The properties of the combustion and deflagration to detonation transition(DDT)of Al/Fe_(2)O_(3)/RDX hybrid nanocomposites,a type of potentially novel lead-free primary explosives,were tested in weakly confined condit...The properties of the combustion and deflagration to detonation transition(DDT)of Al/Fe_(2)O_(3)/RDX hybrid nanocomposites,a type of potentially novel lead-free primary explosives,were tested in weakly confined conditions,and the interaction of Al/Fe_(2)O_(3)nanothermite and RDX in the DDT process was studied in detail.Results show that the amount of the Al/Fe_(2)O_(3)nanothermite has a great effect on the DDT properties of Al/Fe_(2)O_(3)/RDX nanocomposites.The addition of Al/Fe_(2)O_(3)nanothermite to RDX apparently improves the firing properties of RDX.A small amount of Al/Fe_(2)O_(3)nanothermite greatly increases the initial combustion velocity of Al/Fe_(2)O_(3)/RDX nanocomposites,accelerating their DDT process.When the contents of Al/Fe_(2)O_(3)nanothermite are less than 20 wt%,the DDT mechanisms of Al/Fe_(2)O_(3)/RDX nanocomposites follow the distinct abrupt mode,and are consistent with that of RDX,though their DDT processes are different.The RDX added into the Al/Fe_(2)O_(3)nanothermite increases the latter's peak combustion velocity and makes it generate the DDT when the RDX content is at least 10 wt%.RDX plays a key role in the shock compressive combustion,the formation and the properties of the DDT in the flame propagation of nanocomposites.Compared with RDX,the fast DDT of Al/Fe_(2)O_(3)/RDX nanocomposites could be obtained by adjusting the chemical constituents of nanocomposites.展开更多
Silane coupling agent KH560 was used to modify the surface of nano-α-Al<sub>2</sub>O<sub>3</sub> in ethanol-aqueous solution with different proportions. The particle size of nano-α-Al<sub&...Silane coupling agent KH560 was used to modify the surface of nano-α-Al<sub>2</sub>O<sub>3</sub> in ethanol-aqueous solution with different proportions. The particle size of nano-α-Al<sub>2</sub>O<sub>3</sub> was determined by nano-particle size analyzer, and the effects of nano-α-Al<sub>2</sub>O<sub>3</sub> content, ethanol-aqueous solution ratio and KH560 dosage on the dispersion and particle size of nano-α-Al<sub>2</sub>O<sub>3</sub> were investigated. The material structure before and after modification was determined by Fourier transform infrared spectroscopy (FTIR). Aqueous polyurethane resin and inorganic components are combined with modified nano-α-Al<sub>2</sub>O<sub>3</sub> dispersion to form chromium-free passivation solution. The solution is coated on the galvanized sheet, the adhesion and surface hardness are tested, the bonding strength of the coating and the surface hardness of the substrate are discussed. The corrosion resistance and surface morphology of the matrix were investigated by electrochemical test, neutral salt spray test and scanning electron microscope test. The chromium-free passivation film formed after the modification of nano-α-Al<sub>2</sub>O<sub>3</sub> increases the surface hardness of galvanized sheet by about 85%. The corrosion resistance of the film is better than that of a single polyurethane film. The results show that the surface hardness and corrosion resistance of polyurethane resin composite passivation film are significantly improved by the introduction of nano-α-Al<sub>2</sub>O<sub>3</sub>.展开更多
Selective laser sintering (SLS) is a new process to prepare the polystyrene (PS)/Al2O3 nanocomposites. In this paper, with different laser power and other processing parameters unchanged, the morphology, density a...Selective laser sintering (SLS) is a new process to prepare the polystyrene (PS)/Al2O3 nanocomposites. In this paper, with different laser power and other processing parameters unchanged, the morphology, density and mechanical properties of the sintered specimens were investigated. It was found that nano-sized inorganic particles are uniformly located in the PS matrix and the maximum density of the sintered specimens with pure PS powder reaches 1.07 g/cm^3, higher than 1.04 g/cm^3 that of the sintered specimens with mixture powder. Due to strengthening and toughness of the nano-sized Al2O3 inorganic particles, the maximum notched impact strength and tensile strength of the sintered part mixed with nano-sized inorganic particles are improved greatly from 7.5 to 12.1 kJ/m^2 and from 6.5 to 31.2 MPa, respectively, under the same sintering condition.展开更多
