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Effects of a novel refiner Al-3Ti-4.35La combined with Sr on microstructure and mechanical properties of as-cast A356 alloy
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作者 Mei Xu Wan-wu Ding +4 位作者 Li-wen Hu Shi-hao Chen Hai-xia Zhang Hai-cun Yu Wen-jun Zhao 《China Foundry》 SCIE EI CAS CSCD 2024年第6期641-650,共10页
It is a practically significant issue to refine and modify industrial Al-Si casting alloy to improve its properties.In the present study,a novel refiner Al-3Ti-4.35La alloy,prepared by a melt-reaction method,was used,... It is a practically significant issue to refine and modify industrial Al-Si casting alloy to improve its properties.In the present study,a novel refiner Al-3Ti-4.35La alloy,prepared by a melt-reaction method,was used,combined with Sr to refine the as-cast A356 alloy.Their effects on the as-cast microstructures and mechanical properties of A356 alloy were investigated.The results indicate that the combined addition of Al-3Ti-4.35La intermediate alloy and Sr can improve the microstructure and enhance the mechanical properties of A356 alloy.After adding 0.3wt.%Al-3Ti-4.35La and 0.03wt.%Sr to the as-cast A356 alloy,the average grain size ofα-Al decreases from 693.47μm to 264.13μm(a decrease of 61.91%),the secondary dendrite arm spacing(SDAS)is decreased by 47.8%from 32.09μm to 16.75μm,and the eutectic Si is transformed from an acicular structure to short rods and a granular structure.The ultimate tensile strength(UTS)and elongation(EL)of the as-cast A356 alloy modified by Al-3Ti-4.35La and Sr reach 216.3 MPa and 10.6%,which are enhanced by 29.54%and 134.66%compared with the unmodified alloy,respectively.The fracture mode is transformed from transgranular fracture to intergranular fracture,and the ductile toughness of the alloy is improved.After adding the Al-3Ti-4.35La and Sr,the undercooling for the nucleation ofα-Al and eutectic Si increases,leading to an accelerated nucleation rate and an increased number of nuclei,which shortens the duration of the eutectic reaction and consequently inhibits grain growth. 展开更多
关键词 A356 alloy al-3ti-4.35la SR REFINER grain refinement microstructure mechanical properties
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Al-5Ti-1B-0.6La中La吸附TiAl_(3)表面的第一性原理计算
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作者 李薛松 陈鸿玲 +2 位作者 宋莉莉 傅高升 王火生 《特种铸造及有色合金》 CAS 北大核心 2023年第1期56-61,共6页
采用基于密度泛函理论的第一性原理方法,建立了稀土La在TiAl_(3)相择优生长面(001)吸附的9种La/TiAl_(3)(001)表面模型和La空位吸附前后TiAl_(3)(001)表面堆垛生长表面模型,以此为基础计算并对比了Al-5Ti-1B中间合金中加入La前后TiAl_(3... 采用基于密度泛函理论的第一性原理方法,建立了稀土La在TiAl_(3)相择优生长面(001)吸附的9种La/TiAl_(3)(001)表面模型和La空位吸附前后TiAl_(3)(001)表面堆垛生长表面模型,以此为基础计算并对比了Al-5Ti-1B中间合金中加入La前后TiAl_(3)(001)表面模型的吸附能、表面能和态密度等。同时计算了La吸附前后TiAl_(3)(001)堆垛生长后表面模型的表面能,探讨了Al-5Ti-1B-0.6La中间合金中La对细化相TiAl_(3)生长的影响和作用方式。结果表明,La在TiAl_(3)(001)表面的9个吸附位置均能自主发生强化学表面吸附,其中Al-TiAl_(3)(001)表面空位(V_(2))吸附La后表面能降低幅度最大,吸附能最小,吸附结构最稳定;TiAl_(3)(001)表面空位吸附(V_(2))La后堆垛生长是趋于单位面积内表面能增加,La吸附后的TiAl_(3)(001)表面堆垛生长不稳定,减缓了TiAl_(3)(001)面的生长速度,说明La对TiAl_(3)相的生长有较强的抑制作用。试验表明,La加入Al-5Ti-1B中间合金后,细化相TiAl_(3)的平均尺寸由26.47μm降低到14.52μm, TiAl_(3)相分布较均匀,说明La的加入有利于抑制TiAl_(3)的长大,与模拟结果一致。 展开更多
关键词 al-5ti-1B-0.6la 稀土la TiAl_(3)(001) 表面吸附 第一性原理
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