The interfacial reaction behavior of Al and Ti_3AlC_(2)at different pouring temperatures and its effect on the microstructure and mechanical properties of the composites were investigated.The results show that the add...The interfacial reaction behavior of Al and Ti_3AlC_(2)at different pouring temperatures and its effect on the microstructure and mechanical properties of the composites were investigated.The results show that the addition of3.0 wt.%Ti_3AlC_(2)refines the average grain size ofα(Al)in the composite by 50.1%compared to Al6061 alloy.Morphological analyses indicate that an in-situ Al_(3Ti)transition layer of-180 nm in thickness is generated around the edge of Ti_3AlC_(2)at 720℃,forming a well-bonded Al-Al_(3Ti)interface.At this processing temperature,the ultimate tensile strength of A16061-3.0 wt.%Ti_3AlC_(2)composite is 199.2 MPa,an improvement of 41.5%over the Al6061 matrix.Mechanism analyses further elucidate that 720℃is favourable for forming the nano-sized transition layer at the Ti_3AlC_(2)edges.And,the thermal mismatch strengthening plays a dominant role in this state,with a strengthening contribution of about 74.8%.展开更多
The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted...The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted by transmission electron microscope（TEM）, scanning electron microscope（SEM）, peeling tests and tensile tests. It is found that the ultra-fine grained laminated composites with tight bonding interface are prepared by the roll bonding technique. The annealing prompts the atomic diffusion in the interface between dissimilar matrixes, and even causes the formation of intermetallic compounds. The interfacial bonding strength increases to the maximum value owing to the interfacial solution strengthening at 300 °C annealing, but sharply decreases by the damage effect of intermetallic compounds at elevated temperatures. The composites obtain high tensile strength due to the Al crystallization grains and Cu twins at 300 °C. At 350 °C annealing, however, the composites get high elongation by the interfacial interlayer with submicron thickness.展开更多
Laminated metal composites(LMCs) are a unique composite material and have great application prospects in automobiles, ships, aircraft,and other manufacturing industries. As lightweight materials, the Mg/Al LMCs are ex...Laminated metal composites(LMCs) are a unique composite material and have great application prospects in automobiles, ships, aircraft,and other manufacturing industries. As lightweight materials, the Mg/Al LMCs are expected to combine the advantages of both Mg and Al alloys to broaden their application prospects. Roll-bonding is the most popular process for the fabrication of Mg/Al LMCs due to high production efficiency and good product quality stability. The roll-bonding process involves the deformation of the substrates and the formation of the interfacial diffusion layer. The latter will directly determine the interface bonding strength of Mg/Al LMCs. Bonding strength is very sensitive to the thickness of the reaction layer in the diffusion layer. When the thickness of the reaction layer exceeds 5 μm, the bonding strength decreases sharply. Therefore, controlling the thickness of the reaction layer is very important for the design of rolling parameters.The latest research also showed that the addition of intermediate layer metal and the construction of three-dimensional interfaces can further improve the interface bonding strength. How to apply these methods to roll-bonding is the focus of future research. Recently, a new rolling technique, corrugated roll/plat roll rolling+flat roll/flat roll rolling has been developed to fabricate Mg/Al LMCs. It can effectively promote the deformation of the hard layer and generate a wavy interface, resulting in the enhancement of the bonding quality and rolling quality.In the current review, the effects of rolling parameters and subsequent annealing on the interface structure of Mg/Al LMCs were elaborated in detail. The application of some special rolling techniques in the preparation of Mg/Al LMCs was also summarized. The latest research results on the relationship between interface structure and mechanical properties of Mg/Al LMCs were reviewed. Finally, further research directions in this field were proposed.展开更多
Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al inte...Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al interface;most of TiAl_(3) grains were fine equiaxed with average sizes ranging from hundreds of nanometers to several microns and the TiAl_(3) grain size increased with increasing annealing time and/or temperature,but the effect of annealing temperature on the TiAl_(3) grain size was far greater than that of annealing time.The growth of the TiAl_(3) phase consisted of two stages.The initial stage was governed by chemical reaction with a reaction activation energy of 195.75 kJ/mol,and the reaction rate constant of the TiAl_(3) phase was larger as the Ti/Al interface was bonded with fresh surfaces.At the second stage,the growth was governed by diffusion,the diffusion activation energy was 33.69 kJ/mol,and the diffusion growth rate constant of the TiAl_(3) phase was mainly determined by the grain boundary diffusion owing to the smaller TiAl_(3) grain size.展开更多
Ti/Cu/Ti laminated composites were fabricated by corrugated rolling(CR) and flat rolling(FR) method.Microstructure and mechanical properties of CR and FR laminated composites were investigated by scanning electron mic...Ti/Cu/Ti laminated composites were fabricated by corrugated rolling(CR) and flat rolling(FR) method.Microstructure and mechanical properties of CR and FR laminated composites were investigated by scanning electron microscopy, numerical simulation methods, peel and tensile examinations. The effect of CR and FR was comparatively analyzed. The results showed that the CR and FR laminated composites exhibited different effective plastic strain distributions of the Ti layer and Cu layer at the interface. The recrystallization texture, prismatic texture and pyramidal texture were developed in the Ti layer by CR, while the R-Goss texture and shear texture were developed in the Cu layer by CR. The typical deformation texture components were developed in the Ti layer and Cu layer of FR laminated composites. The CR laminated composites had higher bond strength, tensile strength and ductility.展开更多
In this study,HEA/AI composite interlayer was used to fabricate Ti/Mg bimetal composites by solidliquid compound casting process.The Al layer was prepared on the surface of TC4 alloy by hot dipping,and the FeCoNiCr HE...In this study,HEA/AI composite interlayer was used to fabricate Ti/Mg bimetal composites by solidliquid compound casting process.The Al layer was prepared on the surface of TC4 alloy by hot dipping,and the FeCoNiCr HEA layer was prepared by magnetron sputtering onto the Al layer.The influence of the HEA layer thickness and pouring temperature on interface evolution was investigated based on SEM observation and thermodynamic analysis.Results indicate that the sluggish diffusion effect of HEA can effectively inhibit the interfacial diffusion between Al and Mg,which is conducive to the formation of solid solution,especially when the thickness of HEA is 800 nm.With the increase of casting temperature from 720 ℃ to 730 ℃,740℃,and 750 ℃,α-Al(Mg),α-Al(Mg)+Al3Mg2,Al3Mg2+Al12Mg17,and Al12Mg17+δ-Mg are formed at the interface of Ti/Mg bimetal,respectively.When the thickness of the HEA layer is 800 nm and the pouring temperature is 720 ℃,the bonding strength of the Ti/Mg bimetal can reach the maximum of 93.6 MPa.展开更多
Al-Al3Ti composites were prepared by a direct reaction method, in which Al3Ti was formed by the reaction of Ti and Al in aluminum alloy melt. The morphology of Al3Ti changes apparently from the fine particle, needle-l...Al-Al3Ti composites were prepared by a direct reaction method, in which Al3Ti was formed by the reaction of Ti and Al in aluminum alloy melt. The morphology of Al3Ti changes apparently from the fine particle, needle-like to large block with the increase of Al3Ti content. The addition of magnesium can markedly change the morphology of Al3Ti and reduce their size. Short rod-like Al3Ti was formed and homogeneous distribution was obtained with the addition of 3 wt.% Mg. The effect of Al3Ti and Mg on the microstructure of Al-Al3Ti composites and the mechanism were also discussed.展开更多
An Al-based composite reinforced with core–shell-structured Ti/Al_3Ti was fabricated through a powder metallurgy route followed by hot extrusion and was found to exhibit promising mechanical properties. The ultimate ...An Al-based composite reinforced with core–shell-structured Ti/Al_3Ti was fabricated through a powder metallurgy route followed by hot extrusion and was found to exhibit promising mechanical properties. The ultimate tensile strength and elongation of the composite sintered at 620°C for 5 h and extruded at a mass ratio of 12.75:1 reached 304 MPa and 14%, respectively, and its compressive deformation reached 60%. The promising mechanical properties are due to the core–shell-structured reinforcement, which is mainly composed of Al_3Ti and Ti and is bonded strongly with the Al matrix, and to the reduced crack sensitivity of Al_3Ti. The refined grains after hot extrusion also contribute to the mechanical properties of this composite. The mechanical properties might be further improved through regulating the relative thickness of Al–Ti intermetallics and Ti metal layers by adjusting the sintering time and the subsequent extrusion process.展开更多
