Synchrotron X-ray radiography was used to carry out an in-situ observation of the hydrogen bubble evolution in the liquid Al/solid Ni interconnection. The individual bubble mainly grows in a stochastic way during heat...Synchrotron X-ray radiography was used to carry out an in-situ observation of the hydrogen bubble evolution in the liquid Al/solid Ni interconnection. The individual bubble mainly grows in a stochastic way during heating. The size distribution for groups of bubbles follows a Gaussian distribution in the early stage and Lifshitz-Slyozov-Wagner(LSW) diffusion controlled distribution in the final stage. The intermetallic compounds(IMCs) first form during solidification, following by the hydrogen bubbles. The bubbles between two adjacent Al3Ni grains grow unidirectionally along the liquid channel, with the bottom being impeded by the Al3Ni phase and the radius of the growth front being smaller. For the bubbles at triple junctions, they grow along the liquid channel and the crack with morphology transition.展开更多
The semi-solid slurry of an A356 Al alloy, which was grain-fined by yttrium, was manufactured by low temperature pouring, The effects of grain-refining on the morphology and the grain size of the primary α phase in t...The semi-solid slurry of an A356 Al alloy, which was grain-fined by yttrium, was manufactured by low temperature pouring, The effects of grain-refining on the morphology and the grain size of the primary α phase in the semi-solid A356 Al alloy were researched. The results indicate that the semi-solid A356 AI alloy with particle-like and rosette-like primary α-Al can be prepared by low temperature pouring from a liquid grain-refined A356 alloy. The grain size and particle morphology of primary α-Al in the A356 Al alloy are markedly improved by the addition of 0.5 wt,% Y. The fining mechanism of Y on the morphology and grain size of the primary α-Al in the semi-solid A356 Al alloy was delved.展开更多
The semi-solid slurry of A356 Al alloy was manufactured by low superheat pouring and weak electromagnetic stirring. The effects of pouring temperature on the slurry manufactured by weak electromagnetic stirring were r...The semi-solid slurry of A356 Al alloy was manufactured by low superheat pouring and weak electromagnetic stirring. The effects of pouring temperature on the slurry manufactured by weak electromagnetic stirring were researched. The results indicate that it is feasible to manufacture the slurry with particle-like primary phases by low superheat pouring and weak electromagnetic stirring, and there is an important effect of the pouring temperature (superheat temperature) on the morphology and the size of primaryα-Al in A356 Al alloy. By the action of suitable weak electromagnetic stirring, increasing pouring temperature to put low superheat pouring in practice is capable of obtaining semi-solid slurry of A356 Al alloy with particle-like primary phase. Compared with the samples made only by low superheat pouring without stirring, raising pouring temperature by 15-35 ℃ above the liquidus temperature under condition of weak electromagnetic stirring can ensure the same grain size and morphology of the primary phase.展开更多
The slurry of Al-20Sn alloy was prepared using electromagnetic-mechanical stirring method. The bonding of steel/mushy Al-20Sn was conducted using casting rolling technique. The bonding parameters were 505 ℃ for prehe...The slurry of Al-20Sn alloy was prepared using electromagnetic-mechanical stirring method. The bonding of steel/mushy Al-20Sn was conducted using casting rolling technique. The bonding parameters were 505 ℃ for preheat temperature of steel plate and 10 mm/s for rolling speed. The interfacial mechanical property and structure of steel/mushy Al-20Sn bonding plate were studied. The results show that the relationship between solid fraction of Al-20Sn slurry and interfacial shear strength of bonding plate is S=52.9+0.998φ s-0.014 4φ 2 s (where S is interfacial shear strength, φ s is solid fraction). The largest interfacial shear strength is 70.2 MPa when solid fraction is 34.6%. The interface of bonding plate is made up of Fe-Al compound and Fe-Al solid solution alternatively.展开更多