Mixed micron-sized Cu/Ti3SiC2 (vo15%) powder was mechanically milled using agate balls and zirconia balls separately. Then followed an examination of it with the FEI-SEM. The experimental results show that, distribu...Mixed micron-sized Cu/Ti3SiC2 (vo15%) powder was mechanically milled using agate balls and zirconia balls separately. Then followed an examination of it with the FEI-SEM. The experimental results show that, distributed homogenously in Cu matrix, the Ti3SiC2 particles have a size of about 30-50 nm after milled with agate balls for 8 h, while it remains approximately unchanged after milled with zirconia balls. The microstructure of the mixture at different ball-milling stages was also studied. Bulks of Cu/Ti3SiC2 nano-composite were fabricated by hot pressing nano-sized Cu/Ti3SiC2 powder at the temperature of 1 073 K under 100 MPa. Then came an investigation of the effects of the particle size and agglomerate state of Ti3SiC2 as well as the microstructure of Cu/Ti3SiC2 nano-composite. It was found that the nano-sized Ti3SiC2 particles distribute evenly in copper.展开更多
In this study,an Al2O3/MoS2 nanocomposite coating was created on an aluminum 1050 substrate using the plasma electrolytic oxidation method.The zeta potential measurements showed that small MoS2 particles have negative...In this study,an Al2O3/MoS2 nanocomposite coating was created on an aluminum 1050 substrate using the plasma electrolytic oxidation method.The zeta potential measurements showed that small MoS2 particles have negative potential and move toward the anode electrode.The nanoparticles of MoS2 were found to have a zeta potential of-25 mV,which prevents suspension in the solution.Thus,to produce an Al2O3/MoS2 nanocomposite,one has to use the microparticles of MoS2.The X-ray diffraction analyses showed that the produced coatings containedα-Al2O3,γ-Al2O3,and MoS2,and that the size of MoS2 particles can be reduced to 30 nm.It was observed that prolonged suspension in the electrolyte results in an enhanced formation of an Al2O3/MoS2 nanocomposite.Using the results,it was hypothesized that the mechanism of the formation of the Al2O3/MoS2 nanocomposite coating on the aluminum 1050 substrate is based on electrical energy discharge.展开更多
In this work MgO/Al_2O_3 nanocomposites with weight ratios from 5% to 25% were synthesized by precipitationimpregnation method and their structural properties were characterized. In the next step, the capability of th...In this work MgO/Al_2O_3 nanocomposites with weight ratios from 5% to 25% were synthesized by precipitationimpregnation method and their structural properties were characterized. In the next step, the capability of the nanocomposites in H_2S removal compared to Mg–Al spinel(MgAl_2O_4), synthesized through ion-pair complex precursor route and alumina samples, prepared via sol–gel precipitation methods, was investigated. The results indicated that among the studied sorbents Mg–Al spinel presents a distinctly higher H_2S removal. In addition, the MgO/Al_2O_3 nanocomposites compared to the alumina sorbents, exhibited much better performance in H_2S removal. Also CO_2-TPD analysis reveals higher amounts of basic sites for Mg–Al spinel compared to 25 wt% MgO/75 wt% Al_2O_3 nanocomposite.展开更多