Nb and Ti-13 Nb powders were used for improving the surface of Ti6Al4 V alloy.The deposition of the powders was carried out at various laser powers.The scanning electron microscopy（SEM）-EDS and optical microscopy we...Nb and Ti-13 Nb powders were used for improving the surface of Ti6Al4 V alloy.The deposition of the powders was carried out at various laser powers.The scanning electron microscopy（SEM）-EDS and optical microscopy were used for characterization.X-ray diffractometer（XRD） was used for analyzing the elemental composition and phase constituents.The hardness,wear and corrosion properties were achieved.The corrosion and the wear behaviours of the deposited layers were studied in a Hanks solution（simulated body fluid,SBF）.The microstructures of Nb coatings reveal the presence of orthorhombic,dendritic α″ and metastable β-Nb phases which produce uneven hardness with an average of HV 364.For Ti-13 Nb coatings,martensitic α′ and metastable β-Nb phases with an average hardness of HV 423 were observed.The resistance of wear on dry sliding of Ti-13 Nb coating is attributed to the increase in hardness.Experimental results indicate that deposition of Nb and Ti-13 Nb on Ti6Al4 V grossly reduces the mass fractions of Al and V in all coatings.In SBF,Nb reinforcement produces the best coating that reveals the best wear and corrosion resistances as compared with the substrate.Hence,this coating will perform best for orthopaedic implant material enhancement.展开更多
A novel technique for fabricating TiB_2/Al composites in molten aluminum was introduced. The formation mechanism of brittleAl,Ti particulates up to 30 m in size produced in the composites was studied and a method of e...A novel technique for fabricating TiB_2/Al composites in molten aluminum was introduced. The formation mechanism of brittleAl,Ti particulates up to 30 m in size produced in the composites was studied and a method of eliminating them was proposed. The resultsshow that (l) the brittle Al,Ti particulates are always present in the composites when the molar ratio of Ti to B 'T,:nB is l:2; and (2) theformation of the brittle Al,Ti phase can be avoided entirely from the final product by using a proper 'T,:nB of l:4 in the Ti-B-Al preforms.In the former case, the tensile elongation of the composite is only 4%, much lower than the value of pure aluminum (20%). In the latercase, the tensile elongation of this composite is 10%, higher than the value of the composite with a lot ofAl,Ti (4%), whereas the ultimatetensile stfength of the former is nearly that of the later.展开更多
SiC/7075 aluminum matrix composites were prepared by a liquid stirring method.The role of Ti facilitating the preparation of SiC/7075 aluminum matrix were studied by means of direct-reading spectrometer,scanning elect...SiC/7075 aluminum matrix composites were prepared by a liquid stirring method.The role of Ti facilitating the preparation of SiC/7075 aluminum matrix were studied by means of direct-reading spectrometer,scanning electron microscope,energy dispersive spectrometer,X-ray diffraction and the sessile drop method.The results show that the SiC content in the SiC/7075 composite increases with an increase of Ti addition.The addition of Ti can significantly improve the wettability of SiC/Al system,there is a critical value of above 0.5%of Ti content in improving the wettability of the Al/SiC system at 1173K.The temperature of the"non wetting-wetting"transition for the(Al-2Ti)/SiC system is about 1123K,the contact angle decreases to 88°at 200 seconds and reaches a stable contact angle of 28°at 2100 seconds.展开更多