For the wider applications,it is necessary to improve the ductility as well as the strength and wear-resistance of hypereutectic AlSi-Cu alloys,which are typical light-weight wear-resistant materials.An increase in th...For the wider applications,it is necessary to improve the ductility as well as the strength and wear-resistance of hypereutectic AlSi-Cu alloys,which are typical light-weight wear-resistant materials.An increase in the amounts of primary silicon particles causes the modified wear-resistance of hypereutectic Al-Si-Cu alloys,but leads to the poor strength and ductility.It is known that dual phase steels composed of hetero-structure have succeeded in bringing contradictory mechanical properties of high strength and ductility concurrently.In order to apply the idea of hetero-structure to hypereutectic Al-Si-Cu alloys for the achievement of high strength and ductility along with wear resistance,ultrasonic irradiation of the molten metal during the solidification,which is called sono-solidification,was carried out from its molten state to just above the eutectic temperature.The sono-solidified Al-17Si-4Cu alloy is composed of hetero-structure,which are,hard primary silicon particles,soft non-equilibrium a-Al phase and the eutectic region.Rheo-casting was performed at just above the eutectic temperature with sono-solidified slurry to shape a disk specimen.After the rheo-casting with modified sonosolidified slurry held for 45 s at 570 oC,the quantitative optical microscope observation exhibits that the microstructure is composed of 18area%of hard primary silicon particles and 57area%of soft a-Al phase.In contrast,there exist only 5 area%of primary silicon particles and no a-Al phase in rheo-cast specimen with normally solidified slurry.Hence the tensile tests of T6 treated rheo-cast specimens with modified sono-solidified slurry exhibit improved strength and 5%of elongation,regardless of having more than 3 times higher amounts of primary silicon particles compared to that of rheo-cast specimen with normally solidified slurry.展开更多
The influence of solid fraction of Al 28Pb alloy mushy on distribution of Pb in Al Pb ingot was studied. The special electromagnetic stirring apparatus was used to prepare Al 28Pb alloy mushy and the relationship betw...The influence of solid fraction of Al 28Pb alloy mushy on distribution of Pb in Al Pb ingot was studied. The special electromagnetic stirring apparatus was used to prepare Al 28Pb alloy mushy and the relationship between solid fraction and stirring temperature was gotten. The results show that when solid fraction of Al 28Pb alloy mushy is less than 45%, Pb precipitation usually happens in the ingot. However, Pb precipitation in casting reduces gradually with increasing solid fraction of mushy, and when solid fraction is larger than 45%, Pb precipitation in casting can be removed. [展开更多
The effects of alloying elements, electromagnetic stirring, reheating and semi-solid formation on the microstructure and mechanical properties of Al-Fe alloys prepared by semi-solid formation were studied. It was foun...The effects of alloying elements, electromagnetic stirring, reheating and semi-solid formation on the microstructure and mechanical properties of Al-Fe alloys prepared by semi-solid formation were studied. It was found that alloying elements and electromagnetic stirring can alter the morphology and growth mode of the iron-rich phase in Al-Fe alloys; and effectively refine the primary Al3Fe phase. In contrast to the microstructure obtained in conventional casting, the Al3Fe phase becomes thin short rod-like instead of thick needle-like; and the dendritic grain structure almost disappears in the semi-solid formation. The Al3Fe phase can be further refined through being dissolved or fused during subsequent reheating. It was also found that the larger extrusion ratio of semi-solid formation causes a greater crushing effect and therefore the Al3Fe phase is more refined and has more uniform distribution. Moreover, Al-Fe alloys prepared by semi-solid formation exhibit excellent mechanical properties at both room and high temperatures.展开更多
The splat folis of Al-RE(RE=Y,La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Er and Yb) binary alloys of 0.04—0.06 mm thickness were made by are-melting and hammer-anvil technique,the.cooling rate is in 10~6 K/s order of magnitude.The m...The splat folis of Al-RE(RE=Y,La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Er and Yb) binary alloys of 0.04—0.06 mm thickness were made by are-melting and hammer-anvil technique,the.cooling rate is in 10~6 K/s order of magnitude.The metastable extended solid solubilities of these RE elements have been evaluated by measurements of the lattice spacings of the rapidly solidified(RS)Al-RE alloys,they are 0.4,0.15,0.21,0.21,0.3, 0.5,0.1,0.6,0.65,0.7,0.75,0.2 at.-% for above individual RE clements,respectively.The secondary phase in RS Al-RE alloys were identified to be Al_4RE for alloys containing light RE and Eu elements and Al_3 RE for alloys containing heavy RE and Y elements. Some factors influencing the extension of solid solubility of Al-RE alloy were discussed.展开更多
