Al80Ni6 Y8 Co4 Cu2 amorphous ribbons were isothermally annealed and a mixed structure consisting of α-Al particle with a size of less than 15nm and Al3Ni compound with a size of about 30nm was obtained. The crystall...Al80Ni6 Y8 Co4 Cu2 amorphous ribbons were isothermally annealed and a mixed structure consisting of α-Al particle with a size of less than 15nm and Al3Ni compound with a size of about 30nm was obtained. The crystallization kinetics of Al80Ni6 Y8 Co4 Cu2 amorphous alloy shows that the precipitation of α-Al particles is the growth process controlled by diffusion of the solute elements rejected from the growing crystals. By quenching at different cooling rates, a mixed structure consisting of nanoscale α-Al particles and the remaining glass matrix or structure consisting of nanoscale particle (Al phase or Al3Ni compound) with a size of about 100nm was formed. The addition of Co elements and Cu elements to Al-Ni-Y alloy systems increases the glass formation ability of the alloy and the thermal stability of the supercooled liquid region against crystallization, which results from significant difference of atomic size, strong bonding nature among constituent elements and the low diffisivity of the solute elements due to the concentration gradient in the growing front of crystals.展开更多
The influence of gravity on the solidification microstructure of Al-Al3Ni eutectic alloy was investigated by using a 50-m-long drop tube. It was found that at different growth rates the average inter-rod spacing was a...The influence of gravity on the solidification microstructure of Al-Al3Ni eutectic alloy was investigated by using a 50-m-long drop tube. It was found that at different growth rates the average inter-rod spacing was always larger under rnicrogravity （μg） than those under normal gravity （lg）. Moreover, with increasing growth rate, the spacing difference between lg samples and μg samples reduced progressively. Based on the experimental results and analysis, a physical model was proposed to describe the effect of gravity on the solidification process of eutectic alloy.展开更多
文摘Al80Ni6 Y8 Co4 Cu2 amorphous ribbons were isothermally annealed and a mixed structure consisting of α-Al particle with a size of less than 15nm and Al3Ni compound with a size of about 30nm was obtained. The crystallization kinetics of Al80Ni6 Y8 Co4 Cu2 amorphous alloy shows that the precipitation of α-Al particles is the growth process controlled by diffusion of the solute elements rejected from the growing crystals. By quenching at different cooling rates, a mixed structure consisting of nanoscale α-Al particles and the remaining glass matrix or structure consisting of nanoscale particle (Al phase or Al3Ni compound) with a size of about 100nm was formed. The addition of Co elements and Cu elements to Al-Ni-Y alloy systems increases the glass formation ability of the alloy and the thermal stability of the supercooled liquid region against crystallization, which results from significant difference of atomic size, strong bonding nature among constituent elements and the low diffisivity of the solute elements due to the concentration gradient in the growing front of crystals.
基金supported by the National Natural Science Foundation of China(No.51171196)
文摘The influence of gravity on the solidification microstructure of Al-Al3Ni eutectic alloy was investigated by using a 50-m-long drop tube. It was found that at different growth rates the average inter-rod spacing was always larger under rnicrogravity （μg） than those under normal gravity （lg）. Moreover, with increasing growth rate, the spacing difference between lg samples and μg samples reduced progressively. Based on the experimental results and analysis, a physical model was proposed to describe the effect of gravity on the solidification process of eutectic alloy.