In situ Al2O3 whiskers reinforced Ti-Al intermetallic composites were fabricated at ~1200℃ by reaction sintering of cold-consolidated fillets consisting mainly of Ti, Al, and different additives. The phases and micro...In situ Al2O3 whiskers reinforced Ti-Al intermetallic composites were fabricated at ~1200℃ by reaction sintering of cold-consolidated fillets consisting mainly of Ti, Al, and different additives. The phases and microstructures of the sintered composites were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS). The process of synthesis was investigated using differential thermal analysis (DTA). The effects of processing parameters and additives on the microstructures of the composites and the development of whisker were examined. It is found that the morphology of the whisker is strongly influenced by the additives, the exothermal reaction process, and the processing parameters.展开更多
Anodized composite films containing Si C nanoparticles were synthesized on Ti6Al4 V alloy by anodic oxidation procedure in C4O6H4Na2 electrolyte. Scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) ...Anodized composite films containing Si C nanoparticles were synthesized on Ti6Al4 V alloy by anodic oxidation procedure in C4O6H4Na2 electrolyte. Scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS) were employed to characterize the morphology and composition of the films fabricated in the electrolytes with and without addition of Si C nanoparticles. Results show that Si C particles can be successfully incorporated into the oxide film during the anodizing process and preferentially concentrate within internal cavities and micro-cracks. The ball-on-disk sliding tests indicate that Si C-containing oxide films register much lower wear rate than the oxide films without Si C under dry sliding condition. Si C particles are likely to melt and then are oxidized by frictional heat during sliding tests. Potentiodynamic polarization behavior reveals that the anodized alloy with Si C nanoparticles results in a reduction in passive current density to about 1.54×10-8 A/cm2, which is more than two times lower than that of the Ti O2 film(3.73×10-8 A/cm2). The synthesized composite film has good anti-wear and anti-corrosion properties and the growth mechanism of nanocomposite film is also discussed.展开更多
It is showed that there are Ti 3Al, Ti 2Cu and β phase in the interface of Ti/Ti Al composites reinforced with Y 2O 3 Cr composite soft coated Ti fiber, and that interface bonding is intact. Bending strength ...It is showed that there are Ti 3Al, Ti 2Cu and β phase in the interface of Ti/Ti Al composites reinforced with Y 2O 3 Cr composite soft coated Ti fiber, and that interface bonding is intact. Bending strength of the composites can be increased by 26%, to 709 MPa, and bending deflection increased slightly compared with the Ti/Ti Al composites reinforced by Ti fibers coated with Y 2O 3.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51965040)Science and Technology Project of Jiangxi Provincial Department of Transportation,China(No.2022H0048)。
文摘The interfacial reaction behavior of Al and Ti_3AlC_(2)at different pouring temperatures and its effect on the microstructure and mechanical properties of the composites were investigated.The results show that the addition of3.0 wt.%Ti_3AlC_(2)refines the average grain size ofα(Al)in the composite by 50.1%compared to Al6061 alloy.Morphological analyses indicate that an in-situ Al_(3Ti)transition layer of-180 nm in thickness is generated around the edge of Ti_3AlC_(2)at 720℃,forming a well-bonded Al-Al_(3Ti)interface.At this processing temperature,the ultimate tensile strength of A16061-3.0 wt.%Ti_3AlC_(2)composite is 199.2 MPa,an improvement of 41.5%over the Al6061 matrix.Mechanism analyses further elucidate that 720℃is favourable for forming the nano-sized transition layer at the Ti_3AlC_(2)edges.And,the thermal mismatch strengthening plays a dominant role in this state,with a strengthening contribution of about 74.8%.
基金Projects(50971038,51174058)supported by the National Natural Science Foundation of China
文摘The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted by transmission electron microscope（TEM）, scanning electron microscope（SEM）, peeling tests and tensile tests. It is found that the ultra-fine grained laminated composites with tight bonding interface are prepared by the roll bonding technique. The annealing prompts the atomic diffusion in the interface between dissimilar matrixes, and even causes the formation of intermetallic compounds. The interfacial bonding strength increases to the maximum value owing to the interfacial solution strengthening at 300 °C annealing, but sharply decreases by the damage effect of intermetallic compounds at elevated temperatures. The composites obtain high tensile strength due to the Al crystallization grains and Cu twins at 300 °C. At 350 °C annealing, however, the composites get high elongation by the interfacial interlayer with submicron thickness.