Preparation of semisolid slurry using a cooling slope is increasingly becoming popular,primarily because of the simplicity in design and ease control of the process.In this process,liquid alloy is poured down an incli...Preparation of semisolid slurry using a cooling slope is increasingly becoming popular,primarily because of the simplicity in design and ease control of the process.In this process,liquid alloy is poured down an inclined surface which is cooled from underneath.The cooling enables partial solidification and the incline provides the necessary shear for producing semisolid slurry.However,the final microstructure of the ingot depends on several process parameters such as cooling rate,incline angle of the cooling slope,length of the slope and initial melt superheat.In this work,a CFD model using volume of fluid(VOF) method for simulating flow along the cooling slope was presented.Equations for conservation of mass,momentum,energy and species were solved to predict hydrodynamic and thermal behavior,in addition to predicting solid fraction distribution and macrosegregation.Solidification was modeled using an enthalpy approach and a volume averaged technique for the different phases.The mushy region was modeled as a multi-layered porous medium consisting of fixed columnar dendrites and mobile equiaxed/fragmented grains.The alloy chosen for the study was aluminum alloy A356,for which adequate experimental data were available in the literature.The effects of two key process parameters,namely the slope angle and the pouring temperature,on temperature distribution,velocity distribution and macrosegregation were also studied.展开更多
Relationship between the processing parameters and the properties of semi-solid processed Al alloys were studied and microstructure and mechanical properties of semi-solid processed Al parts for automobile application...Relationship between the processing parameters and the properties of semi-solid processed Al alloys were studied and microstructure and mechanical properties of semi-solid processed Al parts for automobile application as a function of processing parameters were compared with those of die-cast parts and forged parts. In addition, the locations for the gate during the semi-solid processing were varied to elucidate the distribution of micro-porosities and resulting mechanical properties and the T6 heat tre...展开更多
The iron-rich solids formed during solidification of Al-Si alloys which are known to be detrimental to the mechanical,physical and chemical properties of the alloys should be removed.On the other hand,Al-Si hypereutec...The iron-rich solids formed during solidification of Al-Si alloys which are known to be detrimental to the mechanical,physical and chemical properties of the alloys should be removed.On the other hand,Al-Si hypereutectic alloys are used to extract the pure primary silicon which is suitable for photovoltaic cells in the solvent refining process.One of the important issues in iron removal and in solvent refining is the effective separation of the crystallized solids from the Al-Si alloy melts.This paper describes the separation methods of the primary solids from Al-Si alloy melts such as sedimentation,draining,filtration,electromagnetic separation and centrifugal separation,focused on the iron removal and on the separation of silicon in the solvent refining process.展开更多
基金supported by the National Key Research and Development Program (2017YFA0403800)the National Natural Science Foundation of China (51374144, 51727802)+2 种基金the Shanghai Municipal Natural Science Foundation (13ZR1420600)Shanghai Rising-Star Program (14QA1402300)The support of synchrotron radiation phase-contrast imaging by the BL13W1 beam line of Shanghai Synchrotron Radiation Facility (SSRF), China, is gratefully acknowledged
文摘Synchrotron X-ray radiography was used to carry out an in-situ observation of the hydrogen bubble evolution in the liquid Al/solid Ni interconnection. The individual bubble mainly grows in a stochastic way during heating. The size distribution for groups of bubbles follows a Gaussian distribution in the early stage and Lifshitz-Slyozov-Wagner(LSW) diffusion controlled distribution in the final stage. The intermetallic compounds(IMCs) first form during solidification, following by the hydrogen bubbles. The bubbles between two adjacent Al3Ni grains grow unidirectionally along the liquid channel, with the bottom being impeded by the Al3Ni phase and the radius of the growth front being smaller. For the bubbles at triple junctions, they grow along the liquid channel and the crack with morphology transition.
基金the Natural Science Foundation of Jiangxi Province, China (No. 0650047)
文摘The semi-solid slurry of an A356 Al alloy, which was grain-fined by yttrium, was manufactured by low temperature pouring, The effects of grain-refining on the morphology and the grain size of the primary α phase in the semi-solid A356 Al alloy were researched. The results indicate that the semi-solid A356 AI alloy with particle-like and rosette-like primary α-Al can be prepared by low temperature pouring from a liquid grain-refined A356 alloy. The grain size and particle morphology of primary α-Al in the A356 Al alloy are markedly improved by the addition of 0.5 wt,% Y. The fining mechanism of Y on the morphology and grain size of the primary α-Al in the semi-solid A356 Al alloy was delved.
