The oxidation and interdiffusion behavior of a novel AlCoCrFeNiY bond coat deposited on a directionally solidified Ni-based superalloy were systematically studied at 1050,1100 and 1150°C,and compared with a conve...The oxidation and interdiffusion behavior of a novel AlCoCrFeNiY bond coat deposited on a directionally solidified Ni-based superalloy were systematically studied at 1050,1100 and 1150°C,and compared with a conventional NiCoCrAlY coating deposited on the same substrate.The AlCoCrFeNiY bond coat exhibits lower oxide growth rates due to its large columnar grains and low Al activity at the oxide scale/bond coat interface.Meanwhile,AlCoCrFeNiY has higher resistance to oxide spallation than NiCoCrAlY,which is attributed to the formation of a clean and defect-free metal/oxide interface.Significant interdiffusion occurs across the AlCoCrFeNiY/superalloy substrate interface.Our experimental evidence and thermody-namic modelling suggest that Fe accelerates interdiffusion and destabilizes theγ’phase,thereby causing the formation of a thick andγ’-depleted interdiffusion zone.In addition,the AlCoCrFeNiY bond coat un-dergoes more Al depletion and subsequentβtoγtransformation compared with NiCoCrAlY.Based on the findings in this work,a novel AlCoCrFeNiY/NiCoCrAlY double-layer bond coat was designed,tested and validated to achieve optimal balance between oxidation and interdiffusion.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.52201082 and 51971139)the Science Center for Gas Turbine Project(No.P2022-A-I-002-001)+1 种基金the Shanghai Sailing Program(No.22YF1419200)sponsored by the Chenguang Program supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission(No.21CGA10).
文摘The oxidation and interdiffusion behavior of a novel AlCoCrFeNiY bond coat deposited on a directionally solidified Ni-based superalloy were systematically studied at 1050,1100 and 1150°C,and compared with a conventional NiCoCrAlY coating deposited on the same substrate.The AlCoCrFeNiY bond coat exhibits lower oxide growth rates due to its large columnar grains and low Al activity at the oxide scale/bond coat interface.Meanwhile,AlCoCrFeNiY has higher resistance to oxide spallation than NiCoCrAlY,which is attributed to the formation of a clean and defect-free metal/oxide interface.Significant interdiffusion occurs across the AlCoCrFeNiY/superalloy substrate interface.Our experimental evidence and thermody-namic modelling suggest that Fe accelerates interdiffusion and destabilizes theγ’phase,thereby causing the formation of a thick andγ’-depleted interdiffusion zone.In addition,the AlCoCrFeNiY bond coat un-dergoes more Al depletion and subsequentβtoγtransformation compared with NiCoCrAlY.Based on the findings in this work,a novel AlCoCrFeNiY/NiCoCrAlY double-layer bond coat was designed,tested and validated to achieve optimal balance between oxidation and interdiffusion.