基金supported by Guangdong Major Project of Basic and Applied Basic Research,No. 2020B0301030006。
文摘Laminated metal composites(LMCs) are a unique composite material and have great application prospects in automobiles, ships, aircraft,and other manufacturing industries. As lightweight materials, the Mg/Al LMCs are expected to combine the advantages of both Mg and Al alloys to broaden their application prospects. Roll-bonding is the most popular process for the fabrication of Mg/Al LMCs due to high production efficiency and good product quality stability. The roll-bonding process involves the deformation of the substrates and the formation of the interfacial diffusion layer. The latter will directly determine the interface bonding strength of Mg/Al LMCs. Bonding strength is very sensitive to the thickness of the reaction layer in the diffusion layer. When the thickness of the reaction layer exceeds 5 μm, the bonding strength decreases sharply. Therefore, controlling the thickness of the reaction layer is very important for the design of rolling parameters.The latest research also showed that the addition of intermediate layer metal and the construction of three-dimensional interfaces can further improve the interface bonding strength. How to apply these methods to roll-bonding is the focus of future research. Recently, a new rolling technique, corrugated roll/plat roll rolling+flat roll/flat roll rolling has been developed to fabricate Mg/Al LMCs. It can effectively promote the deformation of the hard layer and generate a wavy interface, resulting in the enhancement of the bonding quality and rolling quality.In the current review, the effects of rolling parameters and subsequent annealing on the interface structure of Mg/Al LMCs were elaborated in detail. The application of some special rolling techniques in the preparation of Mg/Al LMCs was also summarized. The latest research results on the relationship between interface structure and mechanical properties of Mg/Al LMCs were reviewed. Finally, further research directions in this field were proposed.
基金the financial supports from the S&T Program of Hebei Province,China(No.20373901D)the National Natural Science Foundation of China(Nos.51807047,51804095)+2 种基金the National Science Foundation of Hebei Province,China(No.E2019402433)the Youth Top Talents Science and Technology Research Project of Hebei Province University,China(No.BJ2019003)the Research and Development Project of Science and Technology of Handan City,China(No.19422111008-19).
文摘Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al interface;most of TiAl_(3) grains were fine equiaxed with average sizes ranging from hundreds of nanometers to several microns and the TiAl_(3) grain size increased with increasing annealing time and/or temperature,but the effect of annealing temperature on the TiAl_(3) grain size was far greater than that of annealing time.The growth of the TiAl_(3) phase consisted of two stages.The initial stage was governed by chemical reaction with a reaction activation energy of 195.75 kJ/mol,and the reaction rate constant of the TiAl_(3) phase was larger as the Ti/Al interface was bonded with fresh surfaces.At the second stage,the growth was governed by diffusion,the diffusion activation energy was 33.69 kJ/mol,and the diffusion growth rate constant of the TiAl_(3) phase was mainly determined by the grain boundary diffusion owing to the smaller TiAl_(3) grain size.
基金financially supported by the National Key R&D Program of China (No.2018YFA0707300)the Natural Science Foundation of Shanxi Province,China (No.201801D221131)+2 种基金the National Natural Science Foundation of China (Nos.51905372,51904206,51805359,52075359)Shanxi Province Science and Technology Major Project,China (No.20181102011)China Postdoctoral Science Foundation (No.2020M670705)。
文摘Ti/Cu/Ti laminated composites were fabricated by corrugated rolling(CR) and flat rolling(FR) method.Microstructure and mechanical properties of CR and FR laminated composites were investigated by scanning electron microscopy, numerical simulation methods, peel and tensile examinations. The effect of CR and FR was comparatively analyzed. The results showed that the CR and FR laminated composites exhibited different effective plastic strain distributions of the Ti layer and Cu layer at the interface. The recrystallization texture, prismatic texture and pyramidal texture were developed in the Ti layer by CR, while the R-Goss texture and shear texture were developed in the Cu layer by CR. The typical deformation texture components were developed in the Ti layer and Cu layer of FR laminated composites. The CR laminated composites had higher bond strength, tensile strength and ductility.