基金Project (G2002AA336080) supported by Hi-tech Research and Development Program of China Project (50374012) supported by the National Natural Science Foundation of China
文摘The semi-solid slurry of A356 Al alloy was manufactured by low superheat pouring and weak electromagnetic stirring. The effects of pouring temperature on the slurry manufactured by weak electromagnetic stirring were researched. The results indicate that it is feasible to manufacture the slurry with particle-like primary phases by low superheat pouring and weak electromagnetic stirring, and there is an important effect of the pouring temperature (superheat temperature) on the morphology and the size of primaryα-Al in A356 Al alloy. By the action of suitable weak electromagnetic stirring, increasing pouring temperature to put low superheat pouring in practice is capable of obtaining semi-solid slurry of A356 Al alloy with particle-like primary phase. Compared with the samples made only by low superheat pouring without stirring, raising pouring temperature by 15-35 ℃ above the liquidus temperature under condition of weak electromagnetic stirring can ensure the same grain size and morphology of the primary phase.
文摘The slurry of Al-20Sn alloy was prepared using electromagnetic-mechanical stirring method. The bonding of steel/mushy Al-20Sn was conducted using casting rolling technique. The bonding parameters were 505 ℃ for preheat temperature of steel plate and 10 mm/s for rolling speed. The interfacial mechanical property and structure of steel/mushy Al-20Sn bonding plate were studied. The results show that the relationship between solid fraction of Al-20Sn slurry and interfacial shear strength of bonding plate is S=52.9+0.998φ s-0.014 4φ 2 s (where S is interfacial shear strength, φ s is solid fraction). The largest interfacial shear strength is 70.2 MPa when solid fraction is 34.6%. The interface of bonding plate is made up of Fe-Al compound and Fe-Al solid solution alternatively.
基金supported by the Grant-in Aid for Scientific Research(23560898)the Support Program for Forming Strategic Research Infrastructure from the Ministry of Education,Science,Sports and Culture,Japan
文摘For the wider applications,it is necessary to improve the ductility as well as the strength and wear-resistance of hypereutectic AlSi-Cu alloys,which are typical light-weight wear-resistant materials.An increase in the amounts of primary silicon particles causes the modified wear-resistance of hypereutectic Al-Si-Cu alloys,but leads to the poor strength and ductility.It is known that dual phase steels composed of hetero-structure have succeeded in bringing contradictory mechanical properties of high strength and ductility concurrently.In order to apply the idea of hetero-structure to hypereutectic Al-Si-Cu alloys for the achievement of high strength and ductility along with wear resistance,ultrasonic irradiation of the molten metal during the solidification,which is called sono-solidification,was carried out from its molten state to just above the eutectic temperature.The sono-solidified Al-17Si-4Cu alloy is composed of hetero-structure,which are,hard primary silicon particles,soft non-equilibrium a-Al phase and the eutectic region.Rheo-casting was performed at just above the eutectic temperature with sono-solidified slurry to shape a disk specimen.After the rheo-casting with modified sonosolidified slurry held for 45 s at 570 oC,the quantitative optical microscope observation exhibits that the microstructure is composed of 18area%of hard primary silicon particles and 57area%of soft a-Al phase.In contrast,there exist only 5 area%of primary silicon particles and no a-Al phase in rheo-cast specimen with normally solidified slurry.Hence the tensile tests of T6 treated rheo-cast specimens with modified sono-solidified slurry exhibit improved strength and 5%of elongation,regardless of having more than 3 times higher amounts of primary silicon particles compared to that of rheo-cast specimen with normally solidified slurry.