Ce-TZP/Al2O3 nanocomposites were prepared from mixture of self-made Ce-TZP nanometer powder and commercial A12O3 powder by hot-pressing method. Influences of nanometer ZrO2 particles on the mechanical properties and m...Ce-TZP/Al2O3 nanocomposites were prepared from mixture of self-made Ce-TZP nanometer powder and commercial A12O3 powder by hot-pressing method. Influences of nanometer ZrO2 particles on the mechanical properties and microstructure of Ce-TZP/Al2O3 ceramics were investigated. Meanwhile, t-—m transformation toughening mechanism was investigated by x-ray diffractometry (XRD) method, and deflection of samples under applied stress were recorded too. The results show that when the percentage of ZrO2 was 20%, the mechanical properties and microstructures of materials were preferential. Additionally, TEM observation show that dislocation structures form both in the A12O3 grain and on the A12O3 grain boundary.展开更多
基金supported by National Nature Science Foundation of China(No.22075230)the financial support of the doctoral research foundation(No.19ZX7102)from Southwest University of Science and Technology。
文摘The properties of the combustion and deflagration to detonation transition(DDT)of Al/Fe_(2)O_(3)/RDX hybrid nanocomposites,a type of potentially novel lead-free primary explosives,were tested in weakly confined conditions,and the interaction of Al/Fe_(2)O_(3)nanothermite and RDX in the DDT process was studied in detail.Results show that the amount of the Al/Fe_(2)O_(3)nanothermite has a great effect on the DDT properties of Al/Fe_(2)O_(3)/RDX nanocomposites.The addition of Al/Fe_(2)O_(3)nanothermite to RDX apparently improves the firing properties of RDX.A small amount of Al/Fe_(2)O_(3)nanothermite greatly increases the initial combustion velocity of Al/Fe_(2)O_(3)/RDX nanocomposites,accelerating their DDT process.When the contents of Al/Fe_(2)O_(3)nanothermite are less than 20 wt%,the DDT mechanisms of Al/Fe_(2)O_(3)/RDX nanocomposites follow the distinct abrupt mode,and are consistent with that of RDX,though their DDT processes are different.The RDX added into the Al/Fe_(2)O_(3)nanothermite increases the latter's peak combustion velocity and makes it generate the DDT when the RDX content is at least 10 wt%.RDX plays a key role in the shock compressive combustion,the formation and the properties of the DDT in the flame propagation of nanocomposites.Compared with RDX,the fast DDT of Al/Fe_(2)O_(3)/RDX nanocomposites could be obtained by adjusting the chemical constituents of nanocomposites.
文摘Silane coupling agent KH560 was used to modify the surface of nano-α-Al<sub>2</sub>O<sub>3</sub> in ethanol-aqueous solution with different proportions. The particle size of nano-α-Al<sub>2</sub>O<sub>3</sub> was determined by nano-particle size analyzer, and the effects of nano-α-Al<sub>2</sub>O<sub>3</sub> content, ethanol-aqueous solution ratio and KH560 dosage on the dispersion and particle size of nano-α-Al<sub>2</sub>O<sub>3</sub> were investigated. The material structure before and after modification was determined by Fourier transform infrared spectroscopy (FTIR). Aqueous polyurethane resin and inorganic components are combined with modified nano-α-Al<sub>2</sub>O<sub>3</sub> dispersion to form chromium-free passivation solution. The solution is coated on the galvanized sheet, the adhesion and surface hardness are tested, the bonding strength of the coating and the surface hardness of the substrate are discussed. The corrosion resistance and surface morphology of the matrix were investigated by electrochemical test, neutral salt spray test and scanning electron microscope test. The chromium-free passivation film formed after the modification of nano-α-Al<sub>2</sub>O<sub>3</sub> increases the surface hardness of galvanized sheet by about 85%. The corrosion resistance of the film is better than that of a single polyurethane film. The results show that the surface hardness and corrosion resistance of polyurethane resin composite passivation film are significantly improved by the introduction of nano-α-Al<sub>2</sub>O<sub>3</sub>.