基金financial supports from the National Natural Science Foundation of China (No. 51875062)China Postdoctoral Science Foundation (No. 2021M700567)。
文摘In this study,HEA/AI composite interlayer was used to fabricate Ti/Mg bimetal composites by solidliquid compound casting process.The Al layer was prepared on the surface of TC4 alloy by hot dipping,and the FeCoNiCr HEA layer was prepared by magnetron sputtering onto the Al layer.The influence of the HEA layer thickness and pouring temperature on interface evolution was investigated based on SEM observation and thermodynamic analysis.Results indicate that the sluggish diffusion effect of HEA can effectively inhibit the interfacial diffusion between Al and Mg,which is conducive to the formation of solid solution,especially when the thickness of HEA is 800 nm.With the increase of casting temperature from 720 ℃ to 730 ℃,740℃,and 750 ℃,α-Al(Mg),α-Al(Mg)+Al3Mg2,Al3Mg2+Al12Mg17,and Al12Mg17+δ-Mg are formed at the interface of Ti/Mg bimetal,respectively.When the thickness of the HEA layer is 800 nm and the pouring temperature is 720 ℃,the bonding strength of the Ti/Mg bimetal can reach the maximum of 93.6 MPa.
文摘Al-Al3Ti composites were prepared by a direct reaction method, in which Al3Ti was formed by the reaction of Ti and Al in aluminum alloy melt. The morphology of Al3Ti changes apparently from the fine particle, needle-like to large block with the increase of Al3Ti content. The addition of magnesium can markedly change the morphology of Al3Ti and reduce their size. Short rod-like Al3Ti was formed and homogeneous distribution was obtained with the addition of 3 wt.% Mg. The effect of Al3Ti and Mg on the microstructure of Al-Al3Ti composites and the mechanism were also discussed.
基金financially supported by the Science and Technology Plan Item of Liaoning Province (No.201601174)the National Natural Science Foundation of China (No.51371121)
文摘An Al-based composite reinforced with core–shell-structured Ti/Al_3Ti was fabricated through a powder metallurgy route followed by hot extrusion and was found to exhibit promising mechanical properties. The ultimate tensile strength and elongation of the composite sintered at 620°C for 5 h and extruded at a mass ratio of 12.75:1 reached 304 MPa and 14%, respectively, and its compressive deformation reached 60%. The promising mechanical properties are due to the core–shell-structured reinforcement, which is mainly composed of Al_3Ti and Ti and is bonded strongly with the Al matrix, and to the reduced crack sensitivity of Al_3Ti. The refined grains after hot extrusion also contribute to the mechanical properties of this composite. The mechanical properties might be further improved through regulating the relative thickness of Al–Ti intermetallics and Ti metal layers by adjusting the sintering time and the subsequent extrusion process.
基金financially supported by the National Research Foundation of South AfricaThe National Laser Centre,CSIR,Pretoria,South Africa,is appreciated for laser facilitythe support from Tshwane University of Technology,South Africa
文摘Nb and Ti-13 Nb powders were used for improving the surface of Ti6Al4 V alloy.The deposition of the powders was carried out at various laser powers.The scanning electron microscopy（SEM）-EDS and optical microscopy were used for characterization.X-ray diffractometer（XRD） was used for analyzing the elemental composition and phase constituents.The hardness,wear and corrosion properties were achieved.The corrosion and the wear behaviours of the deposited layers were studied in a Hanks solution（simulated body fluid,SBF）.The microstructures of Nb coatings reveal the presence of orthorhombic,dendritic α″ and metastable β-Nb phases which produce uneven hardness with an average of HV 364.For Ti-13 Nb coatings,martensitic α′ and metastable β-Nb phases with an average hardness of HV 423 were observed.The resistance of wear on dry sliding of Ti-13 Nb coating is attributed to the increase in hardness.Experimental results indicate that deposition of Nb and Ti-13 Nb on Ti6Al4 V grossly reduces the mass fractions of Al and V in all coatings.In SBF,Nb reinforcement produces the best coating that reveals the best wear and corrosion resistances as compared with the substrate.Hence,this coating will perform best for orthopaedic implant material enhancement.
