In order to obtain a high-performance surface on TiAl alloy that can meet the requirements in hot corrosion environment,Si-Al-Y coatings were fabricated by pack cementation process at 1050℃for 4 h.Corrosion behaviors...In order to obtain a high-performance surface on TiAl alloy that can meet the requirements in hot corrosion environment,Si-Al-Y coatings were fabricated by pack cementation process at 1050℃for 4 h.Corrosion behaviors of the TiAl alloy with and without Si-Al-Y coatings are compared to illustrate the factors and corresponding mechanism in molten salt environment of 25 wt%K2SO4 and 75 wt%Na2SO4 at 900°C.The obtained Si-Al-Y coating was mainly composed of a TiSi2 outer layer,a(Ti,X)5Si4 and(Ti,X)5Si3(X represents Nb or Cr element)middle layer,a TiAl2 inner layer and a Al-rich inter-diffusion zone.The inter-phase selective corrosion containing corrosion pits extending alongα2 phase from lamellar interfaces in hot corrosion tested TiAl alloy was observed.However,by being coated with Si-Al-Y coating,the hot corrosion performance of TiAl alloy was improved remarkably.展开更多
基金Project(2020AAC02025)supported by the Natural Science Foundation of Ningxia Province,ChinaProject(51961003)supported by the National Natural Science Foundation of China+1 种基金Project(TJGC2019040)supported by the Ningxia Youth Talents Supporting Program,ChinaProject(2020xyzc103)supported by the Foundation of North Minzu University,China。
文摘In order to obtain a high-performance surface on TiAl alloy that can meet the requirements in hot corrosion environment,Si-Al-Y coatings were fabricated by pack cementation process at 1050℃for 4 h.Corrosion behaviors of the TiAl alloy with and without Si-Al-Y coatings are compared to illustrate the factors and corresponding mechanism in molten salt environment of 25 wt%K2SO4 and 75 wt%Na2SO4 at 900°C.The obtained Si-Al-Y coating was mainly composed of a TiSi2 outer layer,a(Ti,X)5Si4 and(Ti,X)5Si3(X represents Nb or Cr element)middle layer,a TiAl2 inner layer and a Al-rich inter-diffusion zone.The inter-phase selective corrosion containing corrosion pits extending alongα2 phase from lamellar interfaces in hot corrosion tested TiAl alloy was observed.However,by being coated with Si-Al-Y coating,the hot corrosion performance of TiAl alloy was improved remarkably.