文摘Selective laser sintering (SLS) is a new process to prepare the polystyrene (PS)/Al2O3 nanocomposites. In this paper, with different laser power and other processing parameters unchanged, the morphology, density and mechanical properties of the sintered specimens were investigated. It was found that nano-sized inorganic particles are uniformly located in the PS matrix and the maximum density of the sintered specimens with pure PS powder reaches 1.07 g/cm^3, higher than 1.04 g/cm^3 that of the sintered specimens with mixture powder. Due to strengthening and toughness of the nano-sized Al2O3 inorganic particles, the maximum notched impact strength and tensile strength of the sintered part mixed with nano-sized inorganic particles are improved greatly from 7.5 to 12.1 kJ/m^2 and from 6.5 to 31.2 MPa, respectively, under the same sintering condition.
文摘Mixed micron-sized Cu/Ti3SiC2 (vo15%) powder was mechanically milled using agate balls and zirconia balls separately. Then followed an examination of it with the FEI-SEM. The experimental results show that, distributed homogenously in Cu matrix, the Ti3SiC2 particles have a size of about 30-50 nm after milled with agate balls for 8 h, while it remains approximately unchanged after milled with zirconia balls. The microstructure of the mixture at different ball-milling stages was also studied. Bulks of Cu/Ti3SiC2 nano-composite were fabricated by hot pressing nano-sized Cu/Ti3SiC2 powder at the temperature of 1 073 K under 100 MPa. Then came an investigation of the effects of the particle size and agglomerate state of Ti3SiC2 as well as the microstructure of Cu/Ti3SiC2 nano-composite. It was found that the nano-sized Ti3SiC2 particles distribute evenly in copper.
文摘In this study,an Al2O3/MoS2 nanocomposite coating was created on an aluminum 1050 substrate using the plasma electrolytic oxidation method.The zeta potential measurements showed that small MoS2 particles have negative potential and move toward the anode electrode.The nanoparticles of MoS2 were found to have a zeta potential of-25 mV,which prevents suspension in the solution.Thus,to produce an Al2O3/MoS2 nanocomposite,one has to use the microparticles of MoS2.The X-ray diffraction analyses showed that the produced coatings containedα-Al2O3,γ-Al2O3,and MoS2,and that the size of MoS2 particles can be reduced to 30 nm.It was observed that prolonged suspension in the electrolyte results in an enhanced formation of an Al2O3/MoS2 nanocomposite.Using the results,it was hypothesized that the mechanism of the formation of the Al2O3/MoS2 nanocomposite coating on the aluminum 1050 substrate is based on electrical energy discharge.
基金Supported by the National Science Foundation of Iran(INSF)
文摘In this work MgO/Al_2O_3 nanocomposites with weight ratios from 5% to 25% were synthesized by precipitationimpregnation method and their structural properties were characterized. In the next step, the capability of the nanocomposites in H_2S removal compared to Mg–Al spinel(MgAl_2O_4), synthesized through ion-pair complex precursor route and alumina samples, prepared via sol–gel precipitation methods, was investigated. The results indicated that among the studied sorbents Mg–Al spinel presents a distinctly higher H_2S removal. In addition, the MgO/Al_2O_3 nanocomposites compared to the alumina sorbents, exhibited much better performance in H_2S removal. Also CO_2-TPD analysis reveals higher amounts of basic sites for Mg–Al spinel compared to 25 wt% MgO/75 wt% Al_2O_3 nanocomposite.
基金supports from Educational Fund of Jiangxi province(DB200201009)the Fund of Materials Science and Engineering Center of Jiangxi Province(KG200201020),China are highly appreciated.
文摘Ce-TZP/Al2O3 nanocomposites were prepared from mixture of self-made Ce-TZP nanometer powder and commercial A12O3 powder by hot-pressing method. Influences of nanometer ZrO2 particles on the mechanical properties and microstructure of Ce-TZP/Al2O3 ceramics were investigated. Meanwhile, t-—m transformation toughening mechanism was investigated by x-ray diffractometry (XRD) method, and deflection of samples under applied stress were recorded too. The results show that when the percentage of ZrO2 was 20%, the mechanical properties and microstructures of materials were preferential. Additionally, TEM observation show that dislocation structures form both in the A12O3 grain and on the A12O3 grain boundary.