文摘A novel technique for fabricating TiB_2/Al composites in molten aluminum was introduced. The formation mechanism of brittleAl,Ti particulates up to 30 m in size produced in the composites was studied and a method of eliminating them was proposed. The resultsshow that (l) the brittle Al,Ti particulates are always present in the composites when the molar ratio of Ti to B 'T,:nB is l:2; and (2) theformation of the brittle Al,Ti phase can be avoided entirely from the final product by using a proper 'T,:nB of l:4 in the Ti-B-Al preforms.In the former case, the tensile elongation of the composite is only 4%, much lower than the value of pure aluminum (20%). In the latercase, the tensile elongation of this composite is 10%, higher than the value of the composite with a lot ofAl,Ti (4%), whereas the ultimatetensile stfength of the former is nearly that of the later.
基金the Natural Science Foundation of Shanxi Province,China(No.201801D121108)。
文摘SiC/7075 aluminum matrix composites were prepared by a liquid stirring method.The role of Ti facilitating the preparation of SiC/7075 aluminum matrix were studied by means of direct-reading spectrometer,scanning electron microscope,energy dispersive spectrometer,X-ray diffraction and the sessile drop method.The results show that the SiC content in the SiC/7075 composite increases with an increase of Ti addition.The addition of Ti can significantly improve the wettability of SiC/Al system,there is a critical value of above 0.5%of Ti content in improving the wettability of the Al/SiC system at 1173K.The temperature of the"non wetting-wetting"transition for the(Al-2Ti)/SiC system is about 1123K,the contact angle decreases to 88°at 200 seconds and reaches a stable contact angle of 28°at 2100 seconds.
基金This work was supported by the National Natural Science Foundation of China (No. 50432010, 50372037).
文摘In situ Al2O3 whiskers reinforced Ti-Al intermetallic composites were fabricated at ~1200℃ by reaction sintering of cold-consolidated fillets consisting mainly of Ti, Al, and different additives. The phases and microstructures of the sintered composites were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS). The process of synthesis was investigated using differential thermal analysis (DTA). The effects of processing parameters and additives on the microstructures of the composites and the development of whisker were examined. It is found that the morphology of the whisker is strongly influenced by the additives, the exothermal reaction process, and the processing parameters.
基金Project(51271012)supported by the National Natural Science Foundation of China
文摘Anodized composite films containing Si C nanoparticles were synthesized on Ti6Al4 V alloy by anodic oxidation procedure in C4O6H4Na2 electrolyte. Scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS) were employed to characterize the morphology and composition of the films fabricated in the electrolytes with and without addition of Si C nanoparticles. Results show that Si C particles can be successfully incorporated into the oxide film during the anodizing process and preferentially concentrate within internal cavities and micro-cracks. The ball-on-disk sliding tests indicate that Si C-containing oxide films register much lower wear rate than the oxide films without Si C under dry sliding condition. Si C particles are likely to melt and then are oxidized by frictional heat during sliding tests. Potentiodynamic polarization behavior reveals that the anodized alloy with Si C nanoparticles results in a reduction in passive current density to about 1.54×10-8 A/cm2, which is more than two times lower than that of the Ti O2 film(3.73×10-8 A/cm2). The synthesized composite film has good anti-wear and anti-corrosion properties and the growth mechanism of nanocomposite film is also discussed.
文摘It is showed that there are Ti 3Al, Ti 2Cu and β phase in the interface of Ti/Ti Al composites reinforced with Y 2O 3 Cr composite soft coated Ti fiber, and that interface bonding is intact. Bending strength of the composites can be increased by 26%, to 709 MPa, and bending deflection increased slightly compared with the Ti/Ti Al composites reinforced by Ti fibers coated with Y 2O 3.
