and the AP/Fc Br/GFP mixture,respectively,compared to the pure AP.On the other hand,the temperature in the second decomposition stage decreased by 48.30℃ and 81.70℃ for AP/Fc Br and AP/Fc Br/GFP mixtures,respectively.It was also found that Fc Br might generate ammonia to cover the AP surface.In this case,a reaction between the methyl in Fc Br and perchloric acid caused more ammonia to appear at the AP surface,resulting in the suppression of ammonia desorption.In addition,the coarse AP particles on the quenched surface were of a concave shape relative to the binder matrix under low and high pressures when the catalysts were added.In the process,the decline at the AP/HTPB interface was only exhibited in the propellant with the addition of Ce-Fc-MOF.The ratio of the gas-phase temperature gradient of the propellants containing catalysts was reduced significantly below and above the characteristic pressure,rather than 3.6 times of the difference in the blank propellant.Overall,the obtained results demonstrated that the pressure exponent could be effectively regulated and controlled by adjusting the propellant local heat and mass transfer under high and low pressures.