文摘The influence of solid fraction of Al 28Pb alloy mushy on distribution of Pb in Al Pb ingot was studied. The special electromagnetic stirring apparatus was used to prepare Al 28Pb alloy mushy and the relationship between solid fraction and stirring temperature was gotten. The results show that when solid fraction of Al 28Pb alloy mushy is less than 45%, Pb precipitation usually happens in the ingot. However, Pb precipitation in casting reduces gradually with increasing solid fraction of mushy, and when solid fraction is larger than 45%, Pb precipitation in casting can be removed. [
基金financially supported by Education Department of Liaoning Province, China (2006T104 and 2008RC36)
文摘The effects of alloying elements, electromagnetic stirring, reheating and semi-solid formation on the microstructure and mechanical properties of Al-Fe alloys prepared by semi-solid formation were studied. It was found that alloying elements and electromagnetic stirring can alter the morphology and growth mode of the iron-rich phase in Al-Fe alloys; and effectively refine the primary Al3Fe phase. In contrast to the microstructure obtained in conventional casting, the Al3Fe phase becomes thin short rod-like instead of thick needle-like; and the dendritic grain structure almost disappears in the semi-solid formation. The Al3Fe phase can be further refined through being dissolved or fused during subsequent reheating. It was also found that the larger extrusion ratio of semi-solid formation causes a greater crushing effect and therefore the Al3Fe phase is more refined and has more uniform distribution. Moreover, Al-Fe alloys prepared by semi-solid formation exhibit excellent mechanical properties at both room and high temperatures.
文摘The splat folis of Al-RE(RE=Y,La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Er and Yb) binary alloys of 0.04—0.06 mm thickness were made by are-melting and hammer-anvil technique,the.cooling rate is in 10~6 K/s order of magnitude.The metastable extended solid solubilities of these RE elements have been evaluated by measurements of the lattice spacings of the rapidly solidified(RS)Al-RE alloys,they are 0.4,0.15,0.21,0.21,0.3, 0.5,0.1,0.6,0.65,0.7,0.75,0.2 at.-% for above individual RE clements,respectively.The secondary phase in RS Al-RE alloys were identified to be Al_4RE for alloys containing light RE and Eu elements and Al_3 RE for alloys containing heavy RE and Y elements. Some factors influencing the extension of solid solubility of Al-RE alloy were discussed.
文摘Preparation of semisolid slurry using a cooling slope is increasingly becoming popular,primarily because of the simplicity in design and ease control of the process.In this process,liquid alloy is poured down an inclined surface which is cooled from underneath.The cooling enables partial solidification and the incline provides the necessary shear for producing semisolid slurry.However,the final microstructure of the ingot depends on several process parameters such as cooling rate,incline angle of the cooling slope,length of the slope and initial melt superheat.In this work,a CFD model using volume of fluid(VOF) method for simulating flow along the cooling slope was presented.Equations for conservation of mass,momentum,energy and species were solved to predict hydrodynamic and thermal behavior,in addition to predicting solid fraction distribution and macrosegregation.Solidification was modeled using an enthalpy approach and a volume averaged technique for the different phases.The mushy region was modeled as a multi-layered porous medium consisting of fixed columnar dendrites and mobile equiaxed/fragmented grains.The alloy chosen for the study was aluminum alloy A356,for which adequate experimental data were available in the literature.The effects of two key process parameters,namely the slope angle and the pouring temperature,on temperature distribution,velocity distribution and macrosegregation were also studied.
文摘Relationship between the processing parameters and the properties of semi-solid processed Al alloys were studied and microstructure and mechanical properties of semi-solid processed Al parts for automobile application as a function of processing parameters were compared with those of die-cast parts and forged parts. In addition, the locations for the gate during the semi-solid processing were varied to elucidate the distribution of micro-porosities and resulting mechanical properties and the T6 heat tre...
基金supported by the Basic Science Research Program through the National Research Foundation of Korea(NRF),the Ministry of Education,Science and Technology of Korea(No.2012R1A1A2007476)supported by the Korea University of Technology and Education
文摘The iron-rich solids formed during solidification of Al-Si alloys which are known to be detrimental to the mechanical,physical and chemical properties of the alloys should be removed.On the other hand,Al-Si hypereutectic alloys are used to extract the pure primary silicon which is suitable for photovoltaic cells in the solvent refining process.One of the important issues in iron removal and in solvent refining is the effective separation of the crystallized solids from the Al-Si alloy melts.This paper describes the separation methods of the primary solids from Al-Si alloy melts such as sedimentation,draining,filtration,electromagnetic separation and centrifugal separation,focused on the iron removal and on the separation of silicon in the solvent refining process